Heat of precipitation, ∆H Heat of displacement,, ∆H Heat of neutralisation, ∆H Heat of combustion, ∆H
Example of
set – up of apparatus
1. Chemical equation Reactans A + Reactans B → Products C + Products D
2. Ionic equation Depends on reactants during reaction H+
+ OH-
→ H2O
3. No. moles, x
=mv/1000
X = molarity x volume [ use any one] X= molarity solution x volume solution X for H+
= molarity acid x volume acid
X for OH-
= molarity alkali x volume alkali X =
molarmass
gmassbeforegmass )()( 
4. Heat changes,H
=mc∆Ө
H= mass of mixture x c x [T2-T1] H= mass of solution x c x [T2-T1] H= mass of mixture x c x [T2-T1] H= mass of water x c x [T2-T1]
5. ∆H= H/x ∆H= Heat changes /no. mole
6. Energy level
diagram
A + B
C + D
∆H = - kJ mol-1
Energy
Exothermic Reaction
0.5 g zinc
25cm3
CuSO4
0.2 mol dm-3
A + B
C + D
∆H = + kJ mol-1
Endothermic Reaction
Short note thermo

Short note thermo

  • 1.
    Heat of precipitation,∆H Heat of displacement,, ∆H Heat of neutralisation, ∆H Heat of combustion, ∆H Example of set – up of apparatus 1. Chemical equation Reactans A + Reactans B → Products C + Products D 2. Ionic equation Depends on reactants during reaction H+ + OH- → H2O 3. No. moles, x =mv/1000 X = molarity x volume [ use any one] X= molarity solution x volume solution X for H+ = molarity acid x volume acid X for OH- = molarity alkali x volume alkali X = molarmass gmassbeforegmass )()(  4. Heat changes,H =mc∆Ө H= mass of mixture x c x [T2-T1] H= mass of solution x c x [T2-T1] H= mass of mixture x c x [T2-T1] H= mass of water x c x [T2-T1] 5. ∆H= H/x ∆H= Heat changes /no. mole 6. Energy level diagram A + B C + D ∆H = - kJ mol-1 Energy Exothermic Reaction 0.5 g zinc 25cm3 CuSO4 0.2 mol dm-3 A + B C + D ∆H = + kJ mol-1 Endothermic Reaction