Multi-Protocol Label Switching (MPLS) is a routing technique that assigns short, fixed-length labels to data packets to improve routing speed. MPLS works by mapping IP addresses to labels at the edge of the network. Label Switched Routers inside the network use these labels to make forwarding decisions instead of long IP addresses. The document provides details on MPLS headers, label switched routers, label edge routers, and how to configure and verify MPLS on a sample network topology.