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Paul Bentz
Kevin Cao
Concept
 Bacteria convert substrate into electrons.
 The electrons run through the circuit and to power the
  load.
 The byproducts include carbon dioxide, water, and
  energy.
Components
 Anode
 Cathode
 Exchange membrane
 Electrical circuit
Anode
 The bacteria live in the anode and
  convert substrate to carbon
  dioxide, water, and energy.
 Various things like glucose and
  acetate can be used.
 The bacteria are kept in an oxygen-
  less environment to promote the
  flow of electrons through the
  anode.
Electrical Circuit
 After leaving the anode, the electrons travel through
  the circuit.
 These electrons power the load.
 The voltage multiplied by the current shows the power.
Exchange Membrane
 The protons that the bacteria separated
  from the electrons flows through the
  exchange membrane.
 They recombine on the other side.
 Can be a proton or cation exchange
  membrane.
Cathode
 The electrons and protons recombine
  at the cathode.
 Oxygen is reduced to water.
 A platinum catalyst is used so the
  oxygen is sufficiently reduced.
Video
Reactions
 BEAMR
 Hydrogen evolution reaction
BEAMR
 Utilizes electrohydrogenesis, which uses an anaerobic
  environment to produce pure hydrogen.
 It uses about one ninth of the energy required by
  normal electrolysis.
 It has many different names:
   Bioelectrochemically assisted microbial reactor
   Biocatalyzed electrolysis cells
   Microbial electrolysis cells
Hydrogen Evolution Reaction
 The bacteria in the anode separate the protons and
  electrons.
 This reaction occurs at the cathode, where they
  recombine to form hydrogen gas.
History
 M.C. Potter first performed work on the concept in 1911
  with E. coli at the University of Durham
 In 1976 the current design was came into existence by
  the work of Suzuki
Operating Conditions
 Function well in mild conditions
 Operate at 70-100°F
Uses
 Beer breweries produce biodegradable
  wastewater, which MFCs clean.
 Desalinating water
 Creating fertilizer
Environmental Impact
 If the variety of substrates is increased, waste can be
  used to create more energy.
 Instead of big factory manufacturing, fertilizer for
  farmers can be created with MFCs and common
  materials.
 MFCs can be used to desalinate seawater without
  burning fossil fuels, although not very efficiently yet.
Efficiency
 The efficiency varies based on the substrate used, but
  it can reach very high efficiencies.
 91% efficiency has been reached.
Cost
   Power density = 150 mW/m2
   Volume (MFC): 28 x 10^-6 m3
   A/V-ratio: 25 m2/m3
   Anode surface area (single chamber) = 7 x 10^-4 m2
   Power = 0.165 mW

   Cost of single-chamber fuel cell: (lab-scale)
   Toray paper (10x10 cm): $ 11
   XC-72 (10x10 cm): $65
   Others (perspex, glue, wire): $ 25
   Total = $ 100

 Cost per Watt = $ 600/mW
Future
 More types of substrate
 Ammonia-treated anodes
Substrate
 Currently there is a limit to what can be used as a
  substrate for the bacteria.
 Scientists hope to increase these fuel types to include
  things like sewage and manure.
Ammonia-Treated Anodes
 Anodes of MFCs are naturally
  negative in charge.
 The anodes can be changed to a
  positive charge by being treated
  with ammonia.
 This will make the anode more
  receptive to the electron
  transfer from the bacteria.
 The energy trade-off to produce
  this might not be worth the
  increase in production.
Bibliography
 http://www.microbialfuelcell.org/
 http://www.engr.psu.edu
 http://microbialfuelcell.wordpress.com/
 http://www.sciencedaily.com/releases/2008/01/08010310113
  7.htm
 http://peswiki.com/index.php/Directory:Penn_State_Micr
  obial_Fuel_Cells_Produce_Hydrogen_from_Waste_Water
 www.popsci.com/scitech/article/2009-08/microbial-fuel-
  cell-cleans-wastewater-desalinates-seawater-and-
  generates-power
 http://www.fuelcells.org/info/summer2007.pdf

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Microbial fuel cells

  • 2. Concept  Bacteria convert substrate into electrons.  The electrons run through the circuit and to power the load.  The byproducts include carbon dioxide, water, and energy.
  • 3. Components  Anode  Cathode  Exchange membrane  Electrical circuit
  • 4. Anode  The bacteria live in the anode and convert substrate to carbon dioxide, water, and energy.  Various things like glucose and acetate can be used.  The bacteria are kept in an oxygen- less environment to promote the flow of electrons through the anode.
  • 5. Electrical Circuit  After leaving the anode, the electrons travel through the circuit.  These electrons power the load.  The voltage multiplied by the current shows the power.
  • 6. Exchange Membrane  The protons that the bacteria separated from the electrons flows through the exchange membrane.  They recombine on the other side.  Can be a proton or cation exchange membrane.
  • 7. Cathode  The electrons and protons recombine at the cathode.  Oxygen is reduced to water.  A platinum catalyst is used so the oxygen is sufficiently reduced.
  • 8.
  • 10. Reactions  BEAMR  Hydrogen evolution reaction
  • 11. BEAMR  Utilizes electrohydrogenesis, which uses an anaerobic environment to produce pure hydrogen.  It uses about one ninth of the energy required by normal electrolysis.  It has many different names:  Bioelectrochemically assisted microbial reactor  Biocatalyzed electrolysis cells  Microbial electrolysis cells
  • 12. Hydrogen Evolution Reaction  The bacteria in the anode separate the protons and electrons.  This reaction occurs at the cathode, where they recombine to form hydrogen gas.
  • 13. History  M.C. Potter first performed work on the concept in 1911 with E. coli at the University of Durham  In 1976 the current design was came into existence by the work of Suzuki
  • 14. Operating Conditions  Function well in mild conditions  Operate at 70-100°F
  • 15. Uses  Beer breweries produce biodegradable wastewater, which MFCs clean.  Desalinating water  Creating fertilizer
  • 16. Environmental Impact  If the variety of substrates is increased, waste can be used to create more energy.  Instead of big factory manufacturing, fertilizer for farmers can be created with MFCs and common materials.  MFCs can be used to desalinate seawater without burning fossil fuels, although not very efficiently yet.
  • 17. Efficiency  The efficiency varies based on the substrate used, but it can reach very high efficiencies.  91% efficiency has been reached.
  • 18. Cost  Power density = 150 mW/m2  Volume (MFC): 28 x 10^-6 m3  A/V-ratio: 25 m2/m3  Anode surface area (single chamber) = 7 x 10^-4 m2  Power = 0.165 mW  Cost of single-chamber fuel cell: (lab-scale)  Toray paper (10x10 cm): $ 11  XC-72 (10x10 cm): $65  Others (perspex, glue, wire): $ 25  Total = $ 100  Cost per Watt = $ 600/mW
  • 19. Future  More types of substrate  Ammonia-treated anodes
  • 20. Substrate  Currently there is a limit to what can be used as a substrate for the bacteria.  Scientists hope to increase these fuel types to include things like sewage and manure.
  • 21. Ammonia-Treated Anodes  Anodes of MFCs are naturally negative in charge.  The anodes can be changed to a positive charge by being treated with ammonia.  This will make the anode more receptive to the electron transfer from the bacteria.  The energy trade-off to produce this might not be worth the increase in production.
  • 22. Bibliography  http://www.microbialfuelcell.org/  http://www.engr.psu.edu  http://microbialfuelcell.wordpress.com/  http://www.sciencedaily.com/releases/2008/01/08010310113 7.htm  http://peswiki.com/index.php/Directory:Penn_State_Micr obial_Fuel_Cells_Produce_Hydrogen_from_Waste_Water  www.popsci.com/scitech/article/2009-08/microbial-fuel- cell-cleans-wastewater-desalinates-seawater-and- generates-power  http://www.fuelcells.org/info/summer2007.pdf