This document discusses a study that investigated the effects of different types and amounts of carbon black filler on the mechanical and physical properties of butadiene acrylonitrile rubber (NBR). Five types of carbon black (ISAF, HAF, FEF, GPF, SRF) were incorporated into NBR at concentrations from 0 to 100 parts per hundred rubber. The Young's modulus was found to increase with the carbon black content for all filler types. Percolation thresholds were detected in both the mechanical and physical behavior. Oxygen ion beam irradiation was also found to further increase the Young's modulus of NBR nanocomposites by 2-3 times for samples near the percolation threshold loading.
The effect of functionalized carbon nanotubes on thermalmechanical performanc...journal ijrtem
The new approaches for preparing nanocomposite coating by modificated carbon nanonotubes
(CNTs) and epoxy resin was done in the study. thermal-mechanical performance of nanocomposite coating was
investigated and the results were reported in this paper. The physic-chemical techniques such as Differential
scanning calorimetry (DSC) and Thermal gravimetric analysis (TGA) were used to characterize the thermal
performance of Epoxy nanocomposite coating. The test techniques for mechanical properties of paint coating as
adhesion, hardness, impact resistance and bending strength were employed in the work. The results indicated
that CNTs were dispersed in epoxy coating with only ratio of 0.1 wt% enhanced the Glass Transition
Temperature (Tg), decomposition temperature of epoxy coating and improved mechanical properties
significantly. Also functionalized CNTs can be reinforced thermal-mechanical of the epoxy coating better than
neat CNTs.
The effect of functionalized carbon nanotubes on thermalmechanical performanc...journal ijrtem
The new approaches for preparing nanocomposite coating by modificated carbon nanonotubes
(CNTs) and epoxy resin was done in the study. thermal-mechanical performance of nanocomposite coating was
investigated and the results were reported in this paper. The physic-chemical techniques such as Differential
scanning calorimetry (DSC) and Thermal gravimetric analysis (TGA) were used to characterize the thermal
performance of Epoxy nanocomposite coating. The test techniques for mechanical properties of paint coating as
adhesion, hardness, impact resistance and bending strength were employed in the work. The results indicated
that CNTs were dispersed in epoxy coating with only ratio of 0.1 wt% enhanced the Glass Transition
Temperature (Tg), decomposition temperature of epoxy coating and improved mechanical properties
significantly. Also functionalized CNTs can be reinforced thermal-mechanical of the epoxy coating better than
neat CNTs.
Valorization of an industrial waste (sludge) as an artificial pozzolan in cem...IJERA Editor
The present study fits within the framework of sustainable management of sludge generated from wastewater treatment in industrial network. The studied sludge comes from an industry manufacturing sanitary ceramic products. Physical, chemical and mineralogical characterization was carried out in order to give an identity card to the sludge. We noted the absence of metal pollution. In order to evaluate its pozzolanic character, the industrial sludge has been subjected to thermal activation at various temperatures (from 650°C to 1000°C). The pozzolanic activity was evaluated by physico-chemical and mechanical methods. Pozzolanicity measurement by conductivity, Frattini and Chapelle Test revealed the existence of pozzolanic properties of calcined samples. The best pozzolanic reactivity was obtained for the sample calcined at 800°C. We noticed a decrease in the reactivity of the samples calcined from 850°C. In addition, analysis by means of X-ray diffraction and Fourier transform infrared spectroscopy showed that sludge recrystallization begins at a temperature of 850°C. Pozzolanicity index of the thermally treated samples was determined by measuring the mechanical resistance of mortar specimens previously kept in a saturated lime solution for 28 days. The best pozzolanic activity index was obtained for the sample calcined at 800°C (109.1%). The study of mechanical performances and resistance to chemical attacks of mortars incorporating sludge (calcined at 800°C) with different percentages and at various ages showed an improvement of mechanical and chemical resistance compared to the control mortar (100% cement) . This work is a contribution to the research for new supplying sources of raw materials and additives in the field of construction. It presents a proposition of a promising solution for the valorization of waste material as an additive instead of being discharged into open air dumps causing a major environmental problem.
Studies on Physico - Mechanical Properties of Chloroprene Rubber Vulcanizate ...IJSRD
Among the vulcanized elastomers, the chloroprene rubber (Neoprene) possesses a good performance being one of the most used in the current days. Compounding was carried out in a two-roll mill and vulcanized at 150°C. However, this kind of polymer is seriously playing a vital role for the manufacture of power transmission belts in the automotive industry. A worldwide method that has been used and that is an important tool in the rubber vulcanization in hydraulic press curing at high temperature in which the chloroprene compound has virtual physical and mechanical properties. In this work, the chloroprene samples were prepared according to ASTM standards. The Rheological and the physico-mechanical properties of CR vulcanizate were studied.
Valorization of an industrial waste (sludge) as an artificial pozzolan in cem...IJERA Editor
The present study fits within the framework of sustainable management of sludge generated from wastewater treatment in industrial network. The studied sludge comes from an industry manufacturing sanitary ceramic products. Physical, chemical and mineralogical characterization was carried out in order to give an identity card to the sludge. We noted the absence of metal pollution. In order to evaluate its pozzolanic character, the industrial sludge has been subjected to thermal activation at various temperatures (from 650°C to 1000°C). The pozzolanic activity was evaluated by physico-chemical and mechanical methods. Pozzolanicity measurement by conductivity, Frattini and Chapelle Test revealed the existence of pozzolanic properties of calcined samples. The best pozzolanic reactivity was obtained for the sample calcined at 800°C. We noticed a decrease in the reactivity of the samples calcined from 850°C. In addition, analysis by means of X-ray diffraction and Fourier transform infrared spectroscopy showed that sludge recrystallization begins at a temperature of 850°C. Pozzolanicity index of the thermally treated samples was determined by measuring the mechanical resistance of mortar specimens previously kept in a saturated lime solution for 28 days. The best pozzolanic activity index was obtained for the sample calcined at 800°C (109.1%). The study of mechanical performances and resistance to chemical attacks of mortars incorporating sludge (calcined at 800°C) with different percentages and at various ages showed an improvement of mechanical and chemical resistance compared to the control mortar (100% cement) . This work is a contribution to the research for new supplying sources of raw materials and additives in the field of construction. It presents a proposition of a promising solution for the valorization of waste material as an additive instead of being discharged into open air dumps causing a major environmental problem.
Studies on Physico - Mechanical Properties of Chloroprene Rubber Vulcanizate ...IJSRD
Among the vulcanized elastomers, the chloroprene rubber (Neoprene) possesses a good performance being one of the most used in the current days. Compounding was carried out in a two-roll mill and vulcanized at 150°C. However, this kind of polymer is seriously playing a vital role for the manufacture of power transmission belts in the automotive industry. A worldwide method that has been used and that is an important tool in the rubber vulcanization in hydraulic press curing at high temperature in which the chloroprene compound has virtual physical and mechanical properties. In this work, the chloroprene samples were prepared according to ASTM standards. The Rheological and the physico-mechanical properties of CR vulcanizate were studied.
Cure Characteristics and Physico-Mechanical Properties of Carbonized Bamboo F...IJMER
ABSTRACT: Bamboo fibres were carbonized at 600
0
C and used as particulate filler in natural rubber vulcanizates.
Carbon black was used as the reference filler, while maleic anhydride-grafted-polyisoprene was used as a compatibilizer.
The natural rubber vulcanizates were compounded on a two-roll mill, and test samples were prepared by compression
moulding. The cure characteristics and physico-mechanical properties of the natural rubber vulcanizates were studied at
filler loadings of 0, 2, 4, 6, 10, and 15 phr (parts per hundred parts rubber). The carbonized bamboo fibre was characterized
for filler properties and sieved to 0.08µm and 0.35µm particle sizes. Results obtained showed that compatibilized carbonized
bamboo fibre filled vulcanizates exhibited improvement in the cure properties investigated over the non-compatibilized
vulcanizates. Carbon black exhibited higher tensile strength, modulus, hardness and elongation at break in the vulcanizates
than carbonized bamboo fibre. However, at any given loading of carbonized bamboo fibre, these properties increased with a
reduction in particle size of the filler. Specific gravity of the vulcanizates increased with increases in filler loading, and was
found to be dependent on filler particle size. The smaller particle-sized carbonized bamboo fibre filled vulcanizates exhibited
higher specific gravity than those vulcanizates containing the larger particle-sized filler.
Keywords: bamboo fibre, carbonization, cure characteristics, natural rubber, physico-mechanical properties.
Similar to Influence of Ion Beam and Carbon Black Filler Type on the Mechanical and Physico-Chemical Properties of Butadiene Acrylonitrile Rubber (NBR)
Nanofillers are emerging class of fillers, which are used extensively in rubbers and plastics.
In the present work, effect of alumina nanoparticle addition on the mechanical and wear behavior of
reinforced acrylonitrile butadiene styrene (ABS) polymer has been investigated
Evaluation Of Factors Affecting Sliding Wear Behaviour Of Al-Flyash Metal Mat...IJMER
International Journal of Modern Engineering Research (IJMER) is Peer reviewed, online Journal. It serves as an international archival forum of scholarly research related to engineering and science education.
Today, in the industry of aluminum, the D. C. casting of billets and slabs is playing the major role. The producers of these slabs and billets are many. The end users of the product are OEMs. The degassing technology for producing these aluminum slabs and billets is provided by very few. There are two types of degassing methods currently in use. One of these, vacuum degassing, is used primarily in the steel industry and thus not generally used in the aluminum industry. The second method, generally employed in the aluminum industry, is rotary degassing, which uses finely dispersed argon, chlorine, fluorine to remove dissolved hydrogen and various salts from melt. The challenges associated with producing aluminum are reducing porosity due to hydrogen precipitation during casting through degassing processes; which generates detrimental effects on mechanical properties of alloy castings and removing impurities like; the Ca, Mg salts etc. from the molten metal. Looking at the degassing systems provided by these players, are going to be obsolete as the environment norms will become stricter in the next decade, because of the use of Fluorine and Chlorine for removing the Ca, Mg, etc. impurities from the molten metal as the ozone layer is getting depleted and process becomes more cumbersome and hazardous. So, the innovation in the technology is needed; which leads research interest on development of the ultrasonic degassing as a better option. During this research authors would be using ultrasonic technology over existing technology to compare the results of conventional degasser units available in the market such as LARSTM, SNIFTM, STASTM - ACDTM, AlpurTM, MDUTM etc., and would be finding out the better operating parameters of ultrasonic equipment for the process for replacement of Fluorine and Chlorine based old technology with Ultrasonic Technology. This research paper should underpin improvement in the process and hence improved hardness of material by elimination of the fluorine and chlorine usage by replacing it with ultrasonic technology with suitable mechanical design, metallurgical criteria and thermal analysis consideration. During the entire research and development authors had carried out various operations like Research on thermal and metallurgical behavior of the molten metal and alloys, Comparison of results achieved using ultrasonic technique over existing technique, Formulation of conclusion; making ultrasonic technique a proven technology, and Identifying the further scope of research and development. With the experiments carried out, authors found significant improvement in hardness of the material produced by ultrasonic degassing as compared with the hardness of material produced by conventional degassing.
Today, in the industry of aluminum, the D. C. casting of billets and slabs is playing the major role. The producers of these slabs and billets are many. The end users of the product are OEMs. The degassing technology for producing these aluminum slabs and billets is provided by very few. There are two types of degassing methods currently in use. One of these, vacuum degassing, is used primarily in the steel industry and thus not generally used in the aluminum industry. The second method, generally employed in the aluminum industry, is rotary degassing, which uses finely dispersed argon, chlorine, fluorine to remove dissolved hydrogen and various salts from melt. The challenges associated with producing aluminum are reducing porosity due to hydrogen precipitation during casting through degassing processes; which generates detrimental effects on mechanical properties of alloy castings and removing impurities like; the Ca, Mg salts etc. from the molten metal. Looking at the degassing systems provided by these players, are going to be obsolete as the environment norms will become stricter in the next decade, because of the use of Fluorine and Chlorine for removing the Ca, Mg, etc. impurities from the molten metal as the ozone layer is getting depleted and process becomes more cumbersome and hazardous. So, the innovation in the technology is needed; which leads research interest on development of the ultrasonic degassing as a better option. During this research authors would be using ultrasonic technology over existing technology to compare the results of conventional degasser units available in the market such as LARSTM, SNIFTM, STASTM - ACDTM, AlpurTM, MDUTM etc., and would be finding out the better operating parameters of ultrasonic equipment for the process for replacement of Fluorine and Chlorine based old technology with Ultrasonic Technology. This research paper should underpin improvement in the process and hence improved hardness of material by elimination of the fluorine and chlorine usage by replacing it with ultrasonic technology with suitable mechanical design, metallurgical criteria and thermal analysis consideration. During the entire research and development authors had carried out various operations like Research on thermal and metallurgical behavior of the molten metal and alloys, Comparison of results achieved using ultrasonic technique over existing technique, Formulation of conclusion; making ultrasonic technique a proven technology, and Identifying the further scope of research and development. With the experiments carried out, authors found significant improvement in hardness of the material produced by ultrasonic degassing as compared with the hardness of material produced by conventional degassing.
Electrospun Nanofibers Reinforced Aluminium Matrix Composites, A Trial to Imp...IJAMSE Journal
A comparison between TiO2 nanofibers and carbon nanofibers as fibers reinforced metal matrix composites with respect to mechanical properties improvements have been made in this paper. Al and Mg have been chosen as metal matrices. The used carbon and ceramic nanofibers (Titanium Oxide) were successfully synthesized using electrospinning technique. Various weight percentage of calcined
electrospun TiO2 and carbon nanofibers (1, 3, 5 and 10%) were mixed with metal matrix and fabricated by route of powder metallurgy using High Frequency Induction heat Sintering (HFIHS). Mechanical properties of the sintered composites have been investigated. The manufactured pellets were tested for compression test, hardness and microstructures by the field emission scanning electron microscopes (FESEM), which reveals the homogeneous distribution of nanofibers in the Al/Mg matrices. In addition,
energy-dispersive X-ray spectroscopy (EDS) was employed to obtain the chemical analysis of each composite. The result shows that, the ultimate compressive strength increased to 415 MPa at 5% TiO2, which is 13.5% more than the pure Al. The hardness increased up to 64% in case of using the ceramic nanofibers as reinforcement. While using CNFs as reinforcement to the Al matrix deteriorates the
mechanical properties.
This paper attempts to show that,
activated by adding different loading levels of zinc oxide (ZnO).
to mix and distribute the elements of the rubber compound. MV
rheometer employed to determine the properties of th
6 min. The curing process carried out using the hot press at a temperature of 180°C
and pressure of 10 bars. Results show that the addition
hundred parts of rubber (phr)
scorch time ,curing time with
particularly at 2 and 4 phr
modulus of elasticity at 300% elongation, hardness and compressio
phr represent the best loading level of the ZnO, which had more effect on the aging
and mechanical properties.
especially when the retention percentage of the properties
Experimental Investigations on Tribiological Properties of 6061-T6 Al Alloy b...IJAEMSJORNAL
Microstructure and tribological properties of Al-TiB2 nano surface composite fabricated by Friction Stir Processing (FSP) were evaluated. To vary the percentage of TiB2 three different slot thickness viz. 1mm, 1.5 mm and 2mm were considered. Microstructural evaluations showed a nearly uniform distribution of TiB2 in the aluminium matrix after FSP with the addition of composite powder. Microhardness test results shoes FSW of Al6061-T6 alloy with 2mm groove width has more hardness. tribological properties were evaluated at two different sliding velocities 0.314m/s and 0.48m/s and results shows that at lower loads there is no much difference in wear rate of surface composite made with different slot sizes but with increase in load and sliding velocity wear rate was increased , however, larger slot Al6061-TiB2 Surface composites show better wear resistance.
The effect of functionalized carbon nanotubes on thermalmechanical performanc...IJRTEMJOURNAL
The new approaches for preparing nanocomposite coating by modificated carbon nanonotubes
(CNTs) and epoxy resin was done in the study. thermal-mechanical performance of nanocomposite coating was
investigated and the results were reported in this paper. The physic-chemical techniques such as Differential
scanning calorimetry (DSC) and Thermal gravimetric analysis (TGA) were used to characterize the thermal
performance of Epoxy nanocomposite coating. The test techniques for mechanical properties of paint coating as
adhesion, hardness, impact resistance and bending strength were employed in the work. The results indicated
that CNTs were dispersed in epoxy coating with only ratio of 0.1 wt% enhanced the Glass Transition
Temperature (Tg), decomposition temperature of epoxy coating and improved mechanical properties
significantly. Also functionalized CNTs can be reinforced thermal-mechanical of the epoxy coating better than
neat CNTs.
Effect of Temperature on Wear Rate of Si-Epoxy- Eglass Polymer composite Mate...IDES Editor
With the increase use of polymer composites in
erosive work environment, it has become extremely important
to investigate their erosion characteristics. The hybrid
composite consisting of a Epoxy resin reinforced with Eglass
fiber and Si particles was developed. The effect of temperature
on wear rate applied to Si – Epoxy – Eglass polymer composite
has been studied. It has been found that the wear rate increases
as the temperature of carrier media (air) is increased.
Temperature of carrier media is one of the significant factor
influencing the erosion wear. The results were compared with
the plain epoxy composite material. Micrographs of eroded
surface are also presented to study the wear rate and Wear
behavior of composite.
Study of the effects of carbon and glass fibre reinforcement and other filler...eSAT Journals
Abstract In the present study, composite materials required for elevated temperature applications were fabricated using vacuum bagging technique. Epoxy Resin (ER-VP401) was used as the matrix and Glass fibre was used as reinforcement. SiC, Al2O3 and others were used as fillers to bring in elevated temperature resistance. These composites were subjected to mechanical tests like Tensile, Hardness and Impact test. Tribological tests like two body abrasion and Pin on disc (POD) were carried out. Tensile strength, hardness and impact energy were improved with increase in fillers content. Wear resistance also improved with increase in percentage of fillers substantially. SEM micrographs are used to explain the mechanism of the material strengthening at elevated temperatures. Keywords: Epoxy resin, Glass Fiber (GF), Al2O3, SiC, Elevated Temperature Resistance.
Similar to Influence of Ion Beam and Carbon Black Filler Type on the Mechanical and Physico-Chemical Properties of Butadiene Acrylonitrile Rubber (NBR) (20)
Text Mining in Digital Libraries using OKAPI BM25 ModelEditor IJCATR
The emergence of the internet has made vast amounts of information available and easily accessible online. As a result, most libraries have digitized their content in order to remain relevant to their users and to keep pace with the advancement of the internet. However, these digital libraries have been criticized for using inefficient information retrieval models that do not perform relevance ranking to the retrieved results. This paper proposed the use of OKAPI BM25 model in text mining so as means of improving relevance ranking of digital libraries. Okapi BM25 model was selected because it is a probability-based relevance ranking algorithm. A case study research was conducted and the model design was based on information retrieval processes. The performance of Boolean, vector space, and Okapi BM25 models was compared for data retrieval. Relevant ranked documents were retrieved and displayed at the OPAC framework search page. The results revealed that Okapi BM 25 outperformed Boolean model and Vector Space model. Therefore, this paper proposes the use of Okapi BM25 model to reward terms according to their relative frequencies in a document so as to improve the performance of text mining in digital libraries.
Green Computing, eco trends, climate change, e-waste and eco-friendlyEditor IJCATR
This study focused on the practice of using computing resources more efficiently while maintaining or increasing overall performance. Sustainable IT services require the integration of green computing practices such as power management, virtualization, improving cooling technology, recycling, electronic waste disposal, and optimization of the IT infrastructure to meet sustainability requirements. Studies have shown that costs of power utilized by IT departments can approach 50% of the overall energy costs for an organization. While there is an expectation that green IT should lower costs and the firm’s impact on the environment, there has been far less attention directed at understanding the strategic benefits of sustainable IT services in terms of the creation of customer value, business value and societal value. This paper provides a review of the literature on sustainable IT, key areas of focus, and identifies a core set of principles to guide sustainable IT service design.
Policies for Green Computing and E-Waste in NigeriaEditor IJCATR
Computers today are an integral part of individuals’ lives all around the world, but unfortunately these devices are toxic to the environment given the materials used, their limited battery life and technological obsolescence. Individuals are concerned about the hazardous materials ever present in computers, even if the importance of various attributes differs, and that a more environment -friendly attitude can be obtained through exposure to educational materials. In this paper, we aim to delineate the problem of e-waste in Nigeria and highlight a series of measures and the advantage they herald for our country and propose a series of action steps to develop in these areas further. It is possible for Nigeria to have an immediate economic stimulus and job creation while moving quickly to abide by the requirements of climate change legislation and energy efficiency directives. The costs of implementing energy efficiency and renewable energy measures are minimal as they are not cash expenditures but rather investments paid back by future, continuous energy savings.
Performance Evaluation of VANETs for Evaluating Node Stability in Dynamic Sce...Editor IJCATR
Vehicular ad hoc networks (VANETs) are a favorable area of exploration which empowers the interconnection amid the movable vehicles and between transportable units (vehicles) and road side units (RSU). In Vehicular Ad Hoc Networks (VANETs), mobile vehicles can be organized into assemblage to promote interconnection links. The assemblage arrangement according to dimensions and geographical extend has serious influence on attribute of interaction .Vehicular ad hoc networks (VANETs) are subclass of mobile Ad-hoc network involving more complex mobility patterns. Because of mobility the topology changes very frequently. This raises a number of technical challenges including the stability of the network .There is a need for assemblage configuration leading to more stable realistic network. The paper provides investigation of various simulation scenarios in which cluster using k-means algorithm are generated and their numbers are varied to find the more stable configuration in real scenario of road.
Optimum Location of DG Units Considering Operation ConditionsEditor IJCATR
The optimal sizing and placement of Distributed Generation units (DG) are becoming very attractive to researchers these days. In this paper a two stage approach has been used for allocation and sizing of DGs in distribution system with time varying load model. The strategic placement of DGs can help in reducing energy losses and improving voltage profile. The proposed work discusses time varying loads that can be useful for selecting the location and optimizing DG operation. The method has the potential to be used for integrating the available DGs by identifying the best locations in a power system. The proposed method has been demonstrated on 9-bus test system.
Analysis of Comparison of Fuzzy Knn, C4.5 Algorithm, and Naïve Bayes Classifi...Editor IJCATR
Early detection of diabetes mellitus (DM) can prevent or inhibit complication. There are several laboratory test that must be done to detect DM. The result of this laboratory test then converted into data training. Data training used in this study generated from UCI Pima Database with 6 attributes that were used to classify positive or negative diabetes. There are various classification methods that are commonly used, and in this study three of them were compared, which were fuzzy KNN, C4.5 algorithm and Naïve Bayes Classifier (NBC) with one identical case. The objective of this study was to create software to classify DM using tested methods and compared the three methods based on accuracy, precision, and recall. The results showed that the best method was Fuzzy KNN with average and maximum accuracy reached 96% and 98%, respectively. In second place, NBC method had respective average and maximum accuracy of 87.5% and 90%. Lastly, C4.5 algorithm had average and maximum accuracy of 79.5% and 86%, respectively.
Web Scraping for Estimating new Record from Source SiteEditor IJCATR
Study in the Competitive field of Intelligent, and studies in the field of Web Scraping, have a symbiotic relationship mutualism. In the information age today, the website serves as a main source. The research focus is on how to get data from websites and how to slow down the intensity of the download. The problem that arises is the website sources are autonomous so that vulnerable changes the structure of the content at any time. The next problem is the system intrusion detection snort installed on the server to detect bot crawler. So the researchers propose the use of the methods of Mining Data Records and the method of Exponential Smoothing so that adaptive to changes in the structure of the content and do a browse or fetch automatically follow the pattern of the occurrences of the news. The results of the tests, with the threshold 0.3 for MDR and similarity threshold score 0.65 for STM, using recall and precision values produce f-measure average 92.6%. While the results of the tests of the exponential estimation smoothing using ? = 0.5 produces MAE 18.2 datarecord duplicate. It slowed down to 3.6 datarecord from 21.8 datarecord results schedule download/fetch fix in an average time of occurrence news.
Evaluating Semantic Similarity between Biomedical Concepts/Classes through S...Editor IJCATR
Most of the existing semantic similarity measures that use ontology structure as their primary source can measure semantic similarity between concepts/classes using single ontology. The ontology-based semantic similarity techniques such as structure-based semantic similarity techniques (Path Length Measure, Wu and Palmer’s Measure, and Leacock and Chodorow’s measure), information content-based similarity techniques (Resnik’s measure, Lin’s measure), and biomedical domain ontology techniques (Al-Mubaid and Nguyen’s measure (SimDist)) were evaluated relative to human experts’ ratings, and compared on sets of concepts using the ICD-10 “V1.0” terminology within the UMLS. The experimental results validate the efficiency of the SemDist technique in single ontology, and demonstrate that SemDist semantic similarity techniques, compared with the existing techniques, gives the best overall results of correlation with experts’ ratings.
Semantic Similarity Measures between Terms in the Biomedical Domain within f...Editor IJCATR
The techniques and tests are tools used to define how measure the goodness of ontology or its resources. The similarity between biomedical classes/concepts is an important task for the biomedical information extraction and knowledge discovery. However, most of the semantic similarity techniques can be adopted to be used in the biomedical domain (UMLS). Many experiments have been conducted to check the applicability of these measures. In this paper, we investigate to measure semantic similarity between two terms within single ontology or multiple ontologies in ICD-10 “V1.0” as primary source, and compare my results to human experts score by correlation coefficient.
A Strategy for Improving the Performance of Small Files in Openstack Swift Editor IJCATR
This is an effective way to improve the storage access performance of small files in Openstack Swift by adding an aggregate storage module. Because Swift will lead to too much disk operation when querying metadata, the transfer performance of plenty of small files is low. In this paper, we propose an aggregated storage strategy (ASS), and implement it in Swift. ASS comprises two parts which include merge storage and index storage. At the first stage, ASS arranges the write request queue in chronological order, and then stores objects in volumes. These volumes are large files that are stored in Swift actually. During the short encounter time, the object-to-volume mapping information is stored in Key-Value store at the second stage. The experimental results show that the ASS can effectively improve Swift's small file transfer performance.
Integrated System for Vehicle Clearance and RegistrationEditor IJCATR
Efficient management and control of government's cash resources rely on government banking arrangements. Nigeria, like many low income countries, employed fragmented systems in handling government receipts and payments. Later in 2016, Nigeria implemented a unified structure as recommended by the IMF, where all government funds are collected in one account would reduce borrowing costs, extend credit and improve government's fiscal policy among other benefits to government. This situation motivated us to embark on this research to design and implement an integrated system for vehicle clearance and registration. This system complies with the new Treasury Single Account policy to enable proper interaction and collaboration among five different level agencies (NCS, FRSC, SBIR, VIO and NPF) saddled with vehicular administration and activities in Nigeria. Since the system is web based, Object Oriented Hypermedia Design Methodology (OOHDM) is used. Tools such as Php, JavaScript, css, html, AJAX and other web development technologies were used. The result is a web based system that gives proper information about a vehicle starting from the exact date of importation to registration and renewal of licensing. Vehicle owner information, custom duty information, plate number registration details, etc. will also be efficiently retrieved from the system by any of the agencies without contacting the other agency at any point in time. Also number plate will no longer be the only means of vehicle identification as it is presently the case in Nigeria, because the unified system will automatically generate and assigned a Unique Vehicle Identification Pin Number (UVIPN) on payment of duty in the system to the vehicle and the UVIPN will be linked to the various agencies in the management information system.
Assessment of the Efficiency of Customer Order Management System: A Case Stu...Editor IJCATR
The Supermarket Management System deals with the automation of buying and selling of good and services. It includes both sales and purchase of items. The project Supermarket Management System is to be developed with the objective of making the system reliable, easier, fast, and more informative.
Energy-Aware Routing in Wireless Sensor Network Using Modified Bi-Directional A*Editor IJCATR
Energy is a key component in the Wireless Sensor Network (WSN)[1]. The system will not be able to run according to its function without the availability of adequate power units. One of the characteristics of wireless sensor network is Limitation energy[2]. A lot of research has been done to develop strategies to overcome this problem. One of them is clustering technique. The popular clustering technique is Low Energy Adaptive Clustering Hierarchy (LEACH)[3]. In LEACH, clustering techniques are used to determine Cluster Head (CH), which will then be assigned to forward packets to Base Station (BS). In this research, we propose other clustering techniques, which utilize the Social Network Analysis approach theory of Betweeness Centrality (BC) which will then be implemented in the Setup phase. While in the Steady-State phase, one of the heuristic searching algorithms, Modified Bi-Directional A* (MBDA *) is implemented. The experiment was performed deploy 100 nodes statically in the 100x100 area, with one Base Station at coordinates (50,50). To find out the reliability of the system, the experiment to do in 5000 rounds. The performance of the designed routing protocol strategy will be tested based on network lifetime, throughput, and residual energy. The results show that BC-MBDA * is better than LEACH. This is influenced by the ways of working LEACH in determining the CH that is dynamic, which is always changing in every data transmission process. This will result in the use of energy, because they always doing any computation to determine CH in every transmission process. In contrast to BC-MBDA *, CH is statically determined, so it can decrease energy usage.
Security in Software Defined Networks (SDN): Challenges and Research Opportun...Editor IJCATR
In networks, the rapidly changing traffic patterns of search engines, Internet of Things (IoT) devices, Big Data and data centers has thrown up new challenges for legacy; existing networks; and prompted the need for a more intelligent and innovative way to dynamically manage traffic and allocate limited network resources. Software Defined Network (SDN) which decouples the control plane from the data plane through network vitalizations aims to address these challenges. This paper has explored the SDN architecture and its implementation with the OpenFlow protocol. It has also assessed some of its benefits over traditional network architectures, security concerns and how it can be addressed in future research and related works in emerging economies such as Nigeria.
Measure the Similarity of Complaint Document Using Cosine Similarity Based on...Editor IJCATR
Report handling on "LAPOR!" (Laporan, Aspirasi dan Pengaduan Online Rakyat) system depending on the system administrator who manually reads every incoming report [3]. Read manually can lead to errors in handling complaints [4] if the data flow is huge and grows rapidly, it needs at least three days to prepare a confirmation and it sensitive to inconsistencies [3]. In this study, the authors propose a model that can measure the identities of the Query (Incoming) with Document (Archive). The authors employed Class-Based Indexing term weighting scheme, and Cosine Similarities to analyse document similarities. CoSimTFIDF, CoSimTFICF and CoSimTFIDFICF values used in classification as feature for K-Nearest Neighbour (K-NN) classifier. The optimum result evaluation is pre-processing employ 75% of training data ratio and 25% of test data with CoSimTFIDF feature. It deliver a high accuracy 84%. The k = 5 value obtain high accuracy 84.12%
Hangul Recognition Using Support Vector MachineEditor IJCATR
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Influence of Ion Beam and Carbon Black Filler Type on the Mechanical and Physico-Chemical Properties of Butadiene Acrylonitrile Rubber (NBR)
1. International Journal of Science and Engineering Applications
Volume 5 Issue 2, March-April 2016
www.ijsea.com 95
Influence of Ion Beam and Carbon Black Filler Type on
the Mechanical and Physico-Chemical Properties of
Butadiene Acrylonitrile Rubber (NBR)
H. H. Hassan,
Physics Department,
Faculty of Science,
Cairo University,
Giza, Egypt
A. I. Aboud
Physics Department,
Faculty of Science,
Cairo University,
Giza, Egypt
M.A. El-Waily
Physics Department,
Faculty of Science,
Cairo University,
Giza, Egypt
Abstract: Five types of carbon black nanofillers, namely Intermediate Super-Abrasion Furnace ISAF (N220), High-Abrasion Furnace
HAF-LS (N326), Fast Extruding Furnace FEF (N550), General Purpose Furnace GPF (N660) and Semi-Reinforcing Furnace SRF-HS
(N774) were incorporated with butadiene acrylonitrile rubber (NBR) in order to improve its physical properties. Young's modulus was
found to increase with nanofiller content. Percolation concentration was detected in mechanical as well as in Physico-chemical behavior.
The experimental values of the normalized Young's modulus fit well with Pukanszky et al. model; taking into consideration the difference
in carbon black-filler type. It is noticed that the characteristic time of swelling in toluene, τ is higher for NBR loaded with 30 phr ISAF
and for the rest of samples it increases with increasing of particle size. Finally oxygen ion beam irradiation for percolative loading NBR
nanocomposites increases Young's modulus nearly by 2-3 times.
Keywords: Carbon-black nanofiller; NBR; Nanocomposites; Young's modulus; Percolation threshold; maximum degree of swelling.
1. INTRODUCTION
Most commercial polymers may be classified as insulating,
having volume resistivities of 109
Ohm cm or more. However,
their properties are extensively modified, to antistatic (104
-109
Ohm cm) or conductive (lower than 104
Ohm cm), by
compounding, with fillers having the largest effect on
properties[1,2]. In many cases, it is beneficial to introduce
some level of electrical conductivity into a polymeric material
[3,4]. The highly insulating polymers are susceptible to static
build up. This may be a nuisance, attracting dust to the surface,
or it may lead to damage of sensitive electronic parts, when
manufacturing integrated circuits, for example. Even very low
levels of surface conductivity will resolve this problem [5].
Organic based antistatic additives are available or alternatively
conductive fillers such as carbon black, graphite, or metals may
be added [5]. Antistatic agents are usually highly polar liquids,
which form a surface film that is antistatic in character. This
prevents the build-up of electrostatic charges on the surface of
the product. This type of additive is normally added to light-
colored compounds, as most carbon-black-filled composites
are inherently antistatic [1]; but the need of a white antistatic
materials in industrial applications, such as textile
manufacturing, leads one to use white metals as a filler. One of
the most sensitive methods for determining the degree of
dispersion of filler within a rubber compound is the
measurement of its ac and dc electrical properties as well as
mechanical properties under different conditions. Composites
made with carbon black, long used for elastomer
reinforcement, have recently replaced metals in several
industrial applications. But, the need of white antistatic
materials is still the demand of many technological
applications. Their usefulness depends on how well their
properties can be manipulated, which in turn requires an
understanding of the controlling physical mechanisms involved
[6].
Rubber nanocomposites have attracted many researchers due to
their unique properties. In rubbers, fillers are used to achieve
products with improved properties for end use applications. It
is well known that for most of the applications, rubber must be
reinforced with certain fillers such as carbon blacks (CB),
silica, clay and so on. Rubber nanocomposites are prepared
through different techniques such as melt mixing, mill mixing,
solution mixing, latex stage mixing followed by a co-
coagulation method and polymerization around the filler
particles. As compared with microfiller-reinforced rubber,
nanofiller-reinforced rubber exhibits high hardness, modulus,
anti-aging and gas barrier properties. Therefore, the
2. International Journal of Science and Engineering Applications
Volume 5 Issue 2, March-April 2016
www.ijsea.com 96
nanoconcept is highly relevant for rubber compounds since
their applications require filler reinforcement.
Composites are used in a wide variety of products, from
advanced spacecraft to sporting goods to joint implants. Metal
doped polymer provides suitable properties for EMI shielding
[7]. They are currently being used in various medical
procedures and been developed as candidates for different
types of sensing applications. The conductive and absorptive
properties of insulating polymers doped with conducting fillers
and the absorptive properties of unfilled-insulating polymers
are sensitive to the exposure of gas vapors. Therefore, they can
be used to monitor the existence and concentration of gases in
environment [8].
Energetic ion beams play a vital role in the field of materials
science [9]. Ion beam effect on the materials depends on the ion
species, energy and influence [10]. The interaction of the ion
with material is the deciding factor in the ion beam- induced
material modification. Polymer ion implantation may induce
irreversible changes in their macroscopic characteristics such
as electrical and structural properties and surface related
mechanical property. These changes are responsible to
fundamental events like electronic excitation, ionization, chain
scission and cross links as well as mass loss, which take place
due to ion beam implantation. Therefore, the understanding of
a certain structural rearrangements influences the properties of
the polymeric materials and/or composites opens a way to
design devices with required parameters.
The purpose of this study is to prepare five groups of carbon
black/NBR nanocomposites loaded up to 100 phr, choose the
most sensitive nanocomposite sample among each group; then
investigate the effect of oxygen ion beam influence on its
mechanical parameters as well as solvent penetration
characteristics.
EXPERIMENTAL MATERIALS
Table 1 Composition of NBR samples with different
concentrations of various carbon black filler types
Sample
Ing
(phr)a
NX
0
NX
10
NX
20
NX
30
NX
40
NX
50
NX
60
NX
70
NX
80
NX
90
NX
10
0
NBR
10
0
10
0
10
0
10
0
10
0
10
0
10
0
10
0
10
0
10
0
10
0
St. acid 2 2 2 2 2 2 2 2 2 2 2
Zn O 5 5 5 5 5 5 5 5 5 5 5
DOP. 0 10 10 10 10 10 10 10 10 10 10
X 0 10 20 30 40 50 60
70 80 90 10
0
TMTD 2 2 2 2 2 2 2 2 2 2 2
IPPD
4020
1 1 1 1 1 1 1 1 1 1 1
S 2 2 2 2 2 2 2 2 2 2 2
a
Part per hundred parts of rubber by weight.
Since sample properties depend on the method of preparation it
is important that samples should be made under the same
conditions [11,12]. In this work NBR (density 0.98 g/cm3
and
acrylonitrile content 34% supplied by TRENCO, Alexandria,
Egypt) was used as polymer matrix, with five types of black
fillers, namely Intermediate Super-Abrasion Furnace ISAF
(N220), High-Abrasion Furnace HAF-LS (N326), Fast
Extruding Furnace FEF (N550), General Purpose Furnace GPF
(N660) and Semi-Reinforcing Furnace SRF-HS (N774)
supplied by TRENCO, Alexandria, Egypt. Other compounding
ingredients (supplied by Morgan Chemicals, Cairo, Egypt)
such as zinc oxide and stearic acid (binary activators),
tetramethylthiuram disulfide TMTD (semi-ultra-accelerator),
Processing oil; dioctyl phthalate (DOP), (plasticizer), N-(1,3-
dimethylbutyle)-N-phenylenediamine (IPPD(4020))
(antioxidant, antiozonant, antiflex and ageing retardant) and
sulfur (vulcanizing agent) were used. These materials are
compounded according to the recipe as listed in Table (1). For
each filler type, NBR was loaded with different concentrations
(0, 10, 20, 30 … 100 phr) to achieve suitable physical
properties for specific applications. The physical parameters of
used fillers are shown in Table (2).
Sample Preparation
Ingredients of the rubber blend were mixed, according to the
ASTMD 3182-89, on a two-roll laboratory mill of 170 mm
diameter, 300-mm length, the speed of slow roll being 18 rpm
and gear ratio 1.4. The ingredients were added in the order as
shown in Table (1). The compounded rubber was left for 24
Table 2 Physical properties of carbon blacks
3. International Journal of Science and Engineering Applications
Volume 5 Issue 2, March-April 2016
www.ijsea.com 97
Black
grade
ASTM
numbe
r
Mean
particle
diamete
r (nm)
EmSA
a
(m2
/g)
BETN2SA
b
(m2
/g)
CTAB
c
(m2
/g)
DBPAd
(Cm2
/100g
)
ISAF N220 21 121 116 111 114
HAF
-LS
N326 27 87 85 84 71
FEF N550 56 41 41 43 122
GPF N660 67 35 36 35 91
SRF-
HS
N774 79 29 29 30 77
a
Electron microscope surface area; ASTM D 3849, Dispersion Procedure D
(CAB).
b
Nitrogen adsorption; ASTM D 3037.
c
Cetyltrimethyl ammonium bromide adsorption ASTM D 3765,
d
Di(n-dibutyl) phthalate ASTM D 2414-90
hours before vulcanization. The vulcanization process was
performed according to ASTM: D2084-07 at 153 2°C under
a pressure of 4 MPa for 30 minutes. To insure reproducibility,
the samples were conditioned at 27°C for 30 days [13].
TECHNIQUES OF CHARACTERIZATION
Mechanical Measurements
The mechanical test samples were strips of 4 cm working
length and of 16 mm2
initial cross-sectional areas. The strips
were cut in the milling direction. The stress–strain
measurements were conducted according to ASTM D412-06a
(2013) using a homemade tensile testing machine. The sample
was attached to two clamps from both sides and the weight was
increased by a gear-motor and detected by a digital balance and
elongation was recorded instantaneously from a point then the
data was calculated from the following relation
𝜀 (%) =
∆𝐿
𝐿 𝑜
× 100 & 𝜎 =
𝑚 𝑔
𝐴
(1)
Where Lo (m) and ΔL (m) are the initial length of the sample
and the elongation respectively; m (kg) is the applied mass, g
(m/s2
) is the acceleration due to gravity and A is the cross-
sectional area in m2
.
Physico-chemical Measurements
Swelling measurements of the vulcanized samples were carried
out using toluene as a solvent. Disc-shaped samples of 0.5cm
diameter and 0.2 cm thickness were cut from rubber sheets.
Each sample is weighed by a sensitive balance of 10-4
g
accuracy. The test pieces were immersed in the solvent. The
swelling took place in glass bottles, kept at a working
temperature of 300 K. Every 60 minutes the test piece is
removed and dried by a filter paper and weighed. The degree
of swelling Q is calculated from the formula
𝑄 =
(𝑚−𝑚 𝑜)
𝑚 𝑜
× 100% (2)
where mo is the initial mass of the rubber sample and m is the
mass of swollen rubber sample. After 24 hours; immersion
time, the test piece attained the equilibrium swelling [14,15].
Gas Ion Implantation
The polymer samples of circular shape with common size (0.79
cm2
) were fixed inside the vacuum ended tube with diameter
21 mm. The full length of the accelerating voltage along the
evacuated tube was 57 cm. This tube was evacuated several
times after refreshing it with oxygen gas to minimize air
contamination.
The ignition of microwave (at frequency 2.45 GHz) lunched to
quartz gas tube to generate oxygen ion plasma at fixed gas rate
flow that was kept at constant pressure about 0.5 torr. After
these steps the ions driving high voltage was applied between
the two accelerating plates through a charging capacitor C = 0.5
µF and current control resistance of 6 kΩ (As shown in Fig. 1).
Figure 1 A Schematic Diagram of Tubular Type Plasma Device.
The samples was irradiated with different number of ion shoots
with constant accelerating voltage 12 kV between the two
copper electrodes of 20 and 10 mm outer and inner diameter
respectively. The influence of oxygen gas irradiation is in the
range of 0 - 3.5×1016
ions/m2
.
RESULTS AND DISCUSSION
4. International Journal of Science and Engineering Applications
Volume 5 Issue 2, March-April 2016
www.ijsea.com 98
Mechanical Properties (Effect of Filler Type and Content)
Different researcher studied stress-strain behavior of the
polymer composites with different fillers in the recent era [16].
The nature of deformation of the NBR-carbon rubber
composites under an applied load can be understood from the
stress-strain curves [17].
Figure 2. Stress-strain behavior for NBR composites filled with a.
ISAF, b. HAF, c. FEF, d. GPF and e. SRF black
The stress-strain behavior of the composites of NBR filled with
different concentrations of different carbon black is shown in
Fig. (2). These graphs were plotted for composites loaded up to
100 phr of all types of carbon (ISAF, HAF, FEF, GPF and SRF
respectively). All filled systems show similar trend as well as
high initial moduli. The initial moduli and strength increase
with the filler concentration.
Young's Modulus
Young's Modulus of the composites is the bulk property that
attracted more attention in this area of research [16], where it is
characterizing the rigidity of the materials, calculated as the
slope of the linear part of the stress-strain curve, at low strains
(20 %) [17]. As shown in Fig.(3), it is well known that Young's
modulus increases for a polymer when we incorporate any
reinforcement filler into it. This is reasonable because the ratio
of the filler modulus to that of the polymer for all of the various
filler-polymer combinations exceeds 30:1 [17].
Figure 3. Variation of Young's modulus for NBR composites with
carbon black filler type and content
5. International Journal of Science and Engineering Applications
Volume 5 Issue 2, March-April 2016
www.ijsea.com 99
By increasing the carbon contents for all types the modulus
values increased (c.f. Figure 3). The increase in modulus is
governed by the fact that the filler gives good reinforcement
with the polymer matrix. Also it is attributed to the different
parameters of the added filler to the rubber. They include the
aspect ratio of the added filler; the orientation of fillers and
the nature of filler. In our composites there exists a matrix
filler interaction; which enables the Young's modulus
increase.
The relative Young's modulus of polymer composite to that of
pure NBR matrix Ec/Em are plotted in Fig. (4) as a function of
both filler type and contents. These plots clearly show that this
normalized Young's modulus increases with the filler volume
fraction and ISAF filler has the maximum reinforcement with
NBR matrix.
However, the curves clearly exhibit the existence of a volume
fraction c (≈ 30, 40, 60, 70 and 80 phr for ISAF, HAF, FEF,
GPF and SRF respectively), marking the transition between
two regions defined by the two different linear dependence on
the volume fraction . The existence of this concentration was
identified with a percolation threshold [17].
In this work, we try to apply Pukanszky et al. [18,19] model to
study the behavior of the normalized Young's modulus as a
function of both filler type and volume fraction .
Figure 4. Variation of normalized Young's modulus with filler volume
fraction for NBR composites with different carbon black types, points
represent experimental values and lines represent Pukanszky et al.
model fit.
(B )c
m
E 1
e
E 1 2.5
(3)
Where the fraction [(1 ) /(1 2.5 )] takes into
consideration the decrease of the effective load bearing cross-
section [20], and the exponential describes all other effects
resulting in an increase of the Young's modulus. From the
physical point of view, the parameter B is governed by interface
and interphase properties. Indeed, as shown by Rong et al.[21]
for polypropylene nanocomposites, larger B values correspond
6. International Journal of Science and Engineering Applications
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to higher interfacial adhesion. The following B expression
underlines these effects:
f f i mB (1 S )ln(E / E ) (4)
where τ, the thickness of the interphase, is proportional to the
interfacial adhesion, defined by the parameter ζ12 with τ = λ ζ12
, where λ is a constant. The quantities ρf , Sf ,and Ei represent
the density of filler, the specific surface area of the filler and
the Young's modulus of the interphase, respectively. Since it is
virtually impossible to provide exact values for the absolute
thickness τ and the Young's modulus Ei of the interphase, the
parameter B was determined from the experimental data using
the following expression [17], derived from equation (3):
c
m
E1 1 2.5
B ln
E 1
(5)
Trials to use this model to fit Young's modulus experimental
values is illustrated in Fig. (4), one found that this model fits
much better the experimental results taking into consideration
the different types of carbon filler.
The parameter B is plotted as a function of the volume fraction
(for all types of carbon black) for all samples (as shown in
Figure (5). All carbon black has the same decreasing trend of
the dependence of B on the carbon black concentration.
Figure. 5. Variation of parameter B with filler contents of NBR
composites loaded with different carbon black types.
Physico-chemical Properties ( Solvent Penetration )
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Particle size, structure, physical nature, chemical nature, and
the porosity are the five most important properties of carbon
black, which affect the applications. The smaller the particle
sizes the poorer the processibility and the higher the
reinforcement. Increase in reinforcement means enhancement
of tensile strength, abrasion resistance, and tear resistance.
The chemical nature of the carbon black surface has a direct
connection with the properties, which the black confers on
rubber. Electrical conductivity and rate of cure thus affected to
a considerable degree by the surface chemistry of the carbon
black.
Let us now carry out an experiment to study the effect of adding
different type of fillers on the penetration rate, P, and diffusion
coefficient, Dav, of the NBR composites. The diffusion of a
liquid in the bulk of the rubber blend depends on the
homogeneity of the mix and the way that the filler are
aggregated [22]. Hence, the diffusion values are averages over
the concentration of liquid and dimensions of the sample.
Diffusion theory in elastomers [23] is based on the assumption
that the swelling starts by the sorption of the liquid at the
surface of the sample to a certain concentration equal to that
attained by the whole sample at equilibrium; then the swelling
proceeds by increasing the depth of the swollen layers. The
relation between the average diffusion coefficient, Dav, and the
penetration rate, P, is given by [24, 25] :
2
4
av
P
D
(6)
Where P is given by [22]:
1
2
1
2
t
e
M d
P
Mt
(7)
Where, d, is the sample thickness, eM and tM are the weight
uptake of liquid at equilibrium and after a time, t, respectively.
The increase in weight due to swelling (in toluene) for NBR
loaded with the percolation concentration of different carbon
blacks is plotted against the square root of time, in minutes. The
curves are shown in Fig. (6). The effective reinforcement in the
rubber matrix is evident from this sorption curves [26].
Vulcanization restricts the long-range movements of the
polymer molecules but leaves their local segmental mobility
high. Filler reinforcement modifies this condition. The
attachment of chains to the surface of the filler has been
accomplished through wetting. Carbon blacks can wet polymer
segments, because of the increased probability of multiple
adsorptions. The highest concentration of bound rubber is in
the regions between carbon black particles. This reinforcement
restricts the local freedom of movement of macromolecular
chains and thereby improves the solvent resistance. Among the
different fillers used, NBR loaded with ISAF shows the lowest
penetrant interaction. It can be seen that the sorption follows
the order: ISAF 30 < GPF 70 < FEF 60 < SRF 80 < HAF.40
This trend can be explained on the basis of the difference in
filler content, structure, as well as the particle size of fillers
reinforced to the matrix. For maximum reinforcement, the filler
particles must be of the same size or smaller than the
macromolecular chain end-to-end distance [27]. The degree of
filler reinforcement increases with decrease in particle size or
increase in surface area [28]. Bound rubber increases as the
surface area of carbon black increases. The ISAF black
possesses the lowest particle size compared to other blacks used
and hence executes higher degree of reinforcement. This causes
a high resistance to the rubber chain relaxation and thus the free
volume within the matrix gets reduced, which subsequently
restricts the diffusion of penetrants.
The early linearity of our diffusion curve (see Fig. (6)) may be
due to the low equilibrium volume swelling values. The nearly
horizontal part of the curve means that, the rubber blend
degradation or extraction of its soluble ingredients is extremely
small. The slope 1
2
tM
t
of the straight lines at the early part of
the curves in Fig. (6), was calculated, and eM was obtained at
the equilibrium swelling.
Using equations (6) and (7) the penetration rate, P, and the
average diffusion coefficient, Dav, were calculated for all
samples for different fillers (ISAF, HAF, FEF, GPF, and SRF)
at percolation concentrations and plotted against the particle
size as in Fig. (7) From this figure, it is clear that P and D
decrease with decreasing carbon black particle size. This
decrease might be the result of the physical crosslinking action
induced by carbon black aggregates. These aggregates which
exist at different plate lamellae and act as screens reduce the
penetration rate of the solvent molecules into the bulk of the
rubber mixture [29]. Rubber reinforcement caused by the
addition of carbon black restricts the equilibrium swelling.
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Figure. 6. The increase in weight due to swelling (in toluene) for NBR
loaded with the percolation concentration of different carbon blacks
(ISAF, HAF, FEF, GPF, and SRF) against the square root of time, in
minutes.
Figure 7. Variation of penetration rate and diffusion coefficient with
carbon black particle size.
Swelling Behavior
The swelling process and its kinetics give an idea about the
capacity of cross-linked polymer in different liquids and vapor
media [30]. However, the interaction of polymeric materials
with solvents is an increasing problem from both the academic
and technological points of view [31-34].
The mass and dimension of polymer or rubber systems may be
changed due to the penetration of the solvent into swollen
specimen. Therefore swelling process may lead to deformation
or destruction of the sample microstructure. When a cross-
linked polymer is brought into contact with a solvent, the
network absorbs a certain amount of liquid which depends
strongly on the molecular weight of this liquid and the degree
of cross-linked polymer [35, 36]. It was found that the swelling
of carbon black filled-rubbers in organic solvents has a large
effect on its electrical properties [37].
Figure 8. Variation in the degree of swelling Q%, for NBR loaded with
the percolation concentration of different carbon blacks (ISAF, HAF,
FEF, GPF, and SRF), with time of swelling, t, in toluene at 303 K.
Fig. (8) shows the variation in the degree of swelling Q % for
all rubber vulcanizates, with time of swelling, t, in toluene at
303 K. The general behavior may be approximated by an
exponential growth function for all samples showing positive
swelling mechanism of the form:
Table 3 The fitting parameters Qm and τ for all rubber vulcanizates.
Sample d (nm) Area (m2
/g) Qmax (%) (h)
NI30 21 121 30.91 5.5
NH40 27 87 78.37 0.79
NF60 56 41 61.22 0.85
NG70 67 35 22.19 1.09
NS80 79 29 56.42 0.96
{1 exp( / )} mQ Q t (8)
where, Qm is the degree of maximum swelling and τ is a
characteristic time, which depends on the type of carbon black
used, as is clearly observed from Table (3).
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It is noticed that τ is higher for NBR loaded with 30 phr ISAF
and for the rest of samples it increases with increasing of
particle size; in other words, the rate of the relative change of
swelling, 1/, decreases with the increase of the surface area of
carbon black.
Ion Beam Irradiation Induced modifications
Irradiation effects on polymeric material can depend on many
factors, such as linear energy transfer (LET), temperature, dose
rate, irradiation atmosphere, etc [38].
Most polymeric materials are normally dielectrics and many of
them are good insulators. Many methods such as chemical
doping [39,40], ion implantation [41,42], laser annealing etc.
have been used to alter the polymer properties so that the
material becomes conducting. A number of earlier studies [43-
44] have been established that ion implantation increase the
conductivity of the polymer.
The aim of this section is to study the changes in the mechanical
properties of the NBR composites loaded with the percolation
threshold of the different types of carbon black after
implantation with Oxygen ions.
After ion implantations, it was found that the irradiated region
becomes dense shiny black. This is ascribed to the beam
induced carbonization of the sample. The mechanisms
underlying the large improvements for cross-linking in such
sensitive mechanical properties as hardness, and the basic
parameters to control such changes have not yet been well
understood [45] .Yet, there is substantial evidence showing that
improvements in mechanical properties of polymers induced
by ion implantation are largely due to the formation of a three-
dimensionally connected network formed through cross-
linking of polymer chains. Cross-linking produces strong
chemically bonded networks, increases rigidity of the backbone
structure, provides anchoring points for the chains, and
restrains chain movement, thus improving dimensional
stability, hardness and elastic modulus, as well as creep
resistance [46]. There is also evidence that the linear energy
transfer for the ions can be related to changes in hardness.
While Pivin stated that the breaking of chains by nuclear
collisions has no significant effect on hardening of ion
implanted PAN and PIQ [47-48].
Young's modulus for carbon black percolative loading NBR
before and after O2 ion beam irradiation is illustrated in Table
(4) Comparing the results of Young's modulus obtained before
irradiation with those after irradiation, one may notes that it
increased by nearly 2-3 times by irradiation and NG70 sample
is the most affected sample by irradiation. The modulus of a
polymer matrix is proportional to the number of crosslinks
formed [49,50]. Since the degree of crosslinking (involving
both shorter and longer macromolecular chains) is proportional
to the integral radiation dose absorbed by the polymer, an
increase in modulus is observed with an increase in radiation
dose (as detected by the data of degree of maximum swelling,
Qmax, in toluene after ion beam irradiation).
Table 4 Values of Young's modulus and degree of maximum swelling
for carbon black percolative loading NBR composites before and after
O2 ion beam irradiation.
NI30 NH40 NF60 NG70 NS80
Young's
modulus
(MPa)
Before 4.63 4.86 9.89 6.43 12.78
After 9.41 9.52 13.60 17.66 20.03
%mQ
Before 30.91 78.37 61.06 21.52 56.45
After 19.30 54.01 42.75 13.94 35.54
CONCLUSIONS
From the above results one may summarize:
1. The stress-strain behaviors of the composites show
similar trend as well as high initial moduli. The initial
moduli and strength increase with the increase in filler
concentration.
2. Plots of the relative Young's modulus of polymer
composite to that of pure NBR matrix Ec/Em as a function
of both filler type and contents show that it increases with
the filler volume fraction and ISAF filler has the
maximum reinforcement with NBR matrix.
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3. These curves clearly exhibit the existence of a
volume fraction c (≈ 30, 40, 60, 70 and 80 phr for ISAF,
HAF, FEF, GPF and SRF respectively), marking the
transition between two regions defined by the two
different linear dependence on .
4. Pukanszky et al. model fits well the experimental
results of the normalized Young's modulus taking into
consideration the different types of carbon filler.
5. Among the different fillers used, NBR loaded with
ISAF shows the lowest penetrant interaction; and It can be
seen that the sorption follows the order: ISAF 30 < GPF
70 < FEF 60 < SRF 80 < HAF.40.
6. The penetration rate, P, and the average diffusion
coefficient, Dav, decrease with decreasing carbon black
particle size. This decrease might be the result of the
physical crosslinking action induced by carbon black
aggregates.
7. the characteristic time of swelling τ is higher for
NBR loaded with 30 phr ISAF and for the rest of samples
it increases with increasing of particle size; in other words,
the rate of the relative change of swelling, 1/, decreases
with the increase of the surface area of carbon black.
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