The document discusses alcohols, including their structure, properties, nomenclature, methods of preparation, and reactions. Some key points:
1. Alcohols contain a hydroxyl (-OH) functional group attached to a saturated carbon atom. They can be classified as primary, secondary, or tertiary depending on if the -OH group is attached to a primary, secondary, or tertiary carbon.
2. Common physical properties of alcohols include being colorless liquids with characteristic smells, and higher boiling points than alkanes due to hydrogen bonding between -OH groups.
3. Alcohols can be prepared through hydrolysis of alkyl halides, alkenes,
This is a report about Aldehydes. The content of this slideshow are as follows: What is an aldehyde, How to name aldehydes with IUPAC Nomenclature and Common Names, The Physical Properties of Aldehydes, and the examples of aldehyde and its uses. The main objective of this report is to widen the knowledge of the readers/learners concerning of the stated topic so that they can further understand the concept of aldehydes.
Report made by: Students of Sogod National High School STEM 9-Newton
Kyla Krystelle Salva
Krishia Belle Cambalon
Marycris Felicilda
This is a report about Aldehydes. The content of this slideshow are as follows: What is an aldehyde, How to name aldehydes with IUPAC Nomenclature and Common Names, The Physical Properties of Aldehydes, and the examples of aldehyde and its uses. The main objective of this report is to widen the knowledge of the readers/learners concerning of the stated topic so that they can further understand the concept of aldehydes.
Report made by: Students of Sogod National High School STEM 9-Newton
Kyla Krystelle Salva
Krishia Belle Cambalon
Marycris Felicilda
Introduction to Alcohols.
1. What are Alcohols ?
2. Functional Group
3. Classification
4. Monoatomic, diatomic alcohols
5. Monohydric, dihydric alcohols
6. Nomenclature of Alcohols
Important functional group of organic chemistry alcohol. introduction classification properties preparation and chemical reactions. Alcohols are classified as primary, secondary, or tertiary, based upon the number of carbon atoms connected to the carbon atom that bears the hydroxyl group.
Classification of alcohols: Depending on the number of hydroxyl group present, they are classified into following types.
Monohydric alcohols: Alcohols having only one -OH group is present in the molecule are known monohydric alcohols. Example: Methyl alcohol, Ethyl alcohol etc.,
Dihydric alcohols: Alcohols having two hydroxyl groups in a molecule are known as dihydric alcohols or diols or glycols. Example: 1,2-ethandiol (Glycol).
Trihydric alcohols: Alcohols having three hydroxyl groups are called trihydric alcohols. Example: 1, 2, 3-propantriol (Glycerol).
Alcohols having only one -OH group is present in the molecule are known as monohydric alcohols. Monohydric alcohols are classified depending on the number of carbon atoms which are directly attached to the carbon which contain –OH group are primary (1º), secondary (2º) or tertiary (3º). Depending upon whether the number of alkyl groups bonded to the carbon atom bearing the hydroxyl group is one, two or three, respectively
In organic chemistry, a carbonyl group is a functional group composed of a carbon atom double-bonded to an oxygen atom: C=O. It is common to several classes of organic compounds, as part of many larger functional groups.
Introduction to Alcohols.
1. What are Alcohols ?
2. Functional Group
3. Classification
4. Monoatomic, diatomic alcohols
5. Monohydric, dihydric alcohols
6. Nomenclature of Alcohols
Important functional group of organic chemistry alcohol. introduction classification properties preparation and chemical reactions. Alcohols are classified as primary, secondary, or tertiary, based upon the number of carbon atoms connected to the carbon atom that bears the hydroxyl group.
Classification of alcohols: Depending on the number of hydroxyl group present, they are classified into following types.
Monohydric alcohols: Alcohols having only one -OH group is present in the molecule are known monohydric alcohols. Example: Methyl alcohol, Ethyl alcohol etc.,
Dihydric alcohols: Alcohols having two hydroxyl groups in a molecule are known as dihydric alcohols or diols or glycols. Example: 1,2-ethandiol (Glycol).
Trihydric alcohols: Alcohols having three hydroxyl groups are called trihydric alcohols. Example: 1, 2, 3-propantriol (Glycerol).
Alcohols having only one -OH group is present in the molecule are known as monohydric alcohols. Monohydric alcohols are classified depending on the number of carbon atoms which are directly attached to the carbon which contain –OH group are primary (1º), secondary (2º) or tertiary (3º). Depending upon whether the number of alkyl groups bonded to the carbon atom bearing the hydroxyl group is one, two or three, respectively
In organic chemistry, a carbonyl group is a functional group composed of a carbon atom double-bonded to an oxygen atom: C=O. It is common to several classes of organic compounds, as part of many larger functional groups.
2. Chemistry of Aliphatic Compounds: Introduction, methods of preparation, physical and chemical properties and pharmaceutical applications of alcohols, aldehydes, ketones, hydrocarbons, ester, ethers, amines, amides and carboxylic acids.
Alkanes, Alkenes, Alkynes, Alkyl Halides, Alicyclic Hydrocarbons, Alcohols,
Ethers and Epoxides, Aldehydes and Ketones, Carboxylic Acids and their
Functional Derivatives
The combination of a carbonyl group and a hydroxyl on the same carbon atom is called a carboxyl group. Compounds containing the carboxyl group are called carboxylic acids. The carboxyl group is one of the most widely occurring functional groups in organic chemistry.
Aromatic Carboxylic acids: Carboxylic acids have an aryl group bound to the carboxyl group is known as aromatic carboxylic acids. The general formula of an aliphatic aromatic carboxylic acid is Ar-COOH.
Acidity of carboxylic acid:
A carboxylic acid may dissociate in water to give a proton and a carboxylate ion. Dissociation of a carboxylic acid involves breaking an O-H bond gives a carboxylate ion with the negative charge spread out equally over two oxygen atoms, compared with just one oxygen atom in an alkoxide ion. The delocalized charge makes the carboxylate ion more stable therefore; dissociation of a carboxylic acid to a carboxylate ion is less endothermic.
Preparation Methods:
1. Oxidation:
The oxidation of aldehyde with oxidizing agents such as CrO3 to forms carboxylic acids containing the same numbers of carbon atoms with a oxidizing agents like chromic acid, chromium trioxide. The silver oxide (Ag2O) in aqueous ammonia solution (Tollen’s reagent) is mild reagent give good yield at room temperature. E.g. Acetaldehyde reacts with CrO3 in aqueous acid to give acetic acid.
2. Grignard reagents (from CO2):
Carboxylic acid can be prepared by the reaction of Grignard reagent (alkyl magnesium halide) with carbon dioxide (CO2) in presence of dry ether. Grignard reagents react with carbon dioxide to forms a magnesium carboxylates which on hydrolysis by dilute HCl produces carboxylic acids.
3. Hydrolysis of nitrile:
The hydrolysis of nitrile or cyanide in presence of dilute acid to forms a carboxylic acid. In this reaction –CN group is converted to a –COOH group.
4. Hydrolysis Reactions:
All the carboxylic acid derivatives can be hydrolyzed into the carboxylic acid in the acidic or basic media; the hydrolysis reaction is fast and occurs in presence of water with no acid or base catalyst.
1. From Ester (Hydrolysis of ester): Ester can be hydrolyzed in either acidic or basic medium to yield carboxylic acid. The ester is heated with an excess of water contains strong acid or base catalyst.
Properties of Carboxylic Acids:
1. Low molecular weights carboxylic acids are colourless liquid at room temperature i.e. lower member ate liquid up to C9 and have characteristic odors whereas higher members are solid.
2. Carboxylic acids are polar organic compound. Low molecular weight carboxylic acids (first four members) are soluble in water whereas solubility in water decrease as molecular weight and chain lengthing increases.
3. Aromatic acids are insoluble in water.
4. Carboxylic acids have higher melting and boiling point due to their capacity to readily form stable hydrogen-bonded dimers.
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2. ALCOHOL
Molecular Formula : CnH2n+2O
EX. R-OH
Alcohols are compounds in which a hydroxyl (-OH) group is attached
to saturated carbon atom.
3. ALCOHOL The hydroxyl group is the functional group of alcohols.
Alcohols containing one hydroxyl group are called Monohydric
Alcohols. Alcohols with two, three or more hydroxyl group are known
as Dihydric alcohols, Trihydric alcohols and Polyhydric alcohols
respectively.
4. ALCOHOL Monohydric Alcohols are classified as primary, secondary
or tertiary depending upon whether the –OH group is
attached to a primary, secondary or a tertiary carbon.
5. STRUCTURE Let us consider methyl alcohol(CH3OH) for illustrating the orbital make up of
alcohols.
In methyl alcohol both oxygen and carbon are sp3 hybridised.
Two of the sp3 orbitals of oxygen are completely filled and cannot take part in
bond formation. The C-O bond in methyl alcohol is formed by overlap of an
sp3 orbital of carbon and an sp3 orbital of oxygen.
The O-H bond if formed by overlap of an sp3 orbital of oxygen and s orbital of
hydrogen.
6. STRUCTURE The C-O-H bond angle is 105o. It is less than the
normal tetrahedral angle.
7. NOMENCLATUREAlcohols are named by three systems:
1. Common System
In this system alcohols(R-OH) are named as Alkyl
Alcohols. The alkyl group attached to the –OH group is
named and ‘alcohol’ is added as a separate word. For
example,
8. NOMENCLATUREAs we go higher in the series, it becomes necessary to
indicate whether a particular alcohol is primary,
secondary, or tertiary. The prefix secondary is abbreviated
as sec-, The prefix tertiary is abbreviated as tert- or t-. For
example,
9. NOMENCLATURE2. Carbinol System
In this system alcohols are considered as derivatives of methyl alcohol
which is called Carbinol. The alkyl group attached to the carbon
carrying the –OH group are named in alphabetic order. Then the
suffix – carbinol is added. For example,
10. NOMENCLATURE3. IUPAC SYSTEM
In this system alcohols are named as Alkanols. The IUPAC rules are:
Select the longest continuous carbon chain containing the –OH group.
Change the name of the alkane corresponding to this chain by dropping the ending –e and adding
the suffix –ol.
Number the chain so as to give the carbon carrying the –OH group, the lowest possible number. The
position of the –OH group is indicated by this number.
11. PROPERTIES1. Physical Properties
a) Lower alcohols are colourless, toxic liquids. They have a
characteristic smell.
b) Boiling points of alcohols increase regularly with the
increase in the number of carbon atoms
Name bp oC
Methanol 64.5
Ethanol 78.3
1-Propanol 97.0
1-Butanol 118.0
13. PROPERTIESd) Boiling points of alcohols are much higher than those of the corresponding
alkanes.
The O-H bond of alcohols is highly polar because oxygen is
electronegative. The oxygen carries a partial negative charge (d-). The
hydrogen carries a partial positive charge (d+). The polarity of the O-H
bond gives rise to forces of attraction between a partially positive
hydrogen in one alcohol molecule and partially negative oxygen in
another alcohol molecule. These forces of attraction are referred to as
Hydrogen Bonding. The reason that alcohols have higher boiling points
is that a great deal of energy is required to overcome these attraction
forces.
Alkanes, which have no –OH group, do not undergo hydrogen bonding.
Therefore, their boiling points are low.
14. PROPERTIESe) Lower alcohols (C1 to C3) are completely soluble in
water. As we go higher in the series, the water solubility
falls rapidly.
15. PROPERTIES2. Chemical Properties
Alcohols are reactive compounds. They are attacked by polar or ionic
reagents. This is because
i) The C-O and O-H bonds of alcohols are polar since oxygen is highly
electronegative.
ii) The oxygen atom of alcohol is an electron-rich centre because it has
two unshared pairs of electrons.
16. METHOD OF PREPARATION
Total 6 Methods
1. Hydrolysis of Alkyl Halides
2. Hydrolysis of Alkenes
3. Addition of Grignard Reagents to Aldehydes and Ketones
4. Fermentation of Carbohydrates
5. Hydroboration-Oxidation of Alkenes
6. Reduction of Aldehydes and Ketones
18. METHOD OF PREPARATIONHydrolysis of Alkenes
Alkenes react with sulphuric acid to produce alkyl hydrogen
sulphates (Markovnikov rule is followed). Alkyl hydrogen sulphates
on hydrolysis give alcohols. For example,
19. METHOD OF PREPARATION The overall result of the above reactions appears to be Markovnikov
addition of H2O(Hydration) to a double bond.
20. METHOD OF PREPARATION The overall result of the above reactions appears to be Markovnikov
addition of H2O(Hydration) to a double bond.
21. METHOD OF PREPARATIONHydroboration-Oxidation of Alkenes
Alkenes react with diborane, B2H6 to form trialkylboranes. Diborane adds as
borane BH3.
Trialkylboranes are used for making primary alcohols by reaction with
alkaline aqueous solution of hydrogen peroxide.
22. METHOD OF PREPARATION The overall result of the above reactions appears to be anti-Markovnikov
addition of H2O to a double bond.
24. METHOD OF PREPARATIONReduction of Aldehydes and Ketones
Aldehydes and ketones can be reduced with H2/Ni or lithium aluminium
hydride to form the corresponding alcohols. Aldehydes give primary
alcohols. Ketones give secondary alcohols.
25. METHOD OF PREPARATIONAddition of Grignard Reagents to Aldehydes and Ketones
Grignard reagents react with aldehydes or ketones to form an addition
compound which on hydrolysis with dilute acid gives the corresponding
alcohols.
26. METHOD OF PREPARATIONFermentation of Carbohydrates
Some alcohols can be prepared by fermentation of starches and sugars
under the influence of suitable microorganisms. For example,
27. REACTIONSReaction with Active Metals
Alcohols react with sodium or potassium to form alkoxides with the
liberation of hydrogen gas.
28. REACTIONSReaction with Phosphorus Halides
Alcohols react with phosphorus pentahalides (PX5) and phosphorus
trihalides (PX3) to form alkyl halides.
32. REACTIONSReaction with Sulphuric acid
The reaction of alcohols with sulphuric acid is very sensitive to reaction
conditions. For example,
I) When ethyl alcohol is treated with concentrated sulphuric acid at room
temperature, ethyl hydrogen sulphate is produced.
33. REACTIONSII) Dehydration of Alcohols to Alkenes
When ethyl alcohol is treated with concentrated sulphuric acid at 170oC, ethylene is formed.
Notice that only one alcohol molecule is involved in the reaction.
The ease of dehydration of alcohols follows the order 3o>2o>1o which is also the order of stability
of the carbonium ions.
Dehydration of secondary and tertiary alcohols containing four or more carbon atoms gives a
mixture of two alkenes. For example,
34. REACTIONS The alkene produced in greater abundance is indicated by Saytzeff Rule. It
states that the alkene formed preferentially is the one containing the higher
number of alkyl groups. Therefore, in the above example, 2-butene is the
major product.
35. REACTIONSIII) Dehydration of Alcohols to Ethers
When excess of ethyl alcohol is treated with concentrated sulphuric acid at 140oC, diethyl
ether is formed. Notice that two alcohol molecules are involved in the reaction.
Dehydration of alcohols to ethers or alkenes can also be brought about by passing the
vapours of the alcohol over heated alumina catalyst. For example,
36. REACTIONSReaction with Carboxylic acids
Alcohols react with carboxylic acids to form esters. Concentrated sulphuric acid is used as a
catalyst. The reaction is reversible and can be shifted in the forward direction by removing
water as soon as it is formed. The reaction between an alcohol and a carboxylic acid to
form an ester is called Esterification.
37. REACTIONSReaction with Acid Halides and Acid anhydrides
Alcohols react with acid halides and acid anhydrides to form esters.
39. REACTIONSOxidation
Alcohols can be oxidized. The nature of the product depends on the type of
alcohol and the conditions of the reaction. Most widely used oxidizing agents
are KMnO4 + H2SO4 or Na2Cr2O7 + H2SO4.
Oxidation of alcohols can be used to distinguish between primary, secondary,
and tertiary alcohols.
Primary alcohols are first oxidized to aldehydes and then to acids
40. REACTIONS Secondary alcohols are oxidized to the corresponding ketones
Tertiary alcohols are stable to oxidation under normal conditions.
41. REACTIONSReaction with the Hot Copper; Dehydrogenation
Different types of alcohols give different products when their vapours are
passed over copper gauze at 300oC.
Primary alcohols lose hydrogen and give an aldehyde.
Secondary alcohols lose hydrogen and yield a ketone
42. HOW TO DISTINGUISH BETWEEN
1o, 2o, AND 3o ALCOHOLS ? The following tests are used to distinguish between primary, secondary, and
tertiary alcohols.
Lucas Test
In this test, alcohols are treated with a solution of HCl and Zinc Chloride to
form alkyl halides. Zinc chloride serves as a catalyst.
The three types of alcohols undergo this reaction at different rates. Tertiary
alcohols react with Lucas reagent very rapidly. Secondary alcohols react
somewhat slower. Primary alcohols react with Lucas reagent even more slowly.
43. HOW TO DISTINGUISH BETWEEN
1o, 2o, AND 3o ALCOHOLS ? In practice, the Lucas test is carried out as follows: An alcohol is mixed, at
room temperature, with concentrated HCl and ZnCl2. The alkyl chloride,
which is formed, is insoluble in the medium. It causes the solution to become
cloudy before it separates as distinct layer.
With Tertiary alcohols cloudiness appears immediately.
With Secondary alcohols cloudiness appears in 5 minutes.
With Primary alcohols the solution remains clear. This is because primary
alcohols do not react with Lucas reagent at room temperature. High
temperatures are needed.
44. HOW TO DISTINGUISH BETWEEN
1o, 2o, AND 3o ALCOHOLS ?Dichromate Test
This test is based on the fact that different types of alcohols give different
products on oxidation. The alcohol is treated at room temperature with
sodium dichromate in sulphuric acid (orange solution). Identification of the
products gives us information regarding the type of the alcohol.
Primary alcohols gives a carboxylic acid containing the same number of
carbons. There will be a change in colour of the solution from orange to green.
Secondary alcohols give a ketone containing the same number of carbons.
There will be change in colour of the solution from orange to green.
Tertiary alcohols do not react under these conditions. Solution will remain
orange.