Hydrogen sulfide is one of the most deadly industrial gases especially in oil and gas industry. It has been referred to as a silent killer. This comprehensive PPT covers a wide range of topics including characteristics of H2S, monitoring areas for H2S levels, emergency procedures, hazard minimization, contingency planning, and more. Complete and up-to-date. A great tool for required annual training.
Hydrogen sulfide is one of the most deadly industrial gases especially in oil and gas industry. It has been referred to as a silent killer. This comprehensive PPT covers a wide range of topics including characteristics of H2S, monitoring areas for H2S levels, emergency procedures, hazard minimization, contingency planning, and more. Complete and up-to-date. A great tool for required annual training.
What is a confined space?
Hazards of entering and working in Confined Spaces
Actions to taken / Preparation before entering a confined space
Checklist prior to commencing work in a confined space
What is a confined space?
Hazards of entering and working in Confined Spaces
Actions to taken / Preparation before entering a confined space
Checklist prior to commencing work in a confined space
H2S
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All you need to know about Hydrogen Sulfide - H2SOizom
H2S is formed whenever elemental sulfur or sulfur-containing compounds come into contact with organic materials at high temperatures. Continuous or high-level exposure of the H2S can quickly deaden a person’s sense of smell, making the odour of H2S an unreliable indicator of its presence. Hence, other means such as hydrogen sulfide monitoring is a viable solution to provide adequate warning of hazardous exposure. This article covers information on hydrogen sulfide, its sources in the ambient air, permissible levels, health and environmental impact. Additionally, it also highlights possible corrective measures, the need for H2S monitors and different methods of H2S monitoring.
What is H2S?
H2S is colorless, flammable, poisonous, and corrosive gas with one sulfur atom bonded to two hydrogen atoms. Known as sewer gas, swamp gas or manure gas, H2S has a noticeable rotten-egg odour detectable at concentrations as low as 0.5 ppb. Also, It is highly flammable, explosive gas between 4% and 45% (concentration in air) which may travel to ignition sources and flashback. When ignited, it burns to produce toxic vapors and gases (sulfur oxides).
H2S molecular structure
[Source: https://commons.wikimedia.org/wiki/File:Hydrogen-sulfide-3D-balls.png]
Hydrogen sulfide is slightly heavier than air. It may travel along the ground collecting into low lying, enclosed, or poorly ventilated areas such as basements, sewer lines, underground passages, manholes, etc.
Hydrogen sulfide in Atmosphere
H2S is present naturally in crude petroleum, natural gas, and hot springs. It is released into the atmosphere primarily as gas from volcanoes, geothermal vents, sulfur springs and lakes, salt marshes, and estuaries. Also, bacterial breakdown (anaerobic decay) of organic sulfur compounds also produce H2S.
Core 10 introduction to hydrogen sulfideWayneBourg
Hydrogen sulfide, or H2S, is a hazard that can creep up on you. You cannot see it, and if the concentration is high enough, you will not even be able to smell it. This toxic gas is colorless and collects in low-lying areas. H2S is so powerful that it can kill you with one breath. It is known as “The Silent Killer.” In this chapter, we will review the safe work practices designed to protect you from hazardous exposure to H2S.
Hydrogen Sulfide (H2S)
Hydrogen sulfide is a colorless, flammable, extremely hazardous gas with a “rotten
egg” smell. Some common names for the gas include sewer gas, stink damp,
swamp gas and manure gas. It occurs naturally in crude petroleum, natural gas,
and hot springs. In addition, hydrogen sulfide is produced by bacterial breakdown
of organic materials and human and animal wastes (e.g., sewage).
Industrial activities that can produce the gas include petroleum/natural gas
drilling and refining, wastewater treatment, coke ovens, tanneries, and kraft
paper mills. Hydrogen sulfide can also exist as a liquid compressed gas.
Brief and concise presentation on oxygen therapy. Safety and toxicity to staff anf managment of Battor Catholic Hospital, A very reputable and efficient hospital in Ghana in the Volta Region
Discover the innovative and creative projects that highlight my journey throu...dylandmeas
Discover the innovative and creative projects that highlight my journey through Full Sail University. Below, you’ll find a collection of my work showcasing my skills and expertise in digital marketing, event planning, and media production.
Putting the SPARK into Virtual Training.pptxCynthia Clay
This 60-minute webinar, sponsored by Adobe, was delivered for the Training Mag Network. It explored the five elements of SPARK: Storytelling, Purpose, Action, Relationships, and Kudos. Knowing how to tell a well-structured story is key to building long-term memory. Stating a clear purpose that doesn't take away from the discovery learning process is critical. Ensuring that people move from theory to practical application is imperative. Creating strong social learning is the key to commitment and engagement. Validating and affirming participants' comments is the way to create a positive learning environment.
[Note: This is a partial preview. To download this presentation, visit:
https://www.oeconsulting.com.sg/training-presentations]
Sustainability has become an increasingly critical topic as the world recognizes the need to protect our planet and its resources for future generations. Sustainability means meeting our current needs without compromising the ability of future generations to meet theirs. It involves long-term planning and consideration of the consequences of our actions. The goal is to create strategies that ensure the long-term viability of People, Planet, and Profit.
Leading companies such as Nike, Toyota, and Siemens are prioritizing sustainable innovation in their business models, setting an example for others to follow. In this Sustainability training presentation, you will learn key concepts, principles, and practices of sustainability applicable across industries. This training aims to create awareness and educate employees, senior executives, consultants, and other key stakeholders, including investors, policymakers, and supply chain partners, on the importance and implementation of sustainability.
LEARNING OBJECTIVES
1. Develop a comprehensive understanding of the fundamental principles and concepts that form the foundation of sustainability within corporate environments.
2. Explore the sustainability implementation model, focusing on effective measures and reporting strategies to track and communicate sustainability efforts.
3. Identify and define best practices and critical success factors essential for achieving sustainability goals within organizations.
CONTENTS
1. Introduction and Key Concepts of Sustainability
2. Principles and Practices of Sustainability
3. Measures and Reporting in Sustainability
4. Sustainability Implementation & Best Practices
To download the complete presentation, visit: https://www.oeconsulting.com.sg/training-presentations
VAT Registration Outlined In UAE: Benefits and Requirementsuae taxgpt
Vat Registration is a legal obligation for businesses meeting the threshold requirement, helping companies avoid fines and ramifications. Contact now!
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Digital Transformation and IT Strategy Toolkit and TemplatesAurelien Domont, MBA
This Digital Transformation and IT Strategy Toolkit was created by ex-McKinsey, Deloitte and BCG Management Consultants, after more than 5,000 hours of work. It is considered the world's best & most comprehensive Digital Transformation and IT Strategy Toolkit. It includes all the Frameworks, Best Practices & Templates required to successfully undertake the Digital Transformation of your organization and define a robust IT Strategy.
Editable Toolkit to help you reuse our content: 700 Powerpoint slides | 35 Excel sheets | 84 minutes of Video training
This PowerPoint presentation is only a small preview of our Toolkits. For more details, visit www.domontconsulting.com
LA HUG - Video Testimonials with Chynna Morgan - June 2024Lital Barkan
Have you ever heard that user-generated content or video testimonials can take your brand to the next level? We will explore how you can effectively use video testimonials to leverage and boost your sales, content strategy, and increase your CRM data.🤯
We will dig deeper into:
1. How to capture video testimonials that convert from your audience 🎥
2. How to leverage your testimonials to boost your sales 💲
3. How you can capture more CRM data to understand your audience better through video testimonials. 📊
Enterprise Excellence is Inclusive Excellence.pdfKaiNexus
Enterprise excellence and inclusive excellence are closely linked, and real-world challenges have shown that both are essential to the success of any organization. To achieve enterprise excellence, organizations must focus on improving their operations and processes while creating an inclusive environment that engages everyone. In this interactive session, the facilitator will highlight commonly established business practices and how they limit our ability to engage everyone every day. More importantly, though, participants will likely gain increased awareness of what we can do differently to maximize enterprise excellence through deliberate inclusion.
What is Enterprise Excellence?
Enterprise Excellence is a holistic approach that's aimed at achieving world-class performance across all aspects of the organization.
What might I learn?
A way to engage all in creating Inclusive Excellence. Lessons from the US military and their parallels to the story of Harry Potter. How belt systems and CI teams can destroy inclusive practices. How leadership language invites people to the party. There are three things leaders can do to engage everyone every day: maximizing psychological safety to create environments where folks learn, contribute, and challenge the status quo.
Who might benefit? Anyone and everyone leading folks from the shop floor to top floor.
Dr. William Harvey is a seasoned Operations Leader with extensive experience in chemical processing, manufacturing, and operations management. At Michelman, he currently oversees multiple sites, leading teams in strategic planning and coaching/practicing continuous improvement. William is set to start his eighth year of teaching at the University of Cincinnati where he teaches marketing, finance, and management. William holds various certifications in change management, quality, leadership, operational excellence, team building, and DiSC, among others.
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HR recruiter services offer top talents to companies according to their specific needs. They handle all recruitment tasks from job posting to onboarding and help companies concentrate on their business growth. With their expertise and years of experience, they streamline the hiring process and save time and resources for the company.
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Improving profitability for small businessBen Wann
In this comprehensive presentation, we will explore strategies and practical tips for enhancing profitability in small businesses. Tailored to meet the unique challenges faced by small enterprises, this session covers various aspects that directly impact the bottom line. Attendees will learn how to optimize operational efficiency, manage expenses, and increase revenue through innovative marketing and customer engagement techniques.
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As an Army veteran dedicated to lifelong learning, I bring a disciplined, strategic mindset to my pursuits. I am constantly expanding my knowledge to innovate and lead effectively. My journey is driven by a commitment to excellence, and to make a meaningful impact in the world.
2. H2S SAFETY TRAININGH2S SAFETY TRAINING
What is Hydrogen Sulfide (H2S)?What is Hydrogen Sulfide (H2S)?
Where do you find H2S?Where do you find H2S?
Properties of H2SProperties of H2S
Detection of H2SDetection of H2S
Protection against H2S hazardsProtection against H2S hazards
How does H2S affect individuals?How does H2S affect individuals?
Emergency Response and Rescue ProceduresEmergency Response and Rescue Procedures
Safety MeasuresSafety Measures
Proper donning, doffing, and storage of SCBAProper donning, doffing, and storage of SCBA
3. H2S SAFETY TRAININGH2S SAFETY TRAINING
What is Hydrogen Sulfide (HWhat is Hydrogen Sulfide (H22S)?S)?
AA colorless (transparent)colorless (transparent) gas that is heavier thangas that is heavier than
air and tends to accumulate in low-lying areasair and tends to accumulate in low-lying areas
Consists ofConsists of 2 Hydrogen2 Hydrogen atoms andatoms and 1 Sulphur1 Sulphur
atomatom
Has anHas an offensive odor similar to rotten eggsoffensive odor similar to rotten eggs atat
low concentration, at higher concentrations itlow concentration, at higher concentrations it
rapidly deadens the sense of smellrapidly deadens the sense of smell
AA poisonous gaspoisonous gas that can paralyze the breathingthat can paralyze the breathing
system and can kill in minutessystem and can kill in minutes
HighlyHighly toxictoxic and veryand very corrosivecorrosive to certain metalsto certain metals
and elastomersand elastomers
Belongs to the inorganicBelongs to the inorganic SulfideSulfide familyfamily
4. Other names referred to H2S:Other names referred to H2S:
H2SH2S
Stink DampStink Damp
Rotten-Egg GasRotten-Egg Gas
Sulphurated HydrogenSulphurated Hydrogen
Hydrosulphuric AcidHydrosulphuric Acid
Sour Crude / Sour GasSour Crude / Sour Gas
Swamp GasSwamp Gas Sewer GasSewer Gas
Dihydrogen SulfideDihydrogen Sulfide
Hepatic GasHepatic Gas
ZwavelwaterstoffZwavelwaterstoff
Hydrogen SulfideHydrogen Sulfide
5. H2S SAFETY TRAININGH2S SAFETY TRAINING
Where do you find H2S?Where do you find H2S?
Natural Sources:Natural Sources:
H2S is produced in nature by the decomposition of organicH2S is produced in nature by the decomposition of organic
materials by bacteriamaterials by bacteria
It may also develop in low Oxygen or low-lying areas and canIt may also develop in low Oxygen or low-lying areas and can
be found with natural gas, petroleum and volcanic gases asbe found with natural gas, petroleum and volcanic gases as
well as unstabilized crude oil and gas streamswell as unstabilized crude oil and gas streams
6. H2S SAFETY TRAININGH2S SAFETY TRAINING
Industrial Sources:Industrial Sources:
H2S is either a product or by-product of waste materials.H2S is either a product or by-product of waste materials.
It can be found in familiar industries such as natural gasIt can be found in familiar industries such as natural gas
processing plants, petroleum refineries, leather tanning,processing plants, petroleum refineries, leather tanning,
pulp mills, iron and steel mills, oil and gas wells, sewagepulp mills, iron and steel mills, oil and gas wells, sewage
treatment, commercial laboratories, etc.treatment, commercial laboratories, etc.
7. H2S SAFETY TRAININGH2S SAFETY TRAINING
Properties of H2SProperties of H2S
Colorless orColorless or
transparenttransparent
HeavierHeavier than airthan air
( Vapor Density = 1.1895 )( Vapor Density = 1.1895 )
and accumulates in low-and accumulates in low-
lying areaslying areas
FlammableFlammable
in concentrations between 4.3%in concentrations between 4.3%
and 46.0% and auto ignites atand 46.0% and auto ignites at
500°F (260°C)500°F (260°C)
CorrosiveCorrosive toto
certain metals andcertain metals and
elastomerselastomers
SolubleSoluble in water andin water and
dissolves in drilling fluidsdissolves in drilling fluids
H2H2
SS
GeneratesGenerates 680680
BTU/HRBTU/HRduringduring
burningburning
Highly ToxicHighly Toxic andand
hazardous to healthhazardous to health
ReadilyReadily dispersed bydispersed by
windwind movement or airmovement or air
currentscurrents
8. Burning HBurning H22S produces another toxic gas called SOS produces another toxic gas called SO22
(Sulphur Dioxide)(Sulphur Dioxide)
Sulphur Dioxide (SOSulphur Dioxide (SO22)) is ais a colorless or transparent gascolorless or transparent gas andand
is non-flammable. It is also heavier than air with a specificis non-flammable. It is also heavier than air with a specific
gravity of 2.264@0°C.gravity of 2.264@0°C.
SOSO22 is extremely irritating to the eyes and mucousis extremely irritating to the eyes and mucous
membranes of the upper respiratory tract. It has exceptionallymembranes of the upper respiratory tract. It has exceptionally
good warning properties in this regard than Hgood warning properties in this regard than H22S.S.
9. H2S SAFETY TRAININGH2S SAFETY TRAINING
ConcentrationConcentration Physiological EffectsPhysiological Effects
0.005 - 0.13ppm0.005 - 0.13ppm Minimal perceptible odourMinimal perceptible odour
5ppm5ppm Easily detectable, moderate odour TWAEasily detectable, moderate odour TWA
10ppm10ppm Beginning eye irritationBeginning eye irritation
27ppm27ppm Strong unpleasant odour, but not intolerableStrong unpleasant odour, but not intolerable
100ppm100ppm Coughing, eye irritation, loss of sense of smellCoughing, eye irritation, loss of sense of smell
after 2-5mins (IDLH)after 2-5mins (IDLH)
200 – 300ppm200 – 300ppm Marked conjunctivitis and respiratory tractMarked conjunctivitis and respiratory tract
irritation after 1hr of exposureirritation after 1hr of exposure
500 – 700ppm500 – 700ppm Loss of consciousness and possible death in 30Loss of consciousness and possible death in 30
minutesminutes
700 – 1000ppm700 – 1000ppm Rapid unconsciousness, cessation of respirationRapid unconsciousness, cessation of respiration
and deathand death
1000 – 2000ppm1000 – 2000ppm Unconsciousness at once, with early cessation ofUnconsciousness at once, with early cessation of
respiration and death in a few minutes.respiration and death in a few minutes.
10. H2S SAFETY TRAININGH2S SAFETY TRAINING
Detection of H2SDetection of H2S
There are many ways to be alerted by the presence of H2S:There are many ways to be alerted by the presence of H2S:
Sense of smell (nose)Sense of smell (nose)
Lead Acetate, Ampoules or Coated StripsLead Acetate, Ampoules or Coated Strips
Colorimetric Tubes (NIOSH certified)Colorimetric Tubes (NIOSH certified)
Electronic Portable or Fixed MonitorsElectronic Portable or Fixed Monitors
Wet Chemistry (Tutweiler method)Wet Chemistry (Tutweiler method)
Gas ChromatographyGas Chromatography
WARNING!!!WARNING!!!
You cannot rely on your sense of smell toYou cannot rely on your sense of smell to
tell how much H2S is present….tell how much H2S is present….
11. H2S SAFETY TRAININGH2S SAFETY TRAINING
Most alarms will consist of anMost alarms will consist of an amberamber strobe light, astrobe light, a blueblue
strobe light, astrobe light, a redred strobe light, and a dual tone audiblestrobe light, and a dual tone audible alarm.alarm.
Types of Alarm:Types of Alarm:
Low Level Alarm:Low Level Alarm: 10ppm10ppm
High Level Alarm:High Level Alarm: 15ppm and above15ppm and above
Note: Alarm set points can be adjusted to conform to local regulationsNote: Alarm set points can be adjusted to conform to local regulations
or company requirements. Generally, the alarm points are set at 10ppm,or company requirements. Generally, the alarm points are set at 10ppm,
15ppm/20ppm. In some areas, they are set at 5ppm and 10ppm. It is15ppm/20ppm. In some areas, they are set at 5ppm and 10ppm. It is
critical to know what is required at your location.critical to know what is required at your location.
ALARMSALARMS
12. Hydrogen Sulfide Condition Levels:Hydrogen Sulfide Condition Levels:
Δ Condition Green “POSSIBLE DANGER”Condition Green “POSSIBLE DANGER”
H2S concentration isH2S concentration is less than 10ppmless than 10ppm. Drilling and. Drilling and
production operations are under control. There are NOproduction operations are under control. There are NO
alarms.alarms.
Δ Condition Yellow “MODERATE DANGER”Condition Yellow “MODERATE DANGER”
H2S concentration isH2S concentration is 10ppm - 15ppm10ppm - 15ppm at some pointat some point
on location and the well or production stream is underon location and the well or production stream is under
control. Amber flashing light is activated.control. Amber flashing light is activated.
Δ Condition Red “EXTREME DANGER”Condition Red “EXTREME DANGER”
H2S concentration isH2S concentration is > 15ppm> 15ppm at any point on theat any point on the
location or loss of well control occurs. Amber flashinglocation or loss of well control occurs. Amber flashing
light and audible alarms are activated.light and audible alarms are activated.
13. H2S SAFETY TRAININGH2S SAFETY TRAINING
Two Common Types of Breathing ApparatusTwo Common Types of Breathing Apparatus
(Respiratory Protection)(Respiratory Protection)
Self Contained Breathing Apparatus (SCBA)Self Contained Breathing Apparatus (SCBA)
This type of apparatus provides air from a cylinder worn onThis type of apparatus provides air from a cylinder worn on
the back. A commonly used cylinder will supply air for 30the back. A commonly used cylinder will supply air for 30
minutes while the wearer is engaged in heavy physical work.minutes while the wearer is engaged in heavy physical work.
Other cylinders are available for longer or shorter usage.Other cylinders are available for longer or shorter usage.
Duration of air supply is dependent on the type of workDuration of air supply is dependent on the type of work
performed and the individual’s physical condition.performed and the individual’s physical condition.
Supplied Air Breathing ApparatusSupplied Air Breathing Apparatus
This is a variation of the self-contained breathing apparatusThis is a variation of the self-contained breathing apparatus
where the back-mounted tank is replaced by a large cylinderwhere the back-mounted tank is replaced by a large cylinder
connected by a hose line to the pigtail on the BA set. Whileconnected by a hose line to the pigtail on the BA set. While
the supplied air apparatus is lighter to wear, it restricts thethe supplied air apparatus is lighter to wear, it restricts the
user’s movements to the length of the hose. The hose alsouser’s movements to the length of the hose. The hose also
forces the user to return by the same route taken whenforces the user to return by the same route taken when
entering the area. An escape bottle must be worn with thisentering the area. An escape bottle must be worn with this
type of apparatus.type of apparatus.
14. H2S SAFETY TRAININGH2S SAFETY TRAINING
Special Problems in Respirator Use:Special Problems in Respirator Use:
Facial HairFacial Hair
Contact LensesContact Lenses
Corrective SpectaclesCorrective Spectacles
Psychological DisturbancesPsychological Disturbances
Miscellaneous Sealing ProblemsMiscellaneous Sealing Problems
““Not everyone can wear a respirator”Not everyone can wear a respirator”
Prior to being allowed to use a breathing air equipment, thePrior to being allowed to use a breathing air equipment, the
worker must have medical clearance and have beenworker must have medical clearance and have been
properly trained to wear respiratory protection.properly trained to wear respiratory protection.
15. H2S SAFETY TRAININGH2S SAFETY TRAINING
How does H2S affect Individuals?How does H2S affect Individuals?
Factors that determine the effect of H2S on individuals:Factors that determine the effect of H2S on individuals:
DurationDuration
The length of time the individual is exposedThe length of time the individual is exposed
FrequencyFrequency
How often the individual has been exposedHow often the individual has been exposed
IntensityIntensity
How much concentration the individual was exposed toHow much concentration the individual was exposed to
Individual SusceptibilityIndividual Susceptibility
The individual’s physiological make-upThe individual’s physiological make-up
16. Target organs subject to the effects of H2S:Target organs subject to the effects of H2S:
Olfactory NervesOlfactory Nerves
LungsLungs
EyesEyes
BrainBrain
Respiratory Control CenterRespiratory Control Center
Entry into the Body:Entry into the Body:
IngestionIngestion
InjectionInjection
Skin AbsorptionSkin Absorption
InhalationInhalation
H2S SAFETY TRAININGH2S SAFETY TRAINING
17. H2S SAFETY TRAININGH2S SAFETY TRAINING
Emergency Response and Rescue ProceduresEmergency Response and Rescue Procedures
These are the basic steps to take if you are in the immediate area of spill or leak.These are the basic steps to take if you are in the immediate area of spill or leak.
DO NOT PANIC!DO NOT PANIC!
Hold your breathHold your breath
Move upwind or crosswind and away from the gasMove upwind or crosswind and away from the gas
Put on appropriate breathing apparatusPut on appropriate breathing apparatus
Assist anyone in distressAssist anyone in distress
Move quickly to the upwindMove quickly to the upwind “Safe Briefing or Assembly Area”“Safe Briefing or Assembly Area” to receiveto receive
instructions.instructions.
Always follow company policies and procedures for escape and rescue. BeforeAlways follow company policies and procedures for escape and rescue. Before
attempting to rescue anyone else, always:attempting to rescue anyone else, always:
Protect yourself first.Protect yourself first. Don’t become another victim.Don’t become another victim.
Put on rescue breathing apparatus (30 mins. SCBA) before attempting aPut on rescue breathing apparatus (30 mins. SCBA) before attempting a
rescue.rescue.
Use theUse the “Buddy System”.“Buddy System”. Do not attempt to rescue anyone alone.Do not attempt to rescue anyone alone.
18. H2S SAFETY TRAININGH2S SAFETY TRAINING
““EVERYONEEVERYONE SHOULDSHOULD
KNOWKNOW WHAT HIS ORWHAT HIS OR
HER RESPONSIBILITY IS,HER RESPONSIBILITY IS,
IN THE EVENT OF ANIN THE EVENT OF AN
H2S EMERGENCYH2S EMERGENCY
SITUATION.”SITUATION.”
19. H2S SAFETY TRAININGH2S SAFETY TRAINING
No jobNo job is so importantis so important
andand No serviceNo service is sois so
urgent – that we cannoturgent – that we cannot
take time to perform ourtake time to perform our
workwork SAFELYSAFELY….….