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AL-Bairaq 
I am Discovering Materials 
Cycle 8 
Environmental Catalysis Module 
“Eliminating amyl acetate from effluent” 
Al Khor Independent School for Girls 
Khorg_Gold8 Group 
Hessa Almohannadi Aysha ALraessi 
Raghad Alnajjar Nour Almuraikhi
• Introduction 
• Activity 1: The decomposition of H2O2 using yeast 
as a catalyst 
• Activity 2: Examples of Catalysts . 
• Activity 3: Homogeneous and Heterogeneous Acid 
Catalysis 
• Activity 4: Using a Metal Catalyst to Degrade an Air 
Pollutant 
• Activity 5: Using Photocatalysis to Degrade a Water 
Pollutant 
• Design Project: Water Pollution
Introduction 
Catalysis: 
Definition: Catalysts are substances that help to speed up 
the process of chemical reactions without taking part in 
the reaction. This process of speeding up the speed of 
chemical reaction without taking part in the reaction is 
called catalysis. 
•Over 80% of industrial processes involve catalysts.
Activity 1: The decomposition of H2O2 using 
yeast as a catalyst 
Something decomposes when it breaks down into its 
component parts. 
Hydrogen peroxide is not a very stable compound the 
decomposition goes very slowly. In this reaction, yeast 
catalyzes the decomposition, making the reaction go much 
more quickly. 
Yeast
Activity 1: The decomposition of H2O2 using 
yeast as a catalyst
Activity 2: Examples of 
Catalysts: 
1. Natural catalyst: 
Enzymes are the commonest and most efficient of 
the catalysts found in nature. Most of the chemical 
reactions that occur in the human body and in other 
living things are high-energy reactions that would 
occur slowly, if at all, without the catalysis provided 
by enzymes. For example, in the absence of 
catalysis, it takes several weeks for starch to 
hydrolyze to glucose; a trace of the enzyme ptyalin, 
found in human saliva, accelerates the reaction so 
that starches can be digested. Some enzymes 
increase reaction rates by a factor of one billion or 
more.
2. chemical industry: 
Process catalysts play a vital role in the economy. 
More than 90% of chemical manufacturing processes 
and more than 20% of all industrial products employ 
underlying catalytic steps. Petroleum refining, which 
is the source of by far the largest share of industrial 
products, consists almost entirely of catalytic 
processes. 
This two types of catalysts—petroleum refining 
catalysts and chemical processing catalysts. With 
petroleum refining catalysts, the difference in 
refinery configurations in each region causes 
different patterns of catalyst consumption.
Act. 3: Using a Heterogeneous Acid 
Catalyst 
in chemistry, homogeneous catalysis is a sequence of reactions that involve a catalyst in 
the same phase as the reactants. Phase here refers to solid, liquid, vs. gas. Most 
commonly, a homogeneous catalyst is co dissolved in a solvent with the reactants.
Cont. Activity 
3 
The result: 
1. The pH paper in first 3 minutes of cup No.1 and 3 didn’t change . But cup No.2 change to 
orange color . 
2. No. 2 cup start to become more darker in 6,9, 12 and 15 minutes. But cup No.1and 3 didn’t 
change. 
3. That means that cup No.2 is an acidic. 
4. When we add the baking soda in cup No.3, its start to bubbled and that mean that cup 
No.1 is also acid but it takes time for react with the water.
Act. 4: Using a Metal Catalyst to 
Degrade an Air Pollutant 
In this activity we will investigate the catalytic conversion of ammonia into safe 
molecules . More specifically as a class we will compare the performance of an iron 
catalyst and two types of copper catalyst in breaking down or degrading ammonia . 
Copper 
granules 
Copper 
turnings 
Iron 
fiber
Activity 4
Act. 4: Using a Metal Catalyst to Degrade 
an Air Pollutant 
• The conclusion : 
We found after the activity that the best catalyst that 
change the ammonia to nitrogen and water is : 
1. Copper granules . 
2. Copper turning. 
3. Iron fiber. 
We use indicator called “Phenolphthalein” it color the 
ammonia to pink to show the ammonia level. 
In the activity we notice that the iron fiber had become 
deactivated, or poisoned because it oxidation.
Act. 5: Using Photocatalysis 
to Degrade a Water Pollutant 
A photocatalyst is defined as a substance which is activated by adsorbing a 
photon and is capable of accelerating a reaction without being consumed . 
These substances are invariably semiconductors. Semiconducting oxide 
photocatalysts have been increasingly focused in recent years due to their 
potential applications in solar energy conversion and environmental 
purification . 
+TiO 
2
Act. 5: Using Photocatalysis to 
Degrade a Water Pollutant 
UV Sunlight Dark 
Dye + Dye 
tio2 
Dye + Dye 
tio2 
Dye + Dye 
tio2 
Time 
0 5 5 5 5 5 5 
3 5 5 1 5 5 5 
6 4 5 5 5 
9 4 5 5 5 
12 3 5 5 5 
15 2 5 5 5 
18 2 5 5 5 
The conclusion:
Act. 5: Using Photocatalysis to Degrade a 
Water Pollutant 
6 
5 
4 
3 
2 
1 
0 
Dye + TiO2 
9 8 7 6 5 4 3 2 1 
color change 
Time 
Dark 
sunlight 
UV
Eliminating Amyl acetate From Effluent 
•Introduction: 
The problem of the scarcity of fresh water from the greatest challenges facing 
the State of Qatar, the State in the area of weather conditions are considered 
of the most severe climatic conditions in the world, leading to limited water 
resources, and lack of surface water. Taking into account population equation, 
the State of Qatar is one of the most poverty-stricken areas, water stress in 
the world. 
•Aim of the work : 
treating wastewater produced from food-manufacturing company 
prevents effluent from becoming an environmental nuisance and 
hazard
Eliminating amyl acetate from effluent 
The ester amyl acetate (CH3COOC5H11): 
Is a mixture of five isomers. It is a colorless, flammable, 
volatile liquid that smells and tastes like bananas and is 
something called banana oil. 
Uses: 
1. in a flavoring in foods . 
In solvent in nail polishes. 
1. Leather polishes. 
2. Metallic paints. 
Hazards: 
Is toxic if swallowed or inhaled, can cause irritation to the 
eyes and skin.
The experiment
1. treating wastewater produced from 
food-manufacturing company prevents 
effluent from becoming an 
environmental nuisance and hazard. 
2. Brake down the amyl acetate to acetic 
acid . 
Cu catalyst 
7 
6.5 
6 
5.5 
15 10 5 0.3 
pH 
Time 
Cu catalyst 
TiO2 catalyst 
8 
6 
4 
2 
0 
20 15 10 5 0.3 
pH 
Time 
TiO2 catalyst 
8 
6 
4 
2 
0 
20 15 10 5 0.3 
pH 
Time 
Fe catalyst 
Fe catalyst
: The conclusion 
We found after the experiment that the best catalyst that brake the 
amyl acetate is 
1. Cu 
2. Fe 
3. TiO2 ( it doesn't work ) 
The production of acetic acid can be monitored with pH meter ,showing 
a reduction of pH from 6 to 5.
recommendation: 
we recommended the factories to use our project in large scale and try 
another catalyst to save our environmental in Qatar. 
The problem we had: 
the problem we use TiO2 as a catalyst but it didn't work even though 
we put it in sunlight
Acknowledgment 
Many thanks to my teachers, school and AL-Bairaq team from 
Center for Advanced Materials (CAM), Qatar University for 
supporting us during our journey with a AL-Bairaq. 
Also, I would like to thank the sponsors UNESCO, Ras Gas, 
Maersk Oil and Shell.

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Environmental catalyst - Khor_Gold group-2014

  • 1. AL-Bairaq I am Discovering Materials Cycle 8 Environmental Catalysis Module “Eliminating amyl acetate from effluent” Al Khor Independent School for Girls Khorg_Gold8 Group Hessa Almohannadi Aysha ALraessi Raghad Alnajjar Nour Almuraikhi
  • 2. • Introduction • Activity 1: The decomposition of H2O2 using yeast as a catalyst • Activity 2: Examples of Catalysts . • Activity 3: Homogeneous and Heterogeneous Acid Catalysis • Activity 4: Using a Metal Catalyst to Degrade an Air Pollutant • Activity 5: Using Photocatalysis to Degrade a Water Pollutant • Design Project: Water Pollution
  • 3. Introduction Catalysis: Definition: Catalysts are substances that help to speed up the process of chemical reactions without taking part in the reaction. This process of speeding up the speed of chemical reaction without taking part in the reaction is called catalysis. •Over 80% of industrial processes involve catalysts.
  • 4. Activity 1: The decomposition of H2O2 using yeast as a catalyst Something decomposes when it breaks down into its component parts. Hydrogen peroxide is not a very stable compound the decomposition goes very slowly. In this reaction, yeast catalyzes the decomposition, making the reaction go much more quickly. Yeast
  • 5. Activity 1: The decomposition of H2O2 using yeast as a catalyst
  • 6. Activity 2: Examples of Catalysts: 1. Natural catalyst: Enzymes are the commonest and most efficient of the catalysts found in nature. Most of the chemical reactions that occur in the human body and in other living things are high-energy reactions that would occur slowly, if at all, without the catalysis provided by enzymes. For example, in the absence of catalysis, it takes several weeks for starch to hydrolyze to glucose; a trace of the enzyme ptyalin, found in human saliva, accelerates the reaction so that starches can be digested. Some enzymes increase reaction rates by a factor of one billion or more.
  • 7. 2. chemical industry: Process catalysts play a vital role in the economy. More than 90% of chemical manufacturing processes and more than 20% of all industrial products employ underlying catalytic steps. Petroleum refining, which is the source of by far the largest share of industrial products, consists almost entirely of catalytic processes. This two types of catalysts—petroleum refining catalysts and chemical processing catalysts. With petroleum refining catalysts, the difference in refinery configurations in each region causes different patterns of catalyst consumption.
  • 8. Act. 3: Using a Heterogeneous Acid Catalyst in chemistry, homogeneous catalysis is a sequence of reactions that involve a catalyst in the same phase as the reactants. Phase here refers to solid, liquid, vs. gas. Most commonly, a homogeneous catalyst is co dissolved in a solvent with the reactants.
  • 9. Cont. Activity 3 The result: 1. The pH paper in first 3 minutes of cup No.1 and 3 didn’t change . But cup No.2 change to orange color . 2. No. 2 cup start to become more darker in 6,9, 12 and 15 minutes. But cup No.1and 3 didn’t change. 3. That means that cup No.2 is an acidic. 4. When we add the baking soda in cup No.3, its start to bubbled and that mean that cup No.1 is also acid but it takes time for react with the water.
  • 10. Act. 4: Using a Metal Catalyst to Degrade an Air Pollutant In this activity we will investigate the catalytic conversion of ammonia into safe molecules . More specifically as a class we will compare the performance of an iron catalyst and two types of copper catalyst in breaking down or degrading ammonia . Copper granules Copper turnings Iron fiber
  • 12. Act. 4: Using a Metal Catalyst to Degrade an Air Pollutant • The conclusion : We found after the activity that the best catalyst that change the ammonia to nitrogen and water is : 1. Copper granules . 2. Copper turning. 3. Iron fiber. We use indicator called “Phenolphthalein” it color the ammonia to pink to show the ammonia level. In the activity we notice that the iron fiber had become deactivated, or poisoned because it oxidation.
  • 13. Act. 5: Using Photocatalysis to Degrade a Water Pollutant A photocatalyst is defined as a substance which is activated by adsorbing a photon and is capable of accelerating a reaction without being consumed . These substances are invariably semiconductors. Semiconducting oxide photocatalysts have been increasingly focused in recent years due to their potential applications in solar energy conversion and environmental purification . +TiO 2
  • 14. Act. 5: Using Photocatalysis to Degrade a Water Pollutant UV Sunlight Dark Dye + Dye tio2 Dye + Dye tio2 Dye + Dye tio2 Time 0 5 5 5 5 5 5 3 5 5 1 5 5 5 6 4 5 5 5 9 4 5 5 5 12 3 5 5 5 15 2 5 5 5 18 2 5 5 5 The conclusion:
  • 15. Act. 5: Using Photocatalysis to Degrade a Water Pollutant 6 5 4 3 2 1 0 Dye + TiO2 9 8 7 6 5 4 3 2 1 color change Time Dark sunlight UV
  • 16. Eliminating Amyl acetate From Effluent •Introduction: The problem of the scarcity of fresh water from the greatest challenges facing the State of Qatar, the State in the area of weather conditions are considered of the most severe climatic conditions in the world, leading to limited water resources, and lack of surface water. Taking into account population equation, the State of Qatar is one of the most poverty-stricken areas, water stress in the world. •Aim of the work : treating wastewater produced from food-manufacturing company prevents effluent from becoming an environmental nuisance and hazard
  • 17. Eliminating amyl acetate from effluent The ester amyl acetate (CH3COOC5H11): Is a mixture of five isomers. It is a colorless, flammable, volatile liquid that smells and tastes like bananas and is something called banana oil. Uses: 1. in a flavoring in foods . In solvent in nail polishes. 1. Leather polishes. 2. Metallic paints. Hazards: Is toxic if swallowed or inhaled, can cause irritation to the eyes and skin.
  • 19. 1. treating wastewater produced from food-manufacturing company prevents effluent from becoming an environmental nuisance and hazard. 2. Brake down the amyl acetate to acetic acid . Cu catalyst 7 6.5 6 5.5 15 10 5 0.3 pH Time Cu catalyst TiO2 catalyst 8 6 4 2 0 20 15 10 5 0.3 pH Time TiO2 catalyst 8 6 4 2 0 20 15 10 5 0.3 pH Time Fe catalyst Fe catalyst
  • 20. : The conclusion We found after the experiment that the best catalyst that brake the amyl acetate is 1. Cu 2. Fe 3. TiO2 ( it doesn't work ) The production of acetic acid can be monitored with pH meter ,showing a reduction of pH from 6 to 5.
  • 21. recommendation: we recommended the factories to use our project in large scale and try another catalyst to save our environmental in Qatar. The problem we had: the problem we use TiO2 as a catalyst but it didn't work even though we put it in sunlight
  • 22. Acknowledgment Many thanks to my teachers, school and AL-Bairaq team from Center for Advanced Materials (CAM), Qatar University for supporting us during our journey with a AL-Bairaq. Also, I would like to thank the sponsors UNESCO, Ras Gas, Maersk Oil and Shell.

Editor's Notes

  1. Disadv: it is hard to get the reactant to the surface By product may deactivate (poison the catalyst)
  2. This experiment ties in closely with light-harnessing reactions, photosynthesis, and even ozone depletion. As photocatalysis involves using solar energy to produce a reaction, it is one of the best ways, environmentally-speaking, to use catalysis.