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Fe-Deposits
Supervision by: Dr. Ahmed M. ZayedSupervision by: Dr. Ahmed M. Zayed
Edited by : Mostafa Abdel Azim MasoudEdited by : Mostafa Abdel Azim Masoud
Beni-Suef University- EgyptBeni-Suef University- Egypt
Banded Iron Formations
(BIFs)
Cross-lamination
Slumping
Folding
They are deposits of Precambrian age characterized by
being thin to medium bedded interlaminations of iron
oxide, iron carbonate, or iron silicate materials (layer
rich in iron ≥15% Fe ) with chert, quartz, carbonate, or
jasper (layer poor in iron).
Due to the extreme age of these formations, almost all
BIF have undergone some faulting, fracturing, folding,
compaction, veining, intrusions and metamorphism. 
Although all BIF formations are probably
metamorphosed to some degree, but their general
character is still sedimentary.
N.B. BIFs are known as “taconite” in North America.
Definition:
Banding
Folding
Folding
Fracturing and veining
Classification of BIFs according to
facies: (Mineralogy of BIFs)
Oxide facies: Magnetite and hematite (taconite(.
Silicate facies: Cummingtonite, grunerite, greenalite, minnesotaite,
stilpnomelane, Fe chlorites, and Fe amphiboles.
Carbonate facies: Ankerite and siderite.
Sulphide facies: pyrite.
The classic facies zonation
from shallow to deeper
water deposition is:
oxide to carbonate to
sulphide.
Classification of BIFs according to
geologic setting:
Three main types of banded iron formations are recorded allover
the world :
Algoma type (Archean age; 3500-3000 Ga)
→Formed by turbidity currents near island
arc trenches and typically sub marine
volcanogenic origin,
Island arc depositional environment.
The iron bands alternate with
metavolcanics and poyroclastics.
Lake- superior type (Early Proterozoic age; 2500-2000 Ga)
→ Shelf sediments precipitated in stable shelf or marginal basin (foreland or back-arc
basins), continental margin depositional environment.
The iron band alternate with metasediments.
Rapitan type ( 1000-500 Ga )
→Non volcanic type which formed in non volcanic rift zone at continental margin
Origin:
Sedimentary origin:
1.BIF has been considered to be ferruginous sedimentary rock, which resulted from
the weathering, transportation, and precipitation of iron derived from landmasses
by erosion, with rhythmic deposition of iron as oxides, hydroxides, and hydrous
oxide-silicate minerals in the sedimentary systems.
2.Iron formations were deposited as end members, or final products, of carbonate
sedimentary cycles.
3.Depositions of iron formations resulted after buildup of iron concentration in the
sea, depending on pH and Eh conditions, the gradual buildup of oxygen and the
depletion of CO2 in the atmosphere lead to the precipitation of iron in seawater as
magnetite, hematite, and siderite.
4.Iron formation resulted from the upwelling of cold, deep seawater onto a warm
continental shelf.
The cold water would be saturated in CO3, Ca2+ , and Fe2+.
Fe2+ would precipitate as ferric oxides, hydroxides, or silicates with increased
temperature, oxidation, and CO2 loss. The same waters would supersaturated in
amorphous silica and would precipitate chert.
Volcanic origin:
1.Silica and iron associated with volcanism were poured out on the sea floor from
springs of magmatic origin.
2.Iron formation beds were originally deposited as more thickly bedded fine-grained
ferruginous tuffs and other iron-rich sediments that were diagenetically oxidized and
silicified under the influence of solutions that were partly volcanic in origin.
The banded iron layers were formed in sea water as the result of
oxygen released by photosynthetic cyanobacteria (blue green algae),
combining with dissolved iron in Earth's oceans to form insoluble iron
oxides, which precipitated out, forming a thin layer on the substrate,
which may have been anoxic mud (forming shale and chert).
Biogenic origin:
Occurrences in Egypt:
 The Egyptian Precambrian
iron formations (BIF) and
the host metavolvanics or
metasediments constitute
widespread and easily
recognizable sequences at
134 localities distributed in
the Central Eastern Desert
(CED) between latitudes 25˚
12` and 26˚ 31`N.
 Among them : ( Umm Nar,
G.El Hadid, Umm Khamis El
Zarga, W.Kareem, and W.
Dabbab ).
Two main genetic models have been postulated for the Precambrian Egyptian BIFs
including the Umm Nar occurrence:
1.A purely sedimentary origin during the accumulation of the Precambrian geosynclinal
sediments,
2.A volcanogenic origin related to submarine magmatism and hydrothermal activity of
pan African island arc assemblages.
Observations:
The original sediments of the BIF host rocks were most probably sandy and calcareous
shales or mudstones, sandstones, and limestones which are now metamorphosed under
greenschist and low amphibolite facies conditions.
Evidence of sedimentary origin of these
metamorphic facies:
1.The geochemical characters of these rocks.
2.The bedded nature of these rocks and their
characteristic mm to cm rhythmic intercalations.
3.The absence of relics of igneous textures or
exsolution pattern.
The lithofacies association of the metasediments
and BIF and their syn-sedimentary structures
(rhythmic bedding and laminations, cross
lamination and flaser structure) suggest deposition
in shelf environment.
(B) according to the present conclusions, the Egyptian
Precambrian BIFs can be preliminary reclassified into
two main genetic types of different ages:
1. Early Proterozoic BIF of pre pan-African shelf
environment, represented by the studied Umm Nar
occurrence, and
2. Late Proterozioc BIF of Pan-African island arc
environment, represented by some other occurrences.
e.g. G. El Hadid, W. Karim and El Dabah
Two main genetic models have been postulated for the
Precambrian Egyptian BIFs including the Umm Nar
occurrence:
(1)A purely sedimentary origin during the accumulation of
the Precambrian geosynclinal sediments, and
(2)A volcanogenic origin related to submarine magmatism
and hydrothermal activity of pan African island arc
assemblages.
→ A detailed geologic, structural, and petrographic studies
of Umm Nar BIFs are included in the publication of El Aref,
Abdel Wahed, El Duogdoug and El Manawi (1993).and
they concluded the followings:
(a) The original sediments of the BIF host rocks were most
probably sandy and calc. shales or mudstones, sandstones,
and limestones now metamorphosed under greenschist and
low amphibolite conditions.
Phanerozoic
Ironstones
(Ironstone Quarry, Hengistbury Head, England)
Ironstone is a fine-grained, heavy and compact
sedimentary rock.
Its main components are the carbonate or oxide of
iron, clay and/or sand. It can be thought of as a
concretionary form of siderite.
Ironstone also contains clay, and sometimes calcite
and quartz.
Definition:
Classification of Ironstones:
Bog ore
Bog iron ores:
Formed in peat bogs, marshes, swamps and lakes in regions of
Pleistocene glaciations and in volcanic lakes.
1.Lake ores are formed as oolitic goethite in agitated waters along lake
margins.
2.Volcanic lake ores are made up of purely limonitic material with up to
50% Fe and owe their origin to iron bearing thermal springs.
Clinton type iron ore:
is characterized by :
1.The absence of chert.
2.Presence of hematite and chamosite oolites.
3. Herring bone cross statifications implying intertidal deposition.
Black band & sideritic iron ores:
These are fresh water deposits as thin beds, discontinuous lenses or
nodules associated with coal.
Oolitic ironstones:
Origin:
Source of Iron:
1.From weathering processes upon land, especially in the tropical climate and the subsequent
introduction of iron by rivers into seas and oceans, mostly in the adsorbed form or as colloidal
suspensions. (sedimentary origin)
2.Iron formations are attributable to submarine exhalations of fluids and the ooidal ironstones
especially attributed to hypersaline fluids which have risen to marine bottom along deep faults
(Kimberly, 1989). (volcanic origin)
3.The microbial and the other digenetic processes affecting the clayey sediments, rich in organic
matter and deposited in deltas, lagoons, and stagnant anoxic basins, lead to mobilization of iron
(fe3+→fe2+). According to this hypothesis, the anoxic sediments could have acted as very
important source and temporary storage of huge quantities of iron. (biogenic origin)
Origin of Ooids:
1.By metasomatic ferruginization of ooidal limestones.
2.Ooides growing in the state of suspension, in an agitated, high energy aqueous environment.
SUGGESTED ENVIRONMENTAL SETTINGS
OF THE OOLITIC IRONSTONES
Continental Environments Marine Environments
Low Energy Env. High Energy Env.
Lagoon
Lacustrine
Shallow / Deep Shelf
Tidal Bars
Deltaic Bars
Upon
Submarine
Swells
Lateritic Soil
/Hydromorphic Env.
Fluvial Env.
Occurrences in Egypt:
According to age relations, they are classified as follows:
2 5
2 5 3 0
3 5
M ED ITER R A N EA N SEA
RED
SEA
K H A R G A
O A S I S
D A K H L A
O A S I S
FA R A F R A
O A S I S
E L B A H A R I Y A
O A S I S
S IW A
O A S I S
FA IY U M
O A S IS
C A I R O
S a lu m
A l ex a n d r ia
3 0
1
2
3
4
5
6
7
8
A S W A N
1 0
S I N A I
1= Jurrasic ooltic ironstone, G abal E l M aghara
2= Low er C retaceous oolitic ironstone, G abal E l H alal
3-7= U pper C retaceous oolitic ironstones, w estC entral Sinai (3), north Wadi Q ena (4),
A sw an region (5,6,7)
8-10= M iddle E ocene oolitic ironstones (E l B ahariya region
O C C U R R E N C E S O F T H E E G Y PT IA N P H A N E R O Z O IC
O O L IT IC IR O N ST O N E S
9
Case Study:
El Baharyia Ironstones
Geological map of El
Bahariya Depression
(El Aref et al., 2006)
Cenomanian Bahariya
Formation
Mud-ironstone
Fossiliferous-IS
Nm-Oo-On-IS
Mudstone
lowerISsequence
UpperISsequence
Lateritized iron ore
The Middle Eocene ironstone succession in the southern sector of Gabal
Ghorabi mine area consists of two ironstone sequences.
Types of iron deposits and genesis:
According to El Sharkawi et al., (1987), the Bahariya iron ore can be classified into threeAccording to El Sharkawi et al., (1987), the Bahariya iron ore can be classified into three
types:types:
Genetic type (I):Genetic type (I):
 OOolitic-pisolitic iron ore of limonitic composition.
 The host rock is limestone of the Naqb Fm.
 Mainly shoal and lagoonal depositional environment.
Genetic type (II): (Karst ore)Genetic type (II): (Karst ore)
 Stratabound supergene ore formed due karstification of Qazzun Fm. (Nummulitic
limestone).
 It is barite-bearing, hematite, goethite iron ore (Karst ore).
 Karst textures are dominant.
Genetic type (III):Genetic type (III):
 Statabound supergene ore formed of green sand followed by lateritic weathering of
glauconite in the Upper Eocene HamraFm.
 The ore is mainly composed of glauconite and hematite.

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Fe-deposits

  • 1. Fe-Deposits Supervision by: Dr. Ahmed M. ZayedSupervision by: Dr. Ahmed M. Zayed Edited by : Mostafa Abdel Azim MasoudEdited by : Mostafa Abdel Azim Masoud Beni-Suef University- EgyptBeni-Suef University- Egypt
  • 2.
  • 4. They are deposits of Precambrian age characterized by being thin to medium bedded interlaminations of iron oxide, iron carbonate, or iron silicate materials (layer rich in iron ≥15% Fe ) with chert, quartz, carbonate, or jasper (layer poor in iron). Due to the extreme age of these formations, almost all BIF have undergone some faulting, fracturing, folding, compaction, veining, intrusions and metamorphism.  Although all BIF formations are probably metamorphosed to some degree, but their general character is still sedimentary. N.B. BIFs are known as “taconite” in North America. Definition:
  • 6. Classification of BIFs according to facies: (Mineralogy of BIFs)
  • 7. Oxide facies: Magnetite and hematite (taconite(. Silicate facies: Cummingtonite, grunerite, greenalite, minnesotaite, stilpnomelane, Fe chlorites, and Fe amphiboles. Carbonate facies: Ankerite and siderite. Sulphide facies: pyrite. The classic facies zonation from shallow to deeper water deposition is: oxide to carbonate to sulphide.
  • 8. Classification of BIFs according to geologic setting: Three main types of banded iron formations are recorded allover the world :
  • 9. Algoma type (Archean age; 3500-3000 Ga) →Formed by turbidity currents near island arc trenches and typically sub marine volcanogenic origin, Island arc depositional environment. The iron bands alternate with metavolcanics and poyroclastics. Lake- superior type (Early Proterozoic age; 2500-2000 Ga) → Shelf sediments precipitated in stable shelf or marginal basin (foreland or back-arc basins), continental margin depositional environment. The iron band alternate with metasediments. Rapitan type ( 1000-500 Ga ) →Non volcanic type which formed in non volcanic rift zone at continental margin
  • 10. Origin: Sedimentary origin: 1.BIF has been considered to be ferruginous sedimentary rock, which resulted from the weathering, transportation, and precipitation of iron derived from landmasses by erosion, with rhythmic deposition of iron as oxides, hydroxides, and hydrous oxide-silicate minerals in the sedimentary systems. 2.Iron formations were deposited as end members, or final products, of carbonate sedimentary cycles. 3.Depositions of iron formations resulted after buildup of iron concentration in the sea, depending on pH and Eh conditions, the gradual buildup of oxygen and the depletion of CO2 in the atmosphere lead to the precipitation of iron in seawater as magnetite, hematite, and siderite. 4.Iron formation resulted from the upwelling of cold, deep seawater onto a warm continental shelf. The cold water would be saturated in CO3, Ca2+ , and Fe2+. Fe2+ would precipitate as ferric oxides, hydroxides, or silicates with increased temperature, oxidation, and CO2 loss. The same waters would supersaturated in amorphous silica and would precipitate chert.
  • 11. Volcanic origin: 1.Silica and iron associated with volcanism were poured out on the sea floor from springs of magmatic origin. 2.Iron formation beds were originally deposited as more thickly bedded fine-grained ferruginous tuffs and other iron-rich sediments that were diagenetically oxidized and silicified under the influence of solutions that were partly volcanic in origin.
  • 12. The banded iron layers were formed in sea water as the result of oxygen released by photosynthetic cyanobacteria (blue green algae), combining with dissolved iron in Earth's oceans to form insoluble iron oxides, which precipitated out, forming a thin layer on the substrate, which may have been anoxic mud (forming shale and chert). Biogenic origin:
  • 13. Occurrences in Egypt:  The Egyptian Precambrian iron formations (BIF) and the host metavolvanics or metasediments constitute widespread and easily recognizable sequences at 134 localities distributed in the Central Eastern Desert (CED) between latitudes 25˚ 12` and 26˚ 31`N.  Among them : ( Umm Nar, G.El Hadid, Umm Khamis El Zarga, W.Kareem, and W. Dabbab ).
  • 14. Two main genetic models have been postulated for the Precambrian Egyptian BIFs including the Umm Nar occurrence: 1.A purely sedimentary origin during the accumulation of the Precambrian geosynclinal sediments, 2.A volcanogenic origin related to submarine magmatism and hydrothermal activity of pan African island arc assemblages. Observations: The original sediments of the BIF host rocks were most probably sandy and calcareous shales or mudstones, sandstones, and limestones which are now metamorphosed under greenschist and low amphibolite facies conditions. Evidence of sedimentary origin of these metamorphic facies: 1.The geochemical characters of these rocks. 2.The bedded nature of these rocks and their characteristic mm to cm rhythmic intercalations. 3.The absence of relics of igneous textures or exsolution pattern. The lithofacies association of the metasediments and BIF and their syn-sedimentary structures (rhythmic bedding and laminations, cross lamination and flaser structure) suggest deposition in shelf environment.
  • 15. (B) according to the present conclusions, the Egyptian Precambrian BIFs can be preliminary reclassified into two main genetic types of different ages: 1. Early Proterozoic BIF of pre pan-African shelf environment, represented by the studied Umm Nar occurrence, and 2. Late Proterozioc BIF of Pan-African island arc environment, represented by some other occurrences. e.g. G. El Hadid, W. Karim and El Dabah
  • 16. Two main genetic models have been postulated for the Precambrian Egyptian BIFs including the Umm Nar occurrence: (1)A purely sedimentary origin during the accumulation of the Precambrian geosynclinal sediments, and (2)A volcanogenic origin related to submarine magmatism and hydrothermal activity of pan African island arc assemblages. → A detailed geologic, structural, and petrographic studies of Umm Nar BIFs are included in the publication of El Aref, Abdel Wahed, El Duogdoug and El Manawi (1993).and they concluded the followings: (a) The original sediments of the BIF host rocks were most probably sandy and calc. shales or mudstones, sandstones, and limestones now metamorphosed under greenschist and low amphibolite conditions.
  • 17.
  • 19. Ironstone is a fine-grained, heavy and compact sedimentary rock. Its main components are the carbonate or oxide of iron, clay and/or sand. It can be thought of as a concretionary form of siderite. Ironstone also contains clay, and sometimes calcite and quartz. Definition:
  • 21. Bog iron ores: Formed in peat bogs, marshes, swamps and lakes in regions of Pleistocene glaciations and in volcanic lakes. 1.Lake ores are formed as oolitic goethite in agitated waters along lake margins. 2.Volcanic lake ores are made up of purely limonitic material with up to 50% Fe and owe their origin to iron bearing thermal springs. Clinton type iron ore: is characterized by : 1.The absence of chert. 2.Presence of hematite and chamosite oolites. 3. Herring bone cross statifications implying intertidal deposition. Black band & sideritic iron ores: These are fresh water deposits as thin beds, discontinuous lenses or nodules associated with coal.
  • 23. Origin: Source of Iron: 1.From weathering processes upon land, especially in the tropical climate and the subsequent introduction of iron by rivers into seas and oceans, mostly in the adsorbed form or as colloidal suspensions. (sedimentary origin) 2.Iron formations are attributable to submarine exhalations of fluids and the ooidal ironstones especially attributed to hypersaline fluids which have risen to marine bottom along deep faults (Kimberly, 1989). (volcanic origin) 3.The microbial and the other digenetic processes affecting the clayey sediments, rich in organic matter and deposited in deltas, lagoons, and stagnant anoxic basins, lead to mobilization of iron (fe3+→fe2+). According to this hypothesis, the anoxic sediments could have acted as very important source and temporary storage of huge quantities of iron. (biogenic origin) Origin of Ooids: 1.By metasomatic ferruginization of ooidal limestones. 2.Ooides growing in the state of suspension, in an agitated, high energy aqueous environment.
  • 24. SUGGESTED ENVIRONMENTAL SETTINGS OF THE OOLITIC IRONSTONES Continental Environments Marine Environments Low Energy Env. High Energy Env. Lagoon Lacustrine Shallow / Deep Shelf Tidal Bars Deltaic Bars Upon Submarine Swells Lateritic Soil /Hydromorphic Env. Fluvial Env.
  • 25. Occurrences in Egypt: According to age relations, they are classified as follows:
  • 26. 2 5 2 5 3 0 3 5 M ED ITER R A N EA N SEA RED SEA K H A R G A O A S I S D A K H L A O A S I S FA R A F R A O A S I S E L B A H A R I Y A O A S I S S IW A O A S I S FA IY U M O A S IS C A I R O S a lu m A l ex a n d r ia 3 0 1 2 3 4 5 6 7 8 A S W A N 1 0 S I N A I 1= Jurrasic ooltic ironstone, G abal E l M aghara 2= Low er C retaceous oolitic ironstone, G abal E l H alal 3-7= U pper C retaceous oolitic ironstones, w estC entral Sinai (3), north Wadi Q ena (4), A sw an region (5,6,7) 8-10= M iddle E ocene oolitic ironstones (E l B ahariya region O C C U R R E N C E S O F T H E E G Y PT IA N P H A N E R O Z O IC O O L IT IC IR O N ST O N E S 9
  • 27. Case Study: El Baharyia Ironstones Geological map of El Bahariya Depression (El Aref et al., 2006)
  • 28. Cenomanian Bahariya Formation Mud-ironstone Fossiliferous-IS Nm-Oo-On-IS Mudstone lowerISsequence UpperISsequence Lateritized iron ore The Middle Eocene ironstone succession in the southern sector of Gabal Ghorabi mine area consists of two ironstone sequences.
  • 29. Types of iron deposits and genesis: According to El Sharkawi et al., (1987), the Bahariya iron ore can be classified into threeAccording to El Sharkawi et al., (1987), the Bahariya iron ore can be classified into three types:types: Genetic type (I):Genetic type (I):  OOolitic-pisolitic iron ore of limonitic composition.  The host rock is limestone of the Naqb Fm.  Mainly shoal and lagoonal depositional environment. Genetic type (II): (Karst ore)Genetic type (II): (Karst ore)  Stratabound supergene ore formed due karstification of Qazzun Fm. (Nummulitic limestone).  It is barite-bearing, hematite, goethite iron ore (Karst ore).  Karst textures are dominant. Genetic type (III):Genetic type (III):  Statabound supergene ore formed of green sand followed by lateritic weathering of glauconite in the Upper Eocene HamraFm.  The ore is mainly composed of glauconite and hematite.

Editor's Notes

  1. #Differences between BIFs and Ironstones: Age: BIFs are Precambrian and ironstones are Phanerozoic N.B. Phanerozoic BIFs are recorded, but Phanerozoic is not the age of their formation, it is the age of the tectonic events that led to their exposure like the Alpine, Caledonian orogenies. 2. Textures: BIFs (banding), Ironstones (ooids, peloids, onchoids, etc..) 3. BIFs are affected more by tectonism and metamorphism
  2. #Banded: because BIF is banded and takes all the scales of banding (thick banding-thin banding-laminae-varves). #Formation: not the stratigraphic term, but the same as its English meaning. #BIFs are affected by different sedimentary structures: Primary or synsedimentary deformational textures: BIFs are affected by syndeformational tectonism (like slumping, cross-lamination and folding (as it appears here in the photo)) The folding in this photo is restricted to a definite zone and is not found above or below it, that’s why we say that it is synsedimentary. 2. Secondary or postsedimentary structures (like folding and faulting and veining) #The dark band is Jasper, and the light band is the Fe-rich band The black to gray to silver colored iron oxide layers contrast with the iron rich chert, jasper and shales which are generally red in color.  #Jasper: a form of chalcedony (cryptocrystalline Qz), it is opaque impure variety of silica, Jasper is basically chert which owes its red color to iron III inclusions #Jaspilite is a BIF rock that often has distinctive bands of jasper.
  3. ≥15% Fe in the Iron-rich layer only not in the bulk BIF sample with its different bands, where when we make chemical analysis for BIFs, we analyze each band alone.
  4. Rolling over the sustrate at the interface between seawater and the deposited sediments on a core