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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 43
Influence of organomodified nanoclay on the thermomechanical
behavior of glass/epoxy nanocomposites
Ganesha T1, Sharathkumara k2, Mahendra T K3
1Assitant professor, Dept. of Thermal Power Engineering, Centre for PG studies, VTU Mysuru, India
2M.Tech graduate, Dept. of Thermal Power Engineering, Centre for PG studies, VTU Mysuru, India
3Lecturer, Dept. of Mechanical Engineering, Govt. CPC Polytechnic, Mysuru, India
-----------------------------------------------------------------------------***----------------------------------------------------------------------------
Abstract - Glass fibre-reinforced epoxy resin (GFRE)
composites filled with MMT (K-10) nanomer 1.44P sigma
powder were fabricated, and their mechanical and thermal
properties were investigated. It is observed that with the
increasing percentage of MMT (K-10) nanomer 1.44P sigma
particles, there is a significant enhancement in density of the
composite and void content of the composite, but there is a
decline in tensile strength. Experimental results demonstrate
that the GFRE composites with 3 wt%ofMMT(K-10) nanomer
1.44P sigma loading show maximum density of 2.356 gm/cc
with void content in percentage of 17.564%, but up to 1 wt%
loading void content in percentage of 14.271% could
exempted, FTIR studies in the range of wavenumber500-4000
cm-1, found OH, CH, CH2 and CH3 group with different
stretching vibration in IR spectra, TGA and DTA studies were
conducted to observe thermogram and thermal behavior of
the sample.
Key Words: Epoxy resin, MMT (K-10) nanomer 1.44P sigma,
glass fibre, hand-lay-up technique, GFRE composites.
1. INTRODUCTION
Polymer matrix composite (PMC) materials having good
thermal conductivity and mechanical strength are largely
used in different areas. Properties of a composite can be
improved by adding material to the matrix. Due to the
properties like high specific strength, stiffness, good
dielectric and resistance to corrosion of Glass fiber-
reinforced polymer (GFRP) these composites are used in
aerospace,1automobile industries, armor, microelectronic
packaging, marine, civil engineering structures, electronic
circuit board,sportsgoods,railwaysetc [1-3].Thermosetting
epoxy resin based composites have many application
because of its high thermal stability, low cost and moisture
resistance. Due to curing of epoxy the thermal conductivity
of epoxy is reduced and thermal expansion coefficient(CTE)
can be increased [4]. Fused quartz or silica is used to
reinforce the ceramic powder to lower the thermal
expansion of epoxy to match to that of semiconductor dies
and lead frames [5]. PMC contains polymer or copolymer
having Nano fillers or nanoparticles dispersed in the
polymer matrix.
Montmorillonite is used as nanofillers for polymer
nanocomposites. It belongs to the family of 2:1
phyllosilicates and is a stretchable dioctahedral smectite.
Particles of Montmorillonite are made up of aluminosilicate
layers of 1nm thickness, with a regular interlayer gap. It has
a large surface area of 750 m2/g of, high aspect ratio 1:200
and low surface charge density of 0.25-0.5 equiv. mol-1 ,
because of interparticle force of attraction which help in
either intercalation/exfoliation1within the polymer system
and successfully used to improve thermal, mechanical,
barrier properties at very low loadings of <5wt% of
nanofillers. So MMT-based polymer nanocomposites are
widely used in aerospace, electronics, marine and
automotive industries.
R. Sridhar et.al [6], the properties of degradation and
moisture absorption through filler/vinylestercompositesin
artificial seawatermediumCloisiteNa isa naturallyavailable
nanoclay and Cloisite 15A an organomodifiednanoclaywere
studied to analyze the influence of organomodification on
the moisture1behavior of the nanocomposites processed by
using twin screw extrusion and ultrasonification,at5wt%of
Cloisite 15A dispersion in vinylester reduces the diffusivity
and permeability of the resin by 72% and 45% respectively
and for the Cloisite Na at 5wt% were reduces by 33% and
71% respectively and micro hardness decreases due to the
moisture diffusion of 8.68% and 16.8% respectively. T.S.
Roopa et.al [7], studied the relative performance of
polyester/glass and vinylester/glass laminates fabrication
done by resin transfer molding and hand lay-up techniques.
A resin transfer mold was fabricated and designed for
preparing the laminates. Void content is less in
resin1transfer molding specimens than in that of hand lay-
up, void content in resin transfer molding specimens was
1.4% in vinylester/glassand 0.8%inpolyester/glass.Yukiko
Nakahara [8], both 2 wt% clay reinforced nylon 6 and nylon
6 matrix nanocomposite were used for thermal exposure
tests at temperatures of 800C, 1200C and 1500C respectively.
N.Ragavendra et.al [9], nanoclay was originally modified by
cation exchange method and distributed in vinylester using
twin screw extrusion and ultrasonication using cationic
surfactant HDTMA-Br. XRD shows exfoliation at 4wt%
nanoclay of nanoclay/vinylester indicating that uniform
distribution in the polymer. T.P. Mohan et.al [10], to study
the sisal fiber reinforced polymerandthe watermassuptake
of nanoclay of the composites. Nanoclays at 1 wt%, 3 wt%,
and 5 wt% are synthesized with the epoxy-sisal fiber
composites and placed in water medium. At 5 wt% filler
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 44
filled composites the water transmission rate will decreased
by three times compared to unfilled composites.
2. MATERIALS
In this work the matrix material was used as epoxy resin
(Lapox L-12) and a room temperature hardener (K-6). The
matrix was gives good resistance alkali’s and has good
adhesive property. The Glass fiber having 0.26mm thick
(300GSM).
2.1 Preparation of composites
The glass-epoxy-nanoclay composite can be made from the
technique of hand lay-up as shown in Fig.1 This preparation
includes fibers-resin and montmorillonite nanomer 1.44p
sigma. Hardener is mix in resin with montmorillonite
nanomer 1.44p sigma to polymerize the polymer. Weighed
quantities of room temperature curing epoxy resin-
montmorillonite nanomer 1.44p sigma and hardener mix is
taken and applies on the glass fabric. On this, another1layer
of the glass fabric was put on previous done layer and the
process will be continued up required layers. The full
laminate is cover with the polythene sheet and pasted on
Vaseline for easy removal, for compactability was done by
vacuum pump so that solid network cross-linked polymer
with fiber get compacted, the vacuum pump was compress
about 40 pounds per square inch sothatexcessresinisallow
to come out. The laminate was heat at 1500C for 2 hours in
electric oven. The laminates size of (300 × 300 × 3) in mm
for preparation of the fiber - resin - montmorillonite
nanomer 1.44p sigma composites, fillers are made mixed
with a calculated amount of epoxy.
Fig.1 Hand lay-up method
The details of the composites prepared are to be shown in
Table 1 provides the data of volume fraction of the
composites, The table consists of composites,reinforcement
material in percent volume, matrix material in percent
volume and nanomer 1.44p sigma in percent volume, here
there are seven different types ofcompositesarethere,0.1%
decrement in reinforcement material, matrix material was
constant and 0.5% increment of the nanomer 1.44p sigma
nanoparticle.
Table 1 Volume fraction of the composites.
SL
NO
Composites Reinforcement
(% vol.)
Matrix
(%
vol.)
Nanomer
(% vol.)
1 Nanomer-A 60 % 40 % 0 %
2 Nanomer-B 59.5 % 40 % 0.5 %
3 Nanomer-C 59.0 % 40 % 1.0 %
4 Nanomer- D 58.5 % 40 % 1.5 %
5 Nanomer-E 58% 40 % 2%
6 Nanomer-F 57.5% 40 % 2.5%
7 Nanomer-G 57% 40 % 3%
2.2 Experimental work
Following characterization were conducted in this work.
 Density of composites
 FTIR
 TGA
 DTA
 Density of composites
The composite of a density based upon correctproportionof
the reinforcing, matrix materials and density is also
important test to determining the properties of the
laminates. The theoretical densities of the specimens are
calculated from the density of nanomer-1.44p sigma, epoxy
resin and E-glass fiber as 2.5, 1.29 and 2.48 g/cc,
respectively. The actual1density of the composite can
be1determined by experimentally by the simple water-
immersion technique as shown in the Fig.2
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 45
Fig.2 Water immersion technique
In water immersion techniquedevice,thedistilledwater was
taken into the beaker and placed on waterimmersiondevice
stand, the weighing pan was dipped into the beaker and the
different percentages of filler specimens are placed on the
weighing pan and measured the weight in air and measured
the weight in distilled water the output was taken from
display in grams, using both weighs in air and water also
with density of distilled water at room temperature density.
The information of void content tells how the quality of the
composites can be estimated. If higher the void content
means lower the fatigue resistance and greater the water
penetration.
 Fourier transform infrared spectroscopy
Fourier transform infrared spectroscopy analyses was
executed using PerkinElmer instruments, with the use of
nitrogen flow at a constant rate of 20 ml min-1. Samples of
20-25 mg was heated about 30 to 600 0C at 10 0C min-1 and it
was held for 4 min at 600 0C. The Fourier transform infrared
spectroscopy was linked with the furnace gas transfer line.
The volatiles are scanned in the range of 400-4000 cm-1
wavenumber range and at a resolution of about 4 cm-1. The
Fourier transform infrared spectra was recorded in the
percentages of transmittance with the different wave
number at a range 300 – 9000 cm-1. The Fourier transform
infrared spectroscopy as shown in Fig.3
Fig.3 Fourier transform infrared spectroscopy
Using this FTIR spectroscopy we have to find how the
bonding takes place and to determine the grafting of the
organic modifier on the clay surface. By taking different
percentages like 0%, 0.5%, 1%, 1.5%, 2%, 2.5%, 3%, of
laminates powder and that powderofabout20-25mg placed
in a small hole on the supporting plate after that knob will
rotate and lock the hole and finally in the output will get
graphs at different wave number v/s percentage in
transmittance.
 Thermal gravimetric analysis
Figure 4 shows the TGA instrument used for thermal
analysis. It is used to find the thickness of a polymer layer
around the nanoparticles and also it is used to find
decomposition temperature of polymer between the
samples. The weight ofa sampleiscontinuouslymeasuredas
a function of time and temperature. The test sample is kept
in microbalance and heated in controlled condition and
weight of the test sample is measured for all heating cycles.
Due to change in temperature or decomposition of sample
the change in weight occurs at specific temperatures. The
weight loss during the decomposition of sample in
experiment is due to amount ofpolymerthatwasattached to
the particles in a sample.
Fig.4 Thermal gravimetric analysis
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 46
TA instrument model Q 50 was used to carry TGA at
condition 250C to 7000C and heating rate of 100C/min in N2
atmosphere. Residual weight and thermal degradation
behavior are analyzed and studied using TGA.
 Differential thermal analysis
Differential thermal analysis it isa thermoanalytic technique
and it is similar to the differential scanning calorimetry. In
the differential thermal analysis the study ofmaterial andan
inert reference and they are made to undergo same thermal
cycles, during recording any temperaturebetween reference
and sample. These differential temperatures are plotted
against temperature or time. Changes takes place in the
sample either in the endothermic or exothermic in nature
and that can be detected relatively with the inert reference.
The differential thermal analysis instrumentasshowninthe
Fig 5
Fig 5 Differential thermal analysis
Differential thermal analysisthermogramorcurvegivesdata
of makeovers that have happened, such as crystallization,
glass transitions, sublimation and melting. The area under
the differential1thermal analysispeak providesthe enthalpy
change and that is not affected from the heat capacity of
sample.
3. RESULTS AND DISCUSSION
3.1 Density of composites
Graph:1 shows density of composities graphdrawn between
density and % of filler. In the graph Y-axis as density in
gm/cc, X-axis as % of filler matrial. For 0% of filler density is
2.208gm/cc, for addition of 0.5% of nanomer 1.44p sigma
the density is 2.264gm/cc, for addition of 1% of nanomer
1.44p sigma the density is 2.29gm/cc,for addition of 1.5%of
nanomer 1.44p sigma the densityis2.309gm/cc,foraddition
of 2% of nanomer 1.44p sigma the densityis2.339gm/cc,for
addition of 2.5% of nanomer 1.44p sigma the density is
2.344gm/cc, for addition of 3% of nanomer 1.44p sigma the
density is 2.356gm/cc. As the % of filler content incresesthe
density of the composites will also be increses.
Graph:1 Density of composities
3.2 Void content in percentage
Graph: 2 shows void content in percentage graph plotted as
void content in percentage versespercentageoffiller.For0%
of filler material the void content will be 10.179 %, for 0.5%
of filler material the void content will be 12.974 %, for 1% of
filler material the void content will be 14.271 %, for 1.5% of
filler material the void content will be 15.219 %, for 2% of
filler material the void content will be 16.716 %, for 2.5% of
filler material the void content will be 16.966 %, for 3% of
filler material the void content will be 17.564 %. As the filler
material nanomer 1.44p sigma increases for different seven
laminates the void content in percentage also increases and
important thing is only 15% of void content in acceptable
because more than that laminates will formed more number
of air particles so that up to 1% of filler material will be
ultimate.
Graph.2 Void content in percentage
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 47
3.3 Fourier transforms infrared spectroscopy
Graph: 3 shows FTIR graph plotted between transmittance
in % and wave number in cm-1. In the graph Y-axis shows
transmittance in % and X-axis shows wave number in cm-1.
Graph having different percentages of fillers from 0% to 3%
are been added.
Graph: 3 Fourier transform infrared spectroscopy
FTIR graph indicates the chemical bonding and vibration of
molecules present in different laminates. The peak in the
area at 2900 cm-1 shows OH group, at 1640 cm-1 also
indicates OH group in plane, at 2903 cm-1 indicatesCHgroup
in the fibre this group presence commoninall composites, at
1420 and 1370 cm-1 indicates CH2 and CH3 groups in
laminates, at 1240 and 690 cm-1 indicates epoxideringof the
epoxy resin.
3.4 Thermo-gravimetric analysis
Graph: 4 shows TGA graph for 0% laminate. The graph
plotted TG in % as Y-axis and temperature in degree Celsius
as X-axis.
Created with NETZSCH Proteus software
Project :
Identity :
Date/time :
Laboratory :
Operator :
Sample :
A
16-08-2017 14:39:45
A, 22.335 mg
Material :
Correction file :
Temp.Cal./Sens. Files :
Range :
Sample car./TC :
Mode/type of meas. :
POWDER
TempCal 23.03.2017.ngb-ts4 / SensCal 24.03.2017.ngb-es4
30°C/10.0(K/min)/600°C
DTA/TG Std S / S
DTA-TG / Sample
Segments :
Crucible :
Atmosphere :
TG corr./m. range :
DSC corr./m. range :
1/1
Al2O3 pan for STA2500
N2 / N2
000/500 mg
000/
Instrument : NETZSCH STA 2500 STA2500A-0027-N File : C:NETZSCHProteus61dataMAY 2016ANNAPAAA.ngb-ss4
100 200 300 400 500
Temperature /°C
75
80
85
90
95
100
TG /%
Main 2017-08-21 11:11 User: Admin
[1] A.ngb-ss4
TG
Peak: 37.4 °C, 99.83 %Peak: 121.6 °C, 99.45 %
Peak: 271.5 °C, 98.40 %
Peak: 348.7 °C, 91.43 %
Peak: 481.4 °C, 83.85 %
Peak: 585.0 °C, 76.26 %Residual Mass: 76.24 % (599.5 °C)
[1]
Graph: 4 TGA for 0%
The condition of this TGA experiment carried out in N2
atmosphere, the temperature range 300C- 6000C at flow rate
of 10 K/min, the crucible is Al2O3 pan and sample was taken
as 22.335 mg. At peak 99.83 % of TG the temperature will be
37.40C, for99.45 % of TG thetemperaturewillbe121.60C,for
98.40 % of TG the temperature willbe271.50C,for91.43%of
TG the temperature will be 348.70C, for 83.85 % of TG the
temperature will be 481.40C, for 76.26% of TG the
temperature will be 5850C, from the above graph shows as
the temperature increases the TG will be decreased and
finally the residual mass willbe76.24%ofTGattemperature
599.50C.
Graph: 5 shows TGA graph for 0.5 % laminate. The graph
plotted TG in % as Y-axis and temperature in degree Celsius
as X-axis. The condition of this TGA experiment carried out
in N2 atmosphere, thetemperaturerange300C-6000Catflow
rate of 10 K/min, the crucible is Al2O3 pan and sample was
taken as 22.335 mg. At peak 100.09 % of TGthetemperature
will be 23.30C, for 98.91 % of TG the temperature will be
258.90C, for 87.88 % of TG the temperature will be 380.40C,
for 78.67 % of TG the temperature will be 507.70C, for 73.26
% of TG the temperature will be 557.70C, for 72.41% of TG
the temperature will be 590.60C, from the above graph
shows as the temperature increasesthe TGwill bedecreased
and finally the residual mass will be 72.37 % of TG at
temperature 599.50C.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 48
Created with NETZSCH Proteus software
Project :
Identity:
Date/time :
Laboratory:
Operator :
Sample :
B
17-08-2017 12:31:03
B, 18.556 mg
Material :
Correction file :
Temp.Cal./Sens. Files :
Range :
Sample car./TC :
Mode/type of meas. :
POWDER
TempCal 23.03.2017.ngb-ts4 / SensCal 24.03.2017.ngb-es4
30°C/10.0(K/min)/600°C
DTA/TG Std S / S
DTA-TG / Sample
Segments :
Crucible :
Atmosphere :
TG corr./m. range :
DSC corr./m. range :
1/1
Al2O3 pan for STA2500
N2 / N2
000/500 mg
000/
Instrument : NETZSCH STA 2500 STA2500A-0027-N File : C:NETZSCHProteus61dataMAY 2016ANNAPABB.ngb-ss4
100 200 300 400 500
Temperature /°C
75
80
85
90
95
100
TG /%
Main 2017-08-21 11:14 User: Admin
[1] B.ngb-ss4
TG
Peak: 23.3 °C, 100.09 %
Peak: 258.9 °C, 98.91 %
Peak: 380.4 °C, 87.98 %
Peak: 507.7 °C, 78.67 %
Peak: 557.7 °C, 73.26 %
Peak: 590.6 °C, 72.41 %
Residual Mass: 72.37 % (599.5 °C) [1]
Graph: 5 TGA for 0.5%
3.5 Differential thermal analysis
Graph: 6 shows DTA graph for 0 % laminate. The graph
plotted DTA in mW/mg as Y-axis and temperature in degree
Celsius as X-axis. The condition of this DTA experiment
carried out in N2 atmosphere, the temperature range 300C-
6000C at flow rate of 10 K/min, the crucible is Al2O3 pan and
sample was taken as 22.335 mg. At peak -0.476 mW/mg of
DTA the temperature will be 23.4, for -0.421 mW/mgofDTA
the temperature will be 60.10C, for -0.856 mW/mg of DTA
the temperature will be 199.70C, for -2.229 mW/mg of DTA
the temperature will be 280.20C, for -2.359 mW/mg of DTA
the temperature will be 287.80C, for -1.835mW/mg of DTA
the temperature will be 326.20C, for -2.418 mW/mg of DTA
the temperature will be 429.30C, for -2.340 mW/mg of DTA
the temperature will be 476.80C, from the above graph
shows as the temperature increases, the DTA will be
decreased or increased, finally the sample mass will get
decreased.
Graph: 6 DTA for 0%
Graph: 7 shows DTA graph for 0.5 % laminate. The graph
plotted DTA in mW/mg as Y-axis and temperature in degree
Celsius as X-axis.
Created with NETZSCH Proteus software
Project :
Identity :
Date/time :
Laboratory :
Operator :
Sample :
B
17-08-2017 12:31:03
B, 18.556 mg
Material :
Correction file :
Temp.Cal./Sens. Files :
Range :
Sample car./TC :
Mode/type of meas. :
POWDER
TempCal 23.03.2017.ngb-ts4 / SensCal 24.03.2017.ngb-es4
30°C/10.0(K/min)/600°C
DTA/TG Std S / S
DTA-TG / Sample
Segments :
Crucible :
Atmosphere :
TG corr./m. range :
DSC corr./m. range :
1/1
Al2O3 pan for STA2500
N2 / N2
000/500 mg
000/
Instrument : NETZSCH STA 2500 STA2500A-0027-N File : C:NETZSCHProteus61dataMAY 2016ANNAPABB.ngb-ss4
100 200 300 400 500
Temperature /°C
-3.5
-3.0
-2.5
-2.0
-1.5
-1.0
-0.5
DTA /(mW/mg)
Main 2017-08-21 11:15 User: Admin
[1] B.ngb-ss4
DTA
Peak: 23.2 °C, -0.536 mW/mg
Peak: 38.3 °C, -0.444 mW/mgPeak: 38.3 °C, -0.444 mW/mg
Peak: 156.5 °C, -1.019 mW/mg
Peak: 244.5 °C, -1.604 mW/mg
Peak: 286.5 °C, -3.039 mW/mg
Peak: 324.7 °C, -2.436 mW/mg
Peak: 405.1 °C, -3.066 mW/mg
Peak: 423.8 °C, -3.228 mW/mg
Peak: 459.9 °C, -2.919 mW/mg
Peak: 517.9 °C, -3.626 mW/mg
Peak: 562.8 °C, -1.985 mW/mg
[1]
↓ exo
Graph: 7 DTA for 0.5%
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 49
The condition of this DTA experiment carried out in N2
atmosphere, the temperature range 300C- 6000C atflowrate
of 10 K/min, the crucible is Al2O3 pan and sample was taken
as 22.335 mg. At peak -0.536 mW/mg of DTA the
temperature will be 23.2, for -0.444 mW/mg of DTA the
temperature will be 38.30C, for -1.019 mW/mg of DTA the
temperature will be 156.50C, for -1.604 mW/mg of DTA the
temperature will be 244.50C, for -3.039 mW/mg of DTA the
temperature will be 286.50C, for -2.436mW/mg of DTA the
temperature will be 324.70C, for -2.919 mW/mg of DTA the
temperature will be 459.90C, for -3.228 mW/mg of DTA the
temperature will be 423.80C, from the above graphshowsas
the temperature increases, the DTA will be decreased or
increased, finally the sample mass will get decreased.
3. CONCLUSIONS
In this present work, glass-epoxy-montmorillonite k-10
nanomer1.44p sigma nanocomposite material was selected
for thermal characterization tests from tests following
conclusions were made. Fabrication of glass/epoxy
composites with and without nanoparticle was done using
hand-layup technique.
Density and void test was carried out for different
percentages of filler material with a difference of 0.5% and
density and void will increase with nanomer 1.44p sigma.
FTIR was carried outusingIR spectroscopyinstrumentusing
the all spectra found the chemical bonding nature at
different peaks of the laminates. TGA was carried out using
TG instrument found the thermal behavior of the sample
with the temperature. DTA was carried out using DTA
instrument found the thermal behavior of the sample with
different temperature for the different laminates.
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properties of nanoclay filled sisal fibre reinforced
epoxy composites." Composites Part A: Applied
Science and Manufacturing 42.4 (2011): 385-393.
BIOGRAPHIES
Mr. Ganesha Tiscurrently working
as Assistant Professor in
Department of Studies in
Mechanical Engineering, PG-
Program Thermal Power
Engineering, Visvesvaraya
Technical university- Belagavi,
Center for Post Graduate Studies,
Mysuru, Karnataka, India. And his
subjects include Thermodynamics,
Fluid Mechanics, Thermal
Engineering, Refrigeration and Air-
Conditioning and Heat Transfer. As
well as he has done more than 22
International and National
publications.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 50
Mr. Sharathkumara k was
graduated in Mechanical
Engineering from RYMEC, BALLARI
and perusing M-Tech in Thermal
Power Engineering, Centre for PG
studies, VTU Mysuru. Karnataka.
Mr. Mahendra T K is working as
Lecturer inMechanical Engineering,
Govt CPC Polytechnic, Mysuru
Completed his graduation from
University BDT college of
Engineering, his areas of interest
are Composite materials, Finite
element method, Thermal
engineering. He was submitted one
international paper on ERP.

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IRJET-TITLE

  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 43 Influence of organomodified nanoclay on the thermomechanical behavior of glass/epoxy nanocomposites Ganesha T1, Sharathkumara k2, Mahendra T K3 1Assitant professor, Dept. of Thermal Power Engineering, Centre for PG studies, VTU Mysuru, India 2M.Tech graduate, Dept. of Thermal Power Engineering, Centre for PG studies, VTU Mysuru, India 3Lecturer, Dept. of Mechanical Engineering, Govt. CPC Polytechnic, Mysuru, India -----------------------------------------------------------------------------***---------------------------------------------------------------------------- Abstract - Glass fibre-reinforced epoxy resin (GFRE) composites filled with MMT (K-10) nanomer 1.44P sigma powder were fabricated, and their mechanical and thermal properties were investigated. It is observed that with the increasing percentage of MMT (K-10) nanomer 1.44P sigma particles, there is a significant enhancement in density of the composite and void content of the composite, but there is a decline in tensile strength. Experimental results demonstrate that the GFRE composites with 3 wt%ofMMT(K-10) nanomer 1.44P sigma loading show maximum density of 2.356 gm/cc with void content in percentage of 17.564%, but up to 1 wt% loading void content in percentage of 14.271% could exempted, FTIR studies in the range of wavenumber500-4000 cm-1, found OH, CH, CH2 and CH3 group with different stretching vibration in IR spectra, TGA and DTA studies were conducted to observe thermogram and thermal behavior of the sample. Key Words: Epoxy resin, MMT (K-10) nanomer 1.44P sigma, glass fibre, hand-lay-up technique, GFRE composites. 1. INTRODUCTION Polymer matrix composite (PMC) materials having good thermal conductivity and mechanical strength are largely used in different areas. Properties of a composite can be improved by adding material to the matrix. Due to the properties like high specific strength, stiffness, good dielectric and resistance to corrosion of Glass fiber- reinforced polymer (GFRP) these composites are used in aerospace,1automobile industries, armor, microelectronic packaging, marine, civil engineering structures, electronic circuit board,sportsgoods,railwaysetc [1-3].Thermosetting epoxy resin based composites have many application because of its high thermal stability, low cost and moisture resistance. Due to curing of epoxy the thermal conductivity of epoxy is reduced and thermal expansion coefficient(CTE) can be increased [4]. Fused quartz or silica is used to reinforce the ceramic powder to lower the thermal expansion of epoxy to match to that of semiconductor dies and lead frames [5]. PMC contains polymer or copolymer having Nano fillers or nanoparticles dispersed in the polymer matrix. Montmorillonite is used as nanofillers for polymer nanocomposites. It belongs to the family of 2:1 phyllosilicates and is a stretchable dioctahedral smectite. Particles of Montmorillonite are made up of aluminosilicate layers of 1nm thickness, with a regular interlayer gap. It has a large surface area of 750 m2/g of, high aspect ratio 1:200 and low surface charge density of 0.25-0.5 equiv. mol-1 , because of interparticle force of attraction which help in either intercalation/exfoliation1within the polymer system and successfully used to improve thermal, mechanical, barrier properties at very low loadings of <5wt% of nanofillers. So MMT-based polymer nanocomposites are widely used in aerospace, electronics, marine and automotive industries. R. Sridhar et.al [6], the properties of degradation and moisture absorption through filler/vinylestercompositesin artificial seawatermediumCloisiteNa isa naturallyavailable nanoclay and Cloisite 15A an organomodifiednanoclaywere studied to analyze the influence of organomodification on the moisture1behavior of the nanocomposites processed by using twin screw extrusion and ultrasonification,at5wt%of Cloisite 15A dispersion in vinylester reduces the diffusivity and permeability of the resin by 72% and 45% respectively and for the Cloisite Na at 5wt% were reduces by 33% and 71% respectively and micro hardness decreases due to the moisture diffusion of 8.68% and 16.8% respectively. T.S. Roopa et.al [7], studied the relative performance of polyester/glass and vinylester/glass laminates fabrication done by resin transfer molding and hand lay-up techniques. A resin transfer mold was fabricated and designed for preparing the laminates. Void content is less in resin1transfer molding specimens than in that of hand lay- up, void content in resin transfer molding specimens was 1.4% in vinylester/glassand 0.8%inpolyester/glass.Yukiko Nakahara [8], both 2 wt% clay reinforced nylon 6 and nylon 6 matrix nanocomposite were used for thermal exposure tests at temperatures of 800C, 1200C and 1500C respectively. N.Ragavendra et.al [9], nanoclay was originally modified by cation exchange method and distributed in vinylester using twin screw extrusion and ultrasonication using cationic surfactant HDTMA-Br. XRD shows exfoliation at 4wt% nanoclay of nanoclay/vinylester indicating that uniform distribution in the polymer. T.P. Mohan et.al [10], to study the sisal fiber reinforced polymerandthe watermassuptake of nanoclay of the composites. Nanoclays at 1 wt%, 3 wt%, and 5 wt% are synthesized with the epoxy-sisal fiber composites and placed in water medium. At 5 wt% filler
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 44 filled composites the water transmission rate will decreased by three times compared to unfilled composites. 2. MATERIALS In this work the matrix material was used as epoxy resin (Lapox L-12) and a room temperature hardener (K-6). The matrix was gives good resistance alkali’s and has good adhesive property. The Glass fiber having 0.26mm thick (300GSM). 2.1 Preparation of composites The glass-epoxy-nanoclay composite can be made from the technique of hand lay-up as shown in Fig.1 This preparation includes fibers-resin and montmorillonite nanomer 1.44p sigma. Hardener is mix in resin with montmorillonite nanomer 1.44p sigma to polymerize the polymer. Weighed quantities of room temperature curing epoxy resin- montmorillonite nanomer 1.44p sigma and hardener mix is taken and applies on the glass fabric. On this, another1layer of the glass fabric was put on previous done layer and the process will be continued up required layers. The full laminate is cover with the polythene sheet and pasted on Vaseline for easy removal, for compactability was done by vacuum pump so that solid network cross-linked polymer with fiber get compacted, the vacuum pump was compress about 40 pounds per square inch sothatexcessresinisallow to come out. The laminate was heat at 1500C for 2 hours in electric oven. The laminates size of (300 × 300 × 3) in mm for preparation of the fiber - resin - montmorillonite nanomer 1.44p sigma composites, fillers are made mixed with a calculated amount of epoxy. Fig.1 Hand lay-up method The details of the composites prepared are to be shown in Table 1 provides the data of volume fraction of the composites, The table consists of composites,reinforcement material in percent volume, matrix material in percent volume and nanomer 1.44p sigma in percent volume, here there are seven different types ofcompositesarethere,0.1% decrement in reinforcement material, matrix material was constant and 0.5% increment of the nanomer 1.44p sigma nanoparticle. Table 1 Volume fraction of the composites. SL NO Composites Reinforcement (% vol.) Matrix (% vol.) Nanomer (% vol.) 1 Nanomer-A 60 % 40 % 0 % 2 Nanomer-B 59.5 % 40 % 0.5 % 3 Nanomer-C 59.0 % 40 % 1.0 % 4 Nanomer- D 58.5 % 40 % 1.5 % 5 Nanomer-E 58% 40 % 2% 6 Nanomer-F 57.5% 40 % 2.5% 7 Nanomer-G 57% 40 % 3% 2.2 Experimental work Following characterization were conducted in this work.  Density of composites  FTIR  TGA  DTA  Density of composites The composite of a density based upon correctproportionof the reinforcing, matrix materials and density is also important test to determining the properties of the laminates. The theoretical densities of the specimens are calculated from the density of nanomer-1.44p sigma, epoxy resin and E-glass fiber as 2.5, 1.29 and 2.48 g/cc, respectively. The actual1density of the composite can be1determined by experimentally by the simple water- immersion technique as shown in the Fig.2
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 45 Fig.2 Water immersion technique In water immersion techniquedevice,thedistilledwater was taken into the beaker and placed on waterimmersiondevice stand, the weighing pan was dipped into the beaker and the different percentages of filler specimens are placed on the weighing pan and measured the weight in air and measured the weight in distilled water the output was taken from display in grams, using both weighs in air and water also with density of distilled water at room temperature density. The information of void content tells how the quality of the composites can be estimated. If higher the void content means lower the fatigue resistance and greater the water penetration.  Fourier transform infrared spectroscopy Fourier transform infrared spectroscopy analyses was executed using PerkinElmer instruments, with the use of nitrogen flow at a constant rate of 20 ml min-1. Samples of 20-25 mg was heated about 30 to 600 0C at 10 0C min-1 and it was held for 4 min at 600 0C. The Fourier transform infrared spectroscopy was linked with the furnace gas transfer line. The volatiles are scanned in the range of 400-4000 cm-1 wavenumber range and at a resolution of about 4 cm-1. The Fourier transform infrared spectra was recorded in the percentages of transmittance with the different wave number at a range 300 – 9000 cm-1. The Fourier transform infrared spectroscopy as shown in Fig.3 Fig.3 Fourier transform infrared spectroscopy Using this FTIR spectroscopy we have to find how the bonding takes place and to determine the grafting of the organic modifier on the clay surface. By taking different percentages like 0%, 0.5%, 1%, 1.5%, 2%, 2.5%, 3%, of laminates powder and that powderofabout20-25mg placed in a small hole on the supporting plate after that knob will rotate and lock the hole and finally in the output will get graphs at different wave number v/s percentage in transmittance.  Thermal gravimetric analysis Figure 4 shows the TGA instrument used for thermal analysis. It is used to find the thickness of a polymer layer around the nanoparticles and also it is used to find decomposition temperature of polymer between the samples. The weight ofa sampleiscontinuouslymeasuredas a function of time and temperature. The test sample is kept in microbalance and heated in controlled condition and weight of the test sample is measured for all heating cycles. Due to change in temperature or decomposition of sample the change in weight occurs at specific temperatures. The weight loss during the decomposition of sample in experiment is due to amount ofpolymerthatwasattached to the particles in a sample. Fig.4 Thermal gravimetric analysis
  • 4. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 46 TA instrument model Q 50 was used to carry TGA at condition 250C to 7000C and heating rate of 100C/min in N2 atmosphere. Residual weight and thermal degradation behavior are analyzed and studied using TGA.  Differential thermal analysis Differential thermal analysis it isa thermoanalytic technique and it is similar to the differential scanning calorimetry. In the differential thermal analysis the study ofmaterial andan inert reference and they are made to undergo same thermal cycles, during recording any temperaturebetween reference and sample. These differential temperatures are plotted against temperature or time. Changes takes place in the sample either in the endothermic or exothermic in nature and that can be detected relatively with the inert reference. The differential thermal analysis instrumentasshowninthe Fig 5 Fig 5 Differential thermal analysis Differential thermal analysisthermogramorcurvegivesdata of makeovers that have happened, such as crystallization, glass transitions, sublimation and melting. The area under the differential1thermal analysispeak providesthe enthalpy change and that is not affected from the heat capacity of sample. 3. RESULTS AND DISCUSSION 3.1 Density of composites Graph:1 shows density of composities graphdrawn between density and % of filler. In the graph Y-axis as density in gm/cc, X-axis as % of filler matrial. For 0% of filler density is 2.208gm/cc, for addition of 0.5% of nanomer 1.44p sigma the density is 2.264gm/cc, for addition of 1% of nanomer 1.44p sigma the density is 2.29gm/cc,for addition of 1.5%of nanomer 1.44p sigma the densityis2.309gm/cc,foraddition of 2% of nanomer 1.44p sigma the densityis2.339gm/cc,for addition of 2.5% of nanomer 1.44p sigma the density is 2.344gm/cc, for addition of 3% of nanomer 1.44p sigma the density is 2.356gm/cc. As the % of filler content incresesthe density of the composites will also be increses. Graph:1 Density of composities 3.2 Void content in percentage Graph: 2 shows void content in percentage graph plotted as void content in percentage versespercentageoffiller.For0% of filler material the void content will be 10.179 %, for 0.5% of filler material the void content will be 12.974 %, for 1% of filler material the void content will be 14.271 %, for 1.5% of filler material the void content will be 15.219 %, for 2% of filler material the void content will be 16.716 %, for 2.5% of filler material the void content will be 16.966 %, for 3% of filler material the void content will be 17.564 %. As the filler material nanomer 1.44p sigma increases for different seven laminates the void content in percentage also increases and important thing is only 15% of void content in acceptable because more than that laminates will formed more number of air particles so that up to 1% of filler material will be ultimate. Graph.2 Void content in percentage
  • 5. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 47 3.3 Fourier transforms infrared spectroscopy Graph: 3 shows FTIR graph plotted between transmittance in % and wave number in cm-1. In the graph Y-axis shows transmittance in % and X-axis shows wave number in cm-1. Graph having different percentages of fillers from 0% to 3% are been added. Graph: 3 Fourier transform infrared spectroscopy FTIR graph indicates the chemical bonding and vibration of molecules present in different laminates. The peak in the area at 2900 cm-1 shows OH group, at 1640 cm-1 also indicates OH group in plane, at 2903 cm-1 indicatesCHgroup in the fibre this group presence commoninall composites, at 1420 and 1370 cm-1 indicates CH2 and CH3 groups in laminates, at 1240 and 690 cm-1 indicates epoxideringof the epoxy resin. 3.4 Thermo-gravimetric analysis Graph: 4 shows TGA graph for 0% laminate. The graph plotted TG in % as Y-axis and temperature in degree Celsius as X-axis. Created with NETZSCH Proteus software Project : Identity : Date/time : Laboratory : Operator : Sample : A 16-08-2017 14:39:45 A, 22.335 mg Material : Correction file : Temp.Cal./Sens. Files : Range : Sample car./TC : Mode/type of meas. : POWDER TempCal 23.03.2017.ngb-ts4 / SensCal 24.03.2017.ngb-es4 30°C/10.0(K/min)/600°C DTA/TG Std S / S DTA-TG / Sample Segments : Crucible : Atmosphere : TG corr./m. range : DSC corr./m. range : 1/1 Al2O3 pan for STA2500 N2 / N2 000/500 mg 000/ Instrument : NETZSCH STA 2500 STA2500A-0027-N File : C:NETZSCHProteus61dataMAY 2016ANNAPAAA.ngb-ss4 100 200 300 400 500 Temperature /°C 75 80 85 90 95 100 TG /% Main 2017-08-21 11:11 User: Admin [1] A.ngb-ss4 TG Peak: 37.4 °C, 99.83 %Peak: 121.6 °C, 99.45 % Peak: 271.5 °C, 98.40 % Peak: 348.7 °C, 91.43 % Peak: 481.4 °C, 83.85 % Peak: 585.0 °C, 76.26 %Residual Mass: 76.24 % (599.5 °C) [1] Graph: 4 TGA for 0% The condition of this TGA experiment carried out in N2 atmosphere, the temperature range 300C- 6000C at flow rate of 10 K/min, the crucible is Al2O3 pan and sample was taken as 22.335 mg. At peak 99.83 % of TG the temperature will be 37.40C, for99.45 % of TG thetemperaturewillbe121.60C,for 98.40 % of TG the temperature willbe271.50C,for91.43%of TG the temperature will be 348.70C, for 83.85 % of TG the temperature will be 481.40C, for 76.26% of TG the temperature will be 5850C, from the above graph shows as the temperature increases the TG will be decreased and finally the residual mass willbe76.24%ofTGattemperature 599.50C. Graph: 5 shows TGA graph for 0.5 % laminate. The graph plotted TG in % as Y-axis and temperature in degree Celsius as X-axis. The condition of this TGA experiment carried out in N2 atmosphere, thetemperaturerange300C-6000Catflow rate of 10 K/min, the crucible is Al2O3 pan and sample was taken as 22.335 mg. At peak 100.09 % of TGthetemperature will be 23.30C, for 98.91 % of TG the temperature will be 258.90C, for 87.88 % of TG the temperature will be 380.40C, for 78.67 % of TG the temperature will be 507.70C, for 73.26 % of TG the temperature will be 557.70C, for 72.41% of TG the temperature will be 590.60C, from the above graph shows as the temperature increasesthe TGwill bedecreased and finally the residual mass will be 72.37 % of TG at temperature 599.50C.
  • 6. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 48 Created with NETZSCH Proteus software Project : Identity: Date/time : Laboratory: Operator : Sample : B 17-08-2017 12:31:03 B, 18.556 mg Material : Correction file : Temp.Cal./Sens. Files : Range : Sample car./TC : Mode/type of meas. : POWDER TempCal 23.03.2017.ngb-ts4 / SensCal 24.03.2017.ngb-es4 30°C/10.0(K/min)/600°C DTA/TG Std S / S DTA-TG / Sample Segments : Crucible : Atmosphere : TG corr./m. range : DSC corr./m. range : 1/1 Al2O3 pan for STA2500 N2 / N2 000/500 mg 000/ Instrument : NETZSCH STA 2500 STA2500A-0027-N File : C:NETZSCHProteus61dataMAY 2016ANNAPABB.ngb-ss4 100 200 300 400 500 Temperature /°C 75 80 85 90 95 100 TG /% Main 2017-08-21 11:14 User: Admin [1] B.ngb-ss4 TG Peak: 23.3 °C, 100.09 % Peak: 258.9 °C, 98.91 % Peak: 380.4 °C, 87.98 % Peak: 507.7 °C, 78.67 % Peak: 557.7 °C, 73.26 % Peak: 590.6 °C, 72.41 % Residual Mass: 72.37 % (599.5 °C) [1] Graph: 5 TGA for 0.5% 3.5 Differential thermal analysis Graph: 6 shows DTA graph for 0 % laminate. The graph plotted DTA in mW/mg as Y-axis and temperature in degree Celsius as X-axis. The condition of this DTA experiment carried out in N2 atmosphere, the temperature range 300C- 6000C at flow rate of 10 K/min, the crucible is Al2O3 pan and sample was taken as 22.335 mg. At peak -0.476 mW/mg of DTA the temperature will be 23.4, for -0.421 mW/mgofDTA the temperature will be 60.10C, for -0.856 mW/mg of DTA the temperature will be 199.70C, for -2.229 mW/mg of DTA the temperature will be 280.20C, for -2.359 mW/mg of DTA the temperature will be 287.80C, for -1.835mW/mg of DTA the temperature will be 326.20C, for -2.418 mW/mg of DTA the temperature will be 429.30C, for -2.340 mW/mg of DTA the temperature will be 476.80C, from the above graph shows as the temperature increases, the DTA will be decreased or increased, finally the sample mass will get decreased. Graph: 6 DTA for 0% Graph: 7 shows DTA graph for 0.5 % laminate. The graph plotted DTA in mW/mg as Y-axis and temperature in degree Celsius as X-axis. Created with NETZSCH Proteus software Project : Identity : Date/time : Laboratory : Operator : Sample : B 17-08-2017 12:31:03 B, 18.556 mg Material : Correction file : Temp.Cal./Sens. Files : Range : Sample car./TC : Mode/type of meas. : POWDER TempCal 23.03.2017.ngb-ts4 / SensCal 24.03.2017.ngb-es4 30°C/10.0(K/min)/600°C DTA/TG Std S / S DTA-TG / Sample Segments : Crucible : Atmosphere : TG corr./m. range : DSC corr./m. range : 1/1 Al2O3 pan for STA2500 N2 / N2 000/500 mg 000/ Instrument : NETZSCH STA 2500 STA2500A-0027-N File : C:NETZSCHProteus61dataMAY 2016ANNAPABB.ngb-ss4 100 200 300 400 500 Temperature /°C -3.5 -3.0 -2.5 -2.0 -1.5 -1.0 -0.5 DTA /(mW/mg) Main 2017-08-21 11:15 User: Admin [1] B.ngb-ss4 DTA Peak: 23.2 °C, -0.536 mW/mg Peak: 38.3 °C, -0.444 mW/mgPeak: 38.3 °C, -0.444 mW/mg Peak: 156.5 °C, -1.019 mW/mg Peak: 244.5 °C, -1.604 mW/mg Peak: 286.5 °C, -3.039 mW/mg Peak: 324.7 °C, -2.436 mW/mg Peak: 405.1 °C, -3.066 mW/mg Peak: 423.8 °C, -3.228 mW/mg Peak: 459.9 °C, -2.919 mW/mg Peak: 517.9 °C, -3.626 mW/mg Peak: 562.8 °C, -1.985 mW/mg [1] ↓ exo Graph: 7 DTA for 0.5%
  • 7. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 49 The condition of this DTA experiment carried out in N2 atmosphere, the temperature range 300C- 6000C atflowrate of 10 K/min, the crucible is Al2O3 pan and sample was taken as 22.335 mg. At peak -0.536 mW/mg of DTA the temperature will be 23.2, for -0.444 mW/mg of DTA the temperature will be 38.30C, for -1.019 mW/mg of DTA the temperature will be 156.50C, for -1.604 mW/mg of DTA the temperature will be 244.50C, for -3.039 mW/mg of DTA the temperature will be 286.50C, for -2.436mW/mg of DTA the temperature will be 324.70C, for -2.919 mW/mg of DTA the temperature will be 459.90C, for -3.228 mW/mg of DTA the temperature will be 423.80C, from the above graphshowsas the temperature increases, the DTA will be decreased or increased, finally the sample mass will get decreased. 3. CONCLUSIONS In this present work, glass-epoxy-montmorillonite k-10 nanomer1.44p sigma nanocomposite material was selected for thermal characterization tests from tests following conclusions were made. Fabrication of glass/epoxy composites with and without nanoparticle was done using hand-layup technique. Density and void test was carried out for different percentages of filler material with a difference of 0.5% and density and void will increase with nanomer 1.44p sigma. FTIR was carried outusingIR spectroscopyinstrumentusing the all spectra found the chemical bonding nature at different peaks of the laminates. TGA was carried out using TG instrument found the thermal behavior of the sample with the temperature. DTA was carried out using DTA instrument found the thermal behavior of the sample with different temperature for the different laminates. REFERENCES 1. Yung, K. C., et al. "Effect of AlN content on the performance of brominated epoxy resin for printed circuit board substrate." Journal ofPolymer Science Part B: Polymer Physics 45.13 (2007): 1662-1674. 2. Toldy, A., B. Szolnoki, and Gy Marosi. "Flame retardancy of fibre-reinforced epoxy resin composites for aerospace applications." Polymer Degradation and Stability 96.3 (2011): 371-376. 3. Lu, Shaorong, Jianfeng Ban, and Kuo Liu. "Preparation and characterization of liquid crystalline polyurethane/Al2O3/epoxy resin composites for electronic packaging." International Journal of Polymer Science 2012 (2011). 4. Kim, Wonho, et al. "Thermally conductive EMC (epoxy molding compound) for microelectronic encapsulation." PolymerEngineering&Science 39.4 (1999): 756-766. 5. Weltevreden, E. R., et al. "A multi-scale approach of the thermo-mechanical properties of silica-filled epoxies used in electronic packaging." Microelectronics Reliability 52.7 (2012): 1300-1305. 6. Sridhar, R., et al. "Moisture diffusion through nanoclay/vinylester processed using twin‐screw extrusion." Journal of Vinyl and Additive Technology 20.3 (2014): 152-159. 7. Roopa, T. S., et al. "Mechanical properties of vinylester/glass and polyester/glass composites fabricated by resin transfer molding and hand lay‐up." Journal of Vinyl and Additive Technology 21.3 (2015): 166-173. 8. Nakahara, Yukiko, et al. "EffectofThermal Exposure on Tensile and Fatigue Properties of Clay Reinforced Nylon Nanocomposites." Materials Science Forum. Vol. 833. Trans Tech Publications, 2015. 9. Raghavendra, N., et al. "Mechanical behavior of organo-modified Indian bentonite nanoclay fiber- reinforced plastic nanocomposites." Frontiers of Materials Science 7.4 (2013): 396-404. 10. Mohan, T. P., and K. Kanny. "Water barrier properties of nanoclay filled sisal fibre reinforced epoxy composites." Composites Part A: Applied Science and Manufacturing 42.4 (2011): 385-393. BIOGRAPHIES Mr. Ganesha Tiscurrently working as Assistant Professor in Department of Studies in Mechanical Engineering, PG- Program Thermal Power Engineering, Visvesvaraya Technical university- Belagavi, Center for Post Graduate Studies, Mysuru, Karnataka, India. And his subjects include Thermodynamics, Fluid Mechanics, Thermal Engineering, Refrigeration and Air- Conditioning and Heat Transfer. As well as he has done more than 22 International and National publications.
  • 8. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 04 Issue: 09 | Sep -2017 www.irjet.net p-ISSN: 2395-0072 © 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 50 Mr. Sharathkumara k was graduated in Mechanical Engineering from RYMEC, BALLARI and perusing M-Tech in Thermal Power Engineering, Centre for PG studies, VTU Mysuru. Karnataka. Mr. Mahendra T K is working as Lecturer inMechanical Engineering, Govt CPC Polytechnic, Mysuru Completed his graduation from University BDT college of Engineering, his areas of interest are Composite materials, Finite element method, Thermal engineering. He was submitted one international paper on ERP.