This document summarizes research into the factors that affect the glass transition temperature (Tg) of polymers. The researcher hypothesized that differences in interactions between polymer chains (factor 3) cause differences in Tg, if two polymers have identical chain backbones and no side chains (factors 1 and 2 eliminated). Nylon 6,6 and polyester 6,6 were characterized and co-polymers produced to test this. Results from techniques like DSC, FTIR and viscosity measurements were inconclusive regarding the hypothesis. Future work with co-polyamides and co-polyesters was proposed.
Polymers are large molecules composed of repeated chemical units. The smallest repeating unit is called monomer (mono [Single] + mer [part]). The word polymer is derived from the Greek word „poly‟ = many; mers = parts. It is generally described in terms of single repeated units
Methods of polymerisation It is also called as Zeigler – Natta polymerisation.
Zeigler (1953) and Natta (1955) discovered that in the presence of a combination of transition metal halides like TCl4, ZnBr3 etc, with an organometallic compound like triethyl-aluminium or trimethyl-aluminium, stereospecific polymerisation can be carried out.
Combination of metal halides and organometallic compounds are called Zeigler Natta catalyst.
Polymers are large molecules composed of repeated chemical units. The smallest repeating unit is called monomer (mono [Single] + mer [part]). The word polymer is derived from the Greek word „poly‟ = many; mers = parts. It is generally described in terms of single repeated units
Methods of polymerisation It is also called as Zeigler – Natta polymerisation.
Zeigler (1953) and Natta (1955) discovered that in the presence of a combination of transition metal halides like TCl4, ZnBr3 etc, with an organometallic compound like triethyl-aluminium or trimethyl-aluminium, stereospecific polymerisation can be carried out.
Combination of metal halides and organometallic compounds are called Zeigler Natta catalyst.
The basic knowledge of polymerization and further advancement in polymerization.
Different types of polymerization , uses and applications and reactions.
MSEASUSlides: Muddiest Points: Polymers I - Introductionmseasuslides
This slide set was used to create the MaterialsConcepts YouTube Video "Muddiest Points: Polymers I - Introduction". Here is the link to that video:
https://www.youtube.com/watch?v=D0I7ukw18FE
To study the vocab used in this video, visit this site:
http://quizlet.com/21161469/61-polymers-ia-concepts-terms-flash-cards/
This work was supported by NSF Grants #0836041 and #1226325
The basic knowledge of polymerization and further advancement in polymerization.
Different types of polymerization , uses and applications and reactions.
MSEASUSlides: Muddiest Points: Polymers I - Introductionmseasuslides
This slide set was used to create the MaterialsConcepts YouTube Video "Muddiest Points: Polymers I - Introduction". Here is the link to that video:
https://www.youtube.com/watch?v=D0I7ukw18FE
To study the vocab used in this video, visit this site:
http://quizlet.com/21161469/61-polymers-ia-concepts-terms-flash-cards/
This work was supported by NSF Grants #0836041 and #1226325
Brief intro about crystalline and amorphous structures,
glass transition temperature,
free volume theory of glass transition temperature,
factors effecting glass transition temperature etc.
Introduction
Why do we need plasticizers?
Mechanism of action of plasticizers
Properties of plasticizers
Classification of plasticizers
Selection of plasticizers
Effect of plasticizer on permeability of film.
Effect of plasticizer on mechanical properties of film.
Effect on residual internal stress.
Effect of plasticizers on release rates of drug.
Texture of plasticized films.
Limitations.
Conclusion.
The presentation shortly shows the research that I did during my Ph.D. at the Eindhoven University of Technology. The aim is the microencapsulation of salt hydrates for their use in heat storage applications. The central question of the research is: "How to use Pickering emulsions efficiently for microencapsulation?"
International Journal of Engineering Research and Development (IJERD)IJERD Editor
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International Journal of Engineering Research and Development (IJERD)IJERD Editor
call for paper 2012, hard copy of journal, research paper publishing, where to publish research paper,
journal publishing, how to publish research paper, Call For research paper, international journal, publishing a paper, IJERD, journal of science and technology, how to get a research paper published, publishing a paper, publishing of journal, publishing of research paper, reserach and review articles, IJERD Journal, How to publish your research paper, publish research paper, open access engineering journal, Engineering journal, Mathemetics journal, Physics journal, Chemistry journal, Computer Engineering, Computer Science journal, how to submit your paper, peer reviw journal, indexed journal, reserach and review articles, engineering journal, www.ijerd.com, research journals,
yahoo journals, bing journals, International Journal of Engineering Research and Development, google journals, hard copy of journal
Fabrication and characterization of conducting polymer compositeijoejournal
The ion conducting polymer composite specimen has been prepared by using Polyvinyl- pyrrolidone
(PVP) and Potassium hydroxide (KOH) using double distilled water as the solvent. The solution cast
techniques was used to prepare the specimens. The main objective of the project is to study structural and
mechanical properties of the polymer composite specimen. The conductivity and micro structure analysis
has been carried out. The results revealed conductivity and hardness of the polymer composite increased
with concentration of the KOH salt
Dynamics of Poly(ethylene oxide) in the bulk and in close proximity to silica...Eleni 'Hellen' Papananou
The behavior of polymers when they are restricted in space can be very different from that in the bulk especially when the molecules are confined to dimensions comparable to their sizes. The dynamics of polymer chains under confinement and its difference from the respective of the bulk has attracted the scientific interest because it greatly affects many of the material macroscopic properties. Besides planar polymer films, other experimental geometries have been utilized to study the effect of confinement on the various polymer relaxation processes such as: polymer / nanoparticle, polymer / nanorods and polymer / layered silicate nanocomposites to name a few.
In the past, we have systematically pursued the understanding of the parameters that influence the structure and dynamics under confinement in intercalated PEO / layered silicate nanocomposites. The confined polymer chains remain purely amorphous; crystallinity is observed only for hybrids with high polymer content and shows an abrupt drop to zero at a certain composition. The study of dynamics in confinement in comparison to the respective in the bulk utilizing dielectric relaxation spectroscopy showed an acceleration of the PEO segmental dynamics that display an Arrhenius temperature dependence with very low activation energy, whereas the local β-process remains unaffected.
Using nanoparticles to restrict the polymer can provide the advantage of altering the polymer confinement by changing the nanoparticle size and loading. Thus, in this work, we utilize PEO / SiO2 nanohybrids to control the thickness of the confined polymer film. DSC measurements showed decreasing crystallinity with the amount of additive whereas in hybrids with polymer content lower than 50wt%, a second crystallization and melting appears, indicating that the polymer crystallizes differently, when forced to crystallize near the silica surface.
The PEO dynamics is studied utilizing dielectric spectroscopy for hybrids with different composition to investigate the effect of the chain proximity to the surface on dynamics. The results are compared to the respective results on PEO / clay nanocomposites and the effect of the geometry of the filler on the behavior will be explored, as well.
Nano Technology & Nano Materials
by Ray Fernando, PHD
California Polytechnic State University
Polymers and Coatings Program
Department of Chemistry and Biochemistry
San Luis Obispo, CA
www.polymerscoatings.calpoly.edu
Delivered 22 June 2009 @ SLINTEC
Surface Modification of Nanoparticles for Biomedical ApplicationsReset_co
Surface ligands on nanoparticles control their properties and interactions, which can be harnessed for biomedical imaging, cell targeting, and therapeutic applications.
Chitosan capped Silver nanoparticles used as Pressure sensorsIOSR Journals
In the present work, we report the synthesis and characterization of silver nanoparticles, capped with chitosan (biopolymer ). The majority of the particles produced in this way had sizes around 18 nm. Composite films of capped silver nanoparticles and chitosan polymer were studied to understand the charge transport under different pressure. Films of different compositions were prepared to measure current voltage curves across the film thickness. The results reveal that these materials exhibit electrical conductivity as predicted by the “classical theory of percolation”. Pressure dependent electrical conductivity and these composites can be explored to develop low cost pressure sensors.
3. Crystallinity
• Crystalline
– Ordered Crystalline
• Amorphous Amorphous
– Random
• Semi-crystalline Semi-crystalline
– Consists of both Figure 5 – Crystalline, amorphous, and
semi-crystalline polymers
4. Glass Transition Temperature (Tg)
• Hard, brittle Soft, rubbery
Figure 6 – Visual representation of polymers’ actions at Tg.
5. Factors Suggested to Affect Tg
1. Conformational flexibilities of individual
polymer chain backbones
2. Sizes or steric bulk of side-chains
3. Interactions between polymer chains
6. Review of Literature
• Richardson, M. J. and Savill, N. G. “Derivation of Accurate
Glass Transition Temperatures by Differential Scanning
Calorimetry.” Polymer (1975). 753
• Kim, Y. W. et al. “Molecular Thermodynamic Model of the
Glass Transition Temperature: Dependence on Molecular
Weight.” Polymers for Advanced Technologies (2008).
944-946
• Makhiyanov, N. and Temnikova, E. V. “Glass-Transition
Temperature and Microstructure of Polybutadienes.”
Polymer Science (2010). 2102-2111
7. Statement of the Problem
The focus of this research is to determine if
differences in the contributions made by the
three structural factors cause and explain the
wide range of Tgs observed for structurally
different polymers.
8. Research Questions
1. Why do polymers with different or even
somewhat similar microstructures show different
softening temperatures, sometimes ranging over
several hundreds degrees Celsius?
2. Are each of the three factors (inherent
conformational flexibilities of polymer chain
backbones, sizes or steric bulk of side chains,
and interactions between polymer chains)
important in determining a polymer’s Tg?
9. Hypothesis
If two amorphous polymers, both with nearly
identical inherent conformational flexibilities of
their polymer chain backbones (factor 1) and no
side chains (factor 2), differ in Tg, then it is
caused by differences in the interactions between
polymer chains (factor 3), because the other
factors have been eliminated by their
commonality.
11. Comparison of Polymers
HO
OH
1,6
Adipic Acid Adipic Acid 1,6 Hexanediol
Hexamethylenediamine
O O
Nylon 6,6 Polyester 6,6
Figure 7 – Formula of nylon 6,6 Figure 8 – Formula of polyester 6,6
13. Characterization of Polymers
DSC
X-Ray Diffraction (XRD)
Co-polymerization
Figure 14 – Philips XLF, ATPS X-
Ray Diffractometer
14. FTIR Spectra
* * H e x ame thy di a mi ne
0.3
Hexamethylenediamine
Ab s
0.2
0.1
* * A d i pi c A ci d
0.4 Adipic Acid
Ab s
0.2
* * N y l on 6,6 S al t
0.2 Nylon 6,6 Salt
Ab s
0.1
- 0.0
* * N y l on 6-6
Nylon 6,6
0.2
Ab s
0.1
400 0 350 0 300 0 250 0 200 0 150 0 100 0 500
W av enu mber s ( c m- 1)
Figure 15 – FTIR spectra of nylon 6,6 and its components
15. Homopolymer Melting Scans
Figure 16 – DSC scans of homopolymer nylons
Nylon 6,6 melting point ΔH – 53 J/g Nylon 6,10 melting point ΔH – 76 J/g
16. Intrinsic Viscosity and Molecular
Weight
Intrinsic Viscosity ([η]) and Molecular Weights of Nylon 6,10
Pre-polymers
Initial production [η] Molecular weight
condition (g/mol)
Monomer mixture 0.125 dL/g 1,800
Atmospheric 0.266 dL/g 4,600
From pressure
salts
Elevated pressure 0.802 dL/g 19,000
Figure 17 – Intrinsic viscosity and molecular weight of nylon 6,10 pre-polymers
17. Co-Polyamide Results
Figure 18– DSC scan of co-polyamide
Differences in Melting Points (Tms) and ΔHs of Tms vs Ratios of the Co-polyamides
Co-polyamide ratio (6,6 to Tm ( C) ΔH of melting points (J/g)
6,10)
50% - 50% 192 39
65% - 35% 220 41
80% - 20% 233 57
Figure 19– Tms and ΔHs of co-polyamide variations
18. Conclusion
If two amorphous polymers,
both with nearly identical
inherent conformational
flexibilities of their polymer
chain backbones (factor 1) and • Inconclusive
no side chains (factor 2), differ
in Tg, then this is caused by
different interactions between
polymer chains (factor 3).
19. Future Directions
• Use of nylon mixture (co-polyamide)
• Corresponding polyesters (co-polyester)
Figure 20 – DSC scan of 4 nylon mixture
20. Acknowledgements
• God
• Dr. Alan E. Tonelli, Alper Gurarslan,
Jialong Shen, Kathleen Dreifus
• Friends and Family
• NC Project SEED
• Funders: The North Carolina Local Section of the
American Chemical Society, the Hamner Institute
for Health Sciences, Biogen Idec, Greater
Triangle Community Foundation, and the
Burroughs-Wellcome Fund
Editor's Notes
Good (morning/afternoon/evening). My name is Miles Ndukwe, and I attend Millbrook High School in Raleigh, North Carolina. Over the summer, I have conducted research under the direct supervision of Dr. Alan E. Tonelli in the department of Textile Engineering, Chemistry, and Science at North Carolina State University. The research is entitled “Probing the Bases of Polymer Glass Transitions”.
Polymers are the building blocks of many parts of our bodies and the materials we use everyday. Biopolymers, such as DNA, sustain the lives of living organisms. Various commercial products such as tires, plastics, and clothing are composed of polymers. Through this research, I plan to improve my knowledge of the softening temperature of polymers in order for industries to improve the design of polymer-based products, because their processing and use temperatures are determined by their softening temperatures.
One of the significant characteristics of polymers is crystallinity, or the degree of structural order in a polymer. When the macromolecular chains of a polymer sample are arranged in an orderly fashion, as displayed on the top of Figure 5, it is known as a crystalline polymer. When the chains are arranged randomly and are disordered, the polymer is identified as amorphous, as seen in the middle of Figure 5. In most cases, there are no fully crystalline polymers; therefore, we have semi-crystalline polymers, which are composed of both amorphous and crystalline regions. In my research, I am studying the softening of amorphous polymers.
The temperature at which amorphous polymers, or the amorphous regions of semi-crystalline polymers, soften from a hard and stiff state to a softer, rubbery state is known as the glass-transition temperature, which is denoted as Tg. Tgvaries with the molecular weight and the structure of a polymer. The standing red Solo cup in Figure 6 represents the stiff state of the polymer below Tg , and the melted one is an illustration of what the polymers look like above Tg. In the past, it has been revealed that there are differences in Tgs observed for structurally dissimilar polymers that can range over several hundreds degrees Celsius, and there have been many suggestions for the causes of this wide range in Tgs.
Differences in structural factors, such as (1,2,3) have often been considered to be the leading reasons:The following sources were researched in order to provide some background information.
-In 1975, Richardson and Savill successfully employed a method of determining Tg.-In 2008, Kim et al. discussed the relationship between Tg and the polymer’s molecular weight. -In 2010, Makhiyanov and Temnikova demonstrated that changes in the microstructure of a polymer affects Tg.With the information from these sources, in addition to other background information on this topic, the following statement of the problem was produced.
The focus of this research is to determine if differences in the contributions made by these three structural factors cause and explain the wide range of Tgs observed for structurally different polymers. From this statement of the problem, the following research questions were formulated:
Why do polymers with different or even somewhat similar microstructures show different softening temperatures, sometimes ranging over several hundreds degrees Celsius?Are each of the three factors (inherent conformational flexibilities of polymer chain backbones, sizes or steric bulk of side chains, and interactions between polymer chains) important in determining a polymer’s Tg?Based on these research questions, the following hypothesis was derived:
If two amorphous polymers, both with nearly identical inherent conformational flexibilities of their polymer chain backbones and no side chains, differ in Tg, then it is caused by differences in the interactions between polymer chains because the other factors have been eliminated by their commonality, which I can then independently assess. In order to test this hypothesis, two amorphous co-polymers with structures that only cause different inter-chain interactions will be synthesized, characterized, and their Tgs will be measured and compared. The following materials and methods will be exercised in this research.
A wholly amorphous co-polyamide was attempted to be synthesized before a structurally similar co-polyester.-Homopolymer nylons were synthesized using these production methods before the co-polyamide.-First, two salts were prepared with a mixture of two monomers, and then underwent melt pre-polymerization, so that the monomers would react.-The pre-polymers underwent solid-state polymerization to produce complete polymers of decent molecular weights.-An identical procedure was employed to synthesize the co-polyamide, but the salt consisted of a mixture of both monomer salts. Here is an example of the syntheses of a polyamide and an analogous polyester.
Here, we have the formulas for nylon 6,6, which have amide bonds formed with HMDA, and polyester 6,6, which have ester bonds formed with hexanediol. The nylon is able to hydrogen bond, while the polyester cannot. This is the only difference in structure and would produce different interchain interactions. The following methods characterized the polymers throughout their syntheses.
-Finding the pH of the monomer salts would confirm their formation.-Thermal-Gravimetric Analysis, or TGA, determined the maximum temperature of stability of the salts.-Differential Scanning Calorimetry, or DSC, determined the melting points of the homopolymers and their salts.This information would determine the temperature at which to maintain the salts during melt polymerization.-Fourier Transform Infrared Spectroscopy, or FTIR, analysis confirmed the nylon formation (amide bonds) of the pre-polymers. -Dilute solution viscosity was employed to compare the molecular weights of the polymers before and after solid-state polymerization.
When characterizing the co-polymers, samples of each would undergo DSC, once again, to insure that they are amorphous and to determine their Tgs. XRD would then be employed in order to further characterize any crystallinity, or absence thereof, in the polymers, to determine if they are wholly amorphous. If the Tgs from the DSC scans differ, then I can confirm the hypothesis.
Figure 15 displays the FTIR spectra of the nylon 6,6 polymer, its salt, and its monomer components. The amide bonds are confirmed in the nylon vibrations, such as the peak designated by the asterisk.
Indicated by the DSC scans in Figure 16, the melting points of homopolymers nylon 6,6 and nylon 6,10 are approximately 246 and 211° C, respectively. The change in enthalpy, or ΔH, of the melting point of nylon 6,6 is around 53 J/g, and is approximately 76 J/g for nylon 6,10’s melting point. This information would confirm the nylon formation and would be applied when determining the temperature at which to maintain the polymers during solid state polymerization.
Figure 17 displays the intrinsic viscosity and molecular weights of three samples of nylon 6,10 pre-polymers. Previous procedures did not produce products of high molecular weight. A procedure, consisting of elevated pressure, produced a pre-polymer with decent molecular weight. After undergoing an effective solid state polymerization, the molecular weight should increase even further, so that Tgs will not be affected by low molecular weights.
In the DSC scan of the co-polyamide, the peak in the graph revealed a melting point at approximately 192° C, and this a property not found in amorphous polymers. Melting points indicate crystallinity in polymers; therefore, this method of synthesizing a wholly amorphous polymer was not effective. Other ratios of nylon 6,6 to 6,10 have been synthesized, and their melting points and ΔHs have been compared.
The hypothesis for this research is currently inconclusive, because our method did not produce a wholly amorphous copolymer. However, melting four nylons together as well as revised bulk syntheses did, so soon I may be able to test the hypothesis.
In the future, I would like to employ a mixture of nylon 6, 6,6, 6,10, and 11 in the synthesis of the amorphous co-polyamide. Here, I would compare DSC traces of the physical mixture of the nylons before and after heating for several hours above the temperature of the highest melting Nylon (Nylon-6,6 Tm ~ 260° C). From this scan, this method of synthesizing a wholly amorphous polymer seemed promising, indicating a change in slope, which indicates Tg of approximately 47°C. Once successful in that synthesis, the structurally analogous amorphous co-polyester will then be synthesized using a mixture of corresponding polyesters.