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GLASS
By
GAURINANDANA M.S.
INDRODUCTION
*Glass is an amorphous,hard, brittle,
transparent or translucent super cooled
liquid of infinite viscosity having,no definite
melting point obtained by fusing a mixture of
a number of metallic silicates or borates of
sodium,potassium,calcium,and lead.
PROPERTIES OF GLASS.
Glass is
•amorphous. •brittle. •transparent
•good electrical insulator
•unaffected by air,water,acid or chemical reagents except
HF.
•No definite crystal structure means glass have high
compressive strength.
•can absorb ,transmitt and reflect light.
RAW MATERIALS
GLASS
1.silica(ordinary sand).
2.Alkali metals (Na or K).
3.Alkaline earth metals(Ca or
Ba).
4.Heavy metals and radicals
the chief sources of lead are
PbO and Pb3O4.
5.colouring materials.
COLOURING MATERIALS
NOTES
Na=sodium carbonate,sodium sulphate or sodium nitrate.
K=potassium carbonate or potassium nitrate.
Ca=lime, limestone (CaO,CaCO3).
Ba=Barium carbonate
Heat resisting glass=Zinc(Zinc Oxide)
Opalescent glass= phosphates.( Calcium phosphate)
And also arsenic and antimony.
MANUFACTURE OF
ORDINARY GLASS.
Ordinary glass/soda
glass/window glass.
Na2O.CaO.6SiO2.
STEPS
•Fusion of the raw
materials.
•working of molten
glass.
•Annealing.
Fusion of the
raw materials
Furnace heated by producer gas and works on
the regenerative system of heat economy
.
The raw materials sodium
carbonate calcium
carbonate and sand are
finely powedered and
thoroughly mixed with one
another,A small amount of
scrap glass is also added
which acts as flux.The
mixture is fused in a tank
On continued heating the entire amount of
CO2 is driven out.At the end the opaque
mass turns clear and transparent and is free
from CO2 and SO2.
A glass blower rolls his blowpipe into the molten
mass until the required amount of glass has
adhered to its end.Then blows a bubble in the
adhering mass and give it the required shape
with or without the help of mould .In bigger
factories the greater fraction of products is
machine made while laboratory glassware and
a few better grades of table glass are still
manufactured by the hand blown process.
2.Working of molten glass.
3.ANNEALING
If the glass is cooled rapidly it will
become brittle and if cooled very
slowly it will become opaque.so that
the articles should be cooled neither
rapidly nor very slowly.For this they
are made to pass through a long
tunnel like furnace which is hot at
one end and at room temperature
at the other end.This process of
cooling of glass is called annealing.
TYPES OF GLASS
Types Composition
/raw
materials
Advantages Uses
Sodaglass/soft
glass
SiO2(75%)+Sodi
um
oxide(15%)+Calci
um
oxide(8%)+Alumi
nium oxide(2%)
It softens at
comparatively
lower
temperature.
Potash
glass/hard glass
Sand, limestone,
potassium
carbonate
This has higher
melting point and
can withstand
higher
temperature.
Flint glass/lead
-potash lime
glass
Raw materials are
sand,red lead and
potassium carbonate
Composition-silica(45%
),sodium oxide(4%)
potassium
oxide(4%),CaO(3%),Pb
O(44%)
High refractive
index.
Jena glass Mixture of Zinc
and Barium boro
silicates.
Stronger than
ordinary glass,low
coefficient of
expansion and is very
resistant to heat
,action of acid and
alkali
Pyrex glass Mixture of sodium
aluminium
borosilicates,80%silica,4
%sodium
oxide,0.5%CaO,0.5%pot
assium
oxide,12%B2O3,3%
Al2O3
Coefficient of
expansion is very
low.
Bottle glass
3.5% MgO
and0.5%of
Al2O3Fe2O3
Ordinary soda
lime glass
Quartz
glass/silica glass
It is obtained
from pure silica.
It has a low
coefficient of
expansion.it does
not break even
plunged in water
while red hot.
Ground glass It has been ground
by emery and
turpentine or by
sand blasting.
It is widely used as a
weather and heat proof
light diffuser in ambient
lighting ,namely on
enclosures for lamps
and incandescent
bulbs.Its functions
include reducing glare
and retinal damage by
direct sight of the lamp.
Crooke’s glass It is a special type
of optical glass
containing cerium
oxide.
Cerium oxide in
glass cuts off
ultraviolet rays
harmful to eyes.
Safety
glass/shatter
proof glass.
It is obtained by
placing a layer of
transparent plastic
(usually a sheet of
vinyl acetate resin)
between two layers of
glass by means of a
suitable adhesive and
cementing them by
heat and pressure.
As this glass
does not break
under ordinary
impact so that it
is used in
automobile wind
shields,goggles...
THANK YOU

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Glass.pdf

  • 2. INDRODUCTION *Glass is an amorphous,hard, brittle, transparent or translucent super cooled liquid of infinite viscosity having,no definite melting point obtained by fusing a mixture of a number of metallic silicates or borates of sodium,potassium,calcium,and lead.
  • 3.
  • 4. PROPERTIES OF GLASS. Glass is •amorphous. •brittle. •transparent •good electrical insulator •unaffected by air,water,acid or chemical reagents except HF. •No definite crystal structure means glass have high compressive strength. •can absorb ,transmitt and reflect light.
  • 5. RAW MATERIALS GLASS 1.silica(ordinary sand). 2.Alkali metals (Na or K). 3.Alkaline earth metals(Ca or Ba). 4.Heavy metals and radicals the chief sources of lead are PbO and Pb3O4. 5.colouring materials.
  • 7. NOTES Na=sodium carbonate,sodium sulphate or sodium nitrate. K=potassium carbonate or potassium nitrate. Ca=lime, limestone (CaO,CaCO3). Ba=Barium carbonate Heat resisting glass=Zinc(Zinc Oxide) Opalescent glass= phosphates.( Calcium phosphate) And also arsenic and antimony.
  • 8. MANUFACTURE OF ORDINARY GLASS. Ordinary glass/soda glass/window glass. Na2O.CaO.6SiO2. STEPS •Fusion of the raw materials. •working of molten glass. •Annealing.
  • 9. Fusion of the raw materials Furnace heated by producer gas and works on the regenerative system of heat economy . The raw materials sodium carbonate calcium carbonate and sand are finely powedered and thoroughly mixed with one another,A small amount of scrap glass is also added which acts as flux.The mixture is fused in a tank
  • 10. On continued heating the entire amount of CO2 is driven out.At the end the opaque mass turns clear and transparent and is free from CO2 and SO2.
  • 11. A glass blower rolls his blowpipe into the molten mass until the required amount of glass has adhered to its end.Then blows a bubble in the adhering mass and give it the required shape with or without the help of mould .In bigger factories the greater fraction of products is machine made while laboratory glassware and a few better grades of table glass are still manufactured by the hand blown process. 2.Working of molten glass.
  • 12. 3.ANNEALING If the glass is cooled rapidly it will become brittle and if cooled very slowly it will become opaque.so that the articles should be cooled neither rapidly nor very slowly.For this they are made to pass through a long tunnel like furnace which is hot at one end and at room temperature at the other end.This process of cooling of glass is called annealing.
  • 13. TYPES OF GLASS Types Composition /raw materials Advantages Uses Sodaglass/soft glass SiO2(75%)+Sodi um oxide(15%)+Calci um oxide(8%)+Alumi nium oxide(2%) It softens at comparatively lower temperature.
  • 14. Potash glass/hard glass Sand, limestone, potassium carbonate This has higher melting point and can withstand higher temperature. Flint glass/lead -potash lime glass Raw materials are sand,red lead and potassium carbonate Composition-silica(45% ),sodium oxide(4%) potassium oxide(4%),CaO(3%),Pb O(44%) High refractive index.
  • 15. Jena glass Mixture of Zinc and Barium boro silicates. Stronger than ordinary glass,low coefficient of expansion and is very resistant to heat ,action of acid and alkali Pyrex glass Mixture of sodium aluminium borosilicates,80%silica,4 %sodium oxide,0.5%CaO,0.5%pot assium oxide,12%B2O3,3% Al2O3 Coefficient of expansion is very low.
  • 16. Bottle glass 3.5% MgO and0.5%of Al2O3Fe2O3 Ordinary soda lime glass Quartz glass/silica glass It is obtained from pure silica. It has a low coefficient of expansion.it does not break even plunged in water while red hot.
  • 17. Ground glass It has been ground by emery and turpentine or by sand blasting. It is widely used as a weather and heat proof light diffuser in ambient lighting ,namely on enclosures for lamps and incandescent bulbs.Its functions include reducing glare and retinal damage by direct sight of the lamp. Crooke’s glass It is a special type of optical glass containing cerium oxide. Cerium oxide in glass cuts off ultraviolet rays harmful to eyes.
  • 18. Safety glass/shatter proof glass. It is obtained by placing a layer of transparent plastic (usually a sheet of vinyl acetate resin) between two layers of glass by means of a suitable adhesive and cementing them by heat and pressure. As this glass does not break under ordinary impact so that it is used in automobile wind shields,goggles...