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THERMAL PROPERTIES OF
MATTER
INTRODUCTION
Relation between Joule and Calorie
• 1calorie=4.18 Joules
• 1kilocalorie = 1000 calories
• The S.I. Unit of Temperature is Kelvin (K) and some of the commonly used units are
: Fahrenheit (°F) and Celsius (°C)
• Measurement of Temperature
Mercury in-thermometer
RELATION BETWEEN THE TEMPERATURE IN CELSIUS
AND IN FAHRENHEIT
• Equation is:
• (tf -32)/180 = tc/100
• Where tf = Fahrenheit temperature
• tc= Celsius temperature
IDEAL-GAS EQUATION AND ABSOLUTE TEMPERATURE
• Variables that describe the behavior of gas are:-
• Quantity(mass)
• Pressure
• Volume
• Temperature
• 1.Boyle’s Law– PV = constant
• 2.Charles’ Law- V/T = constant
• PV=μRT where μ, is the number of moles in the sample of gas
• Absolute Zero
• T = tC + 273.15
• Comparison of Kelvin, Celsius and Fahrenheit
temperature Scales
• Thermal Expansion
Examples of Thermal Expansion
• Reason why Thermal Expansion happens
is:-
When an object is cooled it contracts which is referred
as negative thermal expansion.
• Types of Thermal Expansion
Linear Expansion :- The expansion in length
Area Expansion :- The expansion in area
Volume Expansion :- The expansion in volume
• Linear Expansion
Mathematically can be written as:-
Where αl= the coefficient of linear expansion
• Area Expansion
Mathematically can be written as:-
ΔA / A =αa ΔT
Where αa = coefficient of area expansion.
• Volume Expansion
Mathematically can be written as:-
ΔV / V =αv ΔT
Where αv = coefficient of volume.
• Coefficient of volume expansion of copper as a
function of temperature-
Thermal expansion of solids and liquids are small.
• Anomalous Behavior of Water
If we plot temperature on X-axis and Density on Y-Axis we will
obtain the graph as given below:-
• Relation between αv and αl
Relation between coefficient of linear expansion and coefficient of
volume expansion =
• Thermal stress:
 Heat Capacity
• It is denoted by S.
• It is given as S = ΔQ/ ΔT
• Where ΔQ = amount of heat supplied to the
substance and T to T + ΔT change in its temperature.
 Specific heat capacity:
• Mathematically can be written as:-
• ΔQ = amount of heat absorbed or rejected by a substance
• m = mass
• ΔT = temperature change
• It depends on the nature of the substance and its
temperature.
• The SI unit of specific heat capacity is J kg–1 K–1.
Molar specific heat capacity: -
• Mathematically can be written as:-
• C = S/ μ= ΔQ / μ ΔT
• Where
• μ= amount of substance in moles
• C = molar specific heat capacity of the substance.
• ΔQ = amount of heat absorbed or rejected by a
substance.
• ΔT = temperature change
• It depends on the nature of the substance and its
temperature. The SI unit of molar specific heat
capacity is Jmol–1 K–1
• Molar specific heat capacity (Cp):-
• Molar specific heat capacity (Cv):-
Water has highest specific heat of capacity because of
which it is used as a coolant in automobile radiators
and in hot water bags.
• Calorimetry
• Change of State
• The transition from either solid to liquid or gas and gas to either
liquid or solid is termed as change of state.
• Change from solid (ice) to liquid (water) is known as Melting.
• Change from liquid (water) to solid (ice) is known as Fusion.
• Thermal Equilibrium: -
• At this state there is no loss or gain of heat takes place.
• It is depends on the-
o substance
o Pressure.
• Regelation:-
Example
Cause of regelation:-
The image above explains how a copper wire can pass
through the block of ice.
• Vaporisation: -
• Transition from liquid to vapour.
• It depends on nature of substance & pressure
• It increases with increase in pressure and vice versa.
• Sublimation: -
• Transition from Solid to Vapour.
Example:-
• Dry ice (solid CO2) sublimes iodine.
• Naphthalene balls sublimes to gaseous state.
THANK YOU

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Thermal properties-of-matter

  • 2. Relation between Joule and Calorie • 1calorie=4.18 Joules • 1kilocalorie = 1000 calories • The S.I. Unit of Temperature is Kelvin (K) and some of the commonly used units are : Fahrenheit (°F) and Celsius (°C)
  • 3. • Measurement of Temperature Mercury in-thermometer
  • 4. RELATION BETWEEN THE TEMPERATURE IN CELSIUS AND IN FAHRENHEIT • Equation is: • (tf -32)/180 = tc/100 • Where tf = Fahrenheit temperature • tc= Celsius temperature
  • 5. IDEAL-GAS EQUATION AND ABSOLUTE TEMPERATURE • Variables that describe the behavior of gas are:- • Quantity(mass) • Pressure • Volume • Temperature • 1.Boyle’s Law– PV = constant • 2.Charles’ Law- V/T = constant
  • 6. • PV=μRT where μ, is the number of moles in the sample of gas
  • 7. • Absolute Zero • T = tC + 273.15
  • 8. • Comparison of Kelvin, Celsius and Fahrenheit temperature Scales
  • 9. • Thermal Expansion Examples of Thermal Expansion
  • 10.
  • 11. • Reason why Thermal Expansion happens is:- When an object is cooled it contracts which is referred as negative thermal expansion. • Types of Thermal Expansion Linear Expansion :- The expansion in length Area Expansion :- The expansion in area Volume Expansion :- The expansion in volume
  • 12. • Linear Expansion Mathematically can be written as:- Where αl= the coefficient of linear expansion
  • 13. • Area Expansion Mathematically can be written as:- ΔA / A =αa ΔT Where αa = coefficient of area expansion.
  • 14. • Volume Expansion Mathematically can be written as:- ΔV / V =αv ΔT Where αv = coefficient of volume.
  • 15. • Coefficient of volume expansion of copper as a function of temperature- Thermal expansion of solids and liquids are small.
  • 16. • Anomalous Behavior of Water If we plot temperature on X-axis and Density on Y-Axis we will obtain the graph as given below:-
  • 17. • Relation between αv and αl Relation between coefficient of linear expansion and coefficient of volume expansion =
  • 19.  Heat Capacity • It is denoted by S. • It is given as S = ΔQ/ ΔT • Where ΔQ = amount of heat supplied to the substance and T to T + ΔT change in its temperature.  Specific heat capacity: • Mathematically can be written as:- • ΔQ = amount of heat absorbed or rejected by a substance • m = mass • ΔT = temperature change • It depends on the nature of the substance and its temperature. • The SI unit of specific heat capacity is J kg–1 K–1.
  • 20. Molar specific heat capacity: - • Mathematically can be written as:- • C = S/ μ= ΔQ / μ ΔT • Where • μ= amount of substance in moles • C = molar specific heat capacity of the substance. • ΔQ = amount of heat absorbed or rejected by a substance. • ΔT = temperature change • It depends on the nature of the substance and its temperature. The SI unit of molar specific heat capacity is Jmol–1 K–1
  • 21. • Molar specific heat capacity (Cp):- • Molar specific heat capacity (Cv):- Water has highest specific heat of capacity because of which it is used as a coolant in automobile radiators and in hot water bags.
  • 23. • Change of State • The transition from either solid to liquid or gas and gas to either liquid or solid is termed as change of state. • Change from solid (ice) to liquid (water) is known as Melting. • Change from liquid (water) to solid (ice) is known as Fusion.
  • 24. • Thermal Equilibrium: - • At this state there is no loss or gain of heat takes place. • It is depends on the- o substance o Pressure.
  • 25. • Regelation:- Example Cause of regelation:- The image above explains how a copper wire can pass through the block of ice.
  • 26. • Vaporisation: - • Transition from liquid to vapour. • It depends on nature of substance & pressure • It increases with increase in pressure and vice versa.
  • 27. • Sublimation: - • Transition from Solid to Vapour. Example:- • Dry ice (solid CO2) sublimes iodine. • Naphthalene balls sublimes to gaseous state.