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Section 7.4
                Ionization Energy
Dan Corney
Anna Erkalova
Frank Muzika
John Yoffee
Overview
• Ionization energy – the minimum energy required to remove
  an electron from the ground state of the isolated gaseous
  atom or ion.
• Variations in Successive Ionization
  Energies
• Periodic Trends in First Ionization
  Energies
• Electron Configurations of Ions
• Applications outside of class
Ionization Energy Variations

 • Increases with each electron
    – More energy require to remove an electron from a more positive ion
 • Removing inner shell electrons causes GREAT increases in
   energy
    – Inner shells are much closer to the nucleus
 • Large increase always exists when taking from Noble Gas Core
Ionization Energy Variations

             Interesting Facts
First Ionization Energy Trends
First Ionization Energy Trends


 • Within Rows, I increases with Atomic Number
 • Within Groups, I decreases with Atomic
   Number
 • Representative Elements show a larger range
   of values of I
First Ionization Energy Trends

 • Smaller Atoms tend to have Higher Energies
   – Closer to nucleus
   – Minor irregularities due to
      • Electron repulsion (Nitrogen to Oxygen)
      • Electron Shielding (Beryllium to Boron)
First Ionization Energy Trends
            Interesting Facts
Electron Configuration of Ions

 • Electrons are always removed from orbitals
   with largest principal quantum number.
 • This means that 4s would be removed before
   3d
Electron Configuration of Ions
            Interesting Facts
Questions
• By looking at following electronic
  configuration of elements, can you predict
  which element has the lowest first ionization
  energy?
      -(A) 1s2 2s2 2p6 (B) 1s2 2s2 2p4 (C) 1s2 2s2
      2p6 3s2 (D) 1s2 2s2 2p6 3s1 (E) 1s2 2s2 2p5

• Low first ionization energy is considered a
  property of Metals or Non-Metals?
Questions
• Write the Electron Configuration for Co3+.

• Arrange the following atoms in order of
  increasing first ionization energy. Ne, Na, P, Ar, K.

• Ionization energy is the ability to capture an
  electron.
      -True/False
Answers
•   (D) 1s2 2s2 2p6 3s1
•   Metals
•   [Ar]3d6
•   K<Na<P<Ar<Ne
•   True
Outside the Class

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Chem powerpoint

  • 1. Section 7.4 Ionization Energy Dan Corney Anna Erkalova Frank Muzika John Yoffee
  • 2. Overview • Ionization energy – the minimum energy required to remove an electron from the ground state of the isolated gaseous atom or ion. • Variations in Successive Ionization Energies • Periodic Trends in First Ionization Energies • Electron Configurations of Ions • Applications outside of class
  • 3. Ionization Energy Variations • Increases with each electron – More energy require to remove an electron from a more positive ion • Removing inner shell electrons causes GREAT increases in energy – Inner shells are much closer to the nucleus • Large increase always exists when taking from Noble Gas Core
  • 4. Ionization Energy Variations Interesting Facts
  • 6. First Ionization Energy Trends • Within Rows, I increases with Atomic Number • Within Groups, I decreases with Atomic Number • Representative Elements show a larger range of values of I
  • 7. First Ionization Energy Trends • Smaller Atoms tend to have Higher Energies – Closer to nucleus – Minor irregularities due to • Electron repulsion (Nitrogen to Oxygen) • Electron Shielding (Beryllium to Boron)
  • 8. First Ionization Energy Trends Interesting Facts
  • 9. Electron Configuration of Ions • Electrons are always removed from orbitals with largest principal quantum number. • This means that 4s would be removed before 3d
  • 10. Electron Configuration of Ions Interesting Facts
  • 11. Questions • By looking at following electronic configuration of elements, can you predict which element has the lowest first ionization energy? -(A) 1s2 2s2 2p6 (B) 1s2 2s2 2p4 (C) 1s2 2s2 2p6 3s2 (D) 1s2 2s2 2p6 3s1 (E) 1s2 2s2 2p5 • Low first ionization energy is considered a property of Metals or Non-Metals?
  • 12. Questions • Write the Electron Configuration for Co3+. • Arrange the following atoms in order of increasing first ionization energy. Ne, Na, P, Ar, K. • Ionization energy is the ability to capture an electron. -True/False
  • 13. Answers • (D) 1s2 2s2 2p6 3s1 • Metals • [Ar]3d6 • K<Na<P<Ar<Ne • True