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Ch. 20 Notes -- Acids and Bases
What makes something an acid?
Acid Properties:
            sour          lemons
(1) tastes _______-- _______________
                  metals
(2) corrosive to _________




                H+ ] (or [ _____ ] = “_______________” ions)
(3) contains [ ___         H3O+          hydronium
               H+       donor
(4) proton ([ ___ ]) __________-- Brønsted-Lowry Theory
                                             H3O+
                                     Cl− + ______
        Example: HCl + H2O  ______
Examples of Common Acids:
•             citrus            aspirin
    Pepsi, _________ juices, ___________, stomach acid, battery
              vinegar     DNA
    acid, _____________, ______
Acid Vocabulary
•   monoprotic acid- contains ____ [H+] ion in its formula
                               1
                    HCl       HNO3
       Examples: _______ , ________
•                             2
    diprotic acid- contains _____ [H+] ions in its formula
                     H2SO4 H2CO3
        Examples: _______ , ________
•                              3
    triprotic acid- contains _____ [H+] ions in its formula
                      H3PO4 H3BO3
        Examples: _______ , ________
•                           dissociate            many
    strong acid - readily ___________ to produce ______ [H+] ions in
    water
                          HCl
        Examples: _________, HNO , _______H2SO4
                                       3

                              small
•   weak acid - produces a __________ amount of [H+] ions when in
    water
                                        H2CO3 lemon juice
        Examples: HC H O (vinegar) , _________, _________
                       2   3   2
Strong Acids vs. Weak Acids
Indicators
•   An indicator is a chemical that will change ___________ when
                                                    colors
    placed in an acidic, basic or neutral environment.
                       Indicator Colors For Acids
•                     red
    litmus paper = _______
•                         clear
    phenolphthalein = ___________
•   red cabbage juice (universal indicator) = ________
                                                 red
•                      red
    methyl orange = _______
pH Paper : Indicator Colors


Neutral




                        Acidic

  Basic
Properties of Bases
What make something a base?
Base Properties: (…the opposite of acid properties)
             bitter        banana
(1) tastes ________ -- ___________ peel ,
   parsley, dark chocolate




              slippery       soap
(2) feels _____________ -- ________
                OH−
(3) contains [ _____ ] ions
                     acceptor
(4) proton ([H+]) ______________-- Brønsted-Lowry Theory
        Example: NH + H O  ______ NH4+ + _______
                                              OH−
                      3       2
Indicator Colors for Bases
•   litmus paper = _______
                     blue
•                      yellow
    methyl orange = ____________
•                                              blue
    red cabbage juice (universal indicator) =________
•   phenolphthalein = ______
                       pink



phenolphthalein




          Acid                                          Base
Common Bases
•                                                      ammonia
     Examples of Common Bases: milk of magnesia, ___________,
    drain cleaner, soap, blood, ____________ tablets, ___________
                                    antacid              baking
       soda
    ________.
Strong Bases vs. Weak Bases
•   strong base- readily __________ to produce ______ [OH−] ions in
                          dissociate            many
    water
        Examples:             KOH
                     NaOH , ________
•                            small
    weak base- produces a __________ amount of [OH−] ions when in
    water
                    NH3
        Examples: _____ (ammonia); Mg(OH) (milk of magnesia)
                                                2


                          Other Vocabulary
•       Alkaline
    _______________- another term for basic solutions
      Amphoteric
•   _______________- a substance that can act as both an acid and a base
                      H2O           HCO3−
        Examples: ___________ , ____________
Conjugate Acid-Base Pairs

•    Conjugate ______- substance formed when a _______ gains a
                Acid                             base
    [H+] ion.
•               Base                             acid
     Conjugate ______- substance formed when an ______ loses a
    [H+] ion.
•    Practice Problems: Label the acid & base on the left side of the
    reaction and the conjugate acid & conjugate base on the right side.
                a) HCl + H2O  H3O+ + Cl−
                   acid
                  ______  base   C.A.   C.B.
                         ______ ______ ______

                b) NH3 + H2O  NH4+ + OH−
                   base
                  _____  acid   C.A.   C.B.
                        ______ ______ ______
Self-Ionization of Water
•   Pure water is _____________. It can ionize itself to form OH− and
                      neutral
    H3O+ ions in __________ amounts.
                     small
                     H2O +    H2O  H3O+ + OH−
                                    H+
                 (or H2O  _______ + _______   OH− )
                                        green
•   The universal indicator color is ___________ in neutral solutions.




                         self-ionization of water
Measuring the Amount of H+ and OH− Ions in a Solution
•   _____ Scale- measures the _____________ of [H+] ions in a solution
      pH                        concentration
•    pOH                                         OH−
    _____ Scale- measures the concentration of [ ____ ] ions in a solution
                                  Formulas
              pH = − (log [H+])          pOH = −(log [OH−])
                 [H+] = 10−pH             [OH−] = 10−pOH
             [H+] x [OH−] = 1 x 10−14        pH + pOH = 14
•   With the pH scale, we have another way to define acids and bases:
                                      below
                    Acids have a pH _________7.0
                                      above
                    Bases have a pH _________7.0
                                        =
                            Neutral pH ___7.0
Practice Problems:
1)   a) Calculate the pH of a 0.001 M HCl solution
       [H+] = 0.001 M     So…pH = − (log 0.001 M)         pH = 3
     b) What is the pOH of this solution?
        pH + pOH = 14       So…14 − 3 = pOH          pOH = 11
     c) What is the concentration of [OH−] ions in the solution?
         [OH−] = 10−pOH      [OH−] = 10−11 Molar or 1 x 10−11 M

2)   a) Calculate the pOH of a NaOH solution that has a pH of 8.50
     pH + pOH = 14       So…14 − 8.5 = pOH        pOH = 5.5

     b) What is the [OH−] of this solution?
      [OH−] = 10−pOH     [OH−] = 10−5.5 Molar or 3.16 x 10−6 M
     c) What is the concentration of [H+] ions in the solution?
           [H+] = 10−pH [H+] = 10−8.5 Molar or 3.16 x 10−9 M
Ch. 21 Notes -- Neutralization
                        Neutralization Reactions
•                                                             salt
     When an acid and base are mixed, the reaction produces _______
           water
    and ___________.
•    If the initial concentrations and volumes of the reactants are equal,
                               neutral
    the products will be ____________... (pH= 7.0)
•                                        double
     All neutralization reactions are ___________ replacement
    reactions.
                  HX + M(OH)  ______ + ______
                                       MX        H2O
                                     (“Salt”)
Titration
•   Mixing an acid with a base to
    determine a __________________
                       concentration
    is called “titration.”
•    An ____________ is used to
            indicator
    determine when neutralization has
    occurred.
•        Standard
    ________________ Solution - the
    solution of known concentration
•     End      Point
    ______ _________ - the point of
    neutralization when titrating
•            end
    At the ______ point, the moles of
    [H+] ions = moles of [OH−] ions.
Practice Problems:
(1) Complete the following neutralization reactions.
       HNO3 (aq) +                       KNO3          H2O
                         KOH (aq)  _________ + __________
     2 HCl                                CaCl2
                                           +2 −1
                                                       2H2O
             (aq)   +   Ca(OH)2 (aq)  __________ + ___________
(2) How many moles of Ca(OH)2 will it take to neutralize 0.5 moles of
   HCl?
   0.5 moles HCl x 1 mole Ca(OH)2 = 0.25 moles of Ca(OH)2
                    2 moles HCl


3) How many moles of HNO3 will it take to neutralize 3.0 moles of
   KOH?
   3.0 moles KOH x 1 mole HNO3      =      3.0 moles of HNO3
                    1 mole KOH
Determining the Concentration of an Acid (or Base) by Titration
                    (Macid)x(Vacid) = (Mbase)x(Vbase)
Practice Problems:
•    A 25 mL solution of HNO3 is neutralized by 18 mL of 1.0 M
     NaOH standard solution using phenolphthalein as an indicator.
     What is the concentration of the HNO3 solution?
          ( Macid ) x ( 25 mL ) = ( 1.0 M ) x (18 mL )
                          Macid = 0.72 Molar

(2) How many mL of 2.0 M KOH will it take to neutralize 55 mL of
    a 0.76 M HCl standard solution?
         (0.76 M ) x ( 55 mL ) = ( 2.0 M ) x ( Vbase )

                            Vbase = 20.9 mL

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Ch. 20 & 21 notes (acids & bases) teacher

  • 1. Ch. 20 Notes -- Acids and Bases What makes something an acid? Acid Properties: sour lemons (1) tastes _______-- _______________ metals (2) corrosive to _________ H+ ] (or [ _____ ] = “_______________” ions) (3) contains [ ___ H3O+ hydronium H+ donor (4) proton ([ ___ ]) __________-- Brønsted-Lowry Theory H3O+ Cl− + ______ Example: HCl + H2O  ______
  • 2. Examples of Common Acids: • citrus aspirin Pepsi, _________ juices, ___________, stomach acid, battery vinegar DNA acid, _____________, ______
  • 3. Acid Vocabulary • monoprotic acid- contains ____ [H+] ion in its formula 1 HCl HNO3 Examples: _______ , ________ • 2 diprotic acid- contains _____ [H+] ions in its formula H2SO4 H2CO3 Examples: _______ , ________ • 3 triprotic acid- contains _____ [H+] ions in its formula H3PO4 H3BO3 Examples: _______ , ________ • dissociate many strong acid - readily ___________ to produce ______ [H+] ions in water HCl Examples: _________, HNO , _______H2SO4 3 small • weak acid - produces a __________ amount of [H+] ions when in water H2CO3 lemon juice Examples: HC H O (vinegar) , _________, _________ 2 3 2
  • 4. Strong Acids vs. Weak Acids
  • 5. Indicators • An indicator is a chemical that will change ___________ when colors placed in an acidic, basic or neutral environment. Indicator Colors For Acids • red litmus paper = _______ • clear phenolphthalein = ___________ • red cabbage juice (universal indicator) = ________ red • red methyl orange = _______
  • 6. pH Paper : Indicator Colors Neutral Acidic Basic
  • 7. Properties of Bases What make something a base? Base Properties: (…the opposite of acid properties) bitter banana (1) tastes ________ -- ___________ peel , parsley, dark chocolate slippery soap (2) feels _____________ -- ________ OH− (3) contains [ _____ ] ions acceptor (4) proton ([H+]) ______________-- Brønsted-Lowry Theory Example: NH + H O  ______ NH4+ + _______ OH− 3 2
  • 8. Indicator Colors for Bases • litmus paper = _______ blue • yellow methyl orange = ____________ • blue red cabbage juice (universal indicator) =________ • phenolphthalein = ______ pink phenolphthalein Acid Base
  • 9. Common Bases • ammonia Examples of Common Bases: milk of magnesia, ___________, drain cleaner, soap, blood, ____________ tablets, ___________ antacid baking soda ________.
  • 10. Strong Bases vs. Weak Bases • strong base- readily __________ to produce ______ [OH−] ions in dissociate many water Examples: KOH NaOH , ________ • small weak base- produces a __________ amount of [OH−] ions when in water NH3 Examples: _____ (ammonia); Mg(OH) (milk of magnesia) 2 Other Vocabulary • Alkaline _______________- another term for basic solutions Amphoteric • _______________- a substance that can act as both an acid and a base H2O HCO3− Examples: ___________ , ____________
  • 11. Conjugate Acid-Base Pairs • Conjugate ______- substance formed when a _______ gains a Acid base [H+] ion. • Base acid Conjugate ______- substance formed when an ______ loses a [H+] ion. • Practice Problems: Label the acid & base on the left side of the reaction and the conjugate acid & conjugate base on the right side. a) HCl + H2O  H3O+ + Cl− acid ______ base C.A. C.B. ______ ______ ______ b) NH3 + H2O  NH4+ + OH− base _____ acid C.A. C.B. ______ ______ ______
  • 12. Self-Ionization of Water • Pure water is _____________. It can ionize itself to form OH− and neutral H3O+ ions in __________ amounts. small H2O + H2O  H3O+ + OH− H+ (or H2O  _______ + _______ OH− ) green • The universal indicator color is ___________ in neutral solutions. self-ionization of water
  • 13. Measuring the Amount of H+ and OH− Ions in a Solution • _____ Scale- measures the _____________ of [H+] ions in a solution pH concentration • pOH OH− _____ Scale- measures the concentration of [ ____ ] ions in a solution Formulas pH = − (log [H+]) pOH = −(log [OH−]) [H+] = 10−pH [OH−] = 10−pOH [H+] x [OH−] = 1 x 10−14 pH + pOH = 14 • With the pH scale, we have another way to define acids and bases: below Acids have a pH _________7.0 above Bases have a pH _________7.0 = Neutral pH ___7.0
  • 14.
  • 15.
  • 16.
  • 17. Practice Problems: 1) a) Calculate the pH of a 0.001 M HCl solution [H+] = 0.001 M So…pH = − (log 0.001 M) pH = 3 b) What is the pOH of this solution? pH + pOH = 14 So…14 − 3 = pOH pOH = 11 c) What is the concentration of [OH−] ions in the solution? [OH−] = 10−pOH [OH−] = 10−11 Molar or 1 x 10−11 M 2) a) Calculate the pOH of a NaOH solution that has a pH of 8.50 pH + pOH = 14 So…14 − 8.5 = pOH pOH = 5.5 b) What is the [OH−] of this solution? [OH−] = 10−pOH [OH−] = 10−5.5 Molar or 3.16 x 10−6 M c) What is the concentration of [H+] ions in the solution? [H+] = 10−pH [H+] = 10−8.5 Molar or 3.16 x 10−9 M
  • 18. Ch. 21 Notes -- Neutralization Neutralization Reactions • salt When an acid and base are mixed, the reaction produces _______ water and ___________. • If the initial concentrations and volumes of the reactants are equal, neutral the products will be ____________... (pH= 7.0) • double All neutralization reactions are ___________ replacement reactions. HX + M(OH)  ______ + ______ MX H2O (“Salt”)
  • 19. Titration • Mixing an acid with a base to determine a __________________ concentration is called “titration.” • An ____________ is used to indicator determine when neutralization has occurred. • Standard ________________ Solution - the solution of known concentration • End Point ______ _________ - the point of neutralization when titrating • end At the ______ point, the moles of [H+] ions = moles of [OH−] ions.
  • 20. Practice Problems: (1) Complete the following neutralization reactions. HNO3 (aq) + KNO3 H2O KOH (aq)  _________ + __________ 2 HCl CaCl2 +2 −1 2H2O (aq) + Ca(OH)2 (aq)  __________ + ___________ (2) How many moles of Ca(OH)2 will it take to neutralize 0.5 moles of HCl? 0.5 moles HCl x 1 mole Ca(OH)2 = 0.25 moles of Ca(OH)2 2 moles HCl 3) How many moles of HNO3 will it take to neutralize 3.0 moles of KOH? 3.0 moles KOH x 1 mole HNO3 = 3.0 moles of HNO3 1 mole KOH
  • 21. Determining the Concentration of an Acid (or Base) by Titration (Macid)x(Vacid) = (Mbase)x(Vbase) Practice Problems: • A 25 mL solution of HNO3 is neutralized by 18 mL of 1.0 M NaOH standard solution using phenolphthalein as an indicator. What is the concentration of the HNO3 solution? ( Macid ) x ( 25 mL ) = ( 1.0 M ) x (18 mL ) Macid = 0.72 Molar (2) How many mL of 2.0 M KOH will it take to neutralize 55 mL of a 0.76 M HCl standard solution? (0.76 M ) x ( 55 mL ) = ( 2.0 M ) x ( Vbase ) Vbase = 20.9 mL