Six Sigma is a set of techniques used to improve processes and reduce defects. It was developed at Motorola in the 1980s to address high defect rates in television manufacturing. Six Sigma aims to identify and remove the causes of defects and errors in processes by following a structured methodology. It uses statistical tools and follows defined roles like Black Belts, Green Belts, and Master Black Belts. The goal is to make processes as close to perfect as possible by reducing defects to 3.4 per million opportunities.