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• One system which is convenient at an
  introductory level involves classifying
  reactions into four basic types.

• Knowing the different types of reaction
  allows the chemist to predict the products
  of the reactions of different substance.c
TYPES OF REACTIONS:

1.COMBINATION REACTION
2.DECOMPOSITON REACTION
3.SUBSTITUTION REACTION
4.DOUBLE REPLACEMENT REACTION
1. COMBINATION REACTION

  • Type of reaction in which two
    or more substances combine
    to form a more complex
    substance.
  • Also called synthesis reaction
  • Form:
         A + B -> AB
EXAMPLES:

  • C ₍s₎ + O₂₍g₎ -> CO ₂₍g₎

  • 2 Ca ₍s₎ + O ₂₍g₎ -> 2CaO ₍s₎

  • N ₂₍g₎ + 3 H ₂₍g₎ -> 2NH ₃₍g₎

  • 2 Na ₍s₎ + Cl ₂₍g₎ -> 2NaCl ₍s₎
2. DECOMPOSITION REACTION

   Various conditions can cause a substance to
   decompose:
   • The most common type of a decomposition is
     cause by a rise in temperature. This is called
     thermal decomposition.
   Example:

   2 HgO ₍s₎ ->(heat) 2Hg ₍g₎ + O ₂₍g₎

   2KMnO ₄₍s₎ ->(heat) K ₂MnO ₄₍s₎ + MnO ₂₍g₎ + O ₂₍g₎
• If such a decomposition proceeds
  very fast, an explosion may occur
Example:

2NH₄NO ₃₍s₎ ->(heat) 4H₂O ₍g₎ +
                      2N ₂₍g₎ + O ₂₍g₎
• Light is another factor which may
  occur chemical decompositions to
  occur. Such decompositions are
  known as photo-chemical
  decompositions.
Example:

2AgBr ₍s₎ ->(light) 2Ag ₍s₎ + Br ₂₍g₎
• Although catalysts cannot cause chemicals to decompose,
  they can speed up the rate of a chemical decomposition.
  The addition of a tiny amount of manganese dioxide to a
  solution of hydrogen peroxide will immediately result in a
  vigorous evolution of oxygen gas.
Example:

2H ₂O ₂₍aq₎ ->(manganese dioxide/catalyst)2 H ₂O ₍l₎ + O ₂₍g₎
• Electricity can also be used to decompose
  compounds, resulting in electrolytic
  decomposition.

Examples:

2NaCl ->(electrolysis) 2Na + Cl ₂

PbBr ₂ ->(electrolysis) Pb + Br ₂
3. SUBSTITUTION REACTION
     • Also called single replacement reaction
     • Form:

        C + AB -> CB + A
    • more active element replaces a less active element in
      the compound.
    Example:

    Fe + CuSO₄ -> FeSO₄ + Cu
    2 Na + 2H₂O -> 2NaOH + H₂
Metals:
Lithium(Li)     Chromium(Cr)   Mercury(Hg)
Potassium (K)   Iron(Fe)       Platinum(Pt)
Barium(Ba)      Cobalt(Co)     Gold(Au)
Calcium(Ca)     Nickel(Ni)
Sodium(Na)      Tin(Sn)
Magnesium(Mg)   Lead(Pb)
Aluminum(Al)    Hydrogen(H₂)
Manganese(Mn)   Copper(Cu)
Zinc(Zn)         Silver(Ag)
Halogens:
Flourine(F)
Chlorine(Cl)
Bromine(Br)
Iodine(I)
4. DOUBLE REPLACEMENT REACTION
    • Also called ionic reaction
    • Characterized by the exchange of ions
      (charged atoms or molecules) between
      two compounds
    • Form:

              AB + CD -> AD + CB
Several types of double replacement reactions are
frequently encountered:

1. A reaction between a base such as NaOH, KOH or
   Ca(OH)₂ in aqueous solution and an acid such as HCl,
   H₂SO₄ or CH₃COOH. Reactions of this type are called
   neutralizations and the products are always water
   molecules and salt.

HCl + NaOH -> NaCl + H₂O

H₂SO₄ + 2KOH -> K₂SO₄ + 2H₂O
2. A reaction between solutions of two soluble
salts, a soluble salt and an acid, or a soluble
salt and an alkali which, by exchanging cations
and anions, can produce one insoluble
compound.

Examples:

NaCl + AgNO₃ -> NaNO₃ + AgCl

BaCL₂ + MgSO₄ -> MgCl₂ + BaSO₄
Activity:

Given the type of reaction, predict the
products and balance the equation.

1. Combination: Li + F₂
2. Decomposition: CuCO₃
3. Substitution: Mg + HCl
4. Ionic reaction: AgNO₃ + BaCl₂
End …
Thank you!

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Types of Reaction

  • 1.
  • 2. • One system which is convenient at an introductory level involves classifying reactions into four basic types. • Knowing the different types of reaction allows the chemist to predict the products of the reactions of different substance.c
  • 3. TYPES OF REACTIONS: 1.COMBINATION REACTION 2.DECOMPOSITON REACTION 3.SUBSTITUTION REACTION 4.DOUBLE REPLACEMENT REACTION
  • 4. 1. COMBINATION REACTION • Type of reaction in which two or more substances combine to form a more complex substance. • Also called synthesis reaction • Form: A + B -> AB
  • 5. EXAMPLES: • C ₍s₎ + O₂₍g₎ -> CO ₂₍g₎ • 2 Ca ₍s₎ + O ₂₍g₎ -> 2CaO ₍s₎ • N ₂₍g₎ + 3 H ₂₍g₎ -> 2NH ₃₍g₎ • 2 Na ₍s₎ + Cl ₂₍g₎ -> 2NaCl ₍s₎
  • 6. 2. DECOMPOSITION REACTION Various conditions can cause a substance to decompose: • The most common type of a decomposition is cause by a rise in temperature. This is called thermal decomposition. Example: 2 HgO ₍s₎ ->(heat) 2Hg ₍g₎ + O ₂₍g₎ 2KMnO ₄₍s₎ ->(heat) K ₂MnO ₄₍s₎ + MnO ₂₍g₎ + O ₂₍g₎
  • 7. • If such a decomposition proceeds very fast, an explosion may occur Example: 2NH₄NO ₃₍s₎ ->(heat) 4H₂O ₍g₎ + 2N ₂₍g₎ + O ₂₍g₎
  • 8. • Light is another factor which may occur chemical decompositions to occur. Such decompositions are known as photo-chemical decompositions. Example: 2AgBr ₍s₎ ->(light) 2Ag ₍s₎ + Br ₂₍g₎
  • 9. • Although catalysts cannot cause chemicals to decompose, they can speed up the rate of a chemical decomposition. The addition of a tiny amount of manganese dioxide to a solution of hydrogen peroxide will immediately result in a vigorous evolution of oxygen gas. Example: 2H ₂O ₂₍aq₎ ->(manganese dioxide/catalyst)2 H ₂O ₍l₎ + O ₂₍g₎
  • 10. • Electricity can also be used to decompose compounds, resulting in electrolytic decomposition. Examples: 2NaCl ->(electrolysis) 2Na + Cl ₂ PbBr ₂ ->(electrolysis) Pb + Br ₂
  • 11. 3. SUBSTITUTION REACTION • Also called single replacement reaction • Form: C + AB -> CB + A • more active element replaces a less active element in the compound. Example: Fe + CuSO₄ -> FeSO₄ + Cu 2 Na + 2H₂O -> 2NaOH + H₂
  • 12. Metals: Lithium(Li) Chromium(Cr) Mercury(Hg) Potassium (K) Iron(Fe) Platinum(Pt) Barium(Ba) Cobalt(Co) Gold(Au) Calcium(Ca) Nickel(Ni) Sodium(Na) Tin(Sn) Magnesium(Mg) Lead(Pb) Aluminum(Al) Hydrogen(H₂) Manganese(Mn) Copper(Cu) Zinc(Zn) Silver(Ag)
  • 14. 4. DOUBLE REPLACEMENT REACTION • Also called ionic reaction • Characterized by the exchange of ions (charged atoms or molecules) between two compounds • Form: AB + CD -> AD + CB
  • 15. Several types of double replacement reactions are frequently encountered: 1. A reaction between a base such as NaOH, KOH or Ca(OH)₂ in aqueous solution and an acid such as HCl, H₂SO₄ or CH₃COOH. Reactions of this type are called neutralizations and the products are always water molecules and salt. HCl + NaOH -> NaCl + H₂O H₂SO₄ + 2KOH -> K₂SO₄ + 2H₂O
  • 16. 2. A reaction between solutions of two soluble salts, a soluble salt and an acid, or a soluble salt and an alkali which, by exchanging cations and anions, can produce one insoluble compound. Examples: NaCl + AgNO₃ -> NaNO₃ + AgCl BaCL₂ + MgSO₄ -> MgCl₂ + BaSO₄
  • 17. Activity: Given the type of reaction, predict the products and balance the equation. 1. Combination: Li + F₂ 2. Decomposition: CuCO₃ 3. Substitution: Mg + HCl 4. Ionic reaction: AgNO₃ + BaCl₂