The document presents a novel approach to secure wireless communication using simulated annealing guided triangularized encryption with a multilayer perceptron (MLP) generated session key. It describes a method where both sender and receiver synchronize their MLPs to create an identical session key without transmitting it over public channels, thus mitigating man-in-the-middle attacks. The proposed technique is evaluated and compared with existing classical methods, demonstrating comparable performance in terms of security and efficiency.