The Complete Organic Chemistry Worksheet
The Complete Organic Chemistry Worksheet.doc
Name
1. Name the following hydrocarbons.
3 j'- d m.u q'Lxc.$'s
i"'a.CH3-CH2-CH-CH-CH.
I
CHz
I
CHr
CHr
A A -k ,e*qt^'-tt i"' f"l-'"'-lu*",Uo..q b cur-f-is-a",
ll
"'
cH:
?"
3 a-O,trtrc$nt1t
c' cHl-C-CH3
b*fa^q- lt'CH:
. A CH7-CH2-CHJ
4 ,3
- /.eltrt1Ii'*-lt'asq,n,-"r',-J
'cH2-cH3
cH2-cH3
2. Name the following hydrocarbons.
J ^thl[r,k*
CHr
t"a.CH3CH2CH2CHCH3
9H,
I
b.CH3CHCH2CH3
CHI
I
c.CH3CHCHCH3
I
CH2CH3
d'n*{l'1lltnk, t
CHr
t-
CH: 9n'
tte. CHr-CH-CH-CH-CHl
I
CH:
CHr
I
?"' !t'f. CH3-CH2-CH-CH-CH
CHr
CH:
I
CH2
I
g. CH3-CH-CH-CHr
is-cHr-cH,
I
CH:
CHz-CHr
I
h. cH3-cH-cH-cH3
I
c+r3-cH-cH3
d.CHICHzCHCHzCH:
I
CHz
I
CH:
g'ulktlfe J-o'"L
'l.3')'ont'lr,,lyW
3'ml{f ynh'^t
f"' fn' ) u (A nolfu''{ ttu'*u*'Qe.CH3CHCH2CHCH3 cJ 1{
,. .,.[X1".","", a,, - &*]f'f gw-fu{"{
cI{3
A,r'd.'*uf $'
tf W^u*g.CH3CHCH2CH3
I
cH,
l'CH:
?',CH"
l'
h. cH3cHcHCH3
CH;
f, ,3,
q - c' *"jtr1-s.x^t'"*-
j - A.^ r.alh-{hq"{n-"*
3 ;1,
Ll
-.lr iu .t"1ihqaru-
Z, 1, q * ,,0'ah.1F *+ra*r's
vr*
J, q -di r'Ctt P-*,,i::",i::",
Listed below are the condensed structural formulas or names of the nine isomers of heptane, CzHre. Write the formula and
name for each.
a (a[ru
a. CH: CHzCHz CHzCHzCHzCHz
?t' .r- *nlrh*.u(4rt0tCHTCHzCHCHzCHzCHT ) tr re 
ag-d,r"}*tPM*
'"'[|L'"**
i 3-ethvlpentane
f-"-.f
*
Name (use common and systematic for benzene if appropriate; ttre compourFrepresented by the following formulas.
CH: CHI
J,*3, {r,r"ethq
".
.",1-8r.r,
h. 2-methylhexane t)-------r"-k^J.'{-
I
CH:
a. 3-heptyne
cyclopentene
clpheny l-2,2-dimethylhexane
) af
,,r-O*.,*)#@
/-'-/
1 -ethyl-2-methylbezene
,,{r-tx
H,2,4-dimethy l-2-pentene
rlM
6. Listed below are the condensed structural formulas or the names for the eight isomers of C5H11Cl.Write either formula and the
name for each.
,/
'1'l "*-'f:1:P''
:'1e'5 '';
a. CH3CH2CH2CH2CH2CI
CHrifil
. ttr fli,- . !:r'"V'1
b. CH3CHCH2CH2CI ';_;1a$;q.g
Fr
'  c.2-chloropentane
io;;f
d. 2-chloro-2-methylbutane
7. Name the following compounds.
CI
I
e. CH3CH2CHCH2CH3
?", :- 1 i, ,r , ij "r - 1 , c.,1 -
I
a. CHTCHTCCHTCHTBT o i. .., f . lx !*- -l f. i
CHr
t-CHr
j -crt'c,-'b [.,];
si ";
CHI CI
i--' i--^.- 6 -e ''c"n '3-rru'*L?h '''is^rp
CH3CH-CHCH3
l-chloro-2-methylbutane --.-*){
l'---i-
* -I -chloro-2, 2-dimethylpr"?ri_,-X:
CHr
i--1 r - rro*h'{ * }' -
P'tx'':k*eh. CHTCHCH:CHCH:
CH. CH"
' ^'' I
-
l^:' ^" ! 't' -d t {-' .'}ri
"*" Pa^nffrti.CH3C:CCH2CH3
t_.-t,. .-" ".
r
j
'{ .nn/
{t
i
f.
g.
h.
. ^rr ^,,i1,,
+r-qN)n1- 1,{-par{adt**'0,.^..
il, i" ^-- ) , A...ah.i - ,'4 - prr*&re:e'*
5. CHr:CHCHCH-CH, t'CHr-QQgzC-gy1rc',-' ur'
CHr
I
c' CHI-CHCCH3
I
CH:
I O..l 2-methylnaptJralene
!; ir'd,i,*s''ia - 1-bu'knc
!', f",k.cHr-c-c-cH-CHCH3
cHr
rBr
j,3 ,'i-lr'n'r),hql - 1, t -
h''wa.15 l{,u
d.
e.
c6H5cl akot dCli', }l'r)
CH:CH:CHCH2CH3
CHr
I
f. CH3C:CHCH3
g. CH3CH2CH=CH2
Draw structural formulas for the following.
a. 3-heptene
8.
trichloromethane n Ftf
.1't li
d. 2-chloro-3-phenylhexane
^
,^_,_. .,..
-" -Y
e. 1,3-cyclopentadiene
{i1 
_-
L)toluene (methy lbenzene)
g. 1,4-dibromobenzene
tlt :...tls,
h. 2-bromo-3-methyl-2-butene
tJ, i
.'.rt
rite structural formulas for the following compounds.
2-chlorobutane
c.r

/=-'-/
2-butene
//v2-ethyl-3-methy l- I -butanol
t
.-,,^--..-rlo _

3,3-dimethy lbutanoic ucid
/ tl
-4-=4ot-{
2,5,5 -trimethy l-4-hepto-ne
ro
#1,8-nonadiyne
w
L.
Y
J-
g. 1.3-diiodobenzenef
&h. ethoxybenzene
",^-oYt'
i. l-butanol
---^_./--OF+
j. 3-methyl-2-pentene
n. 2-ohenvlbutane L
o
{
o.
)
7-bromo-2-naphthol
r.-, '/
p. 4-bromobenzoic acid
3 -ethyl-2,4-dimethyl-3 -hexanol
5 -chloro-3 -ethyl-2:methy
10. Name the following organic compounds.
i, , I 
,3'r. li-1 l- a.cHrcH-cHCH,cHl
,;p,"'^Janol
-J",
J"to
b. cH3cH28cHcH3
d. CHTCHTCHCHTCHT-l
CI
d. cH,cH.cH"c/ :l-^Inr n!*.
H
?n,
e. cH3cCH2cH2cH2oH d,J - Ah;lvt- 1 y^,hrt'"?.
CHr
rrt ru ,#'{iyi- V-y:e4 $e.rur,q J", ?''
r. cH2:6slg11-cHCH3
5-ftU.jf,,rf * ,q - tW*$,Un* -'1-
""q-OH
c. CH3CHCH-Q!{2
3 n'ofYr* -:L - b"j"r*
11. Name the following organic compounds.
a. CH.CH"CHCH"CI
 -Ch{oo -X -nutt- q I
-1",
L,^)+rl.Q i"tb. CHTC-CHCH,BT
J-$q,rr'r-d 4,j-.krrnxlhq i 1", J",
bula$L
CHr
.. cH,EcLcr, 2.- rnolhq*a *b{r-qrrs'
"l
OH
r. cH3cH2!:cHCH3 !-h *,t**0 - qurnefil-
Br
". A s. ,rmnO*tp':?roflr*.
g. CH3(CH2)2CH2NH2 buJqAfr",rfS.
h.H,N-[-cH2cH3
p/Wcr((^&-[-
c. C5H16
Cl, - Cu. -K -- Ctr - c L{
35d
pj{.,.k {.,0*
t
*!j
f g!.ogl"'r"le*'u
rr1pflt6r,ywill*xr d-pt',pr','*r'a
3- ci".*,crPn'e"na
12.Each ofthe following formulas can be written as two compounds with dif[erent functional groups. Write the structural
formulas, name the compounds, and identify the functional groups.
c]r'C,ilr - c,f+
MaryTL P^cff
rbl
a. CzHoO
eu"-al^-0F- 5 *"d
b. C:HoO
0
ll
a
[
nu^- t-LH.v"5 -)cHr- o -cll3
b. 2-butargne
-/
2-methyl-2-propanol
>{ethanoic acid
o
Aon
trimethanamine
C+:
*i
N tto3
propane
2-pentyne
"'{//'
cyclohexanamine
i(0u*
V2-aminopentane
$a
13. Draw structural formulas for the following.
a. Ethanal O
// -l{
h. cyc
lc 2,4-nitrophenol
Otl
n. propenoic acid
lobutane
rl
'Anou
14. Draw and name the five structural isomers of hexane (CoFir+)
Q nilhllyntiarn
'/o'
cH2cH2cll
J,b)5--|r,ur ddrl  -
8-dt1dscq,.rI
cx{3
-c -cHI
cH3
o,
2cH2CHCH2CH
I
cH2cH3
CH;
b.
3, 5 - A^d.aj - 3 - 'aqRl'*
3- r'nqrh1 h-ue'"o
17. Name each of the following alkenes.
a.
CH, :611
-(]12 -CH3-4.+-
L- buJ'[fa
cll3
c. I
I
cH3cH2cH-cFI-CH-Cr{
/"r
o,

'3l'nCf'qlk $qj.tq

 ./ -J,Q - d''
^.tJ
[t I
)<----/ D',ier
i. orlanq
15. Draw the structural formula for each of the following.
a. 2-Methylpentane
,
-/A------//^-
16. Name each of the following:
a.
CHT CH:
llcH
-c -cH2cH2cH3
ttbH, cH:
),i,3- rr m'dh'1 htxaru
C H3---{H2--{H2-C H
-C Hj
I
clI2_cHj
b. 2,2,4-Tnmethylpentane, also called isooctane. This compound is the reference for octane ratings for gasoline.
,/ 
X- -/---
-/--
c. 2-tert-Butylpentane
d. The name given in part c is incorrect. Give the correct name for this hydrocarbon.
0 ,
!, i - -h taru"I'h'1 ha"v.c$-tl-
18. Give the structure for each of the following:
a. 3-hexene
b. 2,4-Heptadiene
c. 2-Methyl-3-octene

z
19. Give the structure for each ofthe following aromatic hydrocarbons.
a.
/nnvuar","
I -/';'E
Cr-a' f-oi-tert-burvlbenzene
&
c. f-oi"tttrtu.
)nzene
Cl,
d. r_phenyr-2-buten"
e,-=_Z
20, Name each of the following:
a.
ct
-cHz -cHz -cFI -CH3
I
tl
 1i -aicNctobuJ€doo
b' cl{3cll2cr-I2trI3 , ,  - t ic,tfo-cobt"faxlt
c
;)*-f-{"*"
3,i -dd$c', - !,{-d}rRah-'oxo.ra-

Complete organic chemistry worksheet answers

  • 1.
    The Complete OrganicChemistry Worksheet The Complete Organic Chemistry Worksheet.doc Name 1. Name the following hydrocarbons. 3 j'- d m.u q'Lxc.$'s i"'a.CH3-CH2-CH-CH-CH. I CHz I CHr CHr A A -k ,e*qt^'-tt i"' f"l-'"'-lu*",Uo..q b cur-f-is-a", ll "' cH: ?" 3 a-O,trtrc$nt1t c' cHl-C-CH3 b*fa^q- lt'CH: . A CH7-CH2-CHJ 4 ,3 - /.eltrt1Ii'*-lt'asq,n,-"r',-J 'cH2-cH3 cH2-cH3 2. Name the following hydrocarbons. J ^thl[r,k* CHr t"a.CH3CH2CH2CHCH3 9H, I b.CH3CHCH2CH3 CHI I c.CH3CHCHCH3 I CH2CH3 d'n*{l'1lltnk, t CHr t- CH: 9n' tte. CHr-CH-CH-CH-CHl I CH: CHr I ?"' !t'f. CH3-CH2-CH-CH-CH CHr CH: I CH2 I g. CH3-CH-CH-CHr is-cHr-cH, I CH: CHz-CHr I h. cH3-cH-cH-cH3 I c+r3-cH-cH3 d.CHICHzCHCHzCH: I CHz I CH: g'ulktlfe J-o'"L 'l.3')'ont'lr,,lyW 3'ml{f ynh'^t f"' fn' ) u (A nolfu''{ ttu'*u*'Qe.CH3CHCH2CHCH3 cJ 1{ ,. .,.[X1".","", a,, - &*]f'f gw-fu{"{ cI{3 A,r'd.'*uf $' tf W^u*g.CH3CHCH2CH3 I cH, l'CH: ?',CH" l' h. cH3cHcHCH3 CH; f, ,3, q - c' *"jtr1-s.x^t'"*- j - A.^ r.alh-{hq"{n-"* 3 ;1, Ll -.lr iu .t"1ihqaru- Z, 1, q * ,,0'ah.1F *+ra*r's
  • 2.
    vr* J, q -dir'Ctt P-*,,i::",i::", Listed below are the condensed structural formulas or names of the nine isomers of heptane, CzHre. Write the formula and name for each. a (a[ru a. CH: CHzCHz CHzCHzCHzCHz ?t' .r- *nlrh*.u(4rt0tCHTCHzCHCHzCHzCHT ) tr re ag-d,r"}*tPM* '"'[|L'"** i 3-ethvlpentane f-"-.f * Name (use common and systematic for benzene if appropriate; ttre compourFrepresented by the following formulas. CH: CHI J,*3, {r,r"ethq ". .",1-8r.r, h. 2-methylhexane t)-------r"-k^J.'{- I CH: a. 3-heptyne cyclopentene clpheny l-2,2-dimethylhexane ) af ,,r-O*.,*)#@ /-'-/ 1 -ethyl-2-methylbezene ,,{r-tx H,2,4-dimethy l-2-pentene rlM
  • 3.
    6. Listed beloware the condensed structural formulas or the names for the eight isomers of C5H11Cl.Write either formula and the name for each. ,/ '1'l "*-'f:1:P'' :'1e'5 ''; a. CH3CH2CH2CH2CH2CI CHrifil . ttr fli,- . !:r'"V'1 b. CH3CHCH2CH2CI ';_;1a$;q.g Fr ' c.2-chloropentane io;;f d. 2-chloro-2-methylbutane 7. Name the following compounds. CI I e. CH3CH2CHCH2CH3 ?", :- 1 i, ,r , ij "r - 1 , c.,1 - I a. CHTCHTCCHTCHTBT o i. .., f . lx !*- -l f. i CHr t-CHr j -crt'c,-'b [.,]; si "; CHI CI i--' i--^.- 6 -e ''c"n '3-rru'*L?h '''is^rp CH3CH-CHCH3 l-chloro-2-methylbutane --.-*){ l'---i- * -I -chloro-2, 2-dimethylpr"?ri_,-X: CHr i--1 r - rro*h'{ * }' - P'tx'':k*eh. CHTCHCH:CHCH: CH. CH" ' ^'' I - l^:' ^" ! 't' -d t {-' .'}ri "*" Pa^nffrti.CH3C:CCH2CH3 t_.-t,. .-" ". r j '{ .nn/ {t i f. g. h. . ^rr ^,,i1,, +r-qN)n1- 1,{-par{adt**'0,.^.. il, i" ^-- ) , A...ah.i - ,'4 - prr*&re:e'* 5. CHr:CHCHCH-CH, t'CHr-QQgzC-gy1rc',-' ur' CHr I c' CHI-CHCCH3 I CH: I O..l 2-methylnaptJralene !; ir'd,i,*s''ia - 1-bu'knc !', f",k.cHr-c-c-cH-CHCH3 cHr rBr j,3 ,'i-lr'n'r),hql - 1, t - h''wa.15 l{,u d. e. c6H5cl akot dCli', }l'r) CH:CH:CHCH2CH3 CHr I f. CH3C:CHCH3 g. CH3CH2CH=CH2 Draw structural formulas for the following. a. 3-heptene 8. trichloromethane n Ftf .1't li d. 2-chloro-3-phenylhexane ^ ,^_,_. .,.. -" -Y e. 1,3-cyclopentadiene {i1 _- L)toluene (methy lbenzene) g. 1,4-dibromobenzene tlt :...tls, h. 2-bromo-3-methyl-2-butene tJ, i .'.rt
  • 4.
    rite structural formulasfor the following compounds. 2-chlorobutane c.r /=-'-/ 2-butene //v2-ethyl-3-methy l- I -butanol t .-,,^--..-rlo _ 3,3-dimethy lbutanoic ucid / tl -4-=4ot-{ 2,5,5 -trimethy l-4-hepto-ne ro #1,8-nonadiyne w L. Y J- g. 1.3-diiodobenzenef &h. ethoxybenzene ",^-oYt' i. l-butanol ---^_./--OF+ j. 3-methyl-2-pentene n. 2-ohenvlbutane L o { o. ) 7-bromo-2-naphthol r.-, '/ p. 4-bromobenzoic acid 3 -ethyl-2,4-dimethyl-3 -hexanol 5 -chloro-3 -ethyl-2:methy
  • 5.
    10. Name thefollowing organic compounds. i, , I ,3'r. li-1 l- a.cHrcH-cHCH,cHl ,;p,"'^Janol -J", J"to b. cH3cH28cHcH3 d. CHTCHTCHCHTCHT-l CI d. cH,cH.cH"c/ :l-^Inr n!*. H ?n, e. cH3cCH2cH2cH2oH d,J - Ah;lvt- 1 y^,hrt'"?. CHr rrt ru ,#'{iyi- V-y:e4 $e.rur,q J", ?'' r. cH2:6slg11-cHCH3 5-ftU.jf,,rf * ,q - tW*$,Un* -'1- ""q-OH c. CH3CHCH-Q!{2 3 n'ofYr* -:L - b"j"r* 11. Name the following organic compounds. a. CH.CH"CHCH"CI -Ch{oo -X -nutt- q I -1", L,^)+rl.Q i"tb. CHTC-CHCH,BT J-$q,rr'r-d 4,j-.krrnxlhq i 1", J", bula$L CHr .. cH,EcLcr, 2.- rnolhq*a *b{r-qrrs' "l OH r. cH3cH2!:cHCH3 !-h *,t**0 - qurnefil- Br ". A s. ,rmnO*tp':?roflr*. g. CH3(CH2)2CH2NH2 buJqAfr",rfS. h.H,N-[-cH2cH3 p/Wcr((^&-[- c. C5H16 Cl, - Cu. -K -- Ctr - c L{ 35d pj{.,.k {.,0* t *!j f g!.ogl"'r"le*'u rr1pflt6r,ywill*xr d-pt',pr','*r'a 3- ci".*,crPn'e"na 12.Each ofthe following formulas can be written as two compounds with dif[erent functional groups. Write the structural formulas, name the compounds, and identify the functional groups. c]r'C,ilr - c,f+ MaryTL P^cff rbl a. CzHoO eu"-al^-0F- 5 *"d b. C:HoO 0 ll a [ nu^- t-LH.v"5 -)cHr- o -cll3
  • 6.
    b. 2-butargne -/ 2-methyl-2-propanol >{ethanoic acid o Aon trimethanamine C+: *i Ntto3 propane 2-pentyne "'{//' cyclohexanamine i(0u* V2-aminopentane $a 13. Draw structural formulas for the following. a. Ethanal O // -l{ h. cyc lc 2,4-nitrophenol Otl n. propenoic acid lobutane rl 'Anou
  • 7.
    14. Draw andname the five structural isomers of hexane (CoFir+) Q nilhllyntiarn '/o' cH2cH2cll J,b)5--|r,ur ddrl - 8-dt1dscq,.rI cx{3 -c -cHI cH3 o, 2cH2CHCH2CH I cH2cH3 CH; b. 3, 5 - A^d.aj - 3 - 'aqRl'* 3- r'nqrh1 h-ue'"o 17. Name each of the following alkenes. a. CH, :611 -(]12 -CH3-4.+- L- buJ'[fa cll3 c. I I cH3cH2cH-cFI-CH-Cr{ /"r o, '3l'nCf'qlk $qj.tq ./ -J,Q - d'' ^.tJ [t I )<----/ D',ier i. orlanq 15. Draw the structural formula for each of the following. a. 2-Methylpentane , -/A------//^- 16. Name each of the following: a. CHT CH: llcH -c -cH2cH2cH3 ttbH, cH: ),i,3- rr m'dh'1 htxaru C H3---{H2--{H2-C H -C Hj I clI2_cHj b. 2,2,4-Tnmethylpentane, also called isooctane. This compound is the reference for octane ratings for gasoline. ,/ X- -/--- -/-- c. 2-tert-Butylpentane d. The name given in part c is incorrect. Give the correct name for this hydrocarbon. 0 , !, i - -h taru"I'h'1 ha"v.c$-tl-
  • 8.
    18. Give thestructure for each of the following: a. 3-hexene b. 2,4-Heptadiene c. 2-Methyl-3-octene z 19. Give the structure for each ofthe following aromatic hydrocarbons. a. /nnvuar"," I -/';'E Cr-a' f-oi-tert-burvlbenzene & c. f-oi"tttrtu. )nzene Cl, d. r_phenyr-2-buten" e,-=_Z 20, Name each of the following: a. ct -cHz -cHz -cFI -CH3 I tl 1i -aicNctobuJ€doo b' cl{3cll2cr-I2trI3 , , - t ic,tfo-cobt"faxlt c ;)*-f-{"*" 3,i -dd$c', - !,{-d}rRah-'oxo.ra-