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Course: Quantum Electronics
Arpan Deyasi
Topic: Density of states of Bulk and Quantum
Structures
1
Arpan Deyasi, RCCIIT
1/17/2021
1/17/2021 2Arpan Deyasi, RCCIIT
What is DoS?
Number of available energy states
per unit energy interval
per unit dimension
in real space
EC
EC + dEC
EV
EV + dEV
dEV
dEC
E
k
1/17/2021 Arpan Deyasi, RCCIIT 3
What do we mean by ‘dimension’?
For ‘bulk’, it is ‘volume’
For ‘quantum well’, it is ‘area/surface’
For ‘quantum wire’, it is ‘line/length’
For ‘quantum dot’, it is a ‘point/dot’
1/17/2021 4Arpan Deyasi, RCCIIT
Energy band diagram is drawn in E-k plane
‘k’ is wave-vector, not a physical quantity
No of electrons is measured by magnitude of current
So we must know the density of electrons
in real space instead of k-space
1/17/2021 Arpan Deyasi, RCCIIT 5
Fermi sphere
1/17/2021 Arpan Deyasi, RCCIIT 6
Fermi surface
1/17/2021 7Arpan Deyasi, RCCIIT
DoS for bulk semiconductor
Let’s start with Bloch theorem
( , , ) ( , , )x y zx y z x L y L z Lψ ψ= + + +
Consider a 3D semiconductor with dimensions Lx, Ly, Lz
1/17/2021 8Arpan Deyasi, RCCIIT
DoS for bulk semiconductor
For validity of wave function
2
2
2
x x x
y y y
z z z
k L n
k L n
k L n
π
π
π
=
=
=
Volume in k-space
3
(2 ) x y z
x y z
x y z
n n n
k k k
L L L
π
=
1/17/2021 9Arpan Deyasi, RCCIIT
DoS for bulk semiconductor
Let
1x y zn n n= = =
x y zL L L L= = =
Volume of unit cell in k-space
3
3
(2 )
kV
L
π
=
1/17/2021 10Arpan Deyasi, RCCIIT
DoS for bulk semiconductor
Volume of Fermi sphere in k-space
34
3
FV kπ=
Volume of semiconductor in real space
3
RV L=
1/17/2021 11Arpan Deyasi, RCCIIT
DoS for bulk semiconductor
number of energy states in real space
1 1
F
k R
N V
V V
= × ×
3
3
3 3
4 1
3 8
L
N k
L
π
π
= × ×
3
2
( )
6
k
N N k
π
= =
1/17/2021 12Arpan Deyasi, RCCIIT
DoS for bulk semiconductor
Introducing Pauli’s exclusion principle
3 3
2 2
( ) 2
6 3
k k
N k
π π
=× =
2
2
( )
k
N k
k π
∂
=
∂
1/17/2021 13Arpan Deyasi, RCCIIT
DoS for bulk semiconductor
From parabolic dispersion relation
2 2
*
2
k
E
m
=

2
*
E k
k m
∂
=
∂

2
* *
2 * 2E m E E
k m m
∂
= =
∂



1/17/2021 14Arpan Deyasi, RCCIIT
DoS for bulk semiconductor
*
1
2
k m
E E
∂
=
∂ 
N N k
E k E
∂ ∂ ∂
= ×
∂ ∂ ∂
2 *
2
1
2
N k m
E Eπ
∂
= ×
∂ 
1/17/2021 15Arpan Deyasi, RCCIIT
DoS for bulk semiconductor
*
2 2
2 * 1
2
N m E m
E Eπ
∂
= ×
∂  
3/2*
2 2
1 2
2
N m
E
E π
 ∂
= × 
∂  
For a particular material
N
E
E
∂
∝
∂
E
ρ(E)
1/17/2021 16Arpan Deyasi, RCCIIT
DoS for Quantum Well
Area in k-space
2
2
(2 )
kA
L
π
=
Area of Fermi sphere in k-space
Area of semiconductor in real space
2
FA kπ=
2
RA L=
1/17/2021 17Arpan Deyasi, RCCIIT
DoS for Quantum Well
number of energy states in real space
1 1
F
k R
N A
A A
= × ×
2
2
2 2
1
4
L
N k
L
π
π
= × ×
2
( )
4
k
N N k
π
= =
1/17/2021 18Arpan Deyasi, RCCIIT
DoS for Quantum Well
Introducing Pauli’s exclusion principle
2 2
( ) 2
4 2
k k
N k
π π
=× =
( )
k
N k
k π
∂
=
∂
1/17/2021 19Arpan Deyasi, RCCIIT
DoS for Quantum Well
From parabolic dispersion relation
*
1
2
k m
E E
∂
=
∂ 
N N k
E k E
∂ ∂ ∂
= ×
∂ ∂ ∂
*
1
2
N k m
E Eπ
∂
= ×
∂ 
1/17/2021 20Arpan Deyasi, RCCIIT
DoS for Quantum Well
* *
2 1
2
N m E m
E Eπ
∂
= ×
∂  
*
2
N m
E π
∂
=
∂ 
DoS is independent of energy?
1/17/2021 21Arpan Deyasi, RCCIIT
DoS for Quantum Well
The result is obtained for a particular sub-band
Considering all the sub-bands
*
2
1
( )
n
i
i
N m
E E
E π =
∂
= Θ −
∂
∑
E
ρ(E)
E1 E2 E3 Ei-1 Ei Ei+1
1/17/2021 22Arpan Deyasi, RCCIIT
DoS for Quantum Wire
Length in k-space
Length of Fermi sphere in k-space
Length of semiconductor in real space
2
kL
L
π
=
2FL k=
RL L=
1/17/2021 23Arpan Deyasi, RCCIIT
DoS for Quantum Wire
number of energy states in real space
1 1
F
k R
N L
L L
= × ×
1
2
2
L
N k
Lπ
= × ×
k
N
π
=
1/17/2021 24Arpan Deyasi, RCCIIT
DoS for Quantum Wire
Introducing Pauli’s exclusion principle
2
k
N
π
=
2
( )N k
k π
∂
=
∂
1/17/2021 25Arpan Deyasi, RCCIIT
DoS for Quantum Wire
From parabolic dispersion relation
*
1
2
k m
E E
∂
=
∂ 
N N k
E k E
∂ ∂ ∂
= ×
∂ ∂ ∂
*
2 1
2
N m
E Eπ
∂
= ×
∂ 
1/17/2021 26Arpan Deyasi, RCCIIT
DoS for Quantum Wire
2 * 1N m
E Eπ
∂  
=  
∂  
E
ρ(E)
E1 E2 E3 E4 E5
1/17/2021 27Arpan Deyasi, RCCIIT
DoS for Quantum Dot
E4E3E2E1
ρ(E)
E E
ρ(E)
E1 E2 E3 E4

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DoS of bulk and quantum structures

  • 1. Course: Quantum Electronics Arpan Deyasi Topic: Density of states of Bulk and Quantum Structures 1 Arpan Deyasi, RCCIIT 1/17/2021
  • 2. 1/17/2021 2Arpan Deyasi, RCCIIT What is DoS? Number of available energy states per unit energy interval per unit dimension in real space EC EC + dEC EV EV + dEV dEV dEC E k
  • 3. 1/17/2021 Arpan Deyasi, RCCIIT 3 What do we mean by ‘dimension’? For ‘bulk’, it is ‘volume’ For ‘quantum well’, it is ‘area/surface’ For ‘quantum wire’, it is ‘line/length’ For ‘quantum dot’, it is a ‘point/dot’
  • 4. 1/17/2021 4Arpan Deyasi, RCCIIT Energy band diagram is drawn in E-k plane ‘k’ is wave-vector, not a physical quantity No of electrons is measured by magnitude of current So we must know the density of electrons in real space instead of k-space
  • 5. 1/17/2021 Arpan Deyasi, RCCIIT 5 Fermi sphere
  • 6. 1/17/2021 Arpan Deyasi, RCCIIT 6 Fermi surface
  • 7. 1/17/2021 7Arpan Deyasi, RCCIIT DoS for bulk semiconductor Let’s start with Bloch theorem ( , , ) ( , , )x y zx y z x L y L z Lψ ψ= + + + Consider a 3D semiconductor with dimensions Lx, Ly, Lz
  • 8. 1/17/2021 8Arpan Deyasi, RCCIIT DoS for bulk semiconductor For validity of wave function 2 2 2 x x x y y y z z z k L n k L n k L n π π π = = = Volume in k-space 3 (2 ) x y z x y z x y z n n n k k k L L L π =
  • 9. 1/17/2021 9Arpan Deyasi, RCCIIT DoS for bulk semiconductor Let 1x y zn n n= = = x y zL L L L= = = Volume of unit cell in k-space 3 3 (2 ) kV L π =
  • 10. 1/17/2021 10Arpan Deyasi, RCCIIT DoS for bulk semiconductor Volume of Fermi sphere in k-space 34 3 FV kπ= Volume of semiconductor in real space 3 RV L=
  • 11. 1/17/2021 11Arpan Deyasi, RCCIIT DoS for bulk semiconductor number of energy states in real space 1 1 F k R N V V V = × × 3 3 3 3 4 1 3 8 L N k L π π = × × 3 2 ( ) 6 k N N k π = =
  • 12. 1/17/2021 12Arpan Deyasi, RCCIIT DoS for bulk semiconductor Introducing Pauli’s exclusion principle 3 3 2 2 ( ) 2 6 3 k k N k π π =× = 2 2 ( ) k N k k π ∂ = ∂
  • 13. 1/17/2021 13Arpan Deyasi, RCCIIT DoS for bulk semiconductor From parabolic dispersion relation 2 2 * 2 k E m =  2 * E k k m ∂ = ∂  2 * * 2 * 2E m E E k m m ∂ = = ∂   
  • 14. 1/17/2021 14Arpan Deyasi, RCCIIT DoS for bulk semiconductor * 1 2 k m E E ∂ = ∂  N N k E k E ∂ ∂ ∂ = × ∂ ∂ ∂ 2 * 2 1 2 N k m E Eπ ∂ = × ∂ 
  • 15. 1/17/2021 15Arpan Deyasi, RCCIIT DoS for bulk semiconductor * 2 2 2 * 1 2 N m E m E Eπ ∂ = × ∂   3/2* 2 2 1 2 2 N m E E π  ∂ = ×  ∂   For a particular material N E E ∂ ∝ ∂ E ρ(E)
  • 16. 1/17/2021 16Arpan Deyasi, RCCIIT DoS for Quantum Well Area in k-space 2 2 (2 ) kA L π = Area of Fermi sphere in k-space Area of semiconductor in real space 2 FA kπ= 2 RA L=
  • 17. 1/17/2021 17Arpan Deyasi, RCCIIT DoS for Quantum Well number of energy states in real space 1 1 F k R N A A A = × × 2 2 2 2 1 4 L N k L π π = × × 2 ( ) 4 k N N k π = =
  • 18. 1/17/2021 18Arpan Deyasi, RCCIIT DoS for Quantum Well Introducing Pauli’s exclusion principle 2 2 ( ) 2 4 2 k k N k π π =× = ( ) k N k k π ∂ = ∂
  • 19. 1/17/2021 19Arpan Deyasi, RCCIIT DoS for Quantum Well From parabolic dispersion relation * 1 2 k m E E ∂ = ∂  N N k E k E ∂ ∂ ∂ = × ∂ ∂ ∂ * 1 2 N k m E Eπ ∂ = × ∂ 
  • 20. 1/17/2021 20Arpan Deyasi, RCCIIT DoS for Quantum Well * * 2 1 2 N m E m E Eπ ∂ = × ∂   * 2 N m E π ∂ = ∂  DoS is independent of energy?
  • 21. 1/17/2021 21Arpan Deyasi, RCCIIT DoS for Quantum Well The result is obtained for a particular sub-band Considering all the sub-bands * 2 1 ( ) n i i N m E E E π = ∂ = Θ − ∂ ∑ E ρ(E) E1 E2 E3 Ei-1 Ei Ei+1
  • 22. 1/17/2021 22Arpan Deyasi, RCCIIT DoS for Quantum Wire Length in k-space Length of Fermi sphere in k-space Length of semiconductor in real space 2 kL L π = 2FL k= RL L=
  • 23. 1/17/2021 23Arpan Deyasi, RCCIIT DoS for Quantum Wire number of energy states in real space 1 1 F k R N L L L = × × 1 2 2 L N k Lπ = × × k N π =
  • 24. 1/17/2021 24Arpan Deyasi, RCCIIT DoS for Quantum Wire Introducing Pauli’s exclusion principle 2 k N π = 2 ( )N k k π ∂ = ∂
  • 25. 1/17/2021 25Arpan Deyasi, RCCIIT DoS for Quantum Wire From parabolic dispersion relation * 1 2 k m E E ∂ = ∂  N N k E k E ∂ ∂ ∂ = × ∂ ∂ ∂ * 2 1 2 N m E Eπ ∂ = × ∂ 
  • 26. 1/17/2021 26Arpan Deyasi, RCCIIT DoS for Quantum Wire 2 * 1N m E Eπ ∂   =   ∂   E ρ(E) E1 E2 E3 E4 E5
  • 27. 1/17/2021 27Arpan Deyasi, RCCIIT DoS for Quantum Dot E4E3E2E1 ρ(E) E E ρ(E) E1 E2 E3 E4