This research project aims to study the electrocoagulation (EC) process using iron electrodes for water treatment. Specifically, it will apply the EC process to synthetic solutions of methyl orange as a model organic pollutant. The objectives are to optimize the operating conditions of the EC process and identify the mechanisms involved in organic matter removal. Various physicochemical analytical techniques will be used to characterize the implementation and effectiveness of the EC process for removing organic pollutants from water. The research seeks to explore the use of EC with iron electrodes as a promising alternative to conventional water treatment methods, especially those using aluminum, which can cause health issues.
This document discusses electrocoagulation and electrooxidation as electrochemical wastewater treatment technologies. It provides an overview of the fundamentals and processes involved in electrocoagulation, including the electrolytic generation of coagulants through anode dissolution and oxygen/hydrogen generation. It also discusses different types of electrochemical cells used for electrocoagulation and factors like cell configuration, flow patterns and electrode polarity that influence process effectiveness. Electrooxidation processes and various electrode materials and cell designs are also briefly covered.
This document provides an overview of electrocoagulation (EC) as a wastewater treatment process. It describes the basic EC process, which uses sacrificial anode dissolution to introduce metal ions into water that destabilize pollutants. Key factors that affect EC efficiency are discussed, including electrode arrangement, current density, pH, and electrode material. The document also outlines several applications of EC for treating various types of industrial wastewaters and waters containing pollutants like heavy metals, dyes, and organic matter. EC is presented as an effective wastewater treatment alternative that is simple to operate and can remove a wide range of pollutants.
This document describes a hydrometallurgical process for recovering rare earth elements from spent nickel-metal hydride batteries. The process involves three steps:
1) Leaching electrode materials from the batteries in sulfuric acid solutions using ozone as the oxidant, which achieved over 90% recovery of lanthanum, cerium, and neodymium.
2) Separating cobalt and part of the nickel from the leach solution using electrodeposition in an electrochemical reactor.
3) Precipitating the remaining rare earth elements along with the rest of the nickel by adjusting the pH of the solution.
A study on the removal of metal ions by Eichhornia Crassipes Sooraj Garg
The document summarizes a study on using water hyacinth (Eichhornia Crassipes) to remove metal ions from water. It discusses the objectives of studying the plant's efficiency in removing metals and the effect of pH. It reviews literature on the plant's removal of metals like copper, cadmium, and chromium from over 90% within 25 days. The methodology discusses preparing synthetic wastewater with metals like iron, aluminum, copper and chromium at different pH levels and concentrations. Results show the plant removed over 90% of chromium at pH 4.5 but only 33-77% at other pH levels. Iron removal was 78-80% on average. The plant absorbed more iron than other metals.
Advanced Oxidation Process for Industrial Water Treatment and Waste WaterUus Soedjak
This document discusses advanced oxidation processes (AOPs) for water treatment and wastewater. AOPs involve generating strong oxidizing agents like hydroxyl radicals that react with organic contaminants in water. There are several AOP technologies including ozone/ultraviolet irradiation, hydrogen peroxide/ultraviolet irradiation, and Fenton's reaction. While AOPs have been implemented in some industries, their commercial use is still limited due to relatively high costs. The document provides examples of different AOP technologies and references for further information.
New Techniques of wastewater ManagementPrashant Ojha
Wastewater treatment broadly describes water treatment preparing water no longer needed or suitable for its most recent use for return to the water cycle with minimal environmental issues. Wastewater treatment is distinguished from water treatment by focus on disposal rather than use. Water reclamation implies avoidance of disposal by use of wastewater as a raw water supply. Treatment means removing impurities from water being treated; and some methods of treatment are applicable to both water and wastewater. Production of waste brine, however, may discourage wastewater treatment removing dissolved inorganic solids from water by methods like ion exchange, reverse osmosis, and distillation.
Electrocoagulation (EC), is a rapidly growing area of wastewater treatment, less well known as radio frequency diathermy or short wave electrolysis, is a technique used for wash water treatment, wastewater treatment, industrial processed water, and medical treatment. Electricity-based electrocoagulation technology removes contaminants that are generally more difficult to remove by filtration or chemical treatment systems, such as emulsified oil, total petroleum hydrocarbons, refractory organics, suspended solids, and heavy metals. There are many brands of electrocoagulation devices available and they can range in complexity from a simple anode and cathode to much more complex devices with control over electrode potentials, passivation, anode consumption, cell REDOX potentials as well as the introduction of ultrasonic sound, ultraviolet light and a range of gases and reactants to achieve so-called Advanced Oxidation Processes for refractory or recalcitrant organic substances.
This document is a thesis submitted by Okechukwu Pascal Chisom to the Department of Chemical Engineering at Nnamdi Azikiwe University in partial fulfillment of the requirements for a Bachelor's degree in Chemical Engineering. The thesis investigates the use of electrocoagulation technique to remove copper, nickel, and chromium from simulated wastewater. Laboratory experiments are conducted to study the effect of various process parameters such as pH, current density, electrode distance, temperature, charging time, and initial metal ion concentration on the removal efficiency. The results show that electrocoagulation is effective at removing the heavy metals and optimal conditions are identified.
Kinetic model for the sorption of cu (ii) and zn (ii) using lady fernAlexander Decker
This document summarizes a study on the kinetic modeling of copper and zinc ion sorption using lady fern leaf waste biomass. The study found that the rate of copper and zinc sorption was rapid within the initial 5-20 minutes, reaching a maximum in 30 minutes. Kinetic modeling showed the process followed a pseudo-second order model. Equilibrium sorption was examined using Langmuir and Freundlich isotherms, with the Langmuir model revealing a monolayer sorption capacity of 0.09mg/g for both copper and zinc ions. The results indicate lady fern leaf waste could effectively remove toxic metals from industrial effluents.
This document discusses electrocoagulation and electrooxidation as electrochemical wastewater treatment technologies. It provides an overview of the fundamentals and processes involved in electrocoagulation, including the electrolytic generation of coagulants through anode dissolution and oxygen/hydrogen generation. It also discusses different types of electrochemical cells used for electrocoagulation and factors like cell configuration, flow patterns and electrode polarity that influence process effectiveness. Electrooxidation processes and various electrode materials and cell designs are also briefly covered.
This document provides an overview of electrocoagulation (EC) as a wastewater treatment process. It describes the basic EC process, which uses sacrificial anode dissolution to introduce metal ions into water that destabilize pollutants. Key factors that affect EC efficiency are discussed, including electrode arrangement, current density, pH, and electrode material. The document also outlines several applications of EC for treating various types of industrial wastewaters and waters containing pollutants like heavy metals, dyes, and organic matter. EC is presented as an effective wastewater treatment alternative that is simple to operate and can remove a wide range of pollutants.
This document describes a hydrometallurgical process for recovering rare earth elements from spent nickel-metal hydride batteries. The process involves three steps:
1) Leaching electrode materials from the batteries in sulfuric acid solutions using ozone as the oxidant, which achieved over 90% recovery of lanthanum, cerium, and neodymium.
2) Separating cobalt and part of the nickel from the leach solution using electrodeposition in an electrochemical reactor.
3) Precipitating the remaining rare earth elements along with the rest of the nickel by adjusting the pH of the solution.
A study on the removal of metal ions by Eichhornia Crassipes Sooraj Garg
The document summarizes a study on using water hyacinth (Eichhornia Crassipes) to remove metal ions from water. It discusses the objectives of studying the plant's efficiency in removing metals and the effect of pH. It reviews literature on the plant's removal of metals like copper, cadmium, and chromium from over 90% within 25 days. The methodology discusses preparing synthetic wastewater with metals like iron, aluminum, copper and chromium at different pH levels and concentrations. Results show the plant removed over 90% of chromium at pH 4.5 but only 33-77% at other pH levels. Iron removal was 78-80% on average. The plant absorbed more iron than other metals.
Advanced Oxidation Process for Industrial Water Treatment and Waste WaterUus Soedjak
This document discusses advanced oxidation processes (AOPs) for water treatment and wastewater. AOPs involve generating strong oxidizing agents like hydroxyl radicals that react with organic contaminants in water. There are several AOP technologies including ozone/ultraviolet irradiation, hydrogen peroxide/ultraviolet irradiation, and Fenton's reaction. While AOPs have been implemented in some industries, their commercial use is still limited due to relatively high costs. The document provides examples of different AOP technologies and references for further information.
New Techniques of wastewater ManagementPrashant Ojha
Wastewater treatment broadly describes water treatment preparing water no longer needed or suitable for its most recent use for return to the water cycle with minimal environmental issues. Wastewater treatment is distinguished from water treatment by focus on disposal rather than use. Water reclamation implies avoidance of disposal by use of wastewater as a raw water supply. Treatment means removing impurities from water being treated; and some methods of treatment are applicable to both water and wastewater. Production of waste brine, however, may discourage wastewater treatment removing dissolved inorganic solids from water by methods like ion exchange, reverse osmosis, and distillation.
Electrocoagulation (EC), is a rapidly growing area of wastewater treatment, less well known as radio frequency diathermy or short wave electrolysis, is a technique used for wash water treatment, wastewater treatment, industrial processed water, and medical treatment. Electricity-based electrocoagulation technology removes contaminants that are generally more difficult to remove by filtration or chemical treatment systems, such as emulsified oil, total petroleum hydrocarbons, refractory organics, suspended solids, and heavy metals. There are many brands of electrocoagulation devices available and they can range in complexity from a simple anode and cathode to much more complex devices with control over electrode potentials, passivation, anode consumption, cell REDOX potentials as well as the introduction of ultrasonic sound, ultraviolet light and a range of gases and reactants to achieve so-called Advanced Oxidation Processes for refractory or recalcitrant organic substances.
This document is a thesis submitted by Okechukwu Pascal Chisom to the Department of Chemical Engineering at Nnamdi Azikiwe University in partial fulfillment of the requirements for a Bachelor's degree in Chemical Engineering. The thesis investigates the use of electrocoagulation technique to remove copper, nickel, and chromium from simulated wastewater. Laboratory experiments are conducted to study the effect of various process parameters such as pH, current density, electrode distance, temperature, charging time, and initial metal ion concentration on the removal efficiency. The results show that electrocoagulation is effective at removing the heavy metals and optimal conditions are identified.
Kinetic model for the sorption of cu (ii) and zn (ii) using lady fernAlexander Decker
This document summarizes a study on the kinetic modeling of copper and zinc ion sorption using lady fern leaf waste biomass. The study found that the rate of copper and zinc sorption was rapid within the initial 5-20 minutes, reaching a maximum in 30 minutes. Kinetic modeling showed the process followed a pseudo-second order model. Equilibrium sorption was examined using Langmuir and Freundlich isotherms, with the Langmuir model revealing a monolayer sorption capacity of 0.09mg/g for both copper and zinc ions. The results indicate lady fern leaf waste could effectively remove toxic metals from industrial effluents.
IRJET- A Review On Reduction of Phosphate from Industrial Cum Municipal Waste...IRJET Journal
This document reviews technologies for reducing phosphate from industrial and municipal wastewater using Moving Bed Biofilm Reactor (MBBR) technology. It discusses various methods for phosphate removal including physical, chemical, and biological treatments. Specifically, it provides details on MBBR technology, which combines activated sludge and trickling filter processes by using biomass in both suspended flocs and biofilm attached to carriers. The document concludes that MBBR is an effective biological treatment approach for phosphate removal as it can operate at high organic loads and is less sensitive to hydraulic overloading compared to other biological treatment methods.
IRJET- Removal Heavy Metals from Water with CNM IRJET Journal
The document describes a study that aimed to remove heavy metals from water using carbon nano membranes (CNM). It discusses how heavy metals like cadmium, copper, and lead are released into water sources from various industries and how this pollutes drinking water. The study used a multi-stage filtration process to treat wastewater: first with bio-sand filtration, then adding activated carbon and ALOH Np, and finally passing the water through CNM. Water quality parameters like pH, COD, turbidity and heavy metal concentration were tested after each stage. Results showed significant reduction in heavy metals and other contaminants after full treatment, with cadmium, lead and copper all reduced to below detection limits within 24 hours
This document summarizes a study on using electrocoagulation to remove tartrazine dye from simulated wastewater. Tartrazine dye is commonly used in foods, drugs, and textiles but is hazardous. The study investigated the effect of parameters like electrolysis time, dye concentration, pH, and potential on decolorization efficiency. Iron and steel electrodes were used in an electrolytic cell with NaCl electrolyte to treat wastewater samples. Results showed that absorbance decreased with increased time, and maximum removal capacity was achieved. pH was also affected by concentration and time. However, potential changes did not significantly impact absorbance. Overall, electrocoagulation was found to be an effective process for removing the azo dye
This document discusses conventional and biological methods for removing heavy metals from wastewater. It outlines various sources of heavy metal pollution and factors that affect heavy metal removal. Primary methods for removing heavy metals from water include physical and chemical processes, while biological methods include adsorption, the use of activated carbon, agricultural residues, and nanotechnology. Adsorption is recognized as a promising option due to its low cost and ease of use. Both conventional and biological methods should be improved to develop safe and environmentally friendly water treatment techniques.
Selection of an appropriate corrosion inhibitor, inhibitor combination or package is an exceptionally cost
effective and materials saving measure in various industries.
This document discusses key concepts related to waste water treatment including biochemical oxygen demand (BOD), chemical oxygen demand (COD), and dissolved oxygen (DO). BOD measures the amount of oxygen required by microorganisms to break down organic matter in water. COD determines the oxygen required to oxidize organic compounds. DO refers to oxygen dissolved in water that aquatic life requires. The document outlines typical values and measurement methods for BOD, COD and DO in waste and natural waters. It also describes the nature of waste water pollutants and an overview of waste water treatment processes.
This document discusses the impact of organic matter on the performance of LED-based advanced oxidation processes (AOPs). It finds that UV/persulfate was the most effective at removing total organic carbon (TOC), while photo-Fenton and UV/hydrogen peroxide were the least effective at forming disinfection byproducts (DBPs). The document also notes that AOPs performed similarly for TOC reduction after granular activated carbon treatment and water treatment works inlets. It concludes that AOP pre-treatment is not recommended for TOC removal due to producing hydrophilic organics that are difficult to remove.
Electrocoagulation Water Treatment- Water Resource Management in Times of Wat...Nick Nicholas
This presentation discusses innovative water reuse solutions in times of water scarcity utilizing Genesis Water Technologies specialized electrocoagulation water treatment system solutions.
Activated Sludge Process and biological Wastewater treatment systemKalpesh Dankhara
The document discusses biological wastewater treatment, specifically for removing biochemical oxygen demand (BOD) and nitrogen. It covers the types of pollutants found in wastewater, biological treatment methods, microorganisms involved, and the activated sludge process. Key aspects of the activated sludge process discussed include aeration basins, clarifiers, mixed liquor suspended solids, food to mass ratio, recycle and waste sludge streams, and sludge retention time.
Water pollution is one of the environmental challenges facing the world society. Consequently, the pollutants both domestic and industrial wastewater are identified as an environmental threat. Hydrochar (HC) appears as a cost-effective and eco-friendly solution to this environmental threat. HC is the solid produced from the wet pyrolysis process for biomass that is rich in carbon in a sub-critical liquid phase, called the Hydro-Thermal Carbonization Process (HTC). This review aims to address the possibility of using HC as the most effective solution to the industrial wastewater. HTC has proven a greater yield than dry pyrolysis (30%-60% wt). To date, HC is listed as a promising lower-cost alternate adsorbent for removing wastewater pollutants. In Egypt for example, only few studies have been published investigating the properties of HC and its environmental applications. In this review, we will shed light on the preparation, characterization, and previous studies on the development and recent applications of HC. In addition, we will discuss the challenges to produce HC at a commercial scale. To the best of our knowledge, there is only few research studies addressing the HC production in the Middle East countries. Therefore, the door is still opened for more research on developing production techniques on HC from different biomass, and implementation in various environmental applications
The document describes a column study that investigated the efficiency of removing phosphate from wastewater using drinking water treatment sludge (DWTS) and red mud (RM) as adsorbents. Experiments were conducted in glass columns packed with different ratios of DWTS and RM. The effects of adsorbent dose, bed height, contact time, agitation speed, pH, and DWTS-RM ratio on phosphate adsorption were evaluated. The results showed that adding RM to DWTS can significantly increase the operating time of the column, with 33% and 50% RM weight ratios decreasing operating time by 18% and 30% respectively compared to DWTS alone.
Advanced oxidation processes to recover reverse osmosis cleaning watersacciona
Marina Arnaldos, responsable de desalación de desalación y nuevas tecnologías de ACCIONA Agua, presentó la ponencia “Advanced oxidation processes to recover reverse osmosis cleaning waters for irrigation purposes” en la conferencia anual que la asociación europea de desalación ha celebrado en Roma entre los días 22-26 de mayo de 2016.
The radiolytic mineralization of 2-mercaptobenzothiazole, an emerging contami...IRJESJOURNAL
Abstract:The ability of high-energy ionizing radiation has been demonstrated for environmental remediation processing. γ-rayswere applied to treat a solution of 2-mercaptobenzothiazole (2-MBT). 2-MBT (125 µM) was decomposed and mineralized by the γ-radiation. The absorbed doses for 50 and 90% 2-MBT degradation were 0.170 and 0.650 kGy, respectively. Organic by-products were almost fully mineralized when high-absorbed doses in the range of 5-60 kGy were applied. Sulfate radicals (SO4 ●– ) produced through the rapid reaction of persulfate ions (S2O8 2– ) with hydrated electrons(eaq − ; keaq − /S2O8 2– = 1.1 × 1010 M −1 .s−1 ) had a significant effect on the 2-MBT mineralization yield. Because of 2-MBT decomposition,sulfate ions (SO4 2− ) were formed, and thepH and dissolved oxygen concentration were decreased. The degradation efficiency decreased when HCO3 –was added to the 2- MBT solution. No significant effects of NO3 – and Cl– ions on 2-MBT radiolytic eliminationwere observed
This document presents a project proposal for analyzing the biological components of groundwater in selected industrial and residential areas in Chinhoyi, Zimbabwe. It introduces the significance of groundwater and issues of contamination from human and other activities. Key water quality parameters that will be analyzed include microbiological (total coliform, E. coli), chemical (COD, BOD), and physical properties. Methodologies for sample collection, handling, and analyzing COD, BOD and total coliform are described, including calculations. Health risks of coliform contamination are also discussed. The analysis will assess water quality and identify sources of pollution to inform water management.
This document summarizes a seminar presentation on determining sewage quality using the chemical oxygen demand (COD) method. It defines COD as the total oxygen required to chemically oxidize organic matter in water. The presentation covers the history of COD testing using different oxidizing agents, the dichromate principle method, and calculations to determine COD levels in mg/L. Advantages are that COD results are faster than biochemical oxygen demand testing and more compounds are oxidized, while disadvantages are COD cannot differentiate biologically reactive compounds.
Dissolved Oxygen Demand (DO) AND Chemical Oxygen Demand (COD) PDFchetansingh999
Dissolved oxygen (DO) refers to the level of oxygen present in water or other liquids. It is important for assessing water quality and supporting aquatic life. Chemical oxygen demand (COD) measures the amount of oxygen required to chemically break down pollutants in water. DO enters water through diffusion from air and as a byproduct of photosynthesis. It can be measured using electrochemical, optical, or colorimetric methods. COD is determined by using potassium dichromate as an oxidizing agent under acidic conditions, then measuring the amount of chromium formed.
The document discusses two offshore oilfield projects in Southeast Asia that are pioneering the use of customized water treatment to improve oil recovery. Both projects require treated seawater to be injected into reservoirs for chemical EOR processes. A pilot study tested a proprietary reverse osmosis and nanofiltration system to treat seawater and produce different water qualities required by the two projects. The pilot demonstrated the system could reliably achieve various water quality targets and respond quickly to changes. This indicates the system may be suitable to meet the unique water treatment needs of chemical EOR applications in offshore environments.
Evaluation of the levels of haloacetic acids in gharbiya governorate, egypt[#...Ahmed Hasham
The occurrence of haloacetic acids (HAAs) was studied in the drinking water samples from Gharbiya
governorate water treatment plants and its water supply network that served more than 5 million people. Drinking
water disinfection by-products are formed when a disinfectant reacts with natural organic matter and/or
bromide/iodide present in a raw water source. Trihalomethanes and haloacetic acids are the two most prevalent
classes of DBPs and are regulated by the US Environmental Protection Agency as well as being subject to World
Health Organization guidelines due to their potential health risk. Drinking water samples were collected from 4
sites monthly over one year (2017-2018). The aims of the present study are to investigate the levels of HAAs in
Gharbiya governorate (middle of Delta Egypt) drinking water. monochloroacetic acid ranged from 6.8 to 32.5
µg/L, dichloroacetic acid ranged from 9.8 to 43.7 µg/L, and the trichloroacetic acid ranged from 6.5 to 31.8 µg/L,
the minimum values observed during winter 2018 and the maximum value observed during summer 2017., The
HAAs species values were complying with the Egyptian standard (Ministerial Decree No.458/2007) and as well
as WHO 2012) standards for drinking water
01 Judd Sundine - Mine Water Solutions in Extreme Environments 2015Judd Sundine
This document summarizes an article on using electrocoagulation (EC) to remove heavy metals and other contaminants from mine wastewater in an innovative, economical, and efficient way. EC uses electric current passed through metal blades in water to destabilize particles, allowing contaminants to be removed through precipitation and filtration. EC has been shown to remove over 99% of some heavy metals and is more cost effective than traditional chemical coagulation methods. The produced sludge meets standards for non-hazardous waste disposal.
Screening and extraction of heavy metals from anaerobically digested sewage s...IRJET Journal
This document summarizes a study that investigated screening and extracting heavy metals from anaerobically digested sewage sludge using citric acid. The study characterized the sewage sludge and found heavy metal concentrations of copper, lead, nickel and zinc to be above regulatory standards. It then used a full factorial experimental design to study the effects of pH, hydrogen peroxide dosage, and extraction time on removing the heavy metals. Lead removal was highest at 99.9%, followed by nickel, copper and zinc. Statistical analysis found extraction time and hydrogen peroxide dosage to most significantly impact heavy metal removal efficiency.
IRJET- A Review On Reduction of Phosphate from Industrial Cum Municipal Waste...IRJET Journal
This document reviews technologies for reducing phosphate from industrial and municipal wastewater using Moving Bed Biofilm Reactor (MBBR) technology. It discusses various methods for phosphate removal including physical, chemical, and biological treatments. Specifically, it provides details on MBBR technology, which combines activated sludge and trickling filter processes by using biomass in both suspended flocs and biofilm attached to carriers. The document concludes that MBBR is an effective biological treatment approach for phosphate removal as it can operate at high organic loads and is less sensitive to hydraulic overloading compared to other biological treatment methods.
IRJET- Removal Heavy Metals from Water with CNM IRJET Journal
The document describes a study that aimed to remove heavy metals from water using carbon nano membranes (CNM). It discusses how heavy metals like cadmium, copper, and lead are released into water sources from various industries and how this pollutes drinking water. The study used a multi-stage filtration process to treat wastewater: first with bio-sand filtration, then adding activated carbon and ALOH Np, and finally passing the water through CNM. Water quality parameters like pH, COD, turbidity and heavy metal concentration were tested after each stage. Results showed significant reduction in heavy metals and other contaminants after full treatment, with cadmium, lead and copper all reduced to below detection limits within 24 hours
This document summarizes a study on using electrocoagulation to remove tartrazine dye from simulated wastewater. Tartrazine dye is commonly used in foods, drugs, and textiles but is hazardous. The study investigated the effect of parameters like electrolysis time, dye concentration, pH, and potential on decolorization efficiency. Iron and steel electrodes were used in an electrolytic cell with NaCl electrolyte to treat wastewater samples. Results showed that absorbance decreased with increased time, and maximum removal capacity was achieved. pH was also affected by concentration and time. However, potential changes did not significantly impact absorbance. Overall, electrocoagulation was found to be an effective process for removing the azo dye
This document discusses conventional and biological methods for removing heavy metals from wastewater. It outlines various sources of heavy metal pollution and factors that affect heavy metal removal. Primary methods for removing heavy metals from water include physical and chemical processes, while biological methods include adsorption, the use of activated carbon, agricultural residues, and nanotechnology. Adsorption is recognized as a promising option due to its low cost and ease of use. Both conventional and biological methods should be improved to develop safe and environmentally friendly water treatment techniques.
Selection of an appropriate corrosion inhibitor, inhibitor combination or package is an exceptionally cost
effective and materials saving measure in various industries.
This document discusses key concepts related to waste water treatment including biochemical oxygen demand (BOD), chemical oxygen demand (COD), and dissolved oxygen (DO). BOD measures the amount of oxygen required by microorganisms to break down organic matter in water. COD determines the oxygen required to oxidize organic compounds. DO refers to oxygen dissolved in water that aquatic life requires. The document outlines typical values and measurement methods for BOD, COD and DO in waste and natural waters. It also describes the nature of waste water pollutants and an overview of waste water treatment processes.
This document discusses the impact of organic matter on the performance of LED-based advanced oxidation processes (AOPs). It finds that UV/persulfate was the most effective at removing total organic carbon (TOC), while photo-Fenton and UV/hydrogen peroxide were the least effective at forming disinfection byproducts (DBPs). The document also notes that AOPs performed similarly for TOC reduction after granular activated carbon treatment and water treatment works inlets. It concludes that AOP pre-treatment is not recommended for TOC removal due to producing hydrophilic organics that are difficult to remove.
Electrocoagulation Water Treatment- Water Resource Management in Times of Wat...Nick Nicholas
This presentation discusses innovative water reuse solutions in times of water scarcity utilizing Genesis Water Technologies specialized electrocoagulation water treatment system solutions.
Activated Sludge Process and biological Wastewater treatment systemKalpesh Dankhara
The document discusses biological wastewater treatment, specifically for removing biochemical oxygen demand (BOD) and nitrogen. It covers the types of pollutants found in wastewater, biological treatment methods, microorganisms involved, and the activated sludge process. Key aspects of the activated sludge process discussed include aeration basins, clarifiers, mixed liquor suspended solids, food to mass ratio, recycle and waste sludge streams, and sludge retention time.
Water pollution is one of the environmental challenges facing the world society. Consequently, the pollutants both domestic and industrial wastewater are identified as an environmental threat. Hydrochar (HC) appears as a cost-effective and eco-friendly solution to this environmental threat. HC is the solid produced from the wet pyrolysis process for biomass that is rich in carbon in a sub-critical liquid phase, called the Hydro-Thermal Carbonization Process (HTC). This review aims to address the possibility of using HC as the most effective solution to the industrial wastewater. HTC has proven a greater yield than dry pyrolysis (30%-60% wt). To date, HC is listed as a promising lower-cost alternate adsorbent for removing wastewater pollutants. In Egypt for example, only few studies have been published investigating the properties of HC and its environmental applications. In this review, we will shed light on the preparation, characterization, and previous studies on the development and recent applications of HC. In addition, we will discuss the challenges to produce HC at a commercial scale. To the best of our knowledge, there is only few research studies addressing the HC production in the Middle East countries. Therefore, the door is still opened for more research on developing production techniques on HC from different biomass, and implementation in various environmental applications
The document describes a column study that investigated the efficiency of removing phosphate from wastewater using drinking water treatment sludge (DWTS) and red mud (RM) as adsorbents. Experiments were conducted in glass columns packed with different ratios of DWTS and RM. The effects of adsorbent dose, bed height, contact time, agitation speed, pH, and DWTS-RM ratio on phosphate adsorption were evaluated. The results showed that adding RM to DWTS can significantly increase the operating time of the column, with 33% and 50% RM weight ratios decreasing operating time by 18% and 30% respectively compared to DWTS alone.
Advanced oxidation processes to recover reverse osmosis cleaning watersacciona
Marina Arnaldos, responsable de desalación de desalación y nuevas tecnologías de ACCIONA Agua, presentó la ponencia “Advanced oxidation processes to recover reverse osmosis cleaning waters for irrigation purposes” en la conferencia anual que la asociación europea de desalación ha celebrado en Roma entre los días 22-26 de mayo de 2016.
The radiolytic mineralization of 2-mercaptobenzothiazole, an emerging contami...IRJESJOURNAL
Abstract:The ability of high-energy ionizing radiation has been demonstrated for environmental remediation processing. γ-rayswere applied to treat a solution of 2-mercaptobenzothiazole (2-MBT). 2-MBT (125 µM) was decomposed and mineralized by the γ-radiation. The absorbed doses for 50 and 90% 2-MBT degradation were 0.170 and 0.650 kGy, respectively. Organic by-products were almost fully mineralized when high-absorbed doses in the range of 5-60 kGy were applied. Sulfate radicals (SO4 ●– ) produced through the rapid reaction of persulfate ions (S2O8 2– ) with hydrated electrons(eaq − ; keaq − /S2O8 2– = 1.1 × 1010 M −1 .s−1 ) had a significant effect on the 2-MBT mineralization yield. Because of 2-MBT decomposition,sulfate ions (SO4 2− ) were formed, and thepH and dissolved oxygen concentration were decreased. The degradation efficiency decreased when HCO3 –was added to the 2- MBT solution. No significant effects of NO3 – and Cl– ions on 2-MBT radiolytic eliminationwere observed
This document presents a project proposal for analyzing the biological components of groundwater in selected industrial and residential areas in Chinhoyi, Zimbabwe. It introduces the significance of groundwater and issues of contamination from human and other activities. Key water quality parameters that will be analyzed include microbiological (total coliform, E. coli), chemical (COD, BOD), and physical properties. Methodologies for sample collection, handling, and analyzing COD, BOD and total coliform are described, including calculations. Health risks of coliform contamination are also discussed. The analysis will assess water quality and identify sources of pollution to inform water management.
This document summarizes a seminar presentation on determining sewage quality using the chemical oxygen demand (COD) method. It defines COD as the total oxygen required to chemically oxidize organic matter in water. The presentation covers the history of COD testing using different oxidizing agents, the dichromate principle method, and calculations to determine COD levels in mg/L. Advantages are that COD results are faster than biochemical oxygen demand testing and more compounds are oxidized, while disadvantages are COD cannot differentiate biologically reactive compounds.
Dissolved Oxygen Demand (DO) AND Chemical Oxygen Demand (COD) PDFchetansingh999
Dissolved oxygen (DO) refers to the level of oxygen present in water or other liquids. It is important for assessing water quality and supporting aquatic life. Chemical oxygen demand (COD) measures the amount of oxygen required to chemically break down pollutants in water. DO enters water through diffusion from air and as a byproduct of photosynthesis. It can be measured using electrochemical, optical, or colorimetric methods. COD is determined by using potassium dichromate as an oxidizing agent under acidic conditions, then measuring the amount of chromium formed.
The document discusses two offshore oilfield projects in Southeast Asia that are pioneering the use of customized water treatment to improve oil recovery. Both projects require treated seawater to be injected into reservoirs for chemical EOR processes. A pilot study tested a proprietary reverse osmosis and nanofiltration system to treat seawater and produce different water qualities required by the two projects. The pilot demonstrated the system could reliably achieve various water quality targets and respond quickly to changes. This indicates the system may be suitable to meet the unique water treatment needs of chemical EOR applications in offshore environments.
Evaluation of the levels of haloacetic acids in gharbiya governorate, egypt[#...Ahmed Hasham
The occurrence of haloacetic acids (HAAs) was studied in the drinking water samples from Gharbiya
governorate water treatment plants and its water supply network that served more than 5 million people. Drinking
water disinfection by-products are formed when a disinfectant reacts with natural organic matter and/or
bromide/iodide present in a raw water source. Trihalomethanes and haloacetic acids are the two most prevalent
classes of DBPs and are regulated by the US Environmental Protection Agency as well as being subject to World
Health Organization guidelines due to their potential health risk. Drinking water samples were collected from 4
sites monthly over one year (2017-2018). The aims of the present study are to investigate the levels of HAAs in
Gharbiya governorate (middle of Delta Egypt) drinking water. monochloroacetic acid ranged from 6.8 to 32.5
µg/L, dichloroacetic acid ranged from 9.8 to 43.7 µg/L, and the trichloroacetic acid ranged from 6.5 to 31.8 µg/L,
the minimum values observed during winter 2018 and the maximum value observed during summer 2017., The
HAAs species values were complying with the Egyptian standard (Ministerial Decree No.458/2007) and as well
as WHO 2012) standards for drinking water
01 Judd Sundine - Mine Water Solutions in Extreme Environments 2015Judd Sundine
This document summarizes an article on using electrocoagulation (EC) to remove heavy metals and other contaminants from mine wastewater in an innovative, economical, and efficient way. EC uses electric current passed through metal blades in water to destabilize particles, allowing contaminants to be removed through precipitation and filtration. EC has been shown to remove over 99% of some heavy metals and is more cost effective than traditional chemical coagulation methods. The produced sludge meets standards for non-hazardous waste disposal.
Screening and extraction of heavy metals from anaerobically digested sewage s...IRJET Journal
This document summarizes a study that investigated screening and extracting heavy metals from anaerobically digested sewage sludge using citric acid. The study characterized the sewage sludge and found heavy metal concentrations of copper, lead, nickel and zinc to be above regulatory standards. It then used a full factorial experimental design to study the effects of pH, hydrogen peroxide dosage, and extraction time on removing the heavy metals. Lead removal was highest at 99.9%, followed by nickel, copper and zinc. Statistical analysis found extraction time and hydrogen peroxide dosage to most significantly impact heavy metal removal efficiency.
IRJET- Electrocoagulation Treatment of Electroplating Industrial EffluentIRJET Journal
The document discusses electrocoagulation treatment of electroplating industrial effluent. Electrocoagulation uses aluminum electrodes connected to a power source, generating aluminum ions and hydroxide ions that remove pollutants from the effluent. The study treated electroplating effluent with high levels of zinc and nickel. Treatment at 4A/m2 current density for 120 minutes reduced zinc levels by 78.9%, but did not significantly reduce nickel levels due to the effluent's low initial pH of 1.7. Increasing pH improved removal of both metals during electrocoagulation treatment.
ANALYSIS OF HYDROGEOCHEMICAL AND MINERALOGICAL CHARACTERISTICS RELATED TO HEA...IRJET Journal
This document analyzes the hydrogeochemical and mineralogical characteristics related to heavy metal attenuation in a stream polluted by acid mine drainage from an underground metal mine. Water and sediment samples were collected from affected and unaffected areas. Chemical analysis showed affected water had low pH, high sulfate concentrations, and high heavy metal levels. Heavy metal concentrations decreased downstream as pH increased. Mineralogical analysis identified iron oxide minerals like schwertmannite and goethite precipitating from acid mine drainage. Sequential extraction showed heavy metals were primarily bound to iron oxide phases farther from the mine, but closer to the mine they were more exchangeable and bound to organic matter. The study concludes acid mine drainage chemistry is controlled by iron mineral transformations and precip
Hydrogen Gas Production from Tannery Wastewater by Electrocoagulation of a Co...IOSRJAC
The performance of a continuous electrocoagulation (EC) process was investigated for tannery wastewater treatment using aluminum and iron electrodes. The effects of the operating parameters, such as current density, pH of solution and inlet flow rate, on pollutants removal efficiency and recovery of hydrogen gas were investigated in order to optimize process performance. In the case of aluminum electrodes, The results showed that for tannery wastewater with an influent pH adjusted at about 6, the use of a current density of 14 mA/cm2 , and an EC time of 125 min, gave access to pollutants (COD, Color, Cr, and NH3-N) removal efficiency 73, 94, 100 and 51%, respectively. The energy yield of harvested hydrogen was 16% of the electrical energy demand of the electrocoagulation process. However, in the case of iron electrodes, with effluent pH adjusted at about 7, , the use of a current density of 14 mA/cm2 , and an EC time of 125 min, gave access to pollutants (COD, Color, Cr, and NH3-N) removal efficiency 67, 93, 100 and 46 %, respectively. And also, the energy yield of harvested hydrogen was 15 % of the electrical energy demand of the electrocoagulation process. Thus, the operating costs for two cases were found to be 0.675 $/m3 wastewater. It could be seen that hydrogen gas production coupled with pollutants removal efficiency by EC continuous mode would be an effective approach for energy recovery and wastewater reutilization.
Biosorption of cu(ii) ions from aqueous solution usingAlexander Decker
This document summarizes a study that investigated using neem leaf powder as a biosorbent for removing copper (Cu(II)) ions from aqueous solutions. Characterization of the neem leaf powder was conducted including analysis of surface area, functional groups, and surface morphology. Batch biosorption experiments were performed to examine the effects of contact time, copper ion concentration, and chemical treatment on copper ion removal. The neem leaf powder was found to have a surface area of 2.3102 m2/g and contained functional groups like hydroxyl and carboxyl that could bind copper ions. Chemical modification with sodium hydroxide improved copper ion uptake. Equilibrium was reached within 60-120 minutes and removal efficiency decreased with increasing
Biosorption of cu(ii) ions from aqueous solution usingAlexander Decker
This document summarizes a study that investigated using neem leaf powder as a biosorbent for removing copper (Cu(II)) ions from aqueous solutions. Key findings include:
- The neem leaf powder had a surface area of 2.3102 m2/g, within the range of other biosorbents. Scanning electron microscopy and energy-dispersive X-ray spectroscopy analysis showed copper binding to the leaf powder.
- Fourier transform infrared spectroscopy analysis indicated hydroxyl and carboxyl functional groups were involved in copper ion biosorption via mechanisms like ion exchange and complexation.
- Batch experiments found equilibrium was reached within 60-120 minutes and biosorption capacity decreased with increasing initial
Investigation on the Effect of TiO2 and H2O2 for the Treatment of Inorganic C...inventy
Sodium hypochlorite (NaClO) is regularly used as a disinfectant or a bleaching agent because of its high efficiency against many bacteria and viruses present in seawater along with its cheaper cost. Now a days, with the increase in the environmental concerns concerning the use of chlorination for the disinfection or bleaching of treated water related to the formation of potentially harmful chloro-organic by products through reactions with natural organic matter (NOM), it is preferred to implement a process with environmentally friendly chemicals for water treatment processes. About This report aim to study the possibility of reducing the inorganic carbon present in seawater by oxidization reaction of seawater with TiO2 and H2O2. Investigated and a comparison between thin film method and suspension method with a reactor system in conjunction with a light concentrating system has been done.
IRJET- Physical, Chemical, Analysis of Ground Water Around the Eletroplating ...IRJET Journal
This document discusses the removal of heavy metals from industrial wastewater using low-cost agricultural waste materials as adsorbents. It begins by introducing the problem of heavy metal pollution from industries like electroplating. It then provides background on adsorption as a method for wastewater treatment and removal of toxins like lead, chromium, and nickel. The document examines the use of inexpensive adsorbents derived from agricultural waste including maize cob, coffee husk, and cashewnut husk to purify industrial effluent in a cost-effective way. In summary, the document explores a natural approach for remediating heavy metal contamination through adsorption onto low-cost adsorbents from agricultural by
IRJET- Application of Electrocoagulation in Wastewater Treatment: A General R...IRJET Journal
This document reviews the use of electrocoagulation (EC) for wastewater treatment from various industries. EC is a process that uses electric current to pass between metal electrodes in wastewater, treating contaminants without adding chemicals. The document summarizes research on EC for 8 types of wastewater. For municipal wastewater, EC using aluminum electrodes achieved 83.5% COD and 96.9% TSS removal within 60 minutes at low current density. For dairy wastewater, high voltages like 60V over 60 minutes removed over 98% of COD, BOD and TSS. EC has also been shown to effectively treat wastewater from paper/pulp, textiles, landfill le
IRJET- Review on Removel of Heavy Metal using Low - Cost AbsorbentsIRJET Journal
The document reviews the use of low-cost adsorbents for removing heavy metals from wastewater. It discusses how agricultural and industrial wastes can be used effectively as adsorbents due to their low cost. Several studies are summarized that prepared activated carbon from rice husk and used composites of rice husk and polyvinylpyrrolidone to adsorb heavy metals. Other research prepared adsorbents from banana peels and grafted acrylonitrile onto them for chromium removal. Agricultural wastes like African spinach stalk and papaya seeds were also effective at removing metals like manganese and lead. The review concludes that adsorbents produced from cheap, locally available materials like rice hus
This document summarizes a study that investigated the biosorption of cadmium (Cd) from aqueous solution onto sweet potato skin (SPS). The amount of Cd adsorbed was found to depend on solution pH, contact time, and initial Cd concentration. Equilibrium data fit the Freundlich isotherm model best. Thermodynamic parameters indicated the adsorption process was spontaneous and endothermic in nature. The study characterized the functional groups of SPS and evaluated it as a potential low-cost biosorbent for removing heavy metals like Cd from wastewater.
REMOVAL OF CADMIUM CD (II) AND SILVER AG (I) FROM AQUEOUS SOLUTIONS BY NANO A...IAEME Publication
The extent of removal of heavy metal ions (cadmium and silver) in single and binary system by adsorption on alumina has been investigated. Adsorption experiments were performed in continues flow technique (fixed bed) from synthetic solutions using alumina as adsorbent. Several experimental parameters that affect the extent of adsorption of the metal ions of interest have been investigated such as adsorbent bed depth and concentration of the adsorbate with different contact time. The percent of removal efficiency was also been studied. pH of the system used equal =6.5, temperature =25ºC. This work proposes a cost-effective method for the efficient removal of Cd (II) and Ag (I) from aqueous solutions.
IRJET- Treatment of Tannery Wastewater using Plain and Punched Iron Elect...IRJET Journal
This document summarizes a study on treating tannery wastewater using plain and punched iron electrodes via electrocoagulation. Tannery wastewater contains high levels of COD, TDS, chromium and other pollutants that are harmful if discharged untreated. The study examines the effect of parameters like pH, voltage, electrolysis time and electrode shape on removal efficiency of COD, TDS and chromium. Optimum removal of 96.56% COD, 96.16% chromium and 94.62% TDS was achieved at pH 9, voltage of 15V, electrolysis time of 90 minutes and using punched iron electrodes. Electrocoagulation using iron electrodes was found to be an effective process for
Biosorption of Copper (II) Ions by Eclipta Alba Leaf Powder from Aqueous Solu...ijtsrd
The removal of heavy metals from industrial wastewater is of great concern as heavy metals are non-biodegradable, toxic elements that cause serious health problems if disposed of in the surrounding environment. The present study, Karisalangkani (Eclipta Alba) leaves were used for the adsorption of heavy metals like copper (Cu (II)) ions. The bio sorbent was characterized using SEM and BET analysis. The bio sorption experiments are conducted through batch system. The operating parameters studied were initial metal ion concentration, adsorbent dosage, initial solution pH, contact time and effect of temperature Adsorption equilibrium is achieved in 30 min and the adsorption kinetics of Cu (II) is found to follow a pseudo-second-order kinetic model. Equilibrium data for Cu (II) adsorption are fitted well by Langmuir isotherm model. The maximum adsorption capacity for Cu (II) ions is estimated to be 9.2 mgg at 25 °C. The experimental result shows that the materials have good potential to remove heavy metals from effluent and good potential as an alternate low cost adsorbent. Due to their outstanding adsorption capacities, Eclipta Alba is excellent sorbents for the removal of copper (II) ions. B. Kavitha | R. Arunadevi"Biosorption of Copper (II) Ions by Eclipta Alba Leaf Powder from Aqueous Solutions" Published in International Journal of Trend in Scientific Research and Development (ijtsrd), ISSN: 2456-6470, Volume-2 | Issue-5 , August 2018, URL: http://www.ijtsrd.com/papers/ijtsrd17156.pdf http://www.ijtsrd.com/chemistry/environmental-chemistry/17156/biosorption-of-copper-ii-ions-by-eclipta-alba-leaf-powder-from-aqueous-solutions/b-kavitha
Deconttamination of a solution of chromiumIV by marine algae (ulva-lactuca)AM Publications
This document discusses the ability of the marine algae Ulva lactuca to remove chromium from contaminated water solutions. The researchers studied how various factors like pH, algae mass, contact time, and agitation influence the bio-sorption of chromium by U. lactuca. Their results showed that bio-sorption percentage was highest (84%) at pH 5 using 4g of algae biomass. Chromium removal reached 96% at pH 5 using 1g algae over contact times greater than 3 days. Chromium uptake increased rapidly in the first 30 minutes when solutions were agitated. The data fit the Langmuir adsorption isotherm model well, indicating homogeneous binding sites on the algal surface.
TREATING WASTE WATER USING ELECTROCOAGULATION APPROACHIAEME Publication
Performance of Electro coagulation method is evaluated by treating various
sources of water. The electrodes of stainless steel are used for arranging electrolytic
cell. The treatment efficiency is assessed by varying electrical potential and
concentration time. The parameters namely pH, Total Dissolved Solids (TDS), Total
Hardness, Electrical Conductivity, Biochemical Oxygen Demand (BOD) and
Chemical Oxygen Demand (COD) were tested and results were compared to assess
the performance of treatment process. Effects of operating parameters such as
varying electrical potential (3V-12V) and concentration time (10 minutes- 30 minutes)
were evaluated for optimum operating conditions. The result shown that identified
electrolytic arrangement is significantly efficient for treating BOD and COD when
compared to other water quality parameters especially for grey and industrial water
samples. The highest removal efficiency under optimum operating condition for COD
and BOD removal were obtained with 58% and 67% in grey water sample whereas in
industrial waste water sample, the efficiencies are 53% and 57%. Further, the study
suggested the various simulations in the operating parameters with the economic
considerations to optimize the findings and for upcoming progress in the application
of this advanced technology.
Removal of boron from mining wastewaters by electrocoagulation method: Modell...Thiago Ribeiro
The model with a topology of 3-10-1 (corresponding
to input, hidden, and output neurons, respectively) provided satisfactory results in the identification of the optimal conditions.
IRJET- Treatment of Galvanized Waste Water in Industry OutletIRJET Journal
The document discusses the treatment of wastewater from galvanized industries using adsorption processes. Natural adsorbents like watermelon rinds, citrus lemon, and hyacinth plants are used to remove heavy metals like iron, ammonium, and chloride ions from the wastewater. Experiments show the adsorption process is effective and economical for reducing the concentration of these contaminants. The optimum parameters for removing iron, ammonium, and chloride are identified as contact time of 90 minutes, adsorbent dosage of 60mg/L, and initial concentrations of 33mg/L, 23mg/L, and 771mg/L respectively. The treated water can be reused for irrigation after the contamin
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2. 1الوثيقة رقمFRM0065R01
Summary of Research (English)
The production of chemical reagents used in desalination and water treatment satisfying the high
quality standards and the required quantities is a crucial research axis for both human health and
technical and economic reasons. Chemical methods are widely used for the production of such
reagents. However, their efficiencies for natural organic matter (NOM) and artificial organic matter
(AOM) are poor in comparison with electrochemical techniques. These processes are proved more
advantageous for technical and economic reasons. As an electrochemical technology,
electrocoagulation (EC) process using iron electrodes has been shown as a promising for
water/wastewater treatment and seawater pretreatment. This research project aims to study the EC
process using iron electrodes for iron coagulant species’ production for water treatment. The work
focuses on the application of the electrochemical process on synthetic solutions of methyl orange
(MO). MO is chosen as a model of NOM and AOM. The EC process is the updated version of the
chemical coagulation since it uses the electric current to produce in situ cationic metallic species as
coagulants and flocculants. The EC process is becoming largely used due to its several advantages
in comparison with the conventional coagulation. Iron salts are largely used during the last two
decades in comparison with aluminum salts. This is due to several health problems (e.g., Alzheimer
disease) caused by using aluminum in chemical coagulation process. Consequently, the originality
of this research project is the application of a new process (i.e., EC) using a green chemical product
(iron instead of aluminum). In the surface water, NOM and AOM are frequently present and must
be removed. This is why MO is chosen to represent these organic matters. The project aims to
identify the optimal operating conditions and the involved mechanisms in the EC process for
organic matter removal. Physicochemical analytical methods will be used in order to characterize
the implementation of the EC process in local water treatment plants in Saudi Arabia.
Introduction
The scarcity of the water resources in the Saudi Arabia constitutes severe problems. These problems
are accentuated with the growing population and industrial pollutions. Surface water treatment
technology applied in Saudi Arabia is mainly conventional, i.e. coagulation/flocculation, settling,
filtration and disinfection. The low efficiencies of these classical processes in terms of organic
matters removal have pushed water treatment researchers to develop new technologies such as
electrochemical processes. These processes, especially electrocoagulation (EC), know large
successful applications in both water and wastewater treatment. On the other hand, aluminum salts,
which were largely used, are substituted with iron salts due to some provoked health problems
(Alzheimer disease). Consequently, this work constitutes a new research axis and aims to optimize
3. 2الوثيقة رقمFRM0065R01
EC process operating conditions. A particular focus will be made on the organic matters removal
mechanism. Indeed, these objectives may be reached through the EC process application, using iron
electrodes, on synthetic solutions of methyl orange (MO).
Objectives / األهداف
This research project can serve the kingdom of Saudi Arabia Vision 2030 in many aspects such as
Water Desalination, Wastewater Reuse and Pollution Management. This project aims to achieve the
following objectives:
The main objectives of this Research Project are:
1. The optimization of the operating conditions of EC process for methyl orange (MO) removal
using response surface method (RSM).
2. The study of the implicated mechanisms in the EC process using analytical techniques such as
Gas Chromatography/Mass Spectrometry, Ultraviolet-visible, Atomic Absorption Spectrometry and
Fourier Transform Infra-Red.
3. To suggest an adequate procedure for industrial application of the EC process taking in
consideration the organic matter removal.
Literary Survey / األدبي المسح
It is well known that natural organic matter (NOM) and artificial organic matter (AOM) in water
constitute grave health problems. Therefore, their elimination is imposed for several causes: (1)
affect organoleptic features of water (color, taste and odor), (2) react with most oxidants employed
in treating water, thus diminishing their disinfection potential, (3) influence oxidant need, (4)
produce disinfection by-products (DBPs), (5) affect elimination of inorganic solids, (6) influence
coagulant need, (7) could disturb coagulation parameters and efficiency, (7) affect corrosion
phenomena, (8) foul membranes, (11) reduce adsorption potential of granular activated carbon
(GAC)/powder activated carbon (PAC) via pore fouling, and compete with taste and odor for
adsorption sites in GAC/PAC [1-11].
In the water treatment industry, coagulation and flocculation are largely employed. During such
chemical techniques, chemicals (mainly aluminum or iron salts) and different products (like
polyelectrolytes) are injected in water to form bigger agglomerates that could be retained by
decantation process. Coagulation and flocculation needs important land area and a huge supply of
chemical products. Consequently, a more cost-effective technique to purify a large set of
contaminated water is requested for treating water efficiently. Electrocoagulation (EC) treatment of
water could meet this requirement [12-17]. EC implies dissolution of metal from the anode with
concomitant generation of OH-
and H2(g) taking place at the cathode [18-23]. Usually, the EC
4. 3الوثيقة رقمFRM0065R01
devices are employed as a substitution of chemical injection setups and do not benefit from the H2(g)
produced in the EC process. Therefore, EC possesses the potential to eliminate a huge set of
contaminants: suspended solids; heavy metals; petroleum products; color from dye-containing
solution; aquatic humus; and defluoridation of water [24-29].
Research Design and Methodology / البحث ومنهجية تصميم
The project approach consists of the following tasks:
- Bibliographic research.
- Preliminary analysis and experiments.
- Optimization of the experimental conditions of EC process for methyl orange (MO) removal using
RSM.
- Advanced analysis and experiments using design of experiment technology.
- Suggestion of the implicated mechanisms in the EC process using analytical techniques such as
Gas Chromatography/Mass Spectrometry, Ultraviolet-visible, Atomic Absorption Spectrometry and
Fourier Transform Infra-Red.
- Methodology for the industrial application of the EC process as an efficient water treatment
technology, taking in consideration the removal of the organic matter.
- Publications and communications of the obtained results.
- Final report.
Research Management Plan / البحث خطة إدارة
The roles and involvements duration of the Research Group in this proposal are presented below:
Dr. Djamel Ghernaout (Principal Investigator, during the year of the research project):
- General supervision of the project and coordination among team members.
- Purchase of equipment and chemicals
- Publications and communications of the obtained results
- Progress and Final Report for project
Dr. Noureddine Elboughdiri and Dr. Saleh Alarni (Co-investigators, during the year of the research
project):
- Preliminary analysis and experiments
- Advanced analysis and experiments
- Industrial application of the EC process
Dr Alsamani Salih, Dr Ramzi Hadj Lajimi and Dr. Abdelfattah Amari (Co-investigators, during the
year of the research project)
- Optimization of the experimental conditions of EC process using RSM
5. 4الوثيقة رقمFRM0065R01
- Suggestion of the implicated mechanisms in the EC process using analytical techniques such as
GC/MS, UV-vis, SAA
Work Plan / عمل خطة
The work plan duration and phases of Project Research Group are:
- Bibliographic research about the data base and sample collections (Dr. Djamel Ghernaout, Dr.
Noureddine Elboughdiri, and Dr. Mohammed Abu-Dayeh Matouq), month 1-12.
- Preliminary analyses and experiments (Dr. Noureddine Elboughdiri and Dr. Saleh Alarni), Month
1-2
- Optimization of the experimental conditions of EC process for methyl orange (MO) removal using
RSM (Dr Alsamani Salih, Dr Ramzi Hadj Lajimi and Dr. Abdelfattah Amari) (Month 3-5)
- Advanced analysis and experiments (Dr. Noureddine Elboughdiri and Dr. Saleh Alarni), Month 6-
8
- Suggestion of the implicated mechanisms in the EC process using analytical techniques such as
GC/MS, UV-vis, SAA, FTIR, SEM (Dr Alsamani Salih, Dr Ramzi Hadj Lajimi and Dr. Abdelfattah
Amari), Month 8-9
- Methodology for the industrial application of the EC process as an efficient water treatment
technology, taking in consideration the removal of the organic matter (Dr. Noureddine Elboughdiri
and Dr. Saleh Alarni), Month 8-10
- Progress Report for project (Dr. Djamel Ghernaout), month 3-6.
- Publications and communications of the obtained results (all members of the research project)
(Month 4-11)
- Conclusion (Dr. Djamel Ghernaout and Dr. Mohammed Abu-Dayeh Matouq), Month 11-12
References List / قائمة المراجع
[1] D. Ghernaout, B. Ghernaout, A. Kellil, Natural Organic Matter Removal and Enhanced
Coagulation as a Link Between Coagulation and Electrocoagulation, Desalin. Water Treat. 2 (2009)
209-228.
http://www.deswater.com/abstracts/a_116.pdf
[2] D. Ghernaout, B. Ghernaout, M.W. Naceur, Embodying the Chemical Water Treatment in the
Green Chemistry – A review, Desalination 271 (2011) 1-10.
https://www.sciencedirect.com/science/article/abs/pii/S0011916411000439
[3] D. Ghernaout, M.W. Naceur, B. Ghernaout, A Review of Electrocoagulation as a Promising
Coagulation Process for Improved Organic and Inorganic Matters Removal by Electrophoresis and
Electroflotation, Desalin. Water Treat.28 (2011) 287-320.
6. 5الوثيقة رقمFRM0065R01
http://www.deswater.com/abstracts/a_1493.pdf
[4] B. Ghernaout, D. Ghernaout, A. Saiba, Algae and Cyanotoxins Removal by
Coagulation/flocculation: A review, Desalin. Water Treat. 20 (2010) 133-143.
http://www.deswater.com/abstracts/a_1202.pdf
[5] D. Ghernaout, B. Ghernaout, Sweep Flocculation as a Second Form of Charge Neutralisation –
A Review, Desalin. Water Treat. 44 (2012) 15-28.
http://dx.doi.org/10.1080/19443994.2012.691699
[6] D. Ghernaout, B. Ghernaout, From Chemical Disinfection to Electrodisinfection: The
Obligatory Itinerary?,Desalin. Water Treat. 16 (2010) 156-175.
http://www.deswater.com/abstracts/a_1085.pdf
[7] D. Ghernaout, M.W. Naceur, Ferrate(VI): In Situ Generation and Water Treatment – A review,
Desalin. Water Treat. 30 (2011) 319-332.
http://www.deswater.com/abstracts/a_2217.pdf
[8] D. Ghernaout, The Hydrophilic/hydrophobic Ratio vs. Dissolved Organics Removal by
Coagulation – A Review, Journal of King Saud University – Science 26 (2014) 169-180.
http://dx.doi.org/10.1016/j.jksus.2013.09.005
[9] D. Ghernaout, The Best Available Technology of Water/Wastewater Treatment and Seawater
Desalination: Simulation of the Open Sky Seawater Distillation, Green and Sustainable Chemistry,
3 (2013) 68-88.
http://www.scirp.org/journal/PaperInformation.aspx?PaperID=31981
[10] D. Ghernaout, S. Moulay, N. Ait Messaoudene, M. Aichouni, M.W. Naceur, A. Boucherit,
Coagulation and Chlorination of NOM and Algae in Water Treatment: A review, International
Journal of Environmental Monitoring and Analysis (Special Issue: Environmental Science and
Treatment Technology) 2 (2014) 23-34.
http://article.sciencepublishinggroup.com/pdf/10.11648.j.ijema.s.20140203.14.pdf
[11] S. Cotillas, J. Llanos, P. Cañizares, S. Mateo, M.A. Rodrigo, Optimization of an integrated
electrodisinfection/ electrocoagulation process with Al bipolar electrodes for urban wastewater
reclamation, Water Res. 47 (2013) 1741-1750.
http://www.sciencedirect.com/science/article/pii/S0043135412009165
[12] D. Ghernaout, A. Badis, B. Ghernaout, A. Kellil, Application of Electrocoagulation in
Escherichia Coli Culture and two Surface Waters, Desalination, 219 (2008) 118-125.
https://www.sciencedirect.com/science/article/abs/pii/S0011916407005681?via%3Dihub
[13] E. Lacasa, P. Cañizares, C. Sáez, F.J. Fernández, M.A. Rodrigo, Removal of nitrates from
groundwater by electrocoagulation, Chem. Eng. J. 171 (2011) 1012-1017.
http://www.sciencedirect.com/science/article/pii/S1385894711005249
7. 6الوثيقة رقمFRM0065R01
[14] F. Ulu, S. Barışçı, M. Kobya, M. Sillanpää, An evaluation on different origins of natural
organic matters using various anodes by electrocoagulation, Chemosphere (2014),
http://dx.doi.org/10.1016/j.chemosphere.2014.11.063
[15] H.A. Moreno-Casillas, D.L. Cocke, J.A.G. Gomes, P. Morkovsky, J.R. Parga, E. Peterson,
Electrocoagulation mechanism for COD removal, Sep. Purifi. Technol. 56 (2007) 204-211.
http://www.sciencedirect.com/science/article/pii/S1383586607000846
[16] M.Y.A. Mollah, J.A.G. Gomes, K.K. Das, D.L. Cocke, Electrochemical treatment of Orange II
dye solution-Use of aluminum sacrificial electrodes and floc characterization, J. Hazard. Mater. 174
(2010) 851-858.
http://www.sciencedirect.com/science/article/pii/S0304389409015921
[17] K.-W. Pi, Q. Xiao, H.-Q. Zhang, M. Xia, A.R. Gerson, Decolorization of synthetic Methyl
Orange wastewater by electrocoagulation with periodic reversal of electrodes and optimization by
RSM, Process Safety and Environmental Protection 92 (2014) 796-806.
http://www.sciencedirect.com/science/article/pii/S0957582014000159
[18] E-S.Z. El-Ashtoukhy, N.K. Amin, Removal of acid green dye 50 from wastewater by anodic
oxidation and electrocoagulation—A comparative study, J. Hazard. Mater. 179 (2010) 113-119.
http://www.sciencedirect.com/science/article/pii/S0304389410002803
[19] D. Ghernaout, M.W. Naceur, A. Aouabed, On the Dependence of Chlorine By-products
Generated Species Formation of the Electrode Material and Applied Charge during Electrochemical
Water Treatment, Desalination, 270 (2011) 9-22.
https://www.sciencedirect.com/science/article/abs/pii/S001191641100021X
[20] M. Rajab, C. Heim, T. Letzel, J.E. Drewes, B. Helmreich, Electrochemical disinfection using
boron-doped diamond electrode – The synergetic effects of in situ ozone and free chlorine
generation, Chemosphere 121 (2015) 47-53.
http://www.sciencedirect.com/science/article/pii/S0045653514012685
[21] N. Ardhan, E.J. Moore, C. Phalakornkule, Novel anode made of iron scrap for a reduced-cost
electrocoagulator, Chem. Eng. J. 253 (2014) 448-455.
http://www.sciencedirect.com/science/article/pii/S1385894714006408
[22] D. Ghernaout, S. Irki, A. Boucherit, Removal of Cu2+
and Cd2+
, and Humic Acid and Phenol
by Electrocoagulation Using Iron Electrodes, Desalin. Water Treat. 52 (2014) 3256–3270.
http://dx.doi.org/10.1080/19443994.2013.852484
[23] D. Ghernaout, C. Benblidia, F. Khemici, Microalgae Removal from Ghrib Dam (Ain Defla,
Algeria) Water by Electroflotation Using Stainless Steel Electrodes, Desalin. Water Treat. (2015)
(in press).
http://www.tandfonline.com/doi/full/10.1080/19443994.2014.907749#.U040EvJOXX4
8. 7الوثيقة رقمFRM0065R01
[24] D. Ghernaout, A.I. Al-Ghonamy, M.W. Naceur, N. Ait Messaoudene, M. Aichouni, Influence
of operating parameters on electrocoagulation of C.I. disperse yellow 3, J. Electrochem. Sci. Eng.
4(4) (2014) 271-283
http://pub.iapchem.org/ojs/index.php/JESE/article/view/146
[25] D. Ghernaout, A.I. Al-Ghonamy, S. Irki, A. Grini, M.W. Naceur, N. Ait Messaoudene, M.
Aichouni, Decolourization of bromophenol blue by electrocoagulation process, Trends in Chemical
Engineering 15 (2014) 29-39.
http://www.researchtrends.net/tia/abstract.asp?in=0&vn=15&tid=1&aid=5587&pub=2014&type=3
[26] D. Ghernaout, C. Benblidia, F. Khemici, Microalgae Removal from Ghrib Dam (Ain Defla,
Algeria) Water by Electroflotation Using Stainless Steel Electrodes, Desalin. Water Treat. 54
(2015) 3328-3337.
doi: 10.1080/19443994.2014.907749
http://www.tandfonline.com/doi/full/10.1080/19443994.2014.907749#.U040EvJOXX4
[27] S. Irki, D. Ghernaout, M.W. Naceur, Decolourization of Methyl Orange (MO) by
Electrocoagulation (EC) using iron electrodes under a magnetic field (MF), Desalin. Water Treat.
79 (2017) 368-377.
http://www.deswater.com/in_press/abstracts/20797.pdf
[28] D. Ghernaout, Microorganisms’ Electrochemical Disinfection Phenomena, EC Microbiology
9 (2017) 160-169.
https://www.ecronicon.com/ecmi/pdf/ECMI-09-00288.pdf
[29] D. Ghernaout, M. Aichouni, M. Touahmia, Mechanistic Insight into Disinfection by
Electrocoagulation - A Review, Desalination and Water Treatment 141 (2019) 68-81.
http://www.deswater.com/DWT_abstracts/vol_141/141_2019_68.pdf
Expected results and ways to benefit from them / النتائج المتوقعة وطرق االستفادة منه
There are several expected results:
- Knowledge transfer to the Kingdom of Saudi Arabia on recent water treatment technologies.
- Comprehension of the EC Process for water treatment plants.
- Find the optimal conditions to implement the EC process as new and efficient technology in the
Kingdom of Saudi Arabia.
- Publication of papers in international journal with high impact factor.
- Supervision of master and Ph. D. students in the EC process research.
The mechanism for implementation of the results is focused on the following axes:
- Patent the EC technology.
9. 8الوثيقة رقمFRM0065R01
- Present the results of this research to the local industrial that have some water pollution and
wastewater treatment problems.
- Choose an appropriate industrial company for producing EC process devices to be diffused in the
industrial market.
- Encourage and assist industrial companies to applicate the EC process in their water and
wastewater treatment plants.
- Collaborate with national and international industrial partners to ameliorate the industrial
application of the EC process.
- Collaborate with research laboratories at the national and international level.