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Presented By:
Saad Bin Hasan
B.Sc in Chemical Engineering,
Jessore University of Science & Technology
Raw Materials:
 Acrylonitrile-butadiene-styrene (ABS) Plastics
 Copper
 Nickel
 Chromium
Product:
Chromium Plating on ABS Plastic
Flow of Chrome plating
process:
ETCHING
NEUTRALIZING
ACTIVATION
ACCELERATION
ELECTROLESS PLATING
ELECTROPLATING
Etching:
 The bath consist of highly concentrated
acid solution of chrome and sufulric
acid.
 Operate at the temperature between 50
°C and 70 °C.
 Carried out around 1-10 min.
 Organic solvent and solvated hydroxyl
ions to etch the surface of the part to
improve adhesion of a metal coating
with the part.
Neutralizing:
 Rinsed in water and then put into a
neutralizer.
 Materials such as sodium bisulfite that
are designed to eliminate excess
etchant from the parts and racks, usually
by chemical reduction.
 Carried out around 1-10 min
Activation:
 Used to activate the part using activation
bath.
 Activation is done by seeding the
surface with a catalytically active metal,
usually from palladium.
 Carried out around 3-5 min.
Acceleration:
 Accelerator bath is typically mixture of
organic acid solution.
 Carried out around 3-5min.
 Function of this bath is to remove the
excess palladium nuclei which have
been deposited in the part to promote
quicker reaction initiation in the following
electroless deposition step.
CuSO4 + 2HCHO + 4NaOH → Cu + Na2SO4 + 2NaCOOH + 2H2O + H2
NiSO4 + 3NaPO2H2+ 3H2O → Ni + 3NaH2PO3 + H2SO4 + 2H2
Electroless plating:
 To make electrically conductive to
electroplating.
 Coated by Copper and Nickel by chemical
dipping process.
 Nickel and Copper is applied over the
activated palladium layer.
 Chromium can be easily electroplated on the
surface of the part.
 Carried out around 3-5 min.
 Bright Acid Copper has two main functions
(ductility & leveling) in the plating on plastic
line.
Electroplating:
 Final stage in the
chrome plating process.
 Chromium is coated on
the part which have
been plated in the
electroless plating.
 Carried out around 3-5
min.
 Hexa valent chromium
is the source chromium
and catalyst is used.
 Most common catalyst
is sulfate and mixed
catalyst is used in some
special properties. Fig: Electroplating process
After Electroplating:
Thank You

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Crome plating on ABS plastics

  • 1. Presented By: Saad Bin Hasan B.Sc in Chemical Engineering, Jessore University of Science & Technology
  • 2. Raw Materials:  Acrylonitrile-butadiene-styrene (ABS) Plastics  Copper  Nickel  Chromium Product: Chromium Plating on ABS Plastic
  • 3. Flow of Chrome plating process: ETCHING NEUTRALIZING ACTIVATION ACCELERATION ELECTROLESS PLATING ELECTROPLATING
  • 4. Etching:  The bath consist of highly concentrated acid solution of chrome and sufulric acid.  Operate at the temperature between 50 °C and 70 °C.  Carried out around 1-10 min.  Organic solvent and solvated hydroxyl ions to etch the surface of the part to improve adhesion of a metal coating with the part.
  • 5. Neutralizing:  Rinsed in water and then put into a neutralizer.  Materials such as sodium bisulfite that are designed to eliminate excess etchant from the parts and racks, usually by chemical reduction.  Carried out around 1-10 min
  • 6. Activation:  Used to activate the part using activation bath.  Activation is done by seeding the surface with a catalytically active metal, usually from palladium.  Carried out around 3-5 min.
  • 7. Acceleration:  Accelerator bath is typically mixture of organic acid solution.  Carried out around 3-5min.  Function of this bath is to remove the excess palladium nuclei which have been deposited in the part to promote quicker reaction initiation in the following electroless deposition step. CuSO4 + 2HCHO + 4NaOH → Cu + Na2SO4 + 2NaCOOH + 2H2O + H2 NiSO4 + 3NaPO2H2+ 3H2O → Ni + 3NaH2PO3 + H2SO4 + 2H2
  • 8. Electroless plating:  To make electrically conductive to electroplating.  Coated by Copper and Nickel by chemical dipping process.  Nickel and Copper is applied over the activated palladium layer.  Chromium can be easily electroplated on the surface of the part.  Carried out around 3-5 min.  Bright Acid Copper has two main functions (ductility & leveling) in the plating on plastic line.
  • 9. Electroplating:  Final stage in the chrome plating process.  Chromium is coated on the part which have been plated in the electroless plating.  Carried out around 3-5 min.  Hexa valent chromium is the source chromium and catalyst is used.  Most common catalyst is sulfate and mixed catalyst is used in some special properties. Fig: Electroplating process