This document analyzes heat transfer in internal combustion engine cylinders made from different materials through modeling and simulation. It describes designing a cylinder with dimensions of 0.25m length, 0.25m width and 0.2m height. Materials analyzed include gray cast iron, aluminum, stainless steel, and nickel. Transient thermal analysis in ANSYS is conducted with inside cylinder temperatures of 600°C, 1000°C and 2000°C and outside at 22°C. Graphs show total and directional heat flux over time. Gray cast iron has the lowest heat transfer rate due to its low thermal conductivity but can withstand high temperatures. Aluminum and other lightweight materials are alternatives for weight optimization, though cast iron remains common due to