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Research and Practices on CO2 Capture 
and Storage for EOR ( CCS-EOR) 
Shen Pingping, Dou Hongen 
China National Petroleum 
Corporation( CNPC) 
November, 2014
Outline 
1. Introduction 
2. Chinese Government Concerns about Reducing CO2 
and CO2 Utilizing as Resources 
3. Research on CCS-EOR 
4. Practices on CCS-EOR 
5. Prospect on CCS-EOR 
6. Conclusions
The major methods of reducing CO2 emissions : 
 Developing renewable energy and improving the energy 
efficiency is the best way to reduce CO2 emissions 
 CO2 capture and then storage (CCS) is an effective 
method 
 Oil & Gas Reservoirs, saline aquifers and coal beds are 
ideal place for CO2 Storage 
 It is predicted that 923 billion tons of CO2 can be stored in 
oil and gas reservoirs(IEA) 
1. Introduction 
1.Reducing greenhouse gas emissions. 
The continental reservoir geological theory, China’s CO2 storage potential
2. CO2 can be used for enhancing oil recovery 
 The potential for EOR in developed oil field is great 
Natural 
energy 
Water & gas 
injection 
Primary 
Recovery 
Secondary oil 
recovery 
EOR 
Development Mode 
Thermal oil 
recovery 
Chemical 
flooding 
Gas 
injection 
Ultimate 
Recovery Rate 
10- 
15% 
30- 
35% 
40-45% 
Gas flooding 
(Tertiary oil 
recovery) 
1. Introduction 
CO2 –EOR theory, method and potential in china reservoir
1. Introduction 
Injecting the captured CO2 into 
oil reservoirs can not only reduce 
its emissions, but also can 
enhance the oil recovery in a 
practical and economical 
manner
2. Chinese Government Concerns Greatly about Reducing 
CO2Emissions and Utilizing It as Resources 
 In 2006,China Ministry of Science and Technology 
approved CNPC to undertake a National 
Fundamental Research Program—Research on 
Utilizing Greenhouse Gas as a Resource for EOR and 
Storage. 
 In 2007,CNPC sponsored a major science & 
technology research project– Utilizing Greenhouse Gas 
as a Resource and Geological Storage, as well as a pilot 
project—Pilot test of CO2-EOR and CO2 Storage in Jilin 
Oil Field. 
 In 2008,the Chinese government approved a Major 
national program—CO2 Capture and Storage for EOR 
 In 2011, Chinese National Fundamental Research 
Program (973 program) and Chinese National Major 
Science and Technology Project have approved to 
continue by government 
IInntteerrnnaattiioonnaall 
ccooooppeerraattiioonn 2006 
2008 
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((997733 PPrrooggrraamm)) 
CCNNPPCC mmaajjoorr 
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ffiieelldd tteessttss 
NNaattiioonnaall MMaajjoorr 
sscciieennccee aanndd 
tteecchhnnoollooggyy 
pprroojjeeccttss 
863 National 
Research 
Program 
886633 NNaattiioonnaall 
RReesseeaarrcchh 
PPrrooggrraamm 
2008 
2009 
Chinese national 
Foundation Research 
(973 Program) 
CNPC major 
projects 
CNPC major 
field tests 
National Major 
science and 
technology 
projects 
International 
cooperation 
2007- 2008 
(2009- 2010) 
The USA, Japan, Norway et c. 
NNaattiioonnaall mmaajjoorr 
sscciieennccee aanndd 
tteecchhnnoollooggyy 
NNaattiioonnaall mmaajjoorr 
sscciieennccee aanndd 
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pprroojjeeccttss 
pprroojjeeccttss 
2011 
- 
2015
3. Research on CCS-EOR 
1. Research on CO2 storage and CO2-EOR potential 
 Standards and Calculation methods of the 
storage potential as well as the CO2-EOR 
potential are built 
 Storage potential for CO2-EOR of have 
been evaluated in China. And drew 
distribution map of whole China of CO2 
storage and CO2-EOR, expected oil 
recovery factor is over 10%
3. Research on CCS-EOR 
2. Research on phase theory of multiphase and multicomponent 
 HT/HP microscopic physical simulation 
 Major components of the miscible fluid 
in Jinlin oil field: C2-C10 and their 
contents 
 if CO2 with crude oil can keep miscible, 
oil recovery will be raised greatly
3. Research on CCS-EOR 
3. Flow mechanism and law of multiphase and multicomponent 
HT/HP CO2 flooding physical simulation equipment with 30m in length 
was invented 
One-dimensional flow of CO2 in porous media was studied 
CO2-EOR numerical reservoir simulation model were developed
3. Research on CCS-EOR 
4. Engineering technology and method for CO2 injection 
Preventing corrosion and scaling in gas injection 
wells 
Two kinds of corrosion inhibitor and three kinds 
of CO2 transportation method 
Monitoring CO2 flooding process during pilot 
test 
CO2 separation
4. Practices on CCS-EOR 
CO2-EOR Production System 
The gas reservoir of 3500-4000 meters depth, which is developed by means of horizontal 
well technology 
MEA is used to separate 22.5% of CO2 content from produced gas, and then separated CO2 is 
injected into low permeability reservoir to improve oil recovery 
Produced associated gas is separated, and then is re-injected oil reservoirs to realize zero CO2 
emission
4. Practices on CCS-EOR 
1.CO2 source 
CO2 source: natural gas produced 
from Changshen gas field(CO2 
content 22.5%) 
CO2 reserves>100 billion m3 
Using MEA technology to separate 
CO2 from produced gas
2. Geological caprocks of CO2 storage 
 Yaojia Formation and Nenjiang 
Formation, dominated by shale 
with wide and stable distribution 
 The cap rocks are effective for 
CO2 geological storage, with the 
total cap formation thickness of 
over 500 m 
 Few faults and fracture in the 
area 
4. Practices on CCS-EOR
4. Practices on CCS-EOR 
3. CO2-EOR and Storage Potential in Jilin Oilfield 
Typical Block---Block Hei-79 in Daqingzhijing Oilfield 
CO2 utilization coefficient: 0.17 ton/bbl 
Theoretical storage capacity: 0.38million 
tons 
Effective storage capacity:0. 19million tons 
Practical storage capacity:0.17million tons 
Enhanced recovery factor:10%
4. Practices on CCS-EOR 
4. Reservoir conditions for CO2 miscible and immiscible flooding in Jilin Oilfield 
Miscible flooding can be implemented in 
block Hei-59 and Hei-79 
Immiscible flooding can be implemented in 
Block Hong 87-2 and Qian’an
4. Practices on CCS-EOR 
5. Reservoir Engineering for CO2-EOR Pilot in Block Hei-59(the Stage I) 
Well locations in Block Hei-59 Injector: 5 
Producer: 21 
Target Zone: Qing-1 Member 
Injection method: Continuous gas 
injection and then water injection when 
reach desired gas injection volume 
Injection Rate: 40t/d per well 
Maximum injecting pressure at wellhead : 
22 MPa
4. Practices on CCS-EOR 
5. Reservoir Engineering for CO2-EOR Pilot in Block Hei-59(the Stage I) 
6. Reservoir Engineering for CO2-EOR Pilot in Block Hei-59
4. Practices on CCS-EOR 
 The pilot was implemented in Block Hei-59 at 
Stage I(2008.6). The industrial test was carried 
out in Block Hei-79 at Stage II(2010.6). The 
whole Daqingzi oilfield will be applied at Stage 
III. 
 From June 2010, industrial CO2 storage and 
CO2-EOR test in Hei-79 Block were 
implemented with18 injectors and 62 producers. 
By end of 2013, about 0.50 million tone CO2 
were stored, and 0.20 million oil were produced. 
 It is expected incremental oil recovery factor 
can reach 10.5%. Map for pilot and industrial test
5. Prospect on CCS-EOR 
 Developing coal chemical industry 
greatly will be able to capture the high 
purity and low cost of CO2 
Massive extremely low permeability 
oilfields in western China provide great 
potentials for CO2-EOR and storage 
Petrochina and Shenhua Group are 
cooperating, a CO2-EOR pilot test 
project of 100 thousand tones will be 
performed before 2015, Also, an 
expanded CO2-EOR of 1 million tones 
will be carried out after 2015 
Distribution of main oil and gas basins in China 
Xinjiang 
oilfield 
Changqing oilfield
6. Conclusions 
 CO2 Capture and injection into oil reservoirs for EOR is a practical and economical way for 
reducing CO2 emissions and enhancing oil recovery 
 A big potential lies in CNPC for carbon capture and storage, oil production growth through 
the application of CO2-EOR 
 CNPC are willing to join international efforts in CCS-EOR to make due contributions to 
global climate change solutions
Thank you ! 
Thank you !

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Professor Shen Pingping - Research and Practices on CO2 Capture and Storage for EOR(CCS-EOR)

  • 1. Research and Practices on CO2 Capture and Storage for EOR ( CCS-EOR) Shen Pingping, Dou Hongen China National Petroleum Corporation( CNPC) November, 2014
  • 2. Outline 1. Introduction 2. Chinese Government Concerns about Reducing CO2 and CO2 Utilizing as Resources 3. Research on CCS-EOR 4. Practices on CCS-EOR 5. Prospect on CCS-EOR 6. Conclusions
  • 3. The major methods of reducing CO2 emissions :  Developing renewable energy and improving the energy efficiency is the best way to reduce CO2 emissions  CO2 capture and then storage (CCS) is an effective method  Oil & Gas Reservoirs, saline aquifers and coal beds are ideal place for CO2 Storage  It is predicted that 923 billion tons of CO2 can be stored in oil and gas reservoirs(IEA) 1. Introduction 1.Reducing greenhouse gas emissions. The continental reservoir geological theory, China’s CO2 storage potential
  • 4. 2. CO2 can be used for enhancing oil recovery  The potential for EOR in developed oil field is great Natural energy Water & gas injection Primary Recovery Secondary oil recovery EOR Development Mode Thermal oil recovery Chemical flooding Gas injection Ultimate Recovery Rate 10- 15% 30- 35% 40-45% Gas flooding (Tertiary oil recovery) 1. Introduction CO2 –EOR theory, method and potential in china reservoir
  • 5. 1. Introduction Injecting the captured CO2 into oil reservoirs can not only reduce its emissions, but also can enhance the oil recovery in a practical and economical manner
  • 6. 2. Chinese Government Concerns Greatly about Reducing CO2Emissions and Utilizing It as Resources  In 2006,China Ministry of Science and Technology approved CNPC to undertake a National Fundamental Research Program—Research on Utilizing Greenhouse Gas as a Resource for EOR and Storage.  In 2007,CNPC sponsored a major science & technology research project– Utilizing Greenhouse Gas as a Resource and Geological Storage, as well as a pilot project—Pilot test of CO2-EOR and CO2 Storage in Jilin Oil Field.  In 2008,the Chinese government approved a Major national program—CO2 Capture and Storage for EOR  In 2011, Chinese National Fundamental Research Program (973 program) and Chinese National Major Science and Technology Project have approved to continue by government IInntteerrnnaattiioonnaall ccooooppeerraattiioonn 2006 2008 CChhiinneessee nnaattiioonnaall FFoouunnddaattiioonn RReesseeaarrcchh ((997733 PPrrooggrraamm)) CCNNPPCC mmaajjoorr pprroojjeeccttss CCNNPPCC mmaajjoorr ffiieelldd tteessttss NNaattiioonnaall MMaajjoorr sscciieennccee aanndd tteecchhnnoollooggyy pprroojjeeccttss 863 National Research Program 886633 NNaattiioonnaall RReesseeaarrcchh PPrrooggrraamm 2008 2009 Chinese national Foundation Research (973 Program) CNPC major projects CNPC major field tests National Major science and technology projects International cooperation 2007- 2008 (2009- 2010) The USA, Japan, Norway et c. NNaattiioonnaall mmaajjoorr sscciieennccee aanndd tteecchhnnoollooggyy NNaattiioonnaall mmaajjoorr sscciieennccee aanndd tteecchhnnoollooggyy pprroojjeeccttss pprroojjeeccttss 2011 - 2015
  • 7. 3. Research on CCS-EOR 1. Research on CO2 storage and CO2-EOR potential  Standards and Calculation methods of the storage potential as well as the CO2-EOR potential are built  Storage potential for CO2-EOR of have been evaluated in China. And drew distribution map of whole China of CO2 storage and CO2-EOR, expected oil recovery factor is over 10%
  • 8. 3. Research on CCS-EOR 2. Research on phase theory of multiphase and multicomponent  HT/HP microscopic physical simulation  Major components of the miscible fluid in Jinlin oil field: C2-C10 and their contents  if CO2 with crude oil can keep miscible, oil recovery will be raised greatly
  • 9. 3. Research on CCS-EOR 3. Flow mechanism and law of multiphase and multicomponent HT/HP CO2 flooding physical simulation equipment with 30m in length was invented One-dimensional flow of CO2 in porous media was studied CO2-EOR numerical reservoir simulation model were developed
  • 10. 3. Research on CCS-EOR 4. Engineering technology and method for CO2 injection Preventing corrosion and scaling in gas injection wells Two kinds of corrosion inhibitor and three kinds of CO2 transportation method Monitoring CO2 flooding process during pilot test CO2 separation
  • 11. 4. Practices on CCS-EOR CO2-EOR Production System The gas reservoir of 3500-4000 meters depth, which is developed by means of horizontal well technology MEA is used to separate 22.5% of CO2 content from produced gas, and then separated CO2 is injected into low permeability reservoir to improve oil recovery Produced associated gas is separated, and then is re-injected oil reservoirs to realize zero CO2 emission
  • 12. 4. Practices on CCS-EOR 1.CO2 source CO2 source: natural gas produced from Changshen gas field(CO2 content 22.5%) CO2 reserves>100 billion m3 Using MEA technology to separate CO2 from produced gas
  • 13. 2. Geological caprocks of CO2 storage  Yaojia Formation and Nenjiang Formation, dominated by shale with wide and stable distribution  The cap rocks are effective for CO2 geological storage, with the total cap formation thickness of over 500 m  Few faults and fracture in the area 4. Practices on CCS-EOR
  • 14. 4. Practices on CCS-EOR 3. CO2-EOR and Storage Potential in Jilin Oilfield Typical Block---Block Hei-79 in Daqingzhijing Oilfield CO2 utilization coefficient: 0.17 ton/bbl Theoretical storage capacity: 0.38million tons Effective storage capacity:0. 19million tons Practical storage capacity:0.17million tons Enhanced recovery factor:10%
  • 15. 4. Practices on CCS-EOR 4. Reservoir conditions for CO2 miscible and immiscible flooding in Jilin Oilfield Miscible flooding can be implemented in block Hei-59 and Hei-79 Immiscible flooding can be implemented in Block Hong 87-2 and Qian’an
  • 16. 4. Practices on CCS-EOR 5. Reservoir Engineering for CO2-EOR Pilot in Block Hei-59(the Stage I) Well locations in Block Hei-59 Injector: 5 Producer: 21 Target Zone: Qing-1 Member Injection method: Continuous gas injection and then water injection when reach desired gas injection volume Injection Rate: 40t/d per well Maximum injecting pressure at wellhead : 22 MPa
  • 17. 4. Practices on CCS-EOR 5. Reservoir Engineering for CO2-EOR Pilot in Block Hei-59(the Stage I) 6. Reservoir Engineering for CO2-EOR Pilot in Block Hei-59
  • 18. 4. Practices on CCS-EOR  The pilot was implemented in Block Hei-59 at Stage I(2008.6). The industrial test was carried out in Block Hei-79 at Stage II(2010.6). The whole Daqingzi oilfield will be applied at Stage III.  From June 2010, industrial CO2 storage and CO2-EOR test in Hei-79 Block were implemented with18 injectors and 62 producers. By end of 2013, about 0.50 million tone CO2 were stored, and 0.20 million oil were produced.  It is expected incremental oil recovery factor can reach 10.5%. Map for pilot and industrial test
  • 19. 5. Prospect on CCS-EOR  Developing coal chemical industry greatly will be able to capture the high purity and low cost of CO2 Massive extremely low permeability oilfields in western China provide great potentials for CO2-EOR and storage Petrochina and Shenhua Group are cooperating, a CO2-EOR pilot test project of 100 thousand tones will be performed before 2015, Also, an expanded CO2-EOR of 1 million tones will be carried out after 2015 Distribution of main oil and gas basins in China Xinjiang oilfield Changqing oilfield
  • 20. 6. Conclusions  CO2 Capture and injection into oil reservoirs for EOR is a practical and economical way for reducing CO2 emissions and enhancing oil recovery  A big potential lies in CNPC for carbon capture and storage, oil production growth through the application of CO2-EOR  CNPC are willing to join international efforts in CCS-EOR to make due contributions to global climate change solutions
  • 21. Thank you ! Thank you !