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Organic Compounds
Concept in Brief
Organic Compounds
Organic
Compounds
 Coal, petroleum,
natural gas
 Proteins, fats,
carbohydrates
Formulas
 Molecular
 Structural
 Condensed
Closed Chain
 Homo-cyclic
 Heterocyclic
Open chain
 Straight chain
 Branched
Chain
Functional
groups
Containing C, H
and Halogens
E.g. Alkyl halides
Containing C, H
and N
E.g. Amines
Containing C-C
multiple bonds
 Alkenes
 Alkynes
Containing C, H and
O
 Alcohols
 Ethers
 Aldehydes
 Ketones
 Carboxylic
acids
 Esters
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Chemistry Notes
Chapter: Organic Chemistry
Introduction:
Definition of Organic Chemistry:
Organic chemistry is the study of hydrocarbons, which are only composed of carbon and hydrogen,
as well as their derivatives, which are composed of at least one electronegative element, such as
an oxygen, sulphur, or nitrogen atom, or a halogen such as a fluorine, chlorine, iodine or a boron
atom.
Organic Compounds:
Background:
 In the past, it was thought that organic chemicals could only be found in living things. For
example, oil and ghee are made from both plants and animals because they are both living
things, which is why they are said to as organic.
 Wheat is also derived from plants, and we know that plants are living things. In this sense,
wheat was referred to as organic.
 However, as time went on, a German chemist named Fredrick Wohler synthesized urea
(NH2-CO-NH2) in a lab using the inorganic molecule ammonium thiocyanate.
 Following this, the idea that organic molecules can only come from living sources was
disproved.
 The notion that organic molecules can only originate from living sources was then refuted.
 However, there are numerous substances that include carbon but are not organic, such as
NaCN, CO2, CO, and CS2.
 Therefore, the second hypothesis about the identification of organic substances was
likewise disproved.
 A new theory was formed once more, this time defining organic molecules as substances
that contain carbon and hydrogen as well as any of their derivatives.
 This notion of the identification and definition of organic compounds is still in use.
Definition of Organic Compounds:
Carbon and hydrogen containing compounds means hydrocarbons and their derivatives are called
organic compounds.
Hydrocarbons and their derivatives are referred to as organic chemicals since they contain carbon
and hydrogen only or with C and H must have any other atom like; S, O, N and P etc. e.g. CH4,
C2H6, C6H12O6, C12H22O11 etc.
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(Point to Recall): Derivative:
If we want to understand what the word "derivative" means, we must first understand that
compounds containing only carbon and hydrogen are classified as "hydrocarbons," and those
compounds can also be categorized as "organic" if at least one hydrogen atom is substituted with
an atom other than carbon, such as an atom from the group O, S, N, or Cl. They are then referred
to as hydrocarbon derivatives. Or
Derivative of Hydrocarbon:
Definition:
The hydrocarbon which are composed of at least one electronegative element, such as an oxygen,
sulphur, or nitrogen atom, or a halogen such as a fluorine, chlorine, iodine or a boron atom in place
of hydrogen is called derivative of hydrocarbon.
Chemical Diversity and Magnitude of Organic compounds:
(Chemical Variety and Organic Compounds' Size)
 In the periodic table, carbon is positioned in group four.
 It follows that carbon has four electrons in its valence shell (as group number tells us
number of valance electrons of an atom).
 The octet of carbon is therefore incomplete, and as a result, carbon is unstable.
 In greed of stability carbon will establish four covalent connections with other carbon
atoms in order to complete its octet.
 The fact that carbon, the building block of organic compounds, exhibits catenation property
by creating four covalent connections with itself is the explanation for the vast variety of
organic molecules.
Catenation:
Definition:
 The name catenation can be defined as the carbon's capacity for self-linkage e.g.
CH3-CH2-CH2-CH2-CH2-CH2-CH2-CH3
 Because of this catenation feature, organic compounds are abundant and can be found in a
wide variety of forms.
 On the basis of its catenation property, no other element can rival carbon
 While some other elements, such as Si, Se, and S (e.g., S8), are also capable of forming
chains, their capacity is constrained because they can only do so with short chains
 As opposed to carbon atoms, which may form extraordinarily long chains
 There might be thousands of carbon atoms, even in a single chain
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 Isomerism is second in importance to catenation in explaining the diversity of carbon
compounds
Structural Formula:
Definition:
The term "structural formula" refers to a formula that depicts the location of atoms within a
molecule. For instance, in the example below,
 Two organic molecules with the same chemical formula, C2H6O, are shown.
 However, because the atoms are arranged differently in each structure, their structural
formulas differ.
 These two structures are known as isomers of one another, for example
Isomerism:
Definition:
The phenomenon of isomerism refers to organic compounds with the same molecular formula but
a distinct structural formula as a result of a different atom arrangement inside molecules.
Example 1:
Explanation:
 Keep an eye on the two chemical substances mentioned above
 Their molecules share the same formula C4H10
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 Take note of how differently their structures are
 The atoms' varied arrangements explain why the structures differ
 The isomer of normal butane is hence iso-butane
Example 2:
Explanation:
 The three compounds listed above each have a unique structure
 Total the number of atoms in each molecule
 Their chemical formula, which may be determined by counting atoms, is C5H12
 Normal pentane's chemical composition is C5H12
 As was said in the first example, a molecule's structure can vary depending on how its
atoms are arranged
 The isomers of normal pentane are the other two structures, such as iso-pentane and neo-
pentane
Note: The quantity of carbon atoms in a molecule determines how many isomers there are. There
are more isomers as the carbon chain lengthens.
Connection (bonds) with Other Atoms:
 Carbon not only forms connections with other atoms but also with itself.
 For instance, it may form double and triple bonds with its own atoms as well as with oxygen
and nitrogen atoms e.g.
 The creation of numerous bonds between carbon atoms and other atoms is the third major
factor contributing to the diversity of organic molecules.
 Approximately, there are over 20 million chemical compounds known, of which 95% are
carbon molecules.
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General Characteristics of Organic Compound (Organic compounds qualities):
The following list of qualities for organic compounds:
1) Presence:
Both living and non-living things have the means to produce organic compounds
2) Covalent Bond:
Covalent bonds are the most frequent type of chemical connection made between organic
substances (the bond formed by mutual sharing of electrons is called covalent bond)
3) Catenation:
 Carbon, the cornerstone of organic molecules, has the ability to self-link
 This potential for self-linking is regarded as the catenation property
 Organic chemicals are widespread and come in lengthy chain forms because of this
feature
4) Constituents:
Although carbon serves as the foundation for organic molecules, additional elements such
as H, S, N, O, F, Cl, Br, I, and P etc. are also present.
5) Melting and Boiling Points:
 Covalent bonds hold organic components together.
 We are aware that covalent bonds alone are insufficiently strong.
 Therefore, most organic compounds are volatile and have low melting and boiling
temperatures due to bond fragility.
 Bond strength is strongly correlated with melting and boiling points.
 The melting and boiling points will be higher the stronger the relationship.
 Lower melting and boiling points correspond to weaker bonds.
6) Solubility:
 The chemical components that make up the hydrocarbons are non-polar in nature.
 The small difference in electronegativity between carbon and hydrogen atoms is
what causes the non-polar nature.
 In contrast, hydrocarbon derivatives are both polar and organic in nature.
 The difference in electronegativity between carbon and other atoms, such as O, N,
S, P, F, Cl, Br, and I, is what causes their polarity.
 Non-polar organic compounds are soluble in non-polar solvents like benzene, ether,
carbon disulphide, and carbon tetrachloride, according to the “like dissolves like”
rule.
 While polar solvents like methanol and ethanol are used to dissolve polar organic
molecules.
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7) Similarity in Behavior (Homology):
 Organic substances behave remarkably identical to one another.
 They can be conveniently studied in a series known as a homologous series due to
their similar behavior.
 Organic compounds are organized in this series in order of increasing one -CH2-
group size.
 If a compound has two -CH2- groups, the preceding compound will have three, the
after four, and so on.
8) Rate of Reaction:
Organic substances are less stable and have sluggish reaction rates because they have
covalent bonds which are not so much strong in nature.
Condensed Structural Formula:
Definition:
Condensed formula is the name given to the formula that uses shorthand to express each group in
a chain.
For instance, the first three homologous series members' structural formula is;
Now, they can be represented as follows in the condensed structural formula:
CH4 for Methane, CH3CH3 for Ethane, CH3CH2CH3 for Propane
While they can be modelled as; in a molecular formula.
CH4 for Methane, C2H6 for Ethane, C3H8 for Propane
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Table displaying homologous series' condensed structural formulas:
Name Molecular
Formula
Condensed Formula
Methane CH4 CH4
Ethane C2H6 CH3CH3
Propane C3H8 CH3CH2CH3
Butane C4H10 CH3CH2CH2CH3
Pentane C5H12 CH3CH2CH2CH2CH3
Hexane C6H14 CH3CH2CH2CH2CH2CH3
Heptane C7H16 CH3CH2CH2CH2CH2CH2CH3
Octane C8H18 CH3CH2CH2CH2CH2CH2CH2CH3
Nonane C9H20 CH3CH2CH2CH2CH2CH2CH2CH2CH3
Decane C10H22 CH3CH2CH2CH2CH2CH2CH2CH2CH2CH3
 There are millions of organic compounds in existence, and new ones are constantly being
found.
 Therefore, in order to analyze such a great number of compounds, they are divided into
two primary groups.
 One group segregates organic compounds based on their structure, while a second group
distinguishes organic compounds based on functional groups.
Classification of organic compounds:
1) On the basis of Structure
2) On the basis of Functional Group
1): On the basis of structure:
 As the title implies, the organic compounds in this group differ from one another due to
distinct orientations of carbon atoms in the molecules.
 They are further divided into;
a) Open Chain /Acyclic Organic Compounds
b) Closed Chain / Cyclic Organic Compounds
a): Open Chain/ Acyclic Organic Compounds:
 The carbon atoms in these compounds are grouped in open chain form by covalent bonds,
as the title implies.
 Additionally, the chain of carbon atoms connected by a covalent bond might be straight or
branched, for example.
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b): Closed chain / Cyclic Compounds:
 As the name suggests, these compounds' carbon atoms are ordered in closed-chain form,
and the carbons are connected together by covalent bond.
 Or we could say that the carbon atoms in these compounds are structured in cycle form,
through covalent bond for example.
 Another idea is that an organic compound is considered to be homo-cyclic if the ring
exclusively contains carbon atoms.
 As the term homo means "same," it follows that all of the carbon atoms in the ring are
identical to one another, which is why it is called a homo-cyclic compound.
 While hetero means "different" and means that there are not all carbon atoms in the ring
 While the non-carbon atom is also present in the ring
 In this way carbon and non-carbon atoms are not the same but different for each other
 That's why called heterocyclic, if the ring contains one non-carbon atom e.g. N, O, S, Cl
etc.
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The homo-cyclic organic compounds are further divided into two which are given below:
a) Alicyclic
b) Aromatic
a): Alicyclic organic compounds:
The carbon atoms in these straightforward homo-cyclic compounds are joined by covalent bonds
to form rings, for example
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b): Aromatic organic compounds:
 These compounds have one more attribute that distinguishes them from simple homo-
cyclic organic compounds
 This special property is known as aromaticity and denotes the fact that they have alternate
single and double bonds between carbon atoms.
2): On the Basis of Functional group:
What is functional group?
 A functional group is a single atom or a collection of atoms that describes a
compound's physical or chemical characteristics
 Millions of chemical molecules can be studied sequentially thanks to functional
groups
 Due to this functional group, each family of organic compounds can be
conveniently examined.
On the basis of functional group organic compounds are classified as:
1) Hydrocarbons
2) Derivatives of Hydrocarbons
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1): Hydrocarbons:
 Since only carbon and hydrogen atoms are found in organic substances, hydrocarbons are
known as such.
 They could have a ring structure or an open chain structure.
Alkanes:
 Alkanes, also known as saturated hydrocarbons, are hydrocarbons in which all of the
carbon atoms are connected by a single covalent bond, either in a straight chain structure
or a ring shape.
 There won't be any double or triple covalent bonds in saturated hydrocarbons, only single
covalent bonds.
Alkenes:
 Alkenes, also known as "unsaturated hydrocarbons," are hydrocarbons in which at least
two carbon atoms are connected together by a double covalent bond.
Alkynes:
 Alkynes, as well known as "unsaturated hydrocarbons" are hydrocarbons in which at least
two carbon atoms are linked together by a triple covalent bond.
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2): Derivatives of Hydrocarbons:
 We can infer that hydrocarbons of any open-chain or close chain hydrocarbons in which at
least one hydrogen atom has been substituted with a heteroatom, such as N, O, S, or Cl are
called derivatives of hydrocarbons.
 Methane is the first alkane in the homologous series (CH4).
 A simple hydrocarbon is methane.
 By substituting other atoms for its one hydrogen atom, such as OH, Cl, Br, NH2, and CN,
we can create its derivatives.
 For example
CH4, CH3-OH, CH3-Cl, CH3-Br, CH3-NH2, CH3-CN etc.
Derivatives of hydrocarbons are described in depth in the table below.
According to their functional groups, organic compounds are categorized in the following
table:
Table of functional groups of organic compounds:
Class of Compounds Functional
Group/Name
General Formula Example
Alkane
Single Bond
CnH2n+2
Alkene
Double Bond
CnH2n
Alkyne
Triple Bond
CnH2n-2
Alkyl Halide
Halo (X may be F,
Cl, Br, I)
CnH2n+1 X
Alcohol
Hydroxyl
CnH2n+1 OH
Amine
Amino
CnH2n+1 NH2
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Ether
Oxygen
(CnH2n+1)2 O
Ketone
Carbonyl
(CnH2n+1)2 C O
Aldehyde
Formyl
CnH2n+1 CHO
Carboxylic Acid
Carboxyl
CnH2n+1COOH
Acid Halide
Acyl
CnH2n+1COX
Acid Amide
Amide
(CnH2n+1CONH2)
Ester
Ester
(CnH2n+1COOCnH2n+1)
Alkyl Cyanide/Nitrile
Cyano
CnH2n+1 CN
Brief Detail of Functional Groups given in above Table:
Alkanes:
 Alkanes are hydrocarbons that include a single covalent bond holding two or more carbon
atoms together or with a hydrogen atom in an open chain or close chain.
 There won't be any double or triple covalent bonds in alkanes, only single covalent bonds
 For example; CH4, CH3-CH3, CH3-CH2-CH2-CH3 etc.
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Alkenes:
 Alkenes are hydrocarbons that have at least two carbon atoms bound by a double covalent
bond, either in a straight chain or a close chain
 For example; CH2=CH2, CH3-CH=CH-CH3 etc.
Alkynes:
Alkynes are hydrocarbons that contain three triple covalent bonds connecting at least two carbon
atoms e.g.
Alkyl Halide:
 Alkyl halides are hydrocarbons that have at least one hydrogen atom replaced to one of the
halogen atoms F, Cl, Br, or I.
 Halo functional group is present in them (-X)
 For example; CH3-Cl, CH3-Br, CH3-F, CH3-I, CH3-CH2-CH2-Cl, CH3-CH2-CH2-
F, CH3-CH2-CH2-CH2-CH2-Br etc.
For understanding consider methyl chloride (CH3-Cl):
 We are aware that carbon form four covalent connections (bonds) to attain stability.
 This demonstrates how the carbon atom in chloromethane fulfils its valency by creating
three covalent bonds with hydrogen atoms and one covalent bond with any halogen atom
(replaced with hydrogen atom).
Alcohol:
 Alcohols are hydrocarbons that have at least one hydrogen atom replaced with an OH
group.
 They have a hydroxyl functional group (-OH).
 For example; CH3-OH, CH3-CH2-OH, CH3-CH2-CH2-CH2-CH2-OH etc. are open
chain alcohols.
 Even though when –OH group is attached to benzene ring the it is called phenol e.g.
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For understanding consider methanol (CH3-OH):
 We are aware that the carbon atom forms four covalent connections (bonds) to attain
stability.
 In the case of open chain alcohols, the carbon atom in methanol is fulfilling its valency by
creating three covalent bonds with hydrogen atoms and one covalent bond with the OH
group (replaced with hydrogen atom).
 While in phenol carbon number 1 making three covalent bonds with two more carbon
atoms (carbon number 2 and 6) and one covalent bond with an OH group (replaced with
hydrogen atom).
 Therefore, like methanol phenol also fulfils its valency.
Amines:
 Amines are hydrocarbons that have at least one hydrogen atom replaced with an NH2
group.
 The amino functional group is present (-NH2) in amines. .
 For example CH3-NH2, CH3-CH2-NH2, CH3-CH2-CH2-CH2-CH2-NH2 etc. are open
chain amines.
 Even though aniline is an aromatic amine e.g.
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For understanding consider methyl amine (CH3-NH2) and aniline:
 We are aware that the carbon atom forms four covalent connections to attain stability.
 In this example of an open chain amine, the carbon atom is fulfilling its valency by creating
three covalent bonds with hydrogen atoms and one covalent bond with the NH2 group
(replaced with hydrogen atom).
 In aromatic amine, such as aniline, carbon number 1 additionally fulfils its valency by
creating three covalent bonds with two other carbon atoms (carbon number 2 and 6), one
covalent bond with the NH2 group (replaced with hydrogen atom).
Ethers:
 Ethers are hydrocarbons that have at least one hydrogen atom substituted with an O-R
group.
 The oxygen functional group is present (-O-) in ethers
 For example; CH3-O-CH3, CH3-CH2-O-CH3, CH3-CH2-CH2-CH2-CH2-O-CH2-CH3
etc.
For understanding consider dimethyl ether (CH3-O-CH3):
 We are aware that the carbon atom forms four covalent connections to attain stability.
 Here, we can observe that the left and right carbons in dimethyl ether are both satisfying
the valency of the compound by creating three covalent bonds with hydrogen atoms and
one covalent bond with an oxygen atom (replaced with hydrogen atom).
Ketones:
 Ketones are derivatives of hydrocarbons that include a carbonyl functional group (-CO-),
which replaces at least one hydrogen atom in the hydrocarbon.
 Two alkyl groups are affixed to the carbonyl carbon in ketone molecules.
 For example; CH3-CO-CH3, CH3-CH2-CO-CH3, CH3-CH2-CH2-CH2-CH2-CO-CH3
etc.
Aldehydes:
 Aldehydes are derivatives of hydrocarbons that have at least one hydrogen atom removed
in favor of a carbonyl functional group (-COH).
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 Aldehydes are compounds made of carbonyl carbon and one or two hydrogen atoms
attached to that carbonyl carbon atom
 For example; H-CO-H, CH3-CO-H, CH3-CH2-CO-H, CH3-CH2-CH2-CH2-CH2-
CO-H etc.
Carboxylic acids:
 Carboxylic acids are derivatives of hydrocarbons that have a carboxyl functional group in
place of at least one hydrogen atom, also known as the -COOH group
 For example; CH3-CO-OH, CH3-CH2-CO-OH, CH3-CH2-CH2-CH2-CH2-CO-OH
etc.
Acid Halides:
 Acid halides are derivatives of hydrocarbons that have an acyl group (-CO-X) with at least
one hydrogen atom substituted by a COX group
 For example; CH3-CO-Cl, CH3-CH2-CO-Br, CH3-CH2-CH2-CH2-CH2-CO-Cl etc.
Acid Amides:
 Acid amides are derivatives of hydrocarbons that have at least one hydrogen atom replaced
with a CO-NH2 group.
 The amide functional group (-CO-NH2) is present in acid amides
 For example; CH3-CO-NH2, CH3-CH2-CO-NH2, CH3-CH2-CH2-CH2-CH2-CO-NH2
etc.
Esters:
 Esters are derivatives of hydrocarbons that have at least one hydrogen atom replaced with
a COOR group.
 They have ester functional group (-COOR) in them
 For example; CH3-CO-OCH3, CH3-CH2-CO-OCH3, CH3-CH2-CH2-CH2-CH2-CO-
OCH3 etc.
Alkyl Cyanide:
 Alkyl cyanides are hydrocarbons that have at least one hydrogen atom substituted with a
CN group.
 They have “cyano” functional group (-CN) in them
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 For example; CH3-CN, CH3-CH2-CN, CH3-CH2-CH2-CH2-CH2-CN etc.
Alkane and Alkyl Radicals:
Alkane:
 Alkanes are hydrocarbons that include a single covalent bond holding two or more carbon
atoms together or to a hydrogen atom in an open chain or close chain, as was previously
explained.
 There won't be any double or triple covalent bonds in alkanes, only single covalent bonds.
e.g.
Alkyl Radical:
 When one hydrogen atom is removed from alkane then it results in the formation of alkyl
radical
 For example; Methane produces methyl (radical) when one hydrogen atom removed from
it
 Ethane produces ethyl (radical) when one hydrogen atom removed from it
 Propane produces propyl (radical) when one hydrogen atom is removed from it, and so on.
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For example:
Method to convert alkane into alkyl radical:
 Compose the alkane’s member condensed formula
 Dehydrogenate the compound by removing one hydrogen
 Change the ending -ane in the alkane to -yl to give the radical a name
 By removing hydrogen atom from the terminal carbon atom. Normal alkyl (radical) will
be produced e.g.
 By removing hydrogen atom from the second last carbon atom. Iso-alkyl (radical) will be
produced e.g.
Naming Alkanes:
 A naming scheme for each class of hydrocarbons and its derivatives was developed by the
International Union of Pure and Applied Chemistry (IUPAC).
 Here, we shall comprehend the guidelines needed to provide alkanes names.
 The number of carbon atoms in an alkane chain determines the name of the compound.
 The IUPAC name has two components.
i) Prefix
ii) Suffix
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Prefix:
 It refers to how many carbon atoms there are in an alkane chain.
 The prefixes are shown in the table below according to how many carbon atoms are in an
alkane chain.
Prefix Number of
Carbon atoms
Meth- 1
Eth- 2
Prop- 3
But- 4
Pent- 5
Hex- 6
Hept- 7
Oct- 8
Non- 9
Dec- 10
Suffix:
It identifies the hydrocarbon class. The prefix "ane" is used with alkanes.
Example 1:
Consequently, if a compound contains just one carbon atom. Then, how will we name this
compound in accordance with IUPAC rules?
Solution:
 Verify the prefix in the table above for one carbon atom
 Prefix for one carbon atom is Meth-
 Verify each bond in a compound
 When the compounds only have one type of covalent bond (single covalent bond).
Consequently, the chemical is an alkane
 The alkane family's suffix is "ane"
 We'll write the prefix first, then the suffix
 Therefore, the IUPAC name of the compound will be Methane
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Example 2:
If a substance contains four carbon atoms. Then, how will we name this compound in
accordance with IUPAC rules?
CH3-CH2-CH2-CH3
Solution:
 Verify the prefix in the table above for four carbon atom
 Prefix for four carbon atom is But-
 Verify each bond in a compound
 When the compounds only have one type of covalent bond (single covalent bond).
Consequently, the chemical is an alkane
 The alkane family's suffix is "ane"
 We'll write the prefix first, then the suffix
 Therefore, the IUPAC name of the compound will be butane
Example 3:
If a substance contains five carbon atoms. Then, how will we name this compound in accordance
with IUPAC rules?
CH3-CH2-CH2-CH2-CH3
Solution:
 Verify the prefix in the table above for five carbon atom
 Prefix for five carbon atom is pent-
 Verify each bond in a compound
 When the compounds only have one type of covalent bond (single covalent bond).
Consequently, the chemical is an alkane
 The alkane family's suffix is "ane"
 We'll write the prefix first, then the suffix
 Therefore, the IUPAC name of the compound will be pentane
Organic Compounds' Sources:
 There are two primary sources of alkanes for commercial use.
i) One from Natural Sources
ii) And the other from man-made ones (artificial sources).
 Coal, natural gas, petroleum, and living things are examples of natural resources.
 While researchers' laboratory production of organic chemicals is the artificial source.
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Coal:
 The rich trove of organic chemicals is coal.
 Another name for it is solid fuel.
 Because it is solid and used as fuel.
 Coal is dark in color
Destructive Distillation:
High temperature heating of coal produces coal gas, coal tar, and coke when oxygen is not
present. And the term used for this procedure is coal destructive distillation.
Coal gas:
 It's not just one gas, but several.
 However, it contains a combination of gases, including methane, hydrogen, and carbon
monoxide.
 Industrial uses of coal gas include fuel.
Coal Tar:
 The wealth of organic molecules in coal tar is astounding.
 However, it does include benzene and its derivatives.
 Fractional distillation is a process that can be used to extract benzene and its
compounds from coal tar.
 The residue left behind after fractional distillation, which separates useful chemicals
like benzene and its derivatives from coal tar, is also beneficial.
 Pitch, the name of this residue, is used to make metal roadways and building roofs.
 The manufacture of plastics, dyes, textiles, pharmaceuticals, paints, and varnishes,
among other things, uses benzene and its derivatives, which are quite helpful.
Fractional Distillation:
Fractional distillation is the process of separating components of a solution based on the
differences in their boiling points.
Natural Gas:
 Natural gas is not just one type of gas.
 It is a concoction of gases.
 Methane, ethane, propane, and butane are just a few of the low-boiling hydrocarbons
that it contains.
 Methane, however, makes up a much larger portion of the mixture than the other gases
do.
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Petroleum:
 The Latin words petra, which means "rock," and oleum, which means "oil," combine
to form the English word petroleum.
 Thus, petroleum refers to rock oil as it is known to exist underground.
 Dark brown in color, petroleum has a foul odour.
 Petroleum is a mixture of several hydrocarbons.
 However, it's a blend of long chain hydrocarbons.
 It contains aromatic hydrocarbons, cycloalkanes, and alkanes.
 Additionally, there are minor amounts of S, O, and N, Ni, Cu, and V in petroleum.
Living Organisms:
 The primary source of organic molecules is living things.
 Due to the fact that both medications and carbohydrates are derived from plants (living
organisms).
 Animals (living beings) provide us with organic components like proteins and lipids.
Artificial Source (men made):
Laboratory:
 According to the records, mankind have created probably 10 million or more organic
molecules in laboratories.
 And the organic compounds that these men created are extremely beneficial and are
sold as medicines for the treatment of fatal diseases like cancer, HIV, tuberculosis, and
others.
 Additionally, while producing dyes, plastics, paints, cosmetics, detergents, and
fertilizers, along with other things.
Uses of Organic Compounds:
1) As a Fuel:
 Natural gas, petroleum, and coal are examples of organic fuels that can be burned to
generate heat.
 The gases that can be made from natural gas are propane and butane.
 Additionally, these gases are employed in fuel cylinders as a liquid.
2) As a raw material for the synthesis of organic products:
 Coal, natural gas, petroleum are used a raw material for the synthesis of organic
compounds.
 Ethylene is used as raw material for the synthesis of plastic (polyethylene), alcohol
(ethanol), Carboxylic acid (acetic acid), and antifreeze (ethylene glycol).
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 For the production of soap, medicines, cosmetics, detergents, emulsions, and other
organic products, numerous different organic compounds are employed as raw
ingredients.
3) Synthesis of polymers:
Acetylene is utilized as a starting ingredient in the manufacture of polymers like nylon, rubber,
and polyvinyl chloride (PVC).
4) For welding and cutting of metals:
Metals are chopped and joined together using an oxygen-acetylene flame.
5) For artificial ripening of food:
Artificial food ripening is accomplished using acetylene.
6) As an Antiseptic:
Hospitals utilize phenol as an antiseptic.
7) As a Solvent:
Methanol and ethanol are utilized in several reactions as well as solvents for fats, oils, paints
and varnishes.

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Chapter-organic-Chemistry-class-10-notes.pdf

  • 1. Chemistry Tutorials  Digital Kemistry YouTube Chemistry Note  www.mydigitalkemistry.com Join Digital Kemistry Academy, WhatsApp +92-3336753424 Page 1 Organic Compounds Concept in Brief Organic Compounds Organic Compounds  Coal, petroleum, natural gas  Proteins, fats, carbohydrates Formulas  Molecular  Structural  Condensed Closed Chain  Homo-cyclic  Heterocyclic Open chain  Straight chain  Branched Chain Functional groups Containing C, H and Halogens E.g. Alkyl halides Containing C, H and N E.g. Amines Containing C-C multiple bonds  Alkenes  Alkynes Containing C, H and O  Alcohols  Ethers  Aldehydes  Ketones  Carboxylic acids  Esters
  • 2. Chemistry Tutorials  Digital Kemistry YouTube Chemistry Note  www.mydigitalkemistry.com Join Digital Kemistry Academy, WhatsApp +92-3336753424 Page 2 Chemistry Notes Chapter: Organic Chemistry Introduction: Definition of Organic Chemistry: Organic chemistry is the study of hydrocarbons, which are only composed of carbon and hydrogen, as well as their derivatives, which are composed of at least one electronegative element, such as an oxygen, sulphur, or nitrogen atom, or a halogen such as a fluorine, chlorine, iodine or a boron atom. Organic Compounds: Background:  In the past, it was thought that organic chemicals could only be found in living things. For example, oil and ghee are made from both plants and animals because they are both living things, which is why they are said to as organic.  Wheat is also derived from plants, and we know that plants are living things. In this sense, wheat was referred to as organic.  However, as time went on, a German chemist named Fredrick Wohler synthesized urea (NH2-CO-NH2) in a lab using the inorganic molecule ammonium thiocyanate.  Following this, the idea that organic molecules can only come from living sources was disproved.  The notion that organic molecules can only originate from living sources was then refuted.  However, there are numerous substances that include carbon but are not organic, such as NaCN, CO2, CO, and CS2.  Therefore, the second hypothesis about the identification of organic substances was likewise disproved.  A new theory was formed once more, this time defining organic molecules as substances that contain carbon and hydrogen as well as any of their derivatives.  This notion of the identification and definition of organic compounds is still in use. Definition of Organic Compounds: Carbon and hydrogen containing compounds means hydrocarbons and their derivatives are called organic compounds. Hydrocarbons and their derivatives are referred to as organic chemicals since they contain carbon and hydrogen only or with C and H must have any other atom like; S, O, N and P etc. e.g. CH4, C2H6, C6H12O6, C12H22O11 etc.
  • 3. Chemistry Tutorials  Digital Kemistry YouTube Chemistry Note  www.mydigitalkemistry.com Join Digital Kemistry Academy, WhatsApp +92-3336753424 Page 3 (Point to Recall): Derivative: If we want to understand what the word "derivative" means, we must first understand that compounds containing only carbon and hydrogen are classified as "hydrocarbons," and those compounds can also be categorized as "organic" if at least one hydrogen atom is substituted with an atom other than carbon, such as an atom from the group O, S, N, or Cl. They are then referred to as hydrocarbon derivatives. Or Derivative of Hydrocarbon: Definition: The hydrocarbon which are composed of at least one electronegative element, such as an oxygen, sulphur, or nitrogen atom, or a halogen such as a fluorine, chlorine, iodine or a boron atom in place of hydrogen is called derivative of hydrocarbon. Chemical Diversity and Magnitude of Organic compounds: (Chemical Variety and Organic Compounds' Size)  In the periodic table, carbon is positioned in group four.  It follows that carbon has four electrons in its valence shell (as group number tells us number of valance electrons of an atom).  The octet of carbon is therefore incomplete, and as a result, carbon is unstable.  In greed of stability carbon will establish four covalent connections with other carbon atoms in order to complete its octet.  The fact that carbon, the building block of organic compounds, exhibits catenation property by creating four covalent connections with itself is the explanation for the vast variety of organic molecules. Catenation: Definition:  The name catenation can be defined as the carbon's capacity for self-linkage e.g. CH3-CH2-CH2-CH2-CH2-CH2-CH2-CH3  Because of this catenation feature, organic compounds are abundant and can be found in a wide variety of forms.  On the basis of its catenation property, no other element can rival carbon  While some other elements, such as Si, Se, and S (e.g., S8), are also capable of forming chains, their capacity is constrained because they can only do so with short chains  As opposed to carbon atoms, which may form extraordinarily long chains  There might be thousands of carbon atoms, even in a single chain
  • 4. Chemistry Tutorials  Digital Kemistry YouTube Chemistry Note  www.mydigitalkemistry.com Join Digital Kemistry Academy, WhatsApp +92-3336753424 Page 4  Isomerism is second in importance to catenation in explaining the diversity of carbon compounds Structural Formula: Definition: The term "structural formula" refers to a formula that depicts the location of atoms within a molecule. For instance, in the example below,  Two organic molecules with the same chemical formula, C2H6O, are shown.  However, because the atoms are arranged differently in each structure, their structural formulas differ.  These two structures are known as isomers of one another, for example Isomerism: Definition: The phenomenon of isomerism refers to organic compounds with the same molecular formula but a distinct structural formula as a result of a different atom arrangement inside molecules. Example 1: Explanation:  Keep an eye on the two chemical substances mentioned above  Their molecules share the same formula C4H10
  • 5. Chemistry Tutorials  Digital Kemistry YouTube Chemistry Note  www.mydigitalkemistry.com Join Digital Kemistry Academy, WhatsApp +92-3336753424 Page 5  Take note of how differently their structures are  The atoms' varied arrangements explain why the structures differ  The isomer of normal butane is hence iso-butane Example 2: Explanation:  The three compounds listed above each have a unique structure  Total the number of atoms in each molecule  Their chemical formula, which may be determined by counting atoms, is C5H12  Normal pentane's chemical composition is C5H12  As was said in the first example, a molecule's structure can vary depending on how its atoms are arranged  The isomers of normal pentane are the other two structures, such as iso-pentane and neo- pentane Note: The quantity of carbon atoms in a molecule determines how many isomers there are. There are more isomers as the carbon chain lengthens. Connection (bonds) with Other Atoms:  Carbon not only forms connections with other atoms but also with itself.  For instance, it may form double and triple bonds with its own atoms as well as with oxygen and nitrogen atoms e.g.  The creation of numerous bonds between carbon atoms and other atoms is the third major factor contributing to the diversity of organic molecules.  Approximately, there are over 20 million chemical compounds known, of which 95% are carbon molecules.
  • 6. Chemistry Tutorials  Digital Kemistry YouTube Chemistry Note  www.mydigitalkemistry.com Join Digital Kemistry Academy, WhatsApp +92-3336753424 Page 6 General Characteristics of Organic Compound (Organic compounds qualities): The following list of qualities for organic compounds: 1) Presence: Both living and non-living things have the means to produce organic compounds 2) Covalent Bond: Covalent bonds are the most frequent type of chemical connection made between organic substances (the bond formed by mutual sharing of electrons is called covalent bond) 3) Catenation:  Carbon, the cornerstone of organic molecules, has the ability to self-link  This potential for self-linking is regarded as the catenation property  Organic chemicals are widespread and come in lengthy chain forms because of this feature 4) Constituents: Although carbon serves as the foundation for organic molecules, additional elements such as H, S, N, O, F, Cl, Br, I, and P etc. are also present. 5) Melting and Boiling Points:  Covalent bonds hold organic components together.  We are aware that covalent bonds alone are insufficiently strong.  Therefore, most organic compounds are volatile and have low melting and boiling temperatures due to bond fragility.  Bond strength is strongly correlated with melting and boiling points.  The melting and boiling points will be higher the stronger the relationship.  Lower melting and boiling points correspond to weaker bonds. 6) Solubility:  The chemical components that make up the hydrocarbons are non-polar in nature.  The small difference in electronegativity between carbon and hydrogen atoms is what causes the non-polar nature.  In contrast, hydrocarbon derivatives are both polar and organic in nature.  The difference in electronegativity between carbon and other atoms, such as O, N, S, P, F, Cl, Br, and I, is what causes their polarity.  Non-polar organic compounds are soluble in non-polar solvents like benzene, ether, carbon disulphide, and carbon tetrachloride, according to the “like dissolves like” rule.  While polar solvents like methanol and ethanol are used to dissolve polar organic molecules.
  • 7. Chemistry Tutorials  Digital Kemistry YouTube Chemistry Note  www.mydigitalkemistry.com Join Digital Kemistry Academy, WhatsApp +92-3336753424 Page 7 7) Similarity in Behavior (Homology):  Organic substances behave remarkably identical to one another.  They can be conveniently studied in a series known as a homologous series due to their similar behavior.  Organic compounds are organized in this series in order of increasing one -CH2- group size.  If a compound has two -CH2- groups, the preceding compound will have three, the after four, and so on. 8) Rate of Reaction: Organic substances are less stable and have sluggish reaction rates because they have covalent bonds which are not so much strong in nature. Condensed Structural Formula: Definition: Condensed formula is the name given to the formula that uses shorthand to express each group in a chain. For instance, the first three homologous series members' structural formula is; Now, they can be represented as follows in the condensed structural formula: CH4 for Methane, CH3CH3 for Ethane, CH3CH2CH3 for Propane While they can be modelled as; in a molecular formula. CH4 for Methane, C2H6 for Ethane, C3H8 for Propane
  • 8. Chemistry Tutorials  Digital Kemistry YouTube Chemistry Note  www.mydigitalkemistry.com Join Digital Kemistry Academy, WhatsApp +92-3336753424 Page 8 Table displaying homologous series' condensed structural formulas: Name Molecular Formula Condensed Formula Methane CH4 CH4 Ethane C2H6 CH3CH3 Propane C3H8 CH3CH2CH3 Butane C4H10 CH3CH2CH2CH3 Pentane C5H12 CH3CH2CH2CH2CH3 Hexane C6H14 CH3CH2CH2CH2CH2CH3 Heptane C7H16 CH3CH2CH2CH2CH2CH2CH3 Octane C8H18 CH3CH2CH2CH2CH2CH2CH2CH3 Nonane C9H20 CH3CH2CH2CH2CH2CH2CH2CH2CH3 Decane C10H22 CH3CH2CH2CH2CH2CH2CH2CH2CH2CH3  There are millions of organic compounds in existence, and new ones are constantly being found.  Therefore, in order to analyze such a great number of compounds, they are divided into two primary groups.  One group segregates organic compounds based on their structure, while a second group distinguishes organic compounds based on functional groups. Classification of organic compounds: 1) On the basis of Structure 2) On the basis of Functional Group 1): On the basis of structure:  As the title implies, the organic compounds in this group differ from one another due to distinct orientations of carbon atoms in the molecules.  They are further divided into; a) Open Chain /Acyclic Organic Compounds b) Closed Chain / Cyclic Organic Compounds a): Open Chain/ Acyclic Organic Compounds:  The carbon atoms in these compounds are grouped in open chain form by covalent bonds, as the title implies.  Additionally, the chain of carbon atoms connected by a covalent bond might be straight or branched, for example.
  • 9. Chemistry Tutorials  Digital Kemistry YouTube Chemistry Note  www.mydigitalkemistry.com Join Digital Kemistry Academy, WhatsApp +92-3336753424 Page 9 b): Closed chain / Cyclic Compounds:  As the name suggests, these compounds' carbon atoms are ordered in closed-chain form, and the carbons are connected together by covalent bond.  Or we could say that the carbon atoms in these compounds are structured in cycle form, through covalent bond for example.  Another idea is that an organic compound is considered to be homo-cyclic if the ring exclusively contains carbon atoms.  As the term homo means "same," it follows that all of the carbon atoms in the ring are identical to one another, which is why it is called a homo-cyclic compound.  While hetero means "different" and means that there are not all carbon atoms in the ring  While the non-carbon atom is also present in the ring  In this way carbon and non-carbon atoms are not the same but different for each other  That's why called heterocyclic, if the ring contains one non-carbon atom e.g. N, O, S, Cl etc.
  • 10. Chemistry Tutorials  Digital Kemistry YouTube Chemistry Note  www.mydigitalkemistry.com Join Digital Kemistry Academy, WhatsApp +92-3336753424 Page 10 The homo-cyclic organic compounds are further divided into two which are given below: a) Alicyclic b) Aromatic a): Alicyclic organic compounds: The carbon atoms in these straightforward homo-cyclic compounds are joined by covalent bonds to form rings, for example
  • 11. Chemistry Tutorials  Digital Kemistry YouTube Chemistry Note  www.mydigitalkemistry.com Join Digital Kemistry Academy, WhatsApp +92-3336753424 Page 11 b): Aromatic organic compounds:  These compounds have one more attribute that distinguishes them from simple homo- cyclic organic compounds  This special property is known as aromaticity and denotes the fact that they have alternate single and double bonds between carbon atoms. 2): On the Basis of Functional group: What is functional group?  A functional group is a single atom or a collection of atoms that describes a compound's physical or chemical characteristics  Millions of chemical molecules can be studied sequentially thanks to functional groups  Due to this functional group, each family of organic compounds can be conveniently examined. On the basis of functional group organic compounds are classified as: 1) Hydrocarbons 2) Derivatives of Hydrocarbons
  • 12. Chemistry Tutorials  Digital Kemistry YouTube Chemistry Note  www.mydigitalkemistry.com Join Digital Kemistry Academy, WhatsApp +92-3336753424 Page 12 1): Hydrocarbons:  Since only carbon and hydrogen atoms are found in organic substances, hydrocarbons are known as such.  They could have a ring structure or an open chain structure. Alkanes:  Alkanes, also known as saturated hydrocarbons, are hydrocarbons in which all of the carbon atoms are connected by a single covalent bond, either in a straight chain structure or a ring shape.  There won't be any double or triple covalent bonds in saturated hydrocarbons, only single covalent bonds. Alkenes:  Alkenes, also known as "unsaturated hydrocarbons," are hydrocarbons in which at least two carbon atoms are connected together by a double covalent bond. Alkynes:  Alkynes, as well known as "unsaturated hydrocarbons" are hydrocarbons in which at least two carbon atoms are linked together by a triple covalent bond.
  • 13. Chemistry Tutorials  Digital Kemistry YouTube Chemistry Note  www.mydigitalkemistry.com Join Digital Kemistry Academy, WhatsApp +92-3336753424 Page 13 2): Derivatives of Hydrocarbons:  We can infer that hydrocarbons of any open-chain or close chain hydrocarbons in which at least one hydrogen atom has been substituted with a heteroatom, such as N, O, S, or Cl are called derivatives of hydrocarbons.  Methane is the first alkane in the homologous series (CH4).  A simple hydrocarbon is methane.  By substituting other atoms for its one hydrogen atom, such as OH, Cl, Br, NH2, and CN, we can create its derivatives.  For example CH4, CH3-OH, CH3-Cl, CH3-Br, CH3-NH2, CH3-CN etc. Derivatives of hydrocarbons are described in depth in the table below. According to their functional groups, organic compounds are categorized in the following table: Table of functional groups of organic compounds: Class of Compounds Functional Group/Name General Formula Example Alkane Single Bond CnH2n+2 Alkene Double Bond CnH2n Alkyne Triple Bond CnH2n-2 Alkyl Halide Halo (X may be F, Cl, Br, I) CnH2n+1 X Alcohol Hydroxyl CnH2n+1 OH Amine Amino CnH2n+1 NH2
  • 14. Chemistry Tutorials  Digital Kemistry YouTube Chemistry Note  www.mydigitalkemistry.com Join Digital Kemistry Academy, WhatsApp +92-3336753424 Page 14 Ether Oxygen (CnH2n+1)2 O Ketone Carbonyl (CnH2n+1)2 C O Aldehyde Formyl CnH2n+1 CHO Carboxylic Acid Carboxyl CnH2n+1COOH Acid Halide Acyl CnH2n+1COX Acid Amide Amide (CnH2n+1CONH2) Ester Ester (CnH2n+1COOCnH2n+1) Alkyl Cyanide/Nitrile Cyano CnH2n+1 CN Brief Detail of Functional Groups given in above Table: Alkanes:  Alkanes are hydrocarbons that include a single covalent bond holding two or more carbon atoms together or with a hydrogen atom in an open chain or close chain.  There won't be any double or triple covalent bonds in alkanes, only single covalent bonds  For example; CH4, CH3-CH3, CH3-CH2-CH2-CH3 etc.
  • 15. Chemistry Tutorials  Digital Kemistry YouTube Chemistry Note  www.mydigitalkemistry.com Join Digital Kemistry Academy, WhatsApp +92-3336753424 Page 15 Alkenes:  Alkenes are hydrocarbons that have at least two carbon atoms bound by a double covalent bond, either in a straight chain or a close chain  For example; CH2=CH2, CH3-CH=CH-CH3 etc. Alkynes: Alkynes are hydrocarbons that contain three triple covalent bonds connecting at least two carbon atoms e.g. Alkyl Halide:  Alkyl halides are hydrocarbons that have at least one hydrogen atom replaced to one of the halogen atoms F, Cl, Br, or I.  Halo functional group is present in them (-X)  For example; CH3-Cl, CH3-Br, CH3-F, CH3-I, CH3-CH2-CH2-Cl, CH3-CH2-CH2- F, CH3-CH2-CH2-CH2-CH2-Br etc. For understanding consider methyl chloride (CH3-Cl):  We are aware that carbon form four covalent connections (bonds) to attain stability.  This demonstrates how the carbon atom in chloromethane fulfils its valency by creating three covalent bonds with hydrogen atoms and one covalent bond with any halogen atom (replaced with hydrogen atom). Alcohol:  Alcohols are hydrocarbons that have at least one hydrogen atom replaced with an OH group.  They have a hydroxyl functional group (-OH).  For example; CH3-OH, CH3-CH2-OH, CH3-CH2-CH2-CH2-CH2-OH etc. are open chain alcohols.  Even though when –OH group is attached to benzene ring the it is called phenol e.g.
  • 16. Chemistry Tutorials  Digital Kemistry YouTube Chemistry Note  www.mydigitalkemistry.com Join Digital Kemistry Academy, WhatsApp +92-3336753424 Page 16 For understanding consider methanol (CH3-OH):  We are aware that the carbon atom forms four covalent connections (bonds) to attain stability.  In the case of open chain alcohols, the carbon atom in methanol is fulfilling its valency by creating three covalent bonds with hydrogen atoms and one covalent bond with the OH group (replaced with hydrogen atom).  While in phenol carbon number 1 making three covalent bonds with two more carbon atoms (carbon number 2 and 6) and one covalent bond with an OH group (replaced with hydrogen atom).  Therefore, like methanol phenol also fulfils its valency. Amines:  Amines are hydrocarbons that have at least one hydrogen atom replaced with an NH2 group.  The amino functional group is present (-NH2) in amines. .  For example CH3-NH2, CH3-CH2-NH2, CH3-CH2-CH2-CH2-CH2-NH2 etc. are open chain amines.  Even though aniline is an aromatic amine e.g.
  • 17. Chemistry Tutorials  Digital Kemistry YouTube Chemistry Note  www.mydigitalkemistry.com Join Digital Kemistry Academy, WhatsApp +92-3336753424 Page 17 For understanding consider methyl amine (CH3-NH2) and aniline:  We are aware that the carbon atom forms four covalent connections to attain stability.  In this example of an open chain amine, the carbon atom is fulfilling its valency by creating three covalent bonds with hydrogen atoms and one covalent bond with the NH2 group (replaced with hydrogen atom).  In aromatic amine, such as aniline, carbon number 1 additionally fulfils its valency by creating three covalent bonds with two other carbon atoms (carbon number 2 and 6), one covalent bond with the NH2 group (replaced with hydrogen atom). Ethers:  Ethers are hydrocarbons that have at least one hydrogen atom substituted with an O-R group.  The oxygen functional group is present (-O-) in ethers  For example; CH3-O-CH3, CH3-CH2-O-CH3, CH3-CH2-CH2-CH2-CH2-O-CH2-CH3 etc. For understanding consider dimethyl ether (CH3-O-CH3):  We are aware that the carbon atom forms four covalent connections to attain stability.  Here, we can observe that the left and right carbons in dimethyl ether are both satisfying the valency of the compound by creating three covalent bonds with hydrogen atoms and one covalent bond with an oxygen atom (replaced with hydrogen atom). Ketones:  Ketones are derivatives of hydrocarbons that include a carbonyl functional group (-CO-), which replaces at least one hydrogen atom in the hydrocarbon.  Two alkyl groups are affixed to the carbonyl carbon in ketone molecules.  For example; CH3-CO-CH3, CH3-CH2-CO-CH3, CH3-CH2-CH2-CH2-CH2-CO-CH3 etc. Aldehydes:  Aldehydes are derivatives of hydrocarbons that have at least one hydrogen atom removed in favor of a carbonyl functional group (-COH).
  • 18. Chemistry Tutorials  Digital Kemistry YouTube Chemistry Note  www.mydigitalkemistry.com Join Digital Kemistry Academy, WhatsApp +92-3336753424 Page 18  Aldehydes are compounds made of carbonyl carbon and one or two hydrogen atoms attached to that carbonyl carbon atom  For example; H-CO-H, CH3-CO-H, CH3-CH2-CO-H, CH3-CH2-CH2-CH2-CH2- CO-H etc. Carboxylic acids:  Carboxylic acids are derivatives of hydrocarbons that have a carboxyl functional group in place of at least one hydrogen atom, also known as the -COOH group  For example; CH3-CO-OH, CH3-CH2-CO-OH, CH3-CH2-CH2-CH2-CH2-CO-OH etc. Acid Halides:  Acid halides are derivatives of hydrocarbons that have an acyl group (-CO-X) with at least one hydrogen atom substituted by a COX group  For example; CH3-CO-Cl, CH3-CH2-CO-Br, CH3-CH2-CH2-CH2-CH2-CO-Cl etc. Acid Amides:  Acid amides are derivatives of hydrocarbons that have at least one hydrogen atom replaced with a CO-NH2 group.  The amide functional group (-CO-NH2) is present in acid amides  For example; CH3-CO-NH2, CH3-CH2-CO-NH2, CH3-CH2-CH2-CH2-CH2-CO-NH2 etc. Esters:  Esters are derivatives of hydrocarbons that have at least one hydrogen atom replaced with a COOR group.  They have ester functional group (-COOR) in them  For example; CH3-CO-OCH3, CH3-CH2-CO-OCH3, CH3-CH2-CH2-CH2-CH2-CO- OCH3 etc. Alkyl Cyanide:  Alkyl cyanides are hydrocarbons that have at least one hydrogen atom substituted with a CN group.  They have “cyano” functional group (-CN) in them
  • 19. Chemistry Tutorials  Digital Kemistry YouTube Chemistry Note  www.mydigitalkemistry.com Join Digital Kemistry Academy, WhatsApp +92-3336753424 Page 19  For example; CH3-CN, CH3-CH2-CN, CH3-CH2-CH2-CH2-CH2-CN etc. Alkane and Alkyl Radicals: Alkane:  Alkanes are hydrocarbons that include a single covalent bond holding two or more carbon atoms together or to a hydrogen atom in an open chain or close chain, as was previously explained.  There won't be any double or triple covalent bonds in alkanes, only single covalent bonds. e.g. Alkyl Radical:  When one hydrogen atom is removed from alkane then it results in the formation of alkyl radical  For example; Methane produces methyl (radical) when one hydrogen atom removed from it  Ethane produces ethyl (radical) when one hydrogen atom removed from it  Propane produces propyl (radical) when one hydrogen atom is removed from it, and so on.
  • 20. Chemistry Tutorials  Digital Kemistry YouTube Chemistry Note  www.mydigitalkemistry.com Join Digital Kemistry Academy, WhatsApp +92-3336753424 Page 20 For example: Method to convert alkane into alkyl radical:  Compose the alkane’s member condensed formula  Dehydrogenate the compound by removing one hydrogen  Change the ending -ane in the alkane to -yl to give the radical a name  By removing hydrogen atom from the terminal carbon atom. Normal alkyl (radical) will be produced e.g.  By removing hydrogen atom from the second last carbon atom. Iso-alkyl (radical) will be produced e.g. Naming Alkanes:  A naming scheme for each class of hydrocarbons and its derivatives was developed by the International Union of Pure and Applied Chemistry (IUPAC).  Here, we shall comprehend the guidelines needed to provide alkanes names.  The number of carbon atoms in an alkane chain determines the name of the compound.  The IUPAC name has two components. i) Prefix ii) Suffix
  • 21. Chemistry Tutorials  Digital Kemistry YouTube Chemistry Note  www.mydigitalkemistry.com Join Digital Kemistry Academy, WhatsApp +92-3336753424 Page 21 Prefix:  It refers to how many carbon atoms there are in an alkane chain.  The prefixes are shown in the table below according to how many carbon atoms are in an alkane chain. Prefix Number of Carbon atoms Meth- 1 Eth- 2 Prop- 3 But- 4 Pent- 5 Hex- 6 Hept- 7 Oct- 8 Non- 9 Dec- 10 Suffix: It identifies the hydrocarbon class. The prefix "ane" is used with alkanes. Example 1: Consequently, if a compound contains just one carbon atom. Then, how will we name this compound in accordance with IUPAC rules? Solution:  Verify the prefix in the table above for one carbon atom  Prefix for one carbon atom is Meth-  Verify each bond in a compound  When the compounds only have one type of covalent bond (single covalent bond). Consequently, the chemical is an alkane  The alkane family's suffix is "ane"  We'll write the prefix first, then the suffix  Therefore, the IUPAC name of the compound will be Methane
  • 22. Chemistry Tutorials  Digital Kemistry YouTube Chemistry Note  www.mydigitalkemistry.com Join Digital Kemistry Academy, WhatsApp +92-3336753424 Page 22 Example 2: If a substance contains four carbon atoms. Then, how will we name this compound in accordance with IUPAC rules? CH3-CH2-CH2-CH3 Solution:  Verify the prefix in the table above for four carbon atom  Prefix for four carbon atom is But-  Verify each bond in a compound  When the compounds only have one type of covalent bond (single covalent bond). Consequently, the chemical is an alkane  The alkane family's suffix is "ane"  We'll write the prefix first, then the suffix  Therefore, the IUPAC name of the compound will be butane Example 3: If a substance contains five carbon atoms. Then, how will we name this compound in accordance with IUPAC rules? CH3-CH2-CH2-CH2-CH3 Solution:  Verify the prefix in the table above for five carbon atom  Prefix for five carbon atom is pent-  Verify each bond in a compound  When the compounds only have one type of covalent bond (single covalent bond). Consequently, the chemical is an alkane  The alkane family's suffix is "ane"  We'll write the prefix first, then the suffix  Therefore, the IUPAC name of the compound will be pentane Organic Compounds' Sources:  There are two primary sources of alkanes for commercial use. i) One from Natural Sources ii) And the other from man-made ones (artificial sources).  Coal, natural gas, petroleum, and living things are examples of natural resources.  While researchers' laboratory production of organic chemicals is the artificial source.
  • 23. Chemistry Tutorials  Digital Kemistry YouTube Chemistry Note  www.mydigitalkemistry.com Join Digital Kemistry Academy, WhatsApp +92-3336753424 Page 23 Coal:  The rich trove of organic chemicals is coal.  Another name for it is solid fuel.  Because it is solid and used as fuel.  Coal is dark in color Destructive Distillation: High temperature heating of coal produces coal gas, coal tar, and coke when oxygen is not present. And the term used for this procedure is coal destructive distillation. Coal gas:  It's not just one gas, but several.  However, it contains a combination of gases, including methane, hydrogen, and carbon monoxide.  Industrial uses of coal gas include fuel. Coal Tar:  The wealth of organic molecules in coal tar is astounding.  However, it does include benzene and its derivatives.  Fractional distillation is a process that can be used to extract benzene and its compounds from coal tar.  The residue left behind after fractional distillation, which separates useful chemicals like benzene and its derivatives from coal tar, is also beneficial.  Pitch, the name of this residue, is used to make metal roadways and building roofs.  The manufacture of plastics, dyes, textiles, pharmaceuticals, paints, and varnishes, among other things, uses benzene and its derivatives, which are quite helpful. Fractional Distillation: Fractional distillation is the process of separating components of a solution based on the differences in their boiling points. Natural Gas:  Natural gas is not just one type of gas.  It is a concoction of gases.  Methane, ethane, propane, and butane are just a few of the low-boiling hydrocarbons that it contains.  Methane, however, makes up a much larger portion of the mixture than the other gases do.
  • 24. Chemistry Tutorials  Digital Kemistry YouTube Chemistry Note  www.mydigitalkemistry.com Join Digital Kemistry Academy, WhatsApp +92-3336753424 Page 24 Petroleum:  The Latin words petra, which means "rock," and oleum, which means "oil," combine to form the English word petroleum.  Thus, petroleum refers to rock oil as it is known to exist underground.  Dark brown in color, petroleum has a foul odour.  Petroleum is a mixture of several hydrocarbons.  However, it's a blend of long chain hydrocarbons.  It contains aromatic hydrocarbons, cycloalkanes, and alkanes.  Additionally, there are minor amounts of S, O, and N, Ni, Cu, and V in petroleum. Living Organisms:  The primary source of organic molecules is living things.  Due to the fact that both medications and carbohydrates are derived from plants (living organisms).  Animals (living beings) provide us with organic components like proteins and lipids. Artificial Source (men made): Laboratory:  According to the records, mankind have created probably 10 million or more organic molecules in laboratories.  And the organic compounds that these men created are extremely beneficial and are sold as medicines for the treatment of fatal diseases like cancer, HIV, tuberculosis, and others.  Additionally, while producing dyes, plastics, paints, cosmetics, detergents, and fertilizers, along with other things. Uses of Organic Compounds: 1) As a Fuel:  Natural gas, petroleum, and coal are examples of organic fuels that can be burned to generate heat.  The gases that can be made from natural gas are propane and butane.  Additionally, these gases are employed in fuel cylinders as a liquid. 2) As a raw material for the synthesis of organic products:  Coal, natural gas, petroleum are used a raw material for the synthesis of organic compounds.  Ethylene is used as raw material for the synthesis of plastic (polyethylene), alcohol (ethanol), Carboxylic acid (acetic acid), and antifreeze (ethylene glycol).
  • 25. Chemistry Tutorials  Digital Kemistry YouTube Chemistry Note  www.mydigitalkemistry.com Join Digital Kemistry Academy, WhatsApp +92-3336753424 Page 25  For the production of soap, medicines, cosmetics, detergents, emulsions, and other organic products, numerous different organic compounds are employed as raw ingredients. 3) Synthesis of polymers: Acetylene is utilized as a starting ingredient in the manufacture of polymers like nylon, rubber, and polyvinyl chloride (PVC). 4) For welding and cutting of metals: Metals are chopped and joined together using an oxygen-acetylene flame. 5) For artificial ripening of food: Artificial food ripening is accomplished using acetylene. 6) As an Antiseptic: Hospitals utilize phenol as an antiseptic. 7) As a Solvent: Methanol and ethanol are utilized in several reactions as well as solvents for fats, oils, paints and varnishes.