Critical frequency is the maximum frequency that can be reflected by a layer of the ionosphere at vertical incidence. It is different for different ionosphere layers and is proportional to the square root of the maximum electron density in that layer. The critical frequency changes throughout the day and due to atmospheric conditions, making higher frequencies better during the day and lower frequencies better at night. Given the maximum electron density, the critical frequency can be calculated using the formula: fc = 9√Nm, where fc is the critical frequency in MHz and Nm is the maximum electron density in electrons per cubic meter.