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CH-4 Carbon and
it’s Compounds
The Importance of Carbon
• The name carbon comes from the Latin word carbo, which
means coal.
• The earth’s crust has only 0.02% carbon in the form of
minerals and the atmosphere has 0.03% of carbon dioxide
and yet is present in almost every sphere of life.
• Carbon is life’s fundamental building block. Carbon dating
is used for determining the age of prehistoric samples
Covalent Bonding
• The numbers of carbon compounds whose formulae are
known to chemists was recently estimated to be in
millions, this outnumbers the compounds of all other
elements put together
• This is due to 3 properties: Catenation, Tetravalency
and Isomerism
Catenation
Compounds may have long chains of carbon, branched chains of carbon or even
carbon atoms arranged in rings.
In addition, carbon atoms may be linked by single, double or triple
bonds.
Compounds of carbon, which are linked by only single
bonds between the carbon atoms are called Saturated Compounds.
Compounds of carbon having double or triple bonds between their
carbon atoms are called Unsaturated Compounds.
Tetravalency
• Since carbon has a valency of four, it is capable of bonding
with four other atoms of carbon or atoms of some other
mono-valent element
• Again the bonds that carbon forms with most other
elements are very strong making these compounds
exceptionally stable. One reason for the formation of
strong bonds by carbon is its small size. This enables the
nucleus to hold on to the shared pairs of electrons
strongly. The bonds formed by elements having bigger
atoms are much weaker
Isomerism
Isomerism is the phenomenon in which more than one compounds have the same
chemical formula but different chemical structures
Allotropes of Carbon
The element carbon occurs in different forms in nature with
widely varying physical properties. Both diamond and
graphite are formed by carbon atoms, the difference lies in
the manner in which the carbon atoms are bonded to one
another.
Allotropes of Carbon
The element carbon occurs in different forms in nature
with widely varying physical properties. Both diamond
and graphite are formed by carbon atoms, the
difference lies in the manner in which the carbon
atoms are bonded to one another.
Diamond
Each carbon atom is bonded to four other
carbon atoms forming a rigid three
dimensional structure.
Graphite
In graphite, each carbon atom is bonded to three
other carbon atoms in the same plane giving a hexagonal array.
One of these bonds is a double-bond, and thus the valency of
carbon is satisfied. Graphite structure is formed by the
hexagonal arrays being placed in layers one above the other.
Buckministerfullerene
Fullerenes form another class of carbon allotropes. The first
one to be identified was C-60 which has carbon atoms
arranged in the shape of a football. Since this looked like the
geodesic dome designed by the US architect Buckminster
Fuller, the molecule was named fullerene.
Saturated and Unsaturated
Carbon Compounds

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CH-4 Carbon and it’s Compounds.pptx

  • 2. The Importance of Carbon • The name carbon comes from the Latin word carbo, which means coal. • The earth’s crust has only 0.02% carbon in the form of minerals and the atmosphere has 0.03% of carbon dioxide and yet is present in almost every sphere of life. • Carbon is life’s fundamental building block. Carbon dating is used for determining the age of prehistoric samples
  • 4. • The numbers of carbon compounds whose formulae are known to chemists was recently estimated to be in millions, this outnumbers the compounds of all other elements put together • This is due to 3 properties: Catenation, Tetravalency and Isomerism
  • 5. Catenation Compounds may have long chains of carbon, branched chains of carbon or even carbon atoms arranged in rings. In addition, carbon atoms may be linked by single, double or triple bonds. Compounds of carbon, which are linked by only single bonds between the carbon atoms are called Saturated Compounds. Compounds of carbon having double or triple bonds between their carbon atoms are called Unsaturated Compounds.
  • 6. Tetravalency • Since carbon has a valency of four, it is capable of bonding with four other atoms of carbon or atoms of some other mono-valent element • Again the bonds that carbon forms with most other elements are very strong making these compounds exceptionally stable. One reason for the formation of strong bonds by carbon is its small size. This enables the nucleus to hold on to the shared pairs of electrons strongly. The bonds formed by elements having bigger atoms are much weaker
  • 7. Isomerism Isomerism is the phenomenon in which more than one compounds have the same chemical formula but different chemical structures
  • 8. Allotropes of Carbon The element carbon occurs in different forms in nature with widely varying physical properties. Both diamond and graphite are formed by carbon atoms, the difference lies in the manner in which the carbon atoms are bonded to one another.
  • 9. Allotropes of Carbon The element carbon occurs in different forms in nature with widely varying physical properties. Both diamond and graphite are formed by carbon atoms, the difference lies in the manner in which the carbon atoms are bonded to one another.
  • 10. Diamond Each carbon atom is bonded to four other carbon atoms forming a rigid three dimensional structure.
  • 11. Graphite In graphite, each carbon atom is bonded to three other carbon atoms in the same plane giving a hexagonal array. One of these bonds is a double-bond, and thus the valency of carbon is satisfied. Graphite structure is formed by the hexagonal arrays being placed in layers one above the other.
  • 12. Buckministerfullerene Fullerenes form another class of carbon allotropes. The first one to be identified was C-60 which has carbon atoms arranged in the shape of a football. Since this looked like the geodesic dome designed by the US architect Buckminster Fuller, the molecule was named fullerene.