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Ionic liquids (ILs) have been achieving a rapid growth of interest in the last decade. It challenges conventional descriptions of fluids in a variety of ways. Unique properties of these new materials have influenced their potential and current applications.
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
1. INTRODUCTION ,[object Object],[object Object],1.1  What is an Ionic Liquid ,[object Object],[object Object],Eg: 1.2  Properties of Ionic Liquids ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],IONIC LQUIDS ,[object Object]
[object Object],[object Object],[object Object],2.1  What is Lubrication 2.2  What is a Lubricant 2. INTRODUCTION TO TRIBOLOGY ,[object Object],[object Object],[object Object]
2.3  Types of Lubricants
Boundary Lubrication Mixed Lubrication Hydrodynamic Lubrication F F F Stribeck Curve 2.4  Lubrication Regimes Beraring Parameter ηV/F η = Viscosity V = Speed F = Load
2.5  What are Additives? ,[object Object],[object Object],[object Object],[object Object],Eg:
3. TRIBOLOGICAL APPLICATIONS OF IONIC LIQUIDS 3.1  Why can Ionic Liquids be Lubricants?
3.2  What are the Applications of ILs in Tribology? ,[object Object],[object Object],[object Object],[object Object],[object Object]
3.2.1 As Lubrication Oils  Ball-on-disc test for Steel-Steel at 100 0 C Friction coefficient at -30, 100 and 200 0 C for Aluminum-Steel contacts [C 1 C 6 im]BF 4 [C 1 C 8 im]BF 4 PGDO Mineral Oi l < ‘ PGDO: Propylene Glycol Diolate’ Disc-on-disc test for Steel-Steel at 100 0 C [C 2 C 6 im] BF4 X-1P PEPF Max Load   600N 300N 300N Load/N Friction Coefficient [C2C6im]BF 4 X-1P PFPE 200 0.060 0.070 0.120 300 0.055 0.065 0.110 400 0.050 - 0.105 500 0.045 - - 600 0.045 - -
[C2C6im] BF 4 PFPE Friction Coefficient 0.07 0.14
FAP - Tf 2 N -
Metal Surface Anion Cation Lubrication Mechanism
3.3.2  As Additives ,[object Object],[object Object],[object Object],[object Object],[object Object],3.3.3  As Thin Films
4. PROBLEMS OF IL LUBRICANTS AND SOLUTIONS
5. CONCLUSION ,[object Object],[object Object],[object Object],[object Object],[object Object]
References ,[object Object],[object Object],[object Object],[object Object],[object Object]
THE END
THANK YOU
F
bis(trifluoromethylsulfonyl)imide tris (pentafluoroethyl) trifluorophosphate   Tf 2 N -  FAP -
Ionic Liquid Lubricants; design chemistry for engineering applications

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Ionic Liquid Lubricants; design chemistry for engineering applications

  • 1. Ionic liquids (ILs) have been achieving a rapid growth of interest in the last decade. It challenges conventional descriptions of fluids in a variety of ways. Unique properties of these new materials have influenced their potential and current applications.
  • 2.
  • 3.
  • 4.
  • 5.
  • 6. 2.3 Types of Lubricants
  • 7. Boundary Lubrication Mixed Lubrication Hydrodynamic Lubrication F F F Stribeck Curve 2.4 Lubrication Regimes Beraring Parameter ηV/F η = Viscosity V = Speed F = Load
  • 8.
  • 9. 3. TRIBOLOGICAL APPLICATIONS OF IONIC LIQUIDS 3.1 Why can Ionic Liquids be Lubricants?
  • 10.
  • 11. 3.2.1 As Lubrication Oils Ball-on-disc test for Steel-Steel at 100 0 C Friction coefficient at -30, 100 and 200 0 C for Aluminum-Steel contacts [C 1 C 6 im]BF 4 [C 1 C 8 im]BF 4 PGDO Mineral Oi l < ‘ PGDO: Propylene Glycol Diolate’ Disc-on-disc test for Steel-Steel at 100 0 C [C 2 C 6 im] BF4 X-1P PEPF Max Load 600N 300N 300N Load/N Friction Coefficient [C2C6im]BF 4 X-1P PFPE 200 0.060 0.070 0.120 300 0.055 0.065 0.110 400 0.050 - 0.105 500 0.045 - - 600 0.045 - -
  • 12. [C2C6im] BF 4 PFPE Friction Coefficient 0.07 0.14
  • 13. FAP - Tf 2 N -
  • 14. Metal Surface Anion Cation Lubrication Mechanism
  • 15.
  • 16. 4. PROBLEMS OF IL LUBRICANTS AND SOLUTIONS
  • 17.
  • 18.
  • 21.
  • 22.
  • 23.
  • 24. F