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Design of car wash waste water treatment plant using Electro- coagulation
1.
International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 09 Issue: 06 | Jun 2022 www.irjet.net p-ISSN: 2395-0072 © 2022, IRJET | Impact Factor value: 7.529 | ISO 9001:2008 Certified Journal | Page 2773 Design of car wash waste water treatment plant using Electro- coagulation Dwediya N C1 , M A chinnamma2 1Student, Department of Environmental Engineering, MCET, Desamangalam- 679532, Kerala, India 2 professor, Department of Environmental engineering, MCET, Desamangalam- 679532, Kerala, India ---------------------------------------------------------------------***--------------------------------------------------------------------- Abstract - Car wash industry consumes tidy sum of water for laundry of cars. Effluent water generated from car wash station contains great amount of chemical characters they contribute an honest deal of environmental contamination. The effluent water carries different parameters like pH, turbidity, Chemical oxygen demand, oil and grease, were characterized for the collected car washwater. Oiland grease, Chemical oxygen demand contributes to the majority of pollution. The pilot study result show that electro-coagulation has better removal efficiency of oil and grease, Chemical oxygen demand, turbidity, total solidsetc. Thetreatmentplant comprised screening, grit chamber, collection tank, electro- coagulation unit, tube settler, pressure sand filter and carbon filter. Supported treatment resultsthetreatedwatercanreuse for under wash of cars and other washing purposes like cleaning of floor of car wash station. Each operation units dimensions are calculated are, flow is 0.25m3/ hr and every one chambers are designed rectangular sections except filtration units. Key Words: Car wash waste water, Electro-coagulation, pH, oil and grease, COD, TSS, TDS 1. INTRODUCTION Urbanization has made the opportunity for increasing the growth of automobile industry. Therefore, usage of bikes, cars, and truck are increased, and also they led to growth of automobile service stations. Automobile servicestationsare washing (exterior and interior) of vehicle,serviceandrepair the vehicle parts. Based on survey of international car wash association around 100-200 liters of water is used for single car wash. That literally indicates that car wash industry consume large amountofwater.Aroundall carwashstations they contain a fresh water source for washing purpose. In future consumption of fresh water is led to water scarcity problem. The car wash effluent water contains hugeamount of contaminants like COD, TSS,TDS, turbidity pH , oil and grease etc. After washing of vehicle the effluent discharge in to near municipal sewers or water body which is decrease the water quality, harmfully effect onaquatic life.Soitisvery necessary to treat effluent water. The usage of water cannot be decreased, so it can be treating effluentwater,recycleand also reuse the treated water. The study introduced electro- coagulation (EC) technique for removal of all contaminants and emulsified oil and grease, AL used as electrodes in electro-coagulation process. The treatment plant consists screen, grit chamber, EC unit, tube settler, and filtration unit ( pressure sand filter and activated carbon filter). It’s very necessary that treatment plant use less chemicals for treat water, eco-friendly, and sustain for long period. The main objective of project removes all contaminants and reuse of treated water. 1.1 Car wash technology Car wash firstly started in 1914 at United Nations. It's also known as “automatic laundry”. A car wash is defined as non- domestic installation for external leaning of car for get more attractive and clean. In early days the cars were impelled manually through a tunnel, workers are dispensed soap, washed, rinsed and dried by manually using hands. After revolutions the new technology are amended on the car wash systems. In 1946 Thomas Simpsons brought semi- automatic car wash system and on period of 1950-60 Anderson brothers discover fully automatic car wash on the same period India is firstly implemented car wash technology. Other inventions are soft touch, non touch, and rinse less car wash 1.2 Electro-coagulation Electro-coagulation (EC) is an electrochemical process that simultaneously removes heavy metals, suspended solids, emulsified organics and many other contaminants from water and wastewater using electricity instead of expensive chemical reagents. EC is a technique used for waste water treatment, wash water treatment and medical treatment. Although the electro-coagulation mechanisms resemble chemical coagulation in that the cationic species are responsible for neutralization of surface charges. The produced flocks will tend to contain less bound water and more shear resistant, so it can more readily filterable. EC unit contain electrolytic cell, each with the pair of corrosive metal sheets (anode and cathode) these electrodes made up of aluminum or iron which can be organized, arrangements spacing and lengths, which depend upon removal efficiency. Anode continuously produce ions and need to be replaced, which are often called sacrificial anode, the plates are connected extremely a power source and immersed in the waste water, which supply electron current that drives chemical reaction at the electrode. The voltage needed for
2.
International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 09 Issue: 06 | Jun 2022 www.irjet.net p-ISSN: 2395-0072 © 2022, IRJET | Impact Factor value: 7.529 | ISO 9001:2008 Certified Journal | Page 2774 reaction occurs is called potential. Electric DC current cause various reactions, which facilitates dissolution, coagulation, flotation, flocculation, in EC source coagulation is cations produced by degradation of anode metal and activation energy applied, which promotes formation of oxides. The process described below Anode : Al= Al+3e (metal=metal+electron) Cathode : 2H2O+2e H+2OH- In electro-coagulation process pH important factor so pH should maintained 4.8 to 8. Caustic soda used for maintain pH and sodium chloride is used for increasing conductivity. Fig-1: Electro-coagulation process 2. METHODOLOGY Since the car wash industry discharge highly contaminated water so it's a necessity to seek out the parameters for remove them by suitable method and reuse the treated water for laundry purposes (under wash of auto and floor cleaning) Steps are administered procedure withinthe projectisgiven below: •Sample collection • Parameter analysis (pilot study) • Design treatment plant 2.1 Sample collection Car wash effluent water sample were collected from urban car wash station located at kadavantra. Waste water generated by washing of different cars. After washing the effluent water directly drained to municipal sewage treatment unit . The effluent water collected in a 1 liter plastic bottle. Fig-2: Car wash waste water 2.2 Parameter analysis The effluent sample collected and analyzed various parameters like BOD, COD, pH, TSS, TDS, dissolved oxygen, turbidity etc. well water is used as influent for washing of cars. The analysis values are shown below Table–1: Parameter analysis of car wash water Sl.No Parameters Influent water Effluent value 1 BOD (mg/l) 4 136 2 COD (mg/l) 88.2 392.41 3 TSS (mg/l) 0 68 4 TDS (mg/l) 140 314 5 pH 6.53 8.63 6 Turbidity (NTU) 0 98.5 7 Dissolved oxygen (mg/l) 4 3.17 8 Total solids(mg/l) 100 382 9 Oil and grease (mg/l) 0 164 2.3 Experimental set up Electro-Coagulation (EC) method is used for treating car wash waste water. EC reactor size of 0.75 m x 0.7 m x 1.5 m has been used. The reactor is made up of marine plywood with leakage proof. Aluminum used as electrodes (anode & cathode) with size 40 cm x 35 cm x 0.1 cm, and electrodes are places 1 cm spacing. The pH of effluent sample was maintained between 4.9 – 8.1inECreactor.DCpowersupply provided through a rectifier and voltage maintained by variac. The experimental set-up shows below.
3.
International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 09 Issue: 06 | Jun 2022 www.irjet.net p-ISSN: 2395-0072 © 2022, IRJET | Impact Factor value: 7.529 | ISO 9001:2008 Certified Journal | Page 2775 Fig-3: Experimental set-up 2.4 Design of treatment plant The treatment plant encompass different operations such as Screening Grit chamber Electro-Coagulation unit Tube settler Filtration (pressure sand and activated carbon) The designing of all unit operations are done separately. As per data collected from urban car wash center using 3000 liters of water (from well) used for car wash and 500 liters water used for complete cleaning of car wash station. So total water usage is 3500 liters. According to KPCB consideration 80 % of total consumed water converted in to effluent water, so 2800 liter waste water produced in a car wash industry and 5% safety factor is provided. Therefore the capacity of treatment plantis3KLD.Total workinghours taken as 12 hours. Then flow rate 0.25 m3/hrs. 100 L water consumed for single car wash. Assume depth by width ratio of rectangular sections is 1.5, and also all comprised unitsarerectangularinsection except filtration units they ate circular in section. The design begins with collection tank, Volume = 0.25 x 4 (retention period) = 1 m3 As assume breadth as 0.951m then depth is 1.426m so the length is 0.724 m. 0.951 m 1.426m 0.724 m Fig-4: Collection tank Screens are placed 60 degree inclination for retain large particles easily. Manually cleaned screens are used. Assume Surface over flow rate (SOR) as 2 m3/ hr m. Flow rate 0.25 m3/hr Area of screen = flow rate / SOR = 0.5 m2 Assume rectangular section Depth /width ratio is 1.5 Depth of channel = 1.5wxw {D/W=1.5) {area = 0.5} Width of channel = 0.57 = 0.6 and Depth = 0.833 = 0.85 Length of channel = d x (Vh / Vs) assuming Vh and Vs 0.6 m/sec and 0.45 m/sec Vs = settling velocity , Vh = horizontal velocity = 0.85 x (0.6 /0.45) = 1.133 m = 1.5 m Assuming opening 3 cm wide and 1 cm thickness Area of screen As = Area of channel / sin θ = 0.5 / sin (50) , as θ is the inclination of channel it mostly taken 50 degree = 0.653 m2 Net area ( Anet) = As X S / (S+tbar) = 0.653 x ( 3 / (3 + 1) = 0.49 m2 From continuity equation Va x Ac = Vb x Anet Va = approach velocity
4.
International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 09 Issue: 06 | Jun 2022 www.irjet.net p-ISSN: 2395-0072 © 2022, IRJET | Impact Factor value: 7.529 | ISO 9001:2008 Certified Journal | Page 2776 Vb = peak velocity or basin velocity Vb = Va x Ac / Anet = 0.6 x0.5 / 0.49 = 0.612 m/ sec Check: peak velocity of screen should be less than 0.9 m/ sec, Here 0.612 < 0.9 m/ sec so it’s ok Head loss (HL) = Vb2-Va2 / 2 g C C = Normal flow through a screen taken as 0.7 HL = 0.6122-0.62 / 2 x 9.81 x 0.7 = 0.001 m Assume 55 % clogged on screen Net area = 0.55 x 0.49 = 0.269m2 Vb = 0.6 X0.5/ 0.269 = 1.11 m/sec HL = 1.112-0.62/ 2 x 9.81 x0.7 = 0.063m The number of bars screen = ntbar + (n-1) S = w -2 N = 14.75 = 15 nos Dimension of bar screen 1.5 m x 0.85 m x 0.6 m =0.765m3 approximately 1 m3 with 15 bars with opening 3 cm and 1 cm having head loss 0.001 m with slope 60 degree. Next unit operation is grit chamber they are mainly used to remove small particles like grit. Flow rate = 0.25m3/ hr and SOR = 2 m3/hr/m Area = 0.521 m2 Length of channel = d / (Vh x Vs) = 13.26 m A weir provided in grit chamber for control water flow. Y = Q / (Vh /W) Y = total weir length = 0.1 / (0.3 x 0.580) = 0.574 m Depth of weir (mm) = y = (2/3.1) x Y = 0.383 mm The weir must be shaped so that Q = 8.18 x 10-6 x w x y 1.5 Weir width w =51.576 m Head loss = 36% x depth of channel = 0.36 x 0.884 = 0.318m = 0.3m Inlet allowance 30% Dimension of grit chamber 13.26 m x0.589mx0.884mwith free board 0.25 = 7.154 m3 weir width 51.576 m having head loss 0.3 m After grit removal the effluent water led to move EC chamber, so design of chamber given below, Flow rate =0.25 m3 / hr Retention time = 0.5 hrs Volume of EC units = 0.125 m3 Area of EC = flow rate / SOR = 0.25m3/hr / 2 hr m = 0.521 m2 Provide depth = 1.5m width = 0.7 m length = 0.75 m EC unit divided in to 6 chambers diving by FRP sheets of 3 mm thickness. 0.7m 1.5 m Al electrode 0.75 m Aluminum is used as electrode and assume the dimensions are Length =40 cm =0.40 m, breadth = 35 cm = 0.35m thickness = 0.1 cm = 0.01 m After EC operation generated sludge allows for settling for that they were led to flow in to tube settler. Sutro-weir provided inside tube settler to convert sludge particles transition flow to laminar flow for easy settling of particles and for boosting settling process added polymer with 0.035 gm. Design of tube settler described below,
5.
International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 09 Issue: 06 | Jun 2022 www.irjet.net p-ISSN: 2395-0072 © 2022, IRJET | Impact Factor value: 7.529 | ISO 9001:2008 Certified Journal | Page 2777 Flow rate = 0.25 m3/ hr Relative length of settler = l / d Assume l = 1m and d = 0.05m Relative length = 1 / 0.05 = 20m L’ = 0.058 x (Vo / υ) x d = 0.058 x (Vo x 0.05 / 1.01 x 10-6) = 2.87 x 103Vo m / sec = 0.0332 Vo m/ day Effective length = (l/d) – L’ Sc = (Vs / Vo) x (sinθ – cosθ) For rectangular section critical value = 11/8 and assuming settling velocity 120 m/day. 11/8 = (120/Vo) x ( sin (60-(20 – 0.333 Vo)- cos ( 60 ) X (10+0.0165)) Solving above Equation for find Vo Vo = 388.6 m / day Total entrance area of tube = Q/Vo = 2.893 x 10-6 / 4.497 x 10-6 = 0.6433 m2 Assume d/w = 1.5 D = 0.982m and w = 0.654m Volume 0.25 x 4 hrs (detention period) =1 m 3 Length of tube settler = 1.58 m Dimension of tube settler = 1.58 m x 0.654m x 0.982m They bottom provide 60 degree ground inclination After settling the water led to flow in to pressure sand filter and activated carbon filter. They are in circular in section and the dimensions are; Flow rate = 0.25 m3 / hr Retention time = 2 hrs Volume = 0.25 m3/ hr x 2 hrs = 0.5 m3 Area = 2 π r h Height (h) = 0.976 = 1 m Radius ( r) =0.082 m = taken 0.4 m Diameter (d) = 0.2 m Dimension of filters = 0.2 m diameter x 1m height Table–2: Properties of filter units After complete treatmenttreatedwatercollectedina treated water tank which designed as; Flow rate = 0.25 m3 / hrs Retention time = 4 hrs volume V = 0.25 x 4 = 1 m3 Area = flow rate / SOR = 0.512 m2 Depth/ width ratio = 1.5 then width = 0.6m depth = 0.85m length = 1.95m Dimension of treated water tank =2 m x 0.6m x 0.85m specification Pressure sand filter Activated carbon filer Flow rate 0.25 m /hrs 0.25 m /hrs Filtration rate ( assume) 15 m3/ hr m2 13 m3/ hr m2 Height of straight provide ( standard) 1.65 m 1.65m Volume ( standard) 20 m 20 m Diameter 4 m 4m Media Sand and gravel Activated carbon with IV>900
6.
International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 09 Issue: 06 | Jun 2022 www.irjet.net p-ISSN: 2395-0072 © 2022, IRJET | Impact Factor value: 7.529 | ISO 9001:2008 Certified Journal | Page 2778 2.5 Estimation The treatment plant is made up of concrete and steel. Final estimate include fixed cost and running cost of the system. 20 bags of cement, 1.5 tone sand and 0.20 tone gravels are used. The estimate values shows below ; Table–3: Total cost of unit operations Items Volume cost Total cost Bar screen 1m3 15,000 15,000 Grit chamber 7.152m3 15,000 1,07,280 E C unit 0.787 ( 30 units) 20,000 6,00,000 Tube settler 1.5 25,000 37,500 Pressure sand filter 20 (4mdia &1.65 height ) 2500 50,000 Activated carbon filter 20 (4m dia & 1.65m height) 4000 80,000 Collection tank 3 15000 45,000 Treated water tank 1 m3 15,000 15,000 Filter tank 0.5 m3 20,000 10,000 Dosage of pump = 10 ( 5 stand by) { 0.25 hp consumption with 4 hrs} E C unit = 0.5 Hp ( for 20 hrs = 10 hp) Pressure sand filter = 16 Hp Total Hp = 27 HP Rate of 1 unit current =8 /- Cost of current per day =27 x 8 =216/- Per month =6480 /- For an year current consumption cost = 77,760 /- The electrode charges are; Cost of aluminum = 400 / kg Consumption of electrode =I X T X M / (F X N ) x V I = current T = time uses M = molar mass Al F = faradays constant (96485.3329) N = no of electrons in oxidation process V = volume Consumption = 60 x (24x60x60) x 26.89 / ( 96485.3329 x 3 x 30) = 0.0034 kg /m3 Per month = 0.0034 x 30 = 0.102 kg / m3 In case of Al =0.102 x 400 =40.8/- = 41/- Per month = 41 x30 =1230/- 4 electrode used with 14 sets total =56 Total cost = 56 x 1230 = 68,880/- Chemical consumption cost Consumption of caustic soda 0.03-0.035 g/ L Assuming the cost of caustic soda =32 /- (day) For month = 32 x30 = 960/- Chemical consumption cost for an year= 11,520 /- Labor charge for a year = 5,56,000 / year Sludge disposal cost for a n year= 15,000/- Generator (stand by) = 85,000/- Total cost of treatment plant is 25,5,0940 /- 3. RESULT AND DISCUSSION Electro-Coagulation (EC) is most efficient method for removal of contaminants and oil and grease. Firstly car wash effluent water shows alkaline character after treatment that became neutral character. Car wash water shows high oil and grease after treatment that removed 93.54% COD, turbidity and TSS are highly present in car wash effluent water. later treatment process they removed more than 70% The variation of effluent water before and after EC process shows below table and graphical representation; Table–4: Parameters before and after treatment SLno Parameter Car wash water{m g/l} After electro coagulation Percentage of removal efficiency 1 BOD 136 30.23 77.772 % 2 COD 392.41 90.12 77.34% 3 Dissolved oxygen 3.17 8.1 60.86 % back to water
7.
International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 09 Issue: 06 | Jun 2022 www.irjet.net p-ISSN: 2395-0072 © 2022, IRJET | Impact Factor value: 7.529 | ISO 9001:2008 Certified Journal | Page 2779 4 pH 8.63 7.2 - 5 Oil and grease 164 10.59 93.54% 6 Total solids 382 90 76.439 % 7 TDS 314 62 80.25 % 8 turbidity 98.5NTU 10 89.84% 9 TSS 68 2 95 % Chart -1: Before and after treatment of effluent water The table 4 and chart 1 shows effluent water parameter variation before and after treatment process and alsoshows the percentage of removal efficiency of EC. The result shows that most of the contaminants are removed through EC process and the water quality become normal so it can be used for reuse or back washing. Although EC is removes pathogens so the treated water can be used for gardening process. Comparatively EC is one of the method eco-friendly and less usage of chemicals. 4. CONCLUSIONS Water demand increases day by day so the quality and quantity became diminish tidy sum rate. In car washing station reuse and recycle of water is a sustainable solution for water scarcity problem and urban water demand. This project reveals that EC contain AL electrode is the most effective method for removes contaminants in car wash water. EC is simple and eco-friendly method, cost effective method compared to other recycle method. It need less human power and chemicalsfortreatingeffluentwater.ECis integrated technology provide clean and less space. Analyze overall result EC provide more than 75% removal efficiency. So the treated water can reuse with eco-friendly. The sludge produced after treatment can be disposedineco- friendly .because they contain less harmful substance rather than its applicable limit. After analysis final result more than 75% of water can be recycle and reuse they reduce water pollution and environmental pollution. REFERENCES [1] Jamil Ahamad (2017) “Design of car wash waste water treatment process for local station” Pakistan journal deals the design of treatment process in a local station. The treatment process comprised coagulation, sedimentation and filtration unit (sand & gravel). Journal of Pakistan institute of chemical engineers. [2] Sowmya s , Revathi M C (2021) “Treatment of car wash water using electro coagulation, chemical andbiological process” A comparative study of car wash water using biological process and electro coagulation using combo of cu and AL electrode. International journal of creative research thoughts, vol 09 issue 06 [3] S Nimal, Abdul akbar shanaz fathima (2018) “Recycling automobile station wash water Chennai” international journal of civil engineering and technology,vol 9,issue4 [4] Neerja sree and varsha asokan (2019) “ treatment of automobile using plant based coagulants” international research journal of engineering and technology, vol 06, issue 06
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