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Thermochemistry
Thermochemistry  Branch of physical chemistry.
 Deals with thermal or heat change caused by chemical reactions.
Thermodynamics  Branch of physical chemistry.
 Deals with the study of energy and how it transforms.
 Definition of Energy:
The ability to do work.
 Forms of energy:
1) Thermal energy  Energy associated with random motion of atoms and molecules.
2) Chemical energy  Energy stored within the bonds of chemical substances.
3) Nuclear energy  Energy stored within collection of neutrons and protons in atom.
4) Electrical energy  Energy associated with the flow of electrons.
5) Potential energy  Energy available by virtue of an object's position.
 Energy transformations:
 Chemicals in food gives us mechanical energy.
 Sunlight provides light energy for the tree to make
its own food.
 Chemical gasoline provides energy for the motion
of the car.
 Electrical energy in the plug creates the heat to
run the stove.
 Law of conservation of energy 
Energy can neither be created nor destroyed; rather, it transforms from one form to another.
 System and surrounding
System  Definition of system
o Specific part of the universe that is of interest in the study.
 Types of system
Open Closed Isolated
Exchange Mass and Energy Energy Nothing
Shape
Surrounding  Definition of surrounding
o The part outside the system that exchange energy with the system.

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Thermochemistry

  • 1. Thermochemistry Thermochemistry  Branch of physical chemistry.  Deals with thermal or heat change caused by chemical reactions. Thermodynamics  Branch of physical chemistry.  Deals with the study of energy and how it transforms.  Definition of Energy: The ability to do work.  Forms of energy: 1) Thermal energy  Energy associated with random motion of atoms and molecules. 2) Chemical energy  Energy stored within the bonds of chemical substances. 3) Nuclear energy  Energy stored within collection of neutrons and protons in atom. 4) Electrical energy  Energy associated with the flow of electrons. 5) Potential energy  Energy available by virtue of an object's position.  Energy transformations:  Chemicals in food gives us mechanical energy.  Sunlight provides light energy for the tree to make its own food.  Chemical gasoline provides energy for the motion of the car.  Electrical energy in the plug creates the heat to run the stove.  Law of conservation of energy  Energy can neither be created nor destroyed; rather, it transforms from one form to another.  System and surrounding System  Definition of system o Specific part of the universe that is of interest in the study.  Types of system Open Closed Isolated Exchange Mass and Energy Energy Nothing Shape Surrounding  Definition of surrounding o The part outside the system that exchange energy with the system.