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BIOMATERIA
LS
Iqna Qisthiya, ST., M.Eng.
AGENDA
 Bioplastic
 Biometal
 QUIZ
2023 Univweritas Brawijaya 2
BIOPLASTIC
2023 Univweritas Brawijaya 3
DEFINITION OF BIOPLASTIC
2023 Univweritas Brawijaya 4
• Plastic that can be used like conventional plastic but will be
destroyed by the activity of microorganisms into the final
product of water and carbon dioxide gas after it is used up
and thrown into the environment.
Pranamuda (2001)
• A material under certain conditions, at a certain time
experiences changes in its chemical structure, which
affects its properties due to the influence of
microorganisms (bacteria, fungi, algae).
Griffin (1994)
• A polymer material that converts to low molecular weight
compounds where at least one step in the degradation
process occurs through natural organism metabolism.
Seals (1994)
• Environmentally friendly plastic, can be decomposed by the
activity of microorganisms, some or almost all of its
components come from renewable raw materials.
Agustin and
Padmawijaya (2016)
BIOPLASTIC
2023 Univweritas Brawijaya 5
Bioplastics are plastic
that made wholly or in
part from renewable
biomass sources.
Some bioplastics are
biodegradable or even
compostable.
Widely used :
• Food packaging,
• agriculture and horticulture,
• composting bags and
hygiene
• biomedical,
• structural,
• electrical
• other products
BIOPLASTIC BASED ON THEIR
RESOURCES
POLYSACHARRID
ES
Biodegradable
plastic from cassava
starch
 Biodegradable
plastic from potato
Biodegradable
plastic from corn
PROTEIN
Biodegradable plastic
from what gluten
BIOTECHNOLOGIC
AL INVENTIONS
Polylactic acid (PLA)
Polyhydroxyalkanoate
(PHA)
Polyhydroxybutirate
(PHB)
PETROCHEMICAL
Polycaprolactone
Polyvinyl Alcohol
(PVOH)
Polycaprolactone
2023 Univweritas Brawijaya 6
BIOPLASTIC BASED ON THEIR
RESOURCES
• Have higher biodegradability, renewability and good oxygen barrier
• Based on starch
• Higher amylose content can strengthen film
• Amylopectin cause low mechanical properties
• Can be improved by using plasticizers (sorbitol and glycerol)
POLYSACHARRIDES
• Functional properties depends on structural heterogeneity, thermal sensitivity and
hydrophilic behaviour of proteins
• Can used proteins from vegetable and animal sources
PROTEIN
2023 Univweritas Brawijaya 7
BIOPLASTIC BASED ON THEIR
RESOURCES
• Converting plants sugar into plastic
• Producing plastic inside microorganism
• Growing plastic in corn and other crops
• Producing by using fermentation process of microorganism
BIOTECHNOLOGICAL INVENTIONS
• Made from synthetic source (petroleum)
PETROCHEMICAL
2023 Univweritas Brawijaya 8
BIOPLASTIC COMPONENTS
Hydrocolloid Proteins (casein, soy protein, wheat gluten) and carbohydrates (starch, gum )
very good for use as an inhibitor of the transfer of oxygen, carbon dioxide &
fat
Very good at improving the structure of the film so that it is not easily
destroyed
Lipids wax, fatty acids, monoglycerides and resin
as a water vapor barrier, or a coating agent to increase the shine of candy
products
limited because it produces poor film structural strength
Composite lipid and hydrocolloid components
increasing resistance to water evaporation and hydrocolloids themselves can
provide durability
2023 Univweritas Brawijaya 9
MECHANICAL PROPERTIES
Elongation (Percent
Elongation)
• the length of the film when it is pulled until it breaks
• related to the elasticity of the film
• The greater the elongation value of the film, the more
elastic it is and the better the plastic
Tensile Strength
• the maximum pull that can be achieved until the film
remains in place before breaking/tearing
• determine the amount of force required to achieve
maximum tension in each area of the film
• Depends on the concentration and type of material
making up the film, especially the structural cohesion
properties.
2023 Univweritas Brawijaya 10
BIOMETAL
• The periodic table showing the metals (blue), non-metals (green) and intermediate (orange)
elements.
• Metals are good conductors of heat and electricity, opaque to visible light, and have a familiar
metallic lustre.
2023 Univweritas Brawijaya 12
BIOMETAL
 Metallic materials are normally combinations of
metallic elements.
 Have large numbers of nonlocalized electrons
not bound to particular atoms  properties of
metals
 Metal can be formed and machined easily 
usually are long-lasting materials.
 Metal do not react easily with other elements.
 Metals such as iron and aluminum can form compounds
readily (such as ores) so they must be processed to
extract base metals.
 Can react with chemicals in the environment such
as iron and oxygen that form iron-oxide.
2023 Univweritas Brawijaya 13
• One model of a metal, positive ions are surrounded by a sea or cloud of electrons.
• ‘free electrons’ are not bound to any particular metal ion but are free to move around within the
structure.
• It is these ‘free electrons’ that result in some of the typical properties of a metal including the good
conductance of heat and electricity, and the metallic lustre of a polished surface.
2023 Univweritas Brawijaya 14
PROPERTIES OF METALS
 Atoms arranged in a regular repeating structure
 Relatively good strength
 Dense
 Malleable or ductile (high plasticity)
 Resistant to fracture (tough)
 Excellent conductors of electricity and heat
 Opaque to visible light
 Shiny appearance
2023 Univweritas Brawijaya 15
PROPERTIES OF SOME METALS AND
ALLOYS
2023 Univweritas Brawijaya 16
BIOMATERIAL BIOMETAL
• Metal and metal alloys are used for medical requirements include :
• stainless steel (316L),
• titanium and alloys (Cp-'Ti, 'TiGAI4V),
• cobalt chromium alloys (CoCr),
• aluminium alloys,
• zirconium,
• niobium,
• tungsten heavy alloys.
2023 Univweritas Brawijaya 17
BIOMETAL APPLICATIONS
• dental implants,
• craniofacial plates and screws;
• parts of artificial hearts, pacemakers,
• clips, valves, balloon catheters,
• medical devices and equipment;
• bone fixation devices,
• dental materials,
• medical radiation shielding products,
• prosthetic and orthodontic devices
2023 Univweritas Brawijaya 18
THE MAIN CRITERIA IN SELECTION OF
METAL-BASED MATERIALS
• The main criteria in selection of metal-based materials for biomedical applications
• their excellent biocompatibility,
• convenient mechanical properties,
• good corrosion resistance, and
• low cost.
• In comparison to polymers,
• metals have higher ultimate tensile strength and elastic modulus
• lower strains at failure
• In comparison to ceramics
• metals have lower strengths and elastic modulus
• higher strains to failure
2023 Univweritas Brawijaya 19
QUIZ
BIOMATERIAL
2023 Univweritas Brawijaya 20
01
Explain definition of biocompatibility in
biomaterial!
2023 Univweritas Brawijaya 21
02
Write & explain the conditions for a
material to be said to be biocompatible!
(minimum 2)
2023 Univweritas Brawijaya 22
03
What do you know about cytotoxicity
testing?
2023 Univweritas Brawijaya 23
04
Mention 2 mechanical properties (tests)
found in bioplastics!
2023 Univweritas Brawijaya 24
05
Mention the applications that can be
applied in the medical field using
biometals! (minimum 3)
2023 Univweritas Brawijaya 25
THANK YOU
2023 Univweritas Brawijaya 26

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Bioplastic file presentation test (1).pptx

  • 2. AGENDA  Bioplastic  Biometal  QUIZ 2023 Univweritas Brawijaya 2
  • 4. DEFINITION OF BIOPLASTIC 2023 Univweritas Brawijaya 4 • Plastic that can be used like conventional plastic but will be destroyed by the activity of microorganisms into the final product of water and carbon dioxide gas after it is used up and thrown into the environment. Pranamuda (2001) • A material under certain conditions, at a certain time experiences changes in its chemical structure, which affects its properties due to the influence of microorganisms (bacteria, fungi, algae). Griffin (1994) • A polymer material that converts to low molecular weight compounds where at least one step in the degradation process occurs through natural organism metabolism. Seals (1994) • Environmentally friendly plastic, can be decomposed by the activity of microorganisms, some or almost all of its components come from renewable raw materials. Agustin and Padmawijaya (2016)
  • 5. BIOPLASTIC 2023 Univweritas Brawijaya 5 Bioplastics are plastic that made wholly or in part from renewable biomass sources. Some bioplastics are biodegradable or even compostable. Widely used : • Food packaging, • agriculture and horticulture, • composting bags and hygiene • biomedical, • structural, • electrical • other products
  • 6. BIOPLASTIC BASED ON THEIR RESOURCES POLYSACHARRID ES Biodegradable plastic from cassava starch  Biodegradable plastic from potato Biodegradable plastic from corn PROTEIN Biodegradable plastic from what gluten BIOTECHNOLOGIC AL INVENTIONS Polylactic acid (PLA) Polyhydroxyalkanoate (PHA) Polyhydroxybutirate (PHB) PETROCHEMICAL Polycaprolactone Polyvinyl Alcohol (PVOH) Polycaprolactone 2023 Univweritas Brawijaya 6
  • 7. BIOPLASTIC BASED ON THEIR RESOURCES • Have higher biodegradability, renewability and good oxygen barrier • Based on starch • Higher amylose content can strengthen film • Amylopectin cause low mechanical properties • Can be improved by using plasticizers (sorbitol and glycerol) POLYSACHARRIDES • Functional properties depends on structural heterogeneity, thermal sensitivity and hydrophilic behaviour of proteins • Can used proteins from vegetable and animal sources PROTEIN 2023 Univweritas Brawijaya 7
  • 8. BIOPLASTIC BASED ON THEIR RESOURCES • Converting plants sugar into plastic • Producing plastic inside microorganism • Growing plastic in corn and other crops • Producing by using fermentation process of microorganism BIOTECHNOLOGICAL INVENTIONS • Made from synthetic source (petroleum) PETROCHEMICAL 2023 Univweritas Brawijaya 8
  • 9. BIOPLASTIC COMPONENTS Hydrocolloid Proteins (casein, soy protein, wheat gluten) and carbohydrates (starch, gum ) very good for use as an inhibitor of the transfer of oxygen, carbon dioxide & fat Very good at improving the structure of the film so that it is not easily destroyed Lipids wax, fatty acids, monoglycerides and resin as a water vapor barrier, or a coating agent to increase the shine of candy products limited because it produces poor film structural strength Composite lipid and hydrocolloid components increasing resistance to water evaporation and hydrocolloids themselves can provide durability 2023 Univweritas Brawijaya 9
  • 10. MECHANICAL PROPERTIES Elongation (Percent Elongation) • the length of the film when it is pulled until it breaks • related to the elasticity of the film • The greater the elongation value of the film, the more elastic it is and the better the plastic Tensile Strength • the maximum pull that can be achieved until the film remains in place before breaking/tearing • determine the amount of force required to achieve maximum tension in each area of the film • Depends on the concentration and type of material making up the film, especially the structural cohesion properties. 2023 Univweritas Brawijaya 10
  • 12. • The periodic table showing the metals (blue), non-metals (green) and intermediate (orange) elements. • Metals are good conductors of heat and electricity, opaque to visible light, and have a familiar metallic lustre. 2023 Univweritas Brawijaya 12
  • 13. BIOMETAL  Metallic materials are normally combinations of metallic elements.  Have large numbers of nonlocalized electrons not bound to particular atoms  properties of metals  Metal can be formed and machined easily  usually are long-lasting materials.  Metal do not react easily with other elements.  Metals such as iron and aluminum can form compounds readily (such as ores) so they must be processed to extract base metals.  Can react with chemicals in the environment such as iron and oxygen that form iron-oxide. 2023 Univweritas Brawijaya 13
  • 14. • One model of a metal, positive ions are surrounded by a sea or cloud of electrons. • ‘free electrons’ are not bound to any particular metal ion but are free to move around within the structure. • It is these ‘free electrons’ that result in some of the typical properties of a metal including the good conductance of heat and electricity, and the metallic lustre of a polished surface. 2023 Univweritas Brawijaya 14
  • 15. PROPERTIES OF METALS  Atoms arranged in a regular repeating structure  Relatively good strength  Dense  Malleable or ductile (high plasticity)  Resistant to fracture (tough)  Excellent conductors of electricity and heat  Opaque to visible light  Shiny appearance 2023 Univweritas Brawijaya 15
  • 16. PROPERTIES OF SOME METALS AND ALLOYS 2023 Univweritas Brawijaya 16
  • 17. BIOMATERIAL BIOMETAL • Metal and metal alloys are used for medical requirements include : • stainless steel (316L), • titanium and alloys (Cp-'Ti, 'TiGAI4V), • cobalt chromium alloys (CoCr), • aluminium alloys, • zirconium, • niobium, • tungsten heavy alloys. 2023 Univweritas Brawijaya 17
  • 18. BIOMETAL APPLICATIONS • dental implants, • craniofacial plates and screws; • parts of artificial hearts, pacemakers, • clips, valves, balloon catheters, • medical devices and equipment; • bone fixation devices, • dental materials, • medical radiation shielding products, • prosthetic and orthodontic devices 2023 Univweritas Brawijaya 18
  • 19. THE MAIN CRITERIA IN SELECTION OF METAL-BASED MATERIALS • The main criteria in selection of metal-based materials for biomedical applications • their excellent biocompatibility, • convenient mechanical properties, • good corrosion resistance, and • low cost. • In comparison to polymers, • metals have higher ultimate tensile strength and elastic modulus • lower strains at failure • In comparison to ceramics • metals have lower strengths and elastic modulus • higher strains to failure 2023 Univweritas Brawijaya 19
  • 21. 01 Explain definition of biocompatibility in biomaterial! 2023 Univweritas Brawijaya 21
  • 22. 02 Write & explain the conditions for a material to be said to be biocompatible! (minimum 2) 2023 Univweritas Brawijaya 22
  • 23. 03 What do you know about cytotoxicity testing? 2023 Univweritas Brawijaya 23
  • 24. 04 Mention 2 mechanical properties (tests) found in bioplastics! 2023 Univweritas Brawijaya 24
  • 25. 05 Mention the applications that can be applied in the medical field using biometals! (minimum 3) 2023 Univweritas Brawijaya 25