Avoiding Stress Corrosion Cracking of Carbon Low Alloy and Austenitic Stainless Steels in Chloride and Caustic Environments
SYNOPSIS
This Maintenance Best Practice Guide is concerned with the performance of carbon and low alloy steels, and austenitic stainless steels, in chloride and caustic containing fluids. Those factors which are known to promote stress corrosion cracking are outlined, and service charts defining environmental boundaries for stress corrosion cracking in caustic and chloride containing fluids are presented.
General guidance on the avoidance of stress corrosion cracking is provided.
DESIGN OF VENT GAS COLLECTION AND DESTRUCTION SYSTEMS Gerard B. Hawkins
DESIGN OF VENT GAS COLLECTION AND DESTRUCTION SYSTEMS
CONTENTS
1 INTRODUCTION
1.1 Purpose
1.2 Scope of this Guide
1.3 Use of the Guide
2 ENVIRONMENTAL ISSUES
2.1 Principal Concerns
2.2 Mechanisms for Ozone Formation
2.3 Photochemical Ozone Creation Potential
2.4 Health and Environmental Effects
2.5 Air Quality Standards for Ground Level Concentrations of Ozone, Targets for Reduction of VOC Discharges and Statutory Discharge Limits
3 VENTS REDUCTION PHILOSOPHY
3.1 Reduction at Source
3.2 End-of-pipe Treatment
4 METHODOLOGY FOR COLLECTION & ASSESSMENT OF PROCESS FLOW DATA
4.1 General
4.2 Identification of Vent Sources
4.3 Characterization of Vents
4.4 Quantification of Process Vent Flows
4.5 Component Flammability Data Collection
4.6 Identification of Operating Scenarios
4.7 Quantification of Flammability Characteristics for Combined Vents
4.8 Identification, Quantification and Assessment of Possibility of Air Ingress Routes
4.9 Tabulation of Data
4.10 Hazard Study and Risk Assessment
4.11 Note on Aqueous / Organic Wastes
4.12 Complexity of Systems
4.13 Summary
5 SAFE DESIGN OF VENT COLLECTION HEADER SYSTEMS
5.1 General
5.2 Process Design of Vent Headers
5.3 Liquid in Vent Headers
5.4 Materials of Construction
5.5 Static Electricity Hazard
5.6 Diversion Systems
5.7 Snuffing Systems
6 SAFE DESIGN OF THERMAL OXIDISERS
6.1 Introduction
6.2 Design Basis
6.3 Types of High Temperature Thermal Oxidizer
6.4 Refractories
6.5 Flue Gas Treatment
6.6 Control and Safety Systems
6.7 Project Program
6.8 Commissioning
6.9 Operational and Maintenance Management
APPENDICES
A GLOSSARY
B FLAMMABILITY
C EXAMPLE PROFORMA
D REFERENCES
DOCUMENTS REFERRED TO IN THIS PROCESS GUIDE
TABLE
1 PHOTOCHEMICAL OZONE CREATION POTENTIAL REFERENCED
TO ETHYLENE AS UNITY
FIGURES
1 SCHEMATIC OF TYPICAL VENT COLLECTION AND THERMAL OXIDIZER SYSTEM
2 TYPICAL KNOCK-OUT POT WITH LUTED DRAIN
3 SCHEMATIC OF DIVERSION SYSTEM
4 CONVENTIONAL VERTICAL THERMAL OXIDIZER
5 CONVENTIONAL OXIDIZER WITH INTEGRAL WATER SPARGER
6 THERMAL OXIDIZER WITH STAGED AIR INJECTION
7 DOWN-FIRED UNIT WITH WATER BATH QUENCH
8 FLAMELESS THERMAL OXIDATION UNIT
9 THERMAL OXIDIZER WITH REGENERATIVE HEAT RECOVERY
10 TYPICAL PROJECT PROGRAM
11 TYPICAL FLAMMABILITY DIAGRAM
12 EFFECT OF DILUTION WITH AIR
13 EFFECT OF DILUTION WITH AIR ON 100 Rm³ OF FLAMMABLE GAS
Shortcut Methods of Distillation Design
0 INTRODUCTION/PURPOSE
1 SCOPE
2 ESTIMATIONOF PLATEAGE AND REFLUX
REQUIREMENTS
2.1 Generalized Procedure for Nmin and Rmin
2.2 Equation based Procedure for Nmin and Rmin
3 PREDICTION OF OVERALL PLATE EFFICIENCY
4 SIZING OF MAIN PLANT ITEMS
4.1 Column Diameter
4.2 Surface Area of Condensers and Reboilers
FIGURES
1 NON-IDEAL EQUILIBRIUM CURVE
2 AT A GLANCE CHART BASED ON FENSKE,
UNDERWOOD
3 PLATE EFFICIENCY CORRELATION OF O’CONNEL
Fixed Bed Reactor Scale-up Checklist
The purpose of this checklist is to identify the stages and potential problems associated with the scale up of fixed bed reactors from the drawing board to the full scale plant, and to determine how they should be checked.
The checking can be done using various methods. These are:
• Literature data.
• Lab testing.
• Calculation.
• Modeling.
• Semi-tech testing.
• Piloting or Sidestream testing.
Identifying the stages that need to be addressed for a particular catalyst/reactor development will help in estimating the time needed for the development of the reactor
SMR PRE-REFORMER DESIGN
Case Study #0618416GB/H
Contents
1. SMR Pre-Reformer Design
2. Inlet Baffle Design
3. Outlet Collector
4. Hold Down Grating
5. Floating Hold Down Screen
6. Catalyst Drop Out Nozzle
7. Thermowell Detail
8. Technical Performance requirements
9. SMR Pre-Reformer Isolation
Technical Review and Commentary on Proposed Design
APPENDIX
A. Operating / Mechanical Data
B. Materials Specifications
C. Fabrication and Inspection Requirements
D. Weights
E. Nozzle Data
F. Instrument Connections
G. Manholes
GE / Texaco Gasifier Feed to a Lurgi Methanol Plant and its Effect on Methano...Gerard B. Hawkins
GE / Texaco Gasifier Feed to a Lurgi Methanol Plant and its Effect on Methanol Production
CONTENTS
0 Methanol Synthesis Introduction
1 Executive Summary
2 Design Basis
2.1.1 Train I Design Basis
2.1.2 Train II Design Basis
2.1.3 Train III Design Basis
2.2 Design Philosophy
2.2.1 Operability Review
2.3 Assumptions
2.4 Train IV Flowsheet
2.4.1 CO2 Removal
3 Discussion
3.1 Natural Gas Consumption Figures
3.1.1 Base Case
3.1.2 Case 1 – Coal Gasification in Service
3.1.3 Case 2 – Coal Gasification in Service – No CO2 Export
3.2 Methanol Production Figures
3.2.1 Base Case
3.2.2 Case 1 – Coal Gasification in Service
3.2.3 Case 2 – Coal Gasification in Service – No CO2 Export
3.3 85% Natural Gas Availability
3.4 100% Natural Gas Availability
3.5 CO2 Emissions
3.5.1 Base Case
3.5.2 Case 1 – Coal Gasification in Service
3.5.3 Case 2 – Coal Gasification in Service – No CO2 Export
3.6 Specific Consumption Figures
3.6.1 Base Case
3.6.2 Case 1 – Coal Gasification and CO2 Import
3.6.3 Case 2 – Coal Gasification and No CO2 Import
3.7 Train IV Synthesis Gas Composition
4 Further Work
5 Conclusion
APPENDIX
Important Stream Data – Material Balance Stream Data
Texaco Gasifier with HP Steam Raising Boiler
CHARACTERISTICS OF COAL
Material Balance Considerations
Determination of Carbon Dioxide, Ethane And Nitrogen in Natural Gas by Gas C...Gerard B. Hawkins
Determination of Carbon Dioxide, Ethane
And Nitrogen in Natural Gas by Gas Chromatography
1 SCOPE AND FIELD OF APPLICATION
This document is a method for the determination of carbon dioxide, ethane and nitrogen in natural gas in the range 0-10% v/v.
2 PRINCIPLE
The gas sample will be injected automatically by a ten port valve onto the poraplot U column. The nitrogen will elute first and be switched to the mole sieve column. The mole sieve column will be isolated and the poraplot column will elute the carbon dioxide and ethane via a restrictor column to the detector. After the elution of the carbon dioxide and ethane the poraplot column will be back flushed. Then the nitrogen will be allowed to elute from the mole sieve column (see figure 1.) ...
DESIGN OF VENT GAS COLLECTION AND DESTRUCTION SYSTEMS Gerard B. Hawkins
DESIGN OF VENT GAS COLLECTION AND DESTRUCTION SYSTEMS
CONTENTS
1 INTRODUCTION
1.1 Purpose
1.2 Scope of this Guide
1.3 Use of the Guide
2 ENVIRONMENTAL ISSUES
2.1 Principal Concerns
2.2 Mechanisms for Ozone Formation
2.3 Photochemical Ozone Creation Potential
2.4 Health and Environmental Effects
2.5 Air Quality Standards for Ground Level Concentrations of Ozone, Targets for Reduction of VOC Discharges and Statutory Discharge Limits
3 VENTS REDUCTION PHILOSOPHY
3.1 Reduction at Source
3.2 End-of-pipe Treatment
4 METHODOLOGY FOR COLLECTION & ASSESSMENT OF PROCESS FLOW DATA
4.1 General
4.2 Identification of Vent Sources
4.3 Characterization of Vents
4.4 Quantification of Process Vent Flows
4.5 Component Flammability Data Collection
4.6 Identification of Operating Scenarios
4.7 Quantification of Flammability Characteristics for Combined Vents
4.8 Identification, Quantification and Assessment of Possibility of Air Ingress Routes
4.9 Tabulation of Data
4.10 Hazard Study and Risk Assessment
4.11 Note on Aqueous / Organic Wastes
4.12 Complexity of Systems
4.13 Summary
5 SAFE DESIGN OF VENT COLLECTION HEADER SYSTEMS
5.1 General
5.2 Process Design of Vent Headers
5.3 Liquid in Vent Headers
5.4 Materials of Construction
5.5 Static Electricity Hazard
5.6 Diversion Systems
5.7 Snuffing Systems
6 SAFE DESIGN OF THERMAL OXIDISERS
6.1 Introduction
6.2 Design Basis
6.3 Types of High Temperature Thermal Oxidizer
6.4 Refractories
6.5 Flue Gas Treatment
6.6 Control and Safety Systems
6.7 Project Program
6.8 Commissioning
6.9 Operational and Maintenance Management
APPENDICES
A GLOSSARY
B FLAMMABILITY
C EXAMPLE PROFORMA
D REFERENCES
DOCUMENTS REFERRED TO IN THIS PROCESS GUIDE
TABLE
1 PHOTOCHEMICAL OZONE CREATION POTENTIAL REFERENCED
TO ETHYLENE AS UNITY
FIGURES
1 SCHEMATIC OF TYPICAL VENT COLLECTION AND THERMAL OXIDIZER SYSTEM
2 TYPICAL KNOCK-OUT POT WITH LUTED DRAIN
3 SCHEMATIC OF DIVERSION SYSTEM
4 CONVENTIONAL VERTICAL THERMAL OXIDIZER
5 CONVENTIONAL OXIDIZER WITH INTEGRAL WATER SPARGER
6 THERMAL OXIDIZER WITH STAGED AIR INJECTION
7 DOWN-FIRED UNIT WITH WATER BATH QUENCH
8 FLAMELESS THERMAL OXIDATION UNIT
9 THERMAL OXIDIZER WITH REGENERATIVE HEAT RECOVERY
10 TYPICAL PROJECT PROGRAM
11 TYPICAL FLAMMABILITY DIAGRAM
12 EFFECT OF DILUTION WITH AIR
13 EFFECT OF DILUTION WITH AIR ON 100 Rm³ OF FLAMMABLE GAS
Shortcut Methods of Distillation Design
0 INTRODUCTION/PURPOSE
1 SCOPE
2 ESTIMATIONOF PLATEAGE AND REFLUX
REQUIREMENTS
2.1 Generalized Procedure for Nmin and Rmin
2.2 Equation based Procedure for Nmin and Rmin
3 PREDICTION OF OVERALL PLATE EFFICIENCY
4 SIZING OF MAIN PLANT ITEMS
4.1 Column Diameter
4.2 Surface Area of Condensers and Reboilers
FIGURES
1 NON-IDEAL EQUILIBRIUM CURVE
2 AT A GLANCE CHART BASED ON FENSKE,
UNDERWOOD
3 PLATE EFFICIENCY CORRELATION OF O’CONNEL
Fixed Bed Reactor Scale-up Checklist
The purpose of this checklist is to identify the stages and potential problems associated with the scale up of fixed bed reactors from the drawing board to the full scale plant, and to determine how they should be checked.
The checking can be done using various methods. These are:
• Literature data.
• Lab testing.
• Calculation.
• Modeling.
• Semi-tech testing.
• Piloting or Sidestream testing.
Identifying the stages that need to be addressed for a particular catalyst/reactor development will help in estimating the time needed for the development of the reactor
SMR PRE-REFORMER DESIGN
Case Study #0618416GB/H
Contents
1. SMR Pre-Reformer Design
2. Inlet Baffle Design
3. Outlet Collector
4. Hold Down Grating
5. Floating Hold Down Screen
6. Catalyst Drop Out Nozzle
7. Thermowell Detail
8. Technical Performance requirements
9. SMR Pre-Reformer Isolation
Technical Review and Commentary on Proposed Design
APPENDIX
A. Operating / Mechanical Data
B. Materials Specifications
C. Fabrication and Inspection Requirements
D. Weights
E. Nozzle Data
F. Instrument Connections
G. Manholes
GE / Texaco Gasifier Feed to a Lurgi Methanol Plant and its Effect on Methano...Gerard B. Hawkins
GE / Texaco Gasifier Feed to a Lurgi Methanol Plant and its Effect on Methanol Production
CONTENTS
0 Methanol Synthesis Introduction
1 Executive Summary
2 Design Basis
2.1.1 Train I Design Basis
2.1.2 Train II Design Basis
2.1.3 Train III Design Basis
2.2 Design Philosophy
2.2.1 Operability Review
2.3 Assumptions
2.4 Train IV Flowsheet
2.4.1 CO2 Removal
3 Discussion
3.1 Natural Gas Consumption Figures
3.1.1 Base Case
3.1.2 Case 1 – Coal Gasification in Service
3.1.3 Case 2 – Coal Gasification in Service – No CO2 Export
3.2 Methanol Production Figures
3.2.1 Base Case
3.2.2 Case 1 – Coal Gasification in Service
3.2.3 Case 2 – Coal Gasification in Service – No CO2 Export
3.3 85% Natural Gas Availability
3.4 100% Natural Gas Availability
3.5 CO2 Emissions
3.5.1 Base Case
3.5.2 Case 1 – Coal Gasification in Service
3.5.3 Case 2 – Coal Gasification in Service – No CO2 Export
3.6 Specific Consumption Figures
3.6.1 Base Case
3.6.2 Case 1 – Coal Gasification and CO2 Import
3.6.3 Case 2 – Coal Gasification and No CO2 Import
3.7 Train IV Synthesis Gas Composition
4 Further Work
5 Conclusion
APPENDIX
Important Stream Data – Material Balance Stream Data
Texaco Gasifier with HP Steam Raising Boiler
CHARACTERISTICS OF COAL
Material Balance Considerations
Determination of Carbon Dioxide, Ethane And Nitrogen in Natural Gas by Gas C...Gerard B. Hawkins
Determination of Carbon Dioxide, Ethane
And Nitrogen in Natural Gas by Gas Chromatography
1 SCOPE AND FIELD OF APPLICATION
This document is a method for the determination of carbon dioxide, ethane and nitrogen in natural gas in the range 0-10% v/v.
2 PRINCIPLE
The gas sample will be injected automatically by a ten port valve onto the poraplot U column. The nitrogen will elute first and be switched to the mole sieve column. The mole sieve column will be isolated and the poraplot column will elute the carbon dioxide and ethane via a restrictor column to the detector. After the elution of the carbon dioxide and ethane the poraplot column will be back flushed. Then the nitrogen will be allowed to elute from the mole sieve column (see figure 1.) ...
METHANOL PLANT - SHALE GAS FEED PRETREATMENT
CASE STUDY #091406
Case Background
A Methanol plant operator would like to examine the technical feasibility of using Shale Gas as a feedstock to their Methanol plant.
The first step in the Methanol production process is gas pretreatment. The purpose of gas pretreatment is to make the gas suitable for the downstream processes. There are two groups of compounds that are usually present in natural gas and that should be removed during pretreatment—the associate NGL and the sulfur-containing compounds. Some natural gas reservoirs may also have other trace components that must be removed, but these are not discussed here.
This case study examines the impact of CO2 (Carbon Dioxide) on the pre-treatment section design, performance and efficiency of ACME Methanol Plant’ feed gas pre-treatment section.
Case 1: Normal Shale Gas
Case 2: “Bad Gas”
Case 3: Low CO2
Case 4: High CO2
This Engineering Design Guide has several aims.
It is intended to take an experienced mechanical engineer through the steps necessary to specify a gear and to carry out an assessment of gears offered against a particular specification for pumps, fans and compressors driven by electric motors, steam turbines, combustion gas turbines or expanders. It is not part of this Engineering Design Guide to show how to decide that a gear is or is not necessary for a particular duty.
Carbon Formation in Mixed Feed Preheat Coils:
Maximum Mixed Feed Pre-heat Temperature
What follows is a crude but effective routine, which evaluates the maximum possible temperature allowable to prevent excessive carbon laydown in the mixed feed pre-heat coils.
Methanation catalysts are almost always manufactured and transported in the oxidized form, and therefore they must be reduced in the reactor to give nickel metal in order to make them active. The reduction is usually carried out in process gas and occurs by the two reactions:
TEMPERATURE MEASUREMENT:
RESISTANCE ELEMENTS AND THERMOCOUPLES
SPECIFICATION OF FUNCTION
DESCRIPTION OF FLUID
NORMAL OPERATING TEMPERATURE
REQUIRED TEMPERATURE RANGE
ALARM SETTINGS
TRIP SETTINGS
FLUID VELOCITY
REYNOLDS NUMBER
LINE SIZE
LINE REFERENCE
EQUIPMENT REFERENCE
NOZZLE SIZE
MINIMUM DESIGN PRESSURE
CORRESPONDING TEMPERATURE
MAXIMUM DESIGN PRESSURE
CORRESPONDING TEMPERATURE
Reactor Arrangement for Continuous Vapor Phase ChlorinationGerard B. Hawkins
Reactor Arrangement for Continuous Vapor Phase Chlorination
CONTENTS
1 BACKGROUND
2 REACTOR
3 CHEMICAL SYSTEM
4 PROCESS CHEMISTRY
5 KINETICS EXPERIMENTS AND MODELING
6 INTERPRETATION OF KINETICS INFORMATION
7 OPERATING CONDITIONS AND REACTOR DESIGN
8 REACTOR STABILITY AND CONTROL
FIGURES
1 POSTULATED REACTION PATHS FOR PROGRESSIVE CHLORINATION OF B-PICOLINE 3
2 CHLORINATION OF b-PICOLINE: MODEL PREDICTIONS OF PRODUCT DISTRIBUTION IN FULLY-MIXED REACTOR
3 TWO-STAGE REACTOR: RATE OF CHLORINATION OF b-PICOLINE
DOCUMENTS REFERRED TO IN THIS PROCESS ENGINEERING GUIDE
OVERVIEW - FIXED BED ADSORBER DESIGN GUIDELINES
Fixed-bed adsorber design is based upon the following considerations:
• Adsorbent bed profile and media loading capacity characteristics for the specific application and adsorbent material used.
• Pressure drop characteristics across the adsorbent bed.
• Reaction kinetics.
Typically, adsorber design entails use of the following methodology:
• Adsorbent selection based upon performance and application information.
• Bed sizing based upon adsorbent loading data and service life requirements.
• Bed sizing adjustment based upon pressure drop criteria.
• Bed sizing adjustment based upon reaction kinetics criteria.
A discussion of each design consideration follows.
Ammonia Plant Technology
Pre-Commissioning Best Practices
GBHE-APT-0102
PICKLING & PASSIVATION
CONTENTS
1 PURPOSE OF THE WORK
2 CHEMICAL CONCEPT
3 TECHNICAL CONCEPT
4 WASTES & SAFETY CONCEPT
5 TARGET RESULTS
6 THE GENERAL CLEANING SEQUENCE MANAGEMENT
6.6.1 Pre-cleaning or “Physical Cleaning
6.6.2 Pre-rinsing
6.6.3 Chemical Cleaning
6.6.4 Critical Factors in Cleaning Success
6.6.5 Rinsing
6.6.6 Inspection and Re-Cleaning, if Necessary
7 Systems to be treated by Pickling/Passivation
Reactor and Catalyst Design
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 CATALYST DESIGN
4.1 Equivalent Pellet Diameter
4.2 Voidage
4.3 Pellet Density
5 REACTOR DESIGN
6 CATALYST SUPPORT
6.1 Choice of Support
TABLES
1 CATALYST SUPPORT SHAPES
2 SECONDARY REFORMER SPREADSHEET
FIGURES
1 GRAPH OF EFFECTIVENESS v THIELE MODULUS
2 VARIATION OF COSTS WITH CATALYST SIZE
3 VARIATION OF COSTS WITH CATALYST BED VOIDAGE
4 VARIATION OF COSTS WITH VESSEL DIAMETER
Integration of Rotary Positive Displacement Pumps into a ProcessGerard B. Hawkins
Integration of Rotary Positive Displacement Pumps into a Process
This Engineering Design Guide deals with:
(a) The specification of the pump duty for enquiries to be sent to pump vendors,
(b) The estimation of the characteristics and requirements of the pumps in order to provide preliminary information for design work by others.
It applies to pumps in Group 2 and 3 as defined in GBHE-EDS-MAC-21 Series, and is also an essential preliminary step for a pump in Group 1 whose final duty is negotiated with the chosen pump supplier.
It may be used for general-purpose pumps in Group 4; their duties when used in a support role are often inadequately defined, whereupon such pumps can be specified by reference to the manufacturer's data for a pump satisfactorily fulfilling the same process need.
How to Use the GBHE Mixing Guides
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 THE MIXING GUIDES
4.1 Mixing Guides
4.2 GBHE Mixing and Agitation Manual
5 DEVICE SELECTION
6 MIXING QUESTIONNAIRE
6.1 What is being mixed?
6.2 Why is it being mixed?
6.3 How is it to be mixed?
6.4 Is Heat Transfer Important?
6.5 Is Mixing Time Important?
6.6 Is Inventory Important?
6.7 Is Subsequent Phase Separation Important?
6.8 What Quantities?
6.9 What are the Selection Criteria?
6.10 What Data are required?
7 BASICS
7.1 Bulk Movement
7.2 Shear and Elongation
7.3 Turbulent Diffusion
7.4 Molecular Diffusion
7.5 Mixing Mechanisms
APPENDICES
A ROTATING MIXING DEVICES
B MIXING DEVICES WITHOUT MOVING PARTS
During this presentation, Amol Vaidya, senior engineer, global materials characterization and modeling, shares research findings that Owens Corning's Advantex® glass fiber reinforced polymer (E-CR-Glass) provides longer service life and cost savings in corrosive environments, compared to stainless steel and E-glass-based FRP. Corrosion is an economic and environmental issue the oil and gas industry has faced for years, typically addressed with high-cost metal alloys or various coating technologies. Glass fiber reinforced polymer composites can be an effective, low-cost alternative to these expensive alloys.
METHANOL PLANT - SHALE GAS FEED PRETREATMENT
CASE STUDY #091406
Case Background
A Methanol plant operator would like to examine the technical feasibility of using Shale Gas as a feedstock to their Methanol plant.
The first step in the Methanol production process is gas pretreatment. The purpose of gas pretreatment is to make the gas suitable for the downstream processes. There are two groups of compounds that are usually present in natural gas and that should be removed during pretreatment—the associate NGL and the sulfur-containing compounds. Some natural gas reservoirs may also have other trace components that must be removed, but these are not discussed here.
This case study examines the impact of CO2 (Carbon Dioxide) on the pre-treatment section design, performance and efficiency of ACME Methanol Plant’ feed gas pre-treatment section.
Case 1: Normal Shale Gas
Case 2: “Bad Gas”
Case 3: Low CO2
Case 4: High CO2
This Engineering Design Guide has several aims.
It is intended to take an experienced mechanical engineer through the steps necessary to specify a gear and to carry out an assessment of gears offered against a particular specification for pumps, fans and compressors driven by electric motors, steam turbines, combustion gas turbines or expanders. It is not part of this Engineering Design Guide to show how to decide that a gear is or is not necessary for a particular duty.
Carbon Formation in Mixed Feed Preheat Coils:
Maximum Mixed Feed Pre-heat Temperature
What follows is a crude but effective routine, which evaluates the maximum possible temperature allowable to prevent excessive carbon laydown in the mixed feed pre-heat coils.
Methanation catalysts are almost always manufactured and transported in the oxidized form, and therefore they must be reduced in the reactor to give nickel metal in order to make them active. The reduction is usually carried out in process gas and occurs by the two reactions:
TEMPERATURE MEASUREMENT:
RESISTANCE ELEMENTS AND THERMOCOUPLES
SPECIFICATION OF FUNCTION
DESCRIPTION OF FLUID
NORMAL OPERATING TEMPERATURE
REQUIRED TEMPERATURE RANGE
ALARM SETTINGS
TRIP SETTINGS
FLUID VELOCITY
REYNOLDS NUMBER
LINE SIZE
LINE REFERENCE
EQUIPMENT REFERENCE
NOZZLE SIZE
MINIMUM DESIGN PRESSURE
CORRESPONDING TEMPERATURE
MAXIMUM DESIGN PRESSURE
CORRESPONDING TEMPERATURE
Reactor Arrangement for Continuous Vapor Phase ChlorinationGerard B. Hawkins
Reactor Arrangement for Continuous Vapor Phase Chlorination
CONTENTS
1 BACKGROUND
2 REACTOR
3 CHEMICAL SYSTEM
4 PROCESS CHEMISTRY
5 KINETICS EXPERIMENTS AND MODELING
6 INTERPRETATION OF KINETICS INFORMATION
7 OPERATING CONDITIONS AND REACTOR DESIGN
8 REACTOR STABILITY AND CONTROL
FIGURES
1 POSTULATED REACTION PATHS FOR PROGRESSIVE CHLORINATION OF B-PICOLINE 3
2 CHLORINATION OF b-PICOLINE: MODEL PREDICTIONS OF PRODUCT DISTRIBUTION IN FULLY-MIXED REACTOR
3 TWO-STAGE REACTOR: RATE OF CHLORINATION OF b-PICOLINE
DOCUMENTS REFERRED TO IN THIS PROCESS ENGINEERING GUIDE
OVERVIEW - FIXED BED ADSORBER DESIGN GUIDELINES
Fixed-bed adsorber design is based upon the following considerations:
• Adsorbent bed profile and media loading capacity characteristics for the specific application and adsorbent material used.
• Pressure drop characteristics across the adsorbent bed.
• Reaction kinetics.
Typically, adsorber design entails use of the following methodology:
• Adsorbent selection based upon performance and application information.
• Bed sizing based upon adsorbent loading data and service life requirements.
• Bed sizing adjustment based upon pressure drop criteria.
• Bed sizing adjustment based upon reaction kinetics criteria.
A discussion of each design consideration follows.
Ammonia Plant Technology
Pre-Commissioning Best Practices
GBHE-APT-0102
PICKLING & PASSIVATION
CONTENTS
1 PURPOSE OF THE WORK
2 CHEMICAL CONCEPT
3 TECHNICAL CONCEPT
4 WASTES & SAFETY CONCEPT
5 TARGET RESULTS
6 THE GENERAL CLEANING SEQUENCE MANAGEMENT
6.6.1 Pre-cleaning or “Physical Cleaning
6.6.2 Pre-rinsing
6.6.3 Chemical Cleaning
6.6.4 Critical Factors in Cleaning Success
6.6.5 Rinsing
6.6.6 Inspection and Re-Cleaning, if Necessary
7 Systems to be treated by Pickling/Passivation
Reactor and Catalyst Design
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 CATALYST DESIGN
4.1 Equivalent Pellet Diameter
4.2 Voidage
4.3 Pellet Density
5 REACTOR DESIGN
6 CATALYST SUPPORT
6.1 Choice of Support
TABLES
1 CATALYST SUPPORT SHAPES
2 SECONDARY REFORMER SPREADSHEET
FIGURES
1 GRAPH OF EFFECTIVENESS v THIELE MODULUS
2 VARIATION OF COSTS WITH CATALYST SIZE
3 VARIATION OF COSTS WITH CATALYST BED VOIDAGE
4 VARIATION OF COSTS WITH VESSEL DIAMETER
Integration of Rotary Positive Displacement Pumps into a ProcessGerard B. Hawkins
Integration of Rotary Positive Displacement Pumps into a Process
This Engineering Design Guide deals with:
(a) The specification of the pump duty for enquiries to be sent to pump vendors,
(b) The estimation of the characteristics and requirements of the pumps in order to provide preliminary information for design work by others.
It applies to pumps in Group 2 and 3 as defined in GBHE-EDS-MAC-21 Series, and is also an essential preliminary step for a pump in Group 1 whose final duty is negotiated with the chosen pump supplier.
It may be used for general-purpose pumps in Group 4; their duties when used in a support role are often inadequately defined, whereupon such pumps can be specified by reference to the manufacturer's data for a pump satisfactorily fulfilling the same process need.
How to Use the GBHE Mixing Guides
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 THE MIXING GUIDES
4.1 Mixing Guides
4.2 GBHE Mixing and Agitation Manual
5 DEVICE SELECTION
6 MIXING QUESTIONNAIRE
6.1 What is being mixed?
6.2 Why is it being mixed?
6.3 How is it to be mixed?
6.4 Is Heat Transfer Important?
6.5 Is Mixing Time Important?
6.6 Is Inventory Important?
6.7 Is Subsequent Phase Separation Important?
6.8 What Quantities?
6.9 What are the Selection Criteria?
6.10 What Data are required?
7 BASICS
7.1 Bulk Movement
7.2 Shear and Elongation
7.3 Turbulent Diffusion
7.4 Molecular Diffusion
7.5 Mixing Mechanisms
APPENDICES
A ROTATING MIXING DEVICES
B MIXING DEVICES WITHOUT MOVING PARTS
During this presentation, Amol Vaidya, senior engineer, global materials characterization and modeling, shares research findings that Owens Corning's Advantex® glass fiber reinforced polymer (E-CR-Glass) provides longer service life and cost savings in corrosive environments, compared to stainless steel and E-glass-based FRP. Corrosion is an economic and environmental issue the oil and gas industry has faced for years, typically addressed with high-cost metal alloys or various coating technologies. Glass fiber reinforced polymer composites can be an effective, low-cost alternative to these expensive alloys.
Rebooting Operational Excellence in Automotive Paint Shops Using AnalyticsAnita Raj
Paint application is touted to be one of the most complex and demanding activities. Any defects in the painting process can result in poor customer experience and impact the company brand. DataRPM shares ideas on how automakers can improve their output quality, reduce defects and improve the operational efficiencies by applying analytics in the right way across the paint shop.
About Kinder & Co
Kinder & Co is a privately owned Australian company highly respected by its customers and business partners.
The company was founded in 1985 by Neil and Christine Kinder. Over 27 years , earned a reputation second-to-none by delivering excellence in the bulk solids materials handling industries.Kinder & Co is a family operation.
Today Kinder is recognised as a leading independent supplier and manufacturer of innovative and practical solutions to improve and maintain the running efficiency of conveyor and bulk materials handling equipment used to convey a variety of products that include ore, quarried products, grain, sugar, salt and coal.
For more information:
Kinder & Co
Phone: 03 9587 9244
Email sales@kinder.com.au
Website: http://www.kinder.com.au
Other Separations Techniques for Suspensions
PRESSURE-DRIVEN MEMBRANE SEPARATION
PROCESSES
1.1 INTRODUCTION
1.2 MEMBRANES
1.3 OPERATION
1.4 FACTORS AFFECTING PERFORMANCE
1.4.1 Polarization / Fouling
1.4.2 Pressure
1.4.3 Crossflow
1.4.4 Temperature
1.4.5 Concentration
1.4.6 Membrane Pore Size
1.4.7 Particle Size
1.4.8 Particle Charge
1.4.9 Other Factors
1.5 ADVANTAGES / LIMITATIONS
1.6 SUMMARY OF SYMBOLS USED
2 ELECTRO-DIALYSIS
2.1 INTRODUCTION
2.2 EQUIPMENT
2.3 IMPORTANT PARAMETERS IN ED
2.4 EXAMPLES
3 ELECTRODEWATERING AND ELECTRODECANTATION
3.1 INTRODUCTION
3.2 PRINCIPLES AND OPERATION
3.3 EQUIPMENT AND OPERATING PARAMETERS
3.4 EXAMPLES
4 MAGNETIC SEPARATION METHODS
5 REFERENCES
FIGURES
1 APPLICATION RANGES FOR MEMBRANE SEPARATION TECHNIQUES
2 SIMPLE UF / CMF RIG
4 FLUX VERSUS PRESSURE
5 ELECTRODIALYSIS PROCESS
6 ELECTRODIALYSIS PLANT FOR BATCH PROCESS
7 DEPENDENCE OF MEMBRANE AREA AND ENERGY ON
CURRENT DENSITY
8 DIFFUSION ACROSS THE BOUNDARY LAYER
0 INTRODUCTION
The four main sources of Fugitive Emissions on most plants are valves, machine seals, re-makable joints and pressure relief devices. Other possible sources include open-ended lines, sampling connections, drains and vents.
Sometimes special precautions are taken to minimize Fugitive Emissions, for example the use of bellows seal valves. However, generally no special precautions are taken and the subsequent Fugitive Emissions to atmosphere represent a significant amount of plant losses.
Regulatory requirements covering Fugitive Emissions exist in many countries and therefore a leak reduction program should be implemented. Fugitive Emissions also represent financial losses to the business as well as potential damage to the environment.
Integration of Special Purpose Centrifugal Pumps into a ProcessGerard B. Hawkins
Integration of Special Purpose Centrifugal Pumps into a Process
CONTENTS
1 SCOPE
2 PRELIMINARY CHOICE OF PUMP
SECTION A - INLET CONDITIONS
Al Calculation of Basic Nett Positive Suction Head (NPSH)
A2 Correction to Basic NPSH for Temperature Rise at Pump Inlet
A3 Correction to Basic NPSH for Acceleration Head
A4 Calculation of Available NPSH
A5 Correction to NPSH for Fluid Properties
A6 Calculation of Suction Specific Speed
A7 Priming
A8 Submergence
SECTION B – FLOW / HEAD RATING SEQUENCE
B1 Calculation of Static Head
B2 Calculation of Margins for Control
B3 Calculation of Q-H Duty
B4 Stability and Parallel Operation
B5 Corrections to Q-H Duty for Fluid Properties
B6 Guide to Pump Type and Speed
SECTION C – DRIVER POWER RATING
C1 Estimation of Pump Efficiency
C2 Calculation of Absorbed Power
C3 Calculation of Driver Power Rating
C4 Preliminary Power Ratings of Electric Motors
C5 Starting Conditions for Electric Motors
C6 Reverse Flow and Reverse Rotation
SECTION D - CASING PRESSURE RATING
D1 Calculation of Maximum Inlet Pressure
D2 Calculation of Differential Pressure
D3 Pressure Waves
D4 Pressure due to Liquid Thermal Expansion
D5 Casing Hydrostatic Test Pressure
SECTION E – SEALING CONSIDERATIONS
E1 Preliminary Choice of Seal
E2 Fluid Attributes
E3 Definition of Flushing Arrangements
APPENDICES
A RELIABILITY CLASSIFICATION
B SYMBOLS AND PREFERRED UNITS
DOCUMENTS REFERRED TO IN THIS ENGINEERING DESIGN GUIDE
Determination of Argon in Ammonia Plant Process Gas Streams by Gas Chromatogr...Gerard B. Hawkins
Determination of Argon in Ammonia Plant Process Gas Streams by Gas Chromatography
SCOPE AND FIELD OF APPLICATION
This document is a method for the determination of argon in process gas streams in the range 0-10% v/v.
BENFIELD LIQUOR:Determination of Diethanolamine Using an Auto TitratorGerard B. Hawkins
BENFIELD LIQUOR:Determination of Diethanolamine Using an Auto Titrator
1 SCOPE AND FIELD OF APPLICATION
This method is suitable for the determination of diethanolamine in Benfield Liquor.
2 PRINCIPLE
Diethanolamine is converted quantitatively into ammonia by boiling in the presence of sulfuric acid and copper sulfate. The ammonia is distilled from an alkaline medium and absorbed into boric acid. The solution is titrated with standard acid.
Reactor Modeling Tools – Multiple Regressions
CONTENTS
0 INTRODUCTION
1 SCOPE
2 THEORY
3 EXCEL 2007: MULTIPLE REGRESSIONS
3.1 Overview
3.2 Multiple Regression Using the Data Analysis ADD-IN
3.3 Interpret Regression Statistics Table
3.4 Interpret ANOVA Table
3.5 Interpret Regression Coefficients Table
3.6 Confidence Intervals for Slope Coefficients
3.7 Test Hypothesis of Zero Slope Coefficients ("Test of Statistical Significance")
3.8 Test Hypothesis on a Regression Parameter
3.8.1 Using the p-value approach
3.8.2 Using the critical value approach
3.9 Overall Test of Significance of the Regression Parameters
3.10 Predicted Value of Y Given Regressors
3.11 Excel Limitations
4 SPECIAL FEATURES REQUIRING MORE SOPHISTICATED TECHNIQUES
5 USER INFORMATION SUPPLIED
A SUBROUTINE
B DATA
C RESULTS
6 EXAMPLE
Batch Distillation
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 BACKGROUND TO THE DESIGN
4.1 General
4.2 Choice of batch/continuous operation
4.3 Boiling point curve and cut policy
4.4 Method of design
4.5 Scope of calculations required for design
5 SIMPLE BATCH DISTILLATION
6 FRACTIONAL BATCH DISTILLATION
6.1 General
6.2 Approximate methods
6.3 Rigorous design - use of a computer model
6.4 Other factors influencing the design
6.4.1 Occupation
6.4.2 Choice of Batch Rectification or Stripping
6.4.3 Batch size
6.4.4 Initial estimate of cut policy
6.4.5 Liquid Holdup
6.4.6 Total reflux operation and heating-up time
6.4.7 Column operating pressure
6.5 Optimum Design of the Batch Still
6.6 Special design problems
7 GENERAL ASPECTS OF EQUIPMENT DESIGN
7.1 Kettle reboilers
7.2 Column Internals
7.3 Condensers and reflux split boxes
8 PROCESS CONTROL AND INSTRUMENTATION IN
BATCH DISTILLATION
9 MECHANICAL DESIGN FEATURES
10 BIBLIOGRAPHY
APPENDICES
A McCABE - THIELE METHOD - TYPICAL EXAMPLE
Large Water Pumps
CONTENTS
1 SCOPE
SECTION ONE: INTEGRATION OF PUMPS INTO THE PROCESS
2 PROPERTIES OF FLUID
2.1 Cooling Water
2.2 Brine
2.3 Estuary Water
2.4 Harbor Water
2.5 Oil-field water
3 CALCULATION OF DUTY
4 CHOICE OF TYPE AND NUMBER OF PUMPS
4.1 Type of Pump
4.2 Points to Consider
4.3 Number of Pumps
5 RECOMMENDED LINE DIAGRAM
5.1 Check List for Each Pump
6 RECOMMENDED LAYOUT
SECTION TWO: CONSTRUCTION FEATURES
7 HORIZONTAL, AXIALLY SPLIT CASING PUMPS
7.1 Pressure Casing
7.2 Bolting
7.3 Flanges and Connections
7.4 Rotating Elements
7.5 Wear Rings
7.6 Running Clearances
7.7 Mechanical Seals
7.8 Packed Glands
7.9 Bearings and Bearing Housings
7.10 Lubrication
7.11 Couplings
7.12 Guards
7.13 Baseplates
7.14 Flywheels
8 VERTICAL PUMPS
8.1 General
8.2 Pressure Casing
8.3 Bolting
8.4 Flanges and Connections
8.5 Rotating Element
8.6 Packed Glands
8.7 Bearings and Bearing Housings
8.8 Pump Head
8.9 Column Pipes
8.10 Line Shaft and Couplings
8.11 Reverse Rotation
8.12 Gearboxes
9 MATERIALS
9.1 Castings
9.2 Casings
9.3 Impellers
9.4 Shafts
9.5 Shaft Sleeves
9.6 Bolts and Nuts
10 DRIVERS
10.1 Electric Motor Drives
11 BIBLIOGRAPHY
APPENDICES:
A COOLING WATER - EUROPEAN SITE
B TIDAL RIVER ESTUARY
C FLYWHEEL INERTIA FOR PRESSURE SURGE ABATEMENT
D RESIN COATING OF CASINGS FOR WATER PUMPS
E AREA RATIO METHOD
F NOTES ON PUMP IMPELLERS CASTINGS
G LIMIT ON SHAFT DIAMETER FOR HORIZONTAL PUMPS HAVING
ONE DOUBLE-ENTRY IMPELLER SUPPORTED BETWEEN BEARINGS
H FORCES AND BENDING MOMENTS ON RISING MAIN ASSEMBLY
I POWER COSTS
J PUTATIVE COST COMPARISON SHEET
K TECHNICAL COMPARISON SHEETS
FIGURES
2.1 VAPOR TEMPERATURE CURVES
2.2 DENSITY TEMPERATURE CURVES
3.1 TYPICAL HEAD OF PUMPS
3.2 TOTAL HEAD OF VERTICAL IMMERSED PUMP
3.3 TYPICAL TIDAL RIVER ESTUARY LEVELS
3.5 SUBMERGENCE LIMITS
4.1 TYPES OF PUMP
4.2 GUIDE TO PUMP TYPE AND SPEED
5.1 TYPICAL LINE DIAGRAM
6 GUIDE TO SUCTION PIPEWORK DESIGN
7 CASING AND IMPELLER DETAILS
8.1 DRY WELL AND WET WELL PUMP INSTALLATIONS
8.2 BELLMOUTH DIMENSIONS FOR VERTICAL INTAKES
8.3 MAXIMUM SPACING BETWEEN SHAFT GUIDE BUSHING
8.4 LINE SHAFT COUPLING
9 TYPICAL VOLUTE CASING
10 TYPICAL CASE WEAR RINGS
11 SEAL AREA
TABLES
1 LIQUID PROPERTIES SODIUM CHLORIDE (25% W/W)
2 LIQUID PROPERTIES SODIUM CHLORIDE (20% W/W)
3 LIQUID PROPERTIES SODIUM CHLORIDE (16.25% W/W)
4 LIQUID PROPERTIES SODIUM CHLORIDE (15% W/W)
5 LIQUID PROPERTIES SODIUM CHLORIDE (10% W/W)
6 LIQUID PROPERTIES SODIUM CHLORIDE (5% W/W)
7 GUIDE TO PUMP TYPE AND SPEED
8 RECOMMENDED CAST MATERIALS FOR USE IN THE PUMP INDUSTRY
GRAPHS
1 GUIDE TO ROTOR INERTIA
2 LIMITS BETWEEN BEARINGS
DOCUMENTS REFERRED TO IN THIS ENGINEERING DEPARTMENT DESIGN GUIDE
Cast White Metal Bearings
1 SCOPE
2 BACKING MATERIAL
3 SURFACE
4 THICKNESS
5 CLEANING PROCEDURE
6 TINNING
7 WHITE METAL
8 BOND SOUNDNESS
9 WITNESSED INSPECTION
10 MACHINING
11 FINAL INSPECTION OF BOND FOR SEAL RINGS
APPENDIX
A - METHOD OF CALCULATING REFLECTANCE RATIO
Hydrogen Compressors
Engineering Design Guide
1 SCOPE
2 PHYSICAL ROPERTIES
2.1 Data for Pure Hydrogen
2.2 Influence of Impurities
3 MATERIALS OF CONSTRUCTION
3.1 Hydrogen from Electrolytic Cells
3.2 Pure Hydrogen
4 DESIGN
4.1 Pulsation
4.2 Bypass
5 TESTING OR COMMISSIONING RECIPROCATING COMPRESSORS
6 LUBRICATION
7 LAYOUT
8 REFERENCES
FIGURES
1 MOLLIER CHART - HYDROGEN
2 COMPRESSIBILITY CHART
3 NELSON DIAGRAM
4 WATER CONTENT IN HYDROGEN FOR OIL-LUBRICATED COMPRESSORS AS GRAMM/M2 SWEPT CYLINDER AREA
CONTENTS
1 SCOPE
2 PROPERTIES OF FLUID
2.1 General Properties of Sodium Hydroxide
2.2 Physical Properties of Sodium Hydroxide and its Solutions
2.3 Chemical Properties and uses of Sodium Hydroxide
2.4 Physiological effects of Sodium Hydroxide
2.5 Specifications of Commercial Caustic Soda Grades
3 CHOICE OF PUMP TYPE
3.1 Pump Duty
3.2 Pump Type
4 RECOMMENDED LINE DIAGRAMS
5 RECOMMENDED LAYOUT
6 CONSTRUCTION FEATURES
7 MATERIALS OF CONSTRUCTION
7.1 Nickel and Nickel Alloys
7.2 Austenitic Stainless Steel
7.3 Aluminium, Aluminium Alloys, etc.
7.4 Non-Metallic Materials
TABLES
1 PHYSICAL PROPERTIES (Solid Form)
2 PHYSICAL PROPERTIES (Solution Form)
3 CAUSTIC SODA GRADES
FIGURES
1.1 LINE DIAGRAM - HORIZONTAL GLANDED, GLANDLESS AND VERTICAL IN-LINE PUMPS
1.2 LINE DIAGRAM - VERTICAL SPINDLE CANTILEVER PUMPS
1.3 LINE DIAGRAM - SELF PRIMING PUMPS
1.4 LINE DIAGRAM - RECIPROCATING PLUNGER METERING PUMPS
1.5 LINE DIAGRAM - POSITIVE DISPLACEMENT DIAPHRAGM METERING PUMPS
1.6 WATER FLUSHING ARRANGEMENT FOR DOUBLE MECHANICAL SEAL
1.7 WATER FLUSH (QUENCH) ARRANGEMENT FOR SINGLE HARD FACED (CARBIDE) SEAL AND BACK-UP LIP SEAL
2 PHASE DIAGRAM OF NaOH-H2O
3 VISCOSITY OF AQUEOUS CAUSTIC SODA SOLUTIONS
4 VAPOR PRESSURE OF AQUEOUS CAUSTIC SODA SOLUTIONS
5 ENTHALPY CONCENTRATION FOR AQUEOUS CAUSTIC SODA SOLUTIONS
6 SPECIFIC GRAVITY FOR AQUEOUS CAUSTIC SODA SOLUTIONS
7 DILUTION OF CAUSTIC SODA LIQUOR
8 THERMAL CONDUCTIVITY OF AQUEOUS CAUSTIC SODA SOLUTIONS
9 SPECIFIC HEAT OF CAUSTIC SODA SOLUTIONS
10 BOILING POINTS OF STRONG CAUSTIC SODA SOLUTIONS AT REDUCED PRESSURE
11 COMMENCEMENT OF FREEZING OF CAUSTIC SODA SOLUTIONS (0 - 52% W/W)
12 TEMPERATURES ATTAINED ON DISSOLUTION OF ANHYDROUS CAUSTIC SODA
13 HEAT OF SOLUTION FOR ANHYDROUS CAUSTIC SODA
14 SOLUBILITY OF SODIUM CHLORIDE IN CAUSTIC SODA SOLUTIONS
15 DENSITY - CONCENTRATION TABLES FOR CAUSTIC SODA SOLUTIONS AT 600 F (15.5 0 C)
16 MATERIAL SELECTION CHART FOR CAUSTIC SODA HANDLING
Shell and Tube Heat Exchangers Using Cooling Water
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
3.1 HTFS
3.2 TEMA
4 CHECKLIST
5 QUALITY OF COOLING WATER
6 COOLING WATER ON SHELL SIDE OR TUBE SIDE
7 COOLING WATER ON THE SHELL SIDE
7.1 Baffle Spacing
7.2 Impingement Plates
7.3 Horizontal or Vertical Shell Orientation
7.4 Baffle Cut Orientation
7.5 Sludge Blowdown
7.6 Removable Bundles
8 FOULING RESISTANCES AND LIMITING TEMPERATURES
9 PRESSURE DROP
9.1 Pressure Drop Restrictions
9.2 Fouling and Pressure Drop
9.3 Elevation of a Heat Exchanger in the Plant
10 MATERIALS OF CONSTRUCTION
11 WATER VELOCITY
11.1 Low Water Velocity
11.1.1 Tube Side Water Flow
11.1.2 Shell Side Water Flow
11.2 High Water Velocity
12 ECONOMICS
13 DIRECTION OF WATER FLOW
14 VENTS AND DRAINS
15 CONTROL
15.1 Operating Variables
15.2 Heat Load Control
15.2.1 General
15.2.2 Heat load control by varying cooling water flow
15.3 Orifice Plates
16 MAINTENANCE
"SEDIMENTATION"
INTRODUCTION - THE PHENOMENON OF SEDIMENTATION
Sedimentation is the physical process whereby solid particles, of greater density than their suspending medium, will tend to separate into regions of higher concentration under the influence of gravity. As a solids/liquids separation technique it therefore possesses the great advantage of utilizing a natural, and therefore costless, driving force. This section of the suspension processing Guide is Intended to provide an Introduction to the science of the subject, and the means to judge where and how best to exploit sedimentation as a separation (or other processing) technique.
As a scientific discipline the subject of sedimentation is vast with perspectives ranging from the field of chemical engineering through to theoretical physics being covered In the literature [1-11]. Good reviews of the subject, with a bias towards the engineering aspects, have been written by Fitch and Koz [12, 13]. A short summary of some of the more relevant contributions from the literature is also provided in GBHE-SPG-PEG-302 “Basic Principles & Test Methods”, of the Suspensions Processing Guides.
.
The sedimentation process is traditionally divided into ..."
Design and Simulation of Continuous Distillation ColumnsGerard B. Hawkins
Design and Simulation of Continuous Distillation Columns
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 FRACTIONAL DISTILLATION
5 ROUGH METHOD OF COLUMN DESIGN
5.1 Sharp Separations
5.2 Sloppy Separations
6 DETAIL DESIGN USING THE CHEMCAD DISTILLATION PROGRAM
6.1 Sharp Separations
6.2 Sloppy Separations
7 COMPLEX COLUMNS
7.1 Multiple Feeds
7.2 Sidestream Take-Offs
8 DESIGN USING A LABORATORY COLUMN
SIMULATION
9 DESIGN USING ACTUAL PLANT DATA
9.1 Uprating or Debottlenecking Exercises
10 REFERENCES
APPENDICES
A WORKED EXAMPLE
B SLOPPY SEPARATIONS
C SIMULATION USING PLANT DATA : CASE HISTORIES
TABLES
Typical Stabilizer Chloride Management Problems
What Causes NH4Cl Salts?
Mitigating System Fouling
Operating practices
Problems with Water Injection
Design To Mitigate Salt Formation
Prevention
Remove Nitrogen from the feed
Remove chloride from stabilizer feed
Chloride Guard Bed
Caustic Injection
Water Wash
Summary
Reciprocating Compressors - Protection against Crank Case ExplosionsGerard B. Hawkins
Reciprocating Compressors - Protection against Crank Case Explosions
1 SCOPE
2 OIL MIST/AIR MIXTURE EXPLOSIONS
3 PREVENTION AND PROTECTION
3.1 Design
3.2 Maintenance and Operation
FIGURES
1 FLAMMABILITY LIMITS AND SPONTANEOUS IGNITION REGION FOR MIXTURES OF LUBRICATING OIL VAPOR IN AIR.
Introduction High temperature shift Catalysts
Low temperature shift catalysts
Catalyst storage, handling, charging and discharging
Health and safety precautions
Reduction and start-up of high temperature shift catalysts
Operation of high temperature shift catalysts
Reduction and start-up of low temperature shift catalysts
Operation of low temperature shift catalysts
Distillation Sequences, Complex Columns and Heat IntegrationGerard B. Hawkins
Distillation Sequences, Complex Columns and Heat Integration
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 SEQUENCING OF SIMPLE COLUMNS
4.1 Sidestream Columns
4.2 Multi-Feed Columns
5 SIMPLE COLUMN SEQUENCING AND HEAT
INTEGRATION INTERACTIONS
5.1 Energy Quantity and Quality
5.2 Heat Integration within the Total Flowsheet
6 COMPLEX COLUMN ARRANGEMENTS
6.1 Indirect Sequence with Vapor Link
6.2 Sidestream Systems
6.3 Pre-Fractionator Systems
7 COMPLEX COLUMNS AND HEAT INTEGRATION
INTERACTIONS
FIGURES
1 DIRECT AND INDIRECT SEQUENCES
2 A SINGLE SIDESTREAM COLUMN REPLACING 2
SIMPLE COLUMNS
3 A TYPICAL MULTI-FEED COLUMN
4 TYPICAL GRAND COMPOSITION CURVE
5 TYPICAL INDIRECT SEQUENCE WITH VAPOUR LINK
6 SIDESTREAM STRIPPER AND SIDESTREAM
RECTIFIER
7 SIMPLEST PRE-FRACTIONATOR SYSTEM
8 SIMPLEST PRE-FRACTIONATOR SYSTEM
9 PETLYUK COLUMN
Pumps for Ammonium Nitrate Service
Engineering Design Guide: GBHE-EDG-MAC-1503
CONTENTS
1 SCOPE
SECTION ONE: INTEGRATION OF PUMPS INTO THE PROCESS
2 PROPERTIES OF FLUID
2.1 Decomposition
2.2 Combustion
2.3 Detonation
2.4 Deliquescence
2.5 Density
2.6 Viscosity
2.7 Vapor Pressure
2.8 Freezing Point
2.9 Specific Heat
2.10 Surface Tension
2.11 Thermal Conductivity
3 CALCULATION OF DUTY
3.1 Centrifugal Pumps
4 CHOICE OF PUMP TYPE
4.1 Centrifugal Pumps
4.2 Rotary Pumps
4.3 Reciprocating Pumps
5 LINE DIAGRAMS
5.1 Centrifugal Pumps with Mechanical Seals
5.2 Vertical Suspended Cantilever Shaft Pumps for
Melt Service
5.3 Horizontal Self-Priming Pumps
5.4 Reciprocating Pumps
5.5 Seal Water Supply System
6 LAYOUT
6.1 Vertical Cantilever Shaft Pumps - Tank Proportions
SECTION TWO: CONSTRUCTION FEATURES OF PUMPS
7 SEALS FOR CENTRIFUGAL PUMPS
7.1 Below 30% AN
7.2 30-45% AN
7.3 45-90% AN
7.4 Above 90% AN
8 PACKED GLANDS FOR RECIPROCATING PUMPS
8.1 Below 90% AN
9 SEAL WATER SUPPLY SYSTEMS
10 CONSTRUCTION FEATURES OF CENTRIFUGAL PUMPS
10.1 Casing
10.2 Rotor
10.3 Bearing Lubrication
10.4 Coupling
10.5 Baseplate
11 CONSTRUCTION FEATURES OF VERTICAL CANTILEVER SHAFT IMMERSED PUMPS
11.1 Motor
11.2 Insulation and Jacketing
11.3 Rotor
11.4 Bearing Lubrication
11.5 Preservation
12 CONSTRUCTION FEATURES OF RECIPROCATING PLUNGER PUMPS
12.1 Speed Limits
12.2 Casing and Gearbox
12.3 Couplings
13 MATERIALS OF CONSTRUCTION
13.1 Recommended Materials
13.2 Forbidden Materials
APPENDIX A: BEARING LUBRICANTS
FIGURES
2.5.1 DENSITY OF AMMONIUM NITRATE SOLUTIONS
2.5.2 DENSITY OF AMMONIUM NITRATE SOLUTIONS
2.6 KINEMATIC VISCOSITY OF AMMONIUM NITRATE SOLUTIONS
2.7.1 WATER VAPOR PRESSURE ABOVE AMMONIUM NITRATE SOLUTIONS
2.7.2 AMMONIA VAPOR PRESSURE FOR AM!AMMONIUM NITRATE MELT
2.8 FREEZING POINT OF AMMONIUM NITRATE SOLUTIONS
2.9 SPECIFIC HEAT OF AMMONIUM NITRATE SOLUTIONS
4 SELECTION OF PUMP TYPE
5. 1 RECOMMENDED LINE DIAGRAM CENTRIFUGAL PUMPS WITH MECHANICAL SEALS
5.2 RECOMMENDED LINE DIAGRAM: VERTICAL SUSPENDED CANTILEVER PUMPS
5.3 RECOMMENDED LINE DIAGRAM: HORIZONTAL SELF
PRIMING PUMPS
5.4 RECOMMENDED LINE DIAGRAM: RECIPROCATING PLUNGER PUMPS
5.5 RECOMMENDED LINE DIAGRAM SEAL: WATER PUMPS AND INJECTION PUMP SYSTEMS
7.2 TYPICAL ARRANGEMENT OF SEAL WITH NO INJECTION FLUSH
7.3 TYPICAL ARRANGEMENT OF CRANE TYPE 52B WITH 'J' SEAT INCORPORATING TETRALIPS INBOARD AND OUTBOARD
7.4 TYPICAL ARRANGEMENT OF LABYRINTH SEAL FOR VERTICAL SUSPENDED CANTILEVER SHAFT PUMPS
8.1 TYPICAL ARRANGEMENT OF SOFT PACKED GLAND FOR RECIPROCATING PLUNGER PUMPS FOR DELIVERY PRESSURES UP TO 10 BAR G.
12 TEMPERATURES ATTAINED ON DISSOLUTION OF ANHYDROUS CAUSTIC SODA
TABLES
13.1 MATERIALS OF CONSTRUCTION CENTRIFUGAL PUMPS
13.2 MATERIALS OF CONSTRUCTION VERTICAL CANTILEVER
SHAFT IMMERSED PUMPS
13.3 MATERIALS OF CONSTRUCTION RECIPROCATING PLUNGER PUMPS
Fouling Resistances for Cooling Water
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 GENERAL
5 COOLING WATER FOULING
6 CHROMATE SYSTEMS
6.1 General
6.2 Constraints
6.3 Requirements
6.4 Fouling resistances
7 NON-CHROMATE SYSTEMS
7.1 General
7.2 Requirements and Constraints
7.3 Fouling resistances
8 UNTREATED COOLING WATER
9 MATERIALS OTHER THAN MILD STEEL
APPENDICES
A FOULING RESISTANCES FOR COOLING WATER
B FOULING FILM THICKNESS
Introduction
VULCAN Series VHT-S101
Catalyst storage, handling, charging
Health and safety precautions
Start-up of VHT-S101 hydrogenation catalyst
Operation of VHT-S101 hydrogenation catalyst
Shut-down of VHT-S101 hydrogenation catalyst
Sulfiding of hydrodesulfurization catalysts
Catalyst Discharge
Turbulent Heat Transfer to Non Newtonian Fluids in Circular TubesGerard B. Hawkins
Turbulent Heat Transfer to Non Newtonian Fluids in Circular Tubes
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
4 THE INTEGRATION OF THE ENERGY EQUATION
5 THE EDDY VISCOSITY FOR NON-NEWTONIAN AND DRAG REDUCING FLUIDS
6 THE CALCULATION OF HEAT TRANSFER
COEFFICIENTS FOR NON-NEWTONIAN AND DRAG
REDUCING FLUIDS IN TURBULENT PIPE FLOW
6.1 General
6.2 Drag Reducing Fibre Suspensions
6.3 Transition Delay
7 NOMENCLATURE
8 BIBLIOGRAPHY
Estimation of Pressure Drop in Pipe Systems
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
3.1 units
4 SOURCES OF DATA
5 BASIC CONCEPTS
5.1 Equation for Pressure Change in a Flowing
Fluid
5.2 Static and Stagnation Pressures
5.3 Sonic Flow
6 INCOMPRESSIBLE FLOW IN PIPES OF CONSTANT
CROSS-SECTION
6.1 Straight Circular Pipes
6.2 Ducts of Non-circular Cross-section
6.3 Coils
6.4 General Equation for Incompressible Flow
in Pipes of Constant Cross-section
7 COMPRESSIBLE FLOW IN PIPES OF CONSTANT
CROSS-SECTION
7.1 Isothermal Flow
7.2 Adiabatic Flow
7.3 Estimation of Pressure Drop for Adiabatic
Flow in Pipes of Constant Cross-section
7.4 Ratio of Isothermal to Adiabatic Pressure Drop
8 FLOW IN PIPE FITTINGS
8.1 Incompressible Flow
8.2 Compressible Flow
9 FLOW IN BENDS
9.1 Incompressible Flow in Bends
9.2 Compressible Flow in Bends
10 CHANGES IN CROSS-SECTIONAL AREA
9.1 Incompressible Flow
9.2 Compressible Flow
11 ORIFICES, NOZZLES AND VENTURIS
11.1 Incompressible Flow through an Orifice
11.2 Compressible Flow through an Orifice or Nozzle
11.3 Venturi Choke Tubes
12 VALVES
12.1 General
12.2 Incompressible Flow in Valves
12.2 Compressible Flow in Valves
13 COMBINING AND DIVIDING FLOW
9.1 Incompressible Flow
9.2 Compressible Flow
14 COMPUTER PROGRAMS FOR FLUID FLOW
15 NOMENCLATURE
16 REFERENCES
APPENDICES
A BASIC THERMODYNAMICS
B COMPRESSIBLE FLOW THROUGH ORIFICES
C THE ‘TWO-K’ METHOD FOR FITTING PRESSURE LOSS
Centrifugal Compressors
SECTION ONE - ANTI-SURGE PROTECTION AND THROUGHPUT REGULATION
0 INTRODUCTION
1 SCOPE
2 MACHINE CHARACTERISTICS
2.1 Characteristics of a Single Compressor Stage
2.2 Characteristic of a Multiple Stage Having More
Than One Impeller
2.3 Use of Compressor Characteristics in Throughput
Regulation Schemes
3 MECHANISM AND EFFECTS OF SURGE
3.1 Basic Flow Instabilities
3.2 Occurrence of Surge
3.3 Intensity of Surge
3.4 Effects of Surge
3.5 Avoidance of Surge
3.6 Recovery from Surge
4 CONTROL SCHEMES INCLUDING SURGE PROTECTION
4.1 Output Control
4.2 Surge Protection
4.3 Surge Detection and Recovery
5 DYNAMIC CONSIDERATIONS
5.1 Interaction
5.2 Speed of Response of Antisurge Control System
6 SYSTEM EQUIPMENT SPECIFICATIONS
6.1 The Antisurge Control Valve
6.2 Non-return Valve
6.3 Pressure and flow measurement
6.4 Signal transmission
6.5 Controllers
7 TESTING
7.1 Determination of the Surge Line
7.2 Records
8 INLET GUIDE VANE UNITS
8.1 Application
8.2 Effect on Power Consumption of the Compressor
8.3 Effect of Gas Conditions, Properties and Contaminants
8.4 Aerodynamic Considerations
8.5 Control System Linearity
8.6 Actuator Specification
8.7 Avoidance of Surge
8.8 Features of Link Mechanisms
8.9 Limit Stops and Shear Links
APPENDICES
A LIST OF SYMBOLS AND PREFERRED UNITS
B WORKED EXAMPLE 1 COMPRESSOR WITH VARIABLE INLET PRESSURE AND VARIABLE GAS COMPOSITION
C WORKED EXAMPLE 2 A CONSTANT SPEED ~ STAGE COMPRESSOR WITH INTER-COOLING
D WORKED EXAMPLE 3 DYNAMIC RESPONSE OF THE ANTISURGE PROTECTION SYSTEM FOR A SERVICE AIR COMPRESSOR RUNNING AT CONSTANT SPEED
E EXAMPLE OF INLET GUIDE VANE REGULATION
FIGURES
2.1 TYPICAL COMPRESSOR STAGE CHARACTERISTIC PLOTTED WITH FLOW AT DISCHARGE CONDITIONS
2.2 TYPICAL COMPRESSOR STAGE CHARACTERISTIC PLOTTED WITH FLOW AT INLET CONDITIONS
2.3 PERFORMANCE CHARACTERISTICS OF A COMPRESSOR STAGE AT VARYING SPEEDS
2.4 SYSTEM WORKING POINT DEFINED BY INTERSECTION OF PROCESS AND COMPRESSOR CHARACTERISTICS
2.5 DISCHARGE THROTTLE REGULATION
2.6 BYPASS REGULATION
2.7 INLET THROTTLE REGULATION
2.8 INLET GUIDE VANE REGULATION
2.9 VARIABLE SPEED REGULATION
3.1 GAS PULSATION LEVELS FOR A CENTRIFUGAL COMPRESSOR
3.2 REPRESENTATION OF CYCLIC FLOW DURING SURGE OF LONG PERIOD
3.3 TYPICAL WAVEFORM OF DISCHARGE PRESSURE DURING SURGE
3.4 MULTIPLE SURGE LINE FOR A MULTISTAGE CENTRIFUGAL COMPRESSOR
3.5 TYPICAL MULTIPLE SURGE LINES FOR SINGLE STAGE AXIAL-FLOW COMPRESSOR
4.1 GENERAL SCHEMATIC FOR COMPRESSORS OPERATING IN PARALLEL TO FEED MULTIPLE USER PLANTS
4.2 ILLUSTRATION OF SAFETY MARGIN BETWEEN SURGE POINT AND SURGE PROTECTION POINT AT WHICH ANTISURGE SYSTEM IS ACTIVATED
4.3 ANTISURGE SYSTEM FOR COMPRESSOR WITH FLAT PERFO ..........
Similar to Avoiding Stress Corrosion Cracking of Carbon Low Alloy and Austenitic Stainless Steels in Chloride and Caustic Environments (20)
Pressure Relief Systems Vol 2
Causes of Relief Situations
This Volume 2 is a guide to the qualitative identification of common causes of overpressure in process equipment. It cannot be exhaustive; the process engineer and relief systems team should look for any credible situation in addition to those given in this Part which could lead to a need for pressure relief (a relief situation).
Pressure Relief Systems
BACKGROUND TO RELIEF SYSTEM DESIGN Vol.1 of 6
The Guide has been written to advise those involved in the design and engineering of pressure relief systems. It takes the user from the initial identification of potential causes of overpressure or under pressure through the process design of relief systems to the detailed mechanical design. "Hazard Studies" and quantitative hazards analysis are not described; these are seen as complementary activities. Typical users of the Guide will use some Parts in detail and others in overview.
GAS DISPERSION - A Definitive Guide to Accidental Releases of Heavy GasesGerard B. Hawkins
GAS DISPERSION - A Definitive Guide to Accidental Releases of Heavy Gases
This Process Safety Guide has been written with the aim of assisting process engineers, hazard analysts and environmental advisers in carrying out gas dispersion calculations. The Guide aims to provide assistance by:
• Improving awareness of the range of dispersion models available within GBHE, and providing guidance in choosing the most appropriate model for a particular application.
• Providing guidance to ensure that source terms and other model inputs are correctly specified, and the models are used within their range of applicability.
• Providing guidance to deal with particular topics in gas dispersion such as dense gas dispersion, complex terrain, and modeling the chemistry of oxides of nitrogen.
• Providing general background on air quality and dispersion modeling issues such as meteorology and air quality standards.
• Providing example calculations for real practical problems.
SCOPE
The gas dispersion guide contains the following Parts:
1 Fundamentals of meteorology.
2 Overview of air quality standards.
3 Comparison between different air quality models.
4 Designing a stack.
5 Dense gas dispersion.
6 Calculation of source terms.
7 Building wake effects.
8 Overview of the chemistry of the oxides of nitrogen.
9 Overview of the ADMS complex terrain module.
10 Overview of the ADMS deposition module.
11 ADMS examples.
12 Modeling odorous releases.
13 Bibliography of useful gas dispersion books and reports.
14 Glossary of gas dispersion modeling terms.
Appendix A : Modeling Wind Generation of Particulates.
APPENDIX B TABLE OF PROPERTY VALUES FOR SPECIFIC CHEMICALS
Theory of Carbon Formation in Steam Reforming
Contents
1 Introduction
2 Underpinning Theory
2.1 Conceptualization
2.2 Reforming Reactions
2.3 Carbon Formation Chemistry
2.3.1 Natural Gas
2.3.2 Carbon Formation for Naphtha Feeds
2.3.3 Carbon Gasification
2.4 Heat Transfer
3 Causes
3.1 Effects of Carbon Formation
3.2 Types of Carbon
4 What are the Effects of Carbon Formation?
4.1 Why does Carbon Formation Get Worse?
4.1.1 So what is the Next Step?
4.2 Consequences of Carbon Formation
4.3 Why does Carbon Form where it does?
4.3.1 Effect on Process Gas Temperature
4.4 Why does Carbon Formation Propagate Down the Tube?
4.4.1 Effect on Radiation on the Fluegas Side
4.5 Why does Carbon Formation propagate Up the Tube?
5 How do we Prevent Carbon Formation
5.1 The Role of Potash
5.2 Inclusion of Pre-reformer
5.3 Primary Reformer Catalyst Parameters
5.3.1 Activity
5.3.2 Heat Transfer
5.3.3 Increased Steam to Carbon Ratio
6 Steam Out
6.1 Why does increasing the Steam to Carbon Ratio Not Work?
6.2 Why does reducing the Feed Rate not help?
6.3 Fundamental Principles of Steam Outs
TABLES
1 Heat Transfer Coefficients in a Typical Reformer
2 Typical Catalyst Loading Options
FIGURES
1 Hot Bands
2 Conceptual Pellet
3 Naphtha Carbon Formation
4 Heat Transfer within an Reformer
5 Types of Carbon Formation
6 Effect of Carbon on Nickel Crystallites
7 Absorption of Heat
8 Comparison of "Base Case" v Carbon Forming Tube
9 Carbon Formation Vicious Circle
10 Temperature Profiles
11 Carbon Pinch Point
12 Carbon Formation
13 Effect on Process Gas Temperature
14 How does Carbon Propagate into an Unaffected Zone?
15 Movement of the Carbon Forming Region
16 Effect of Hot Bands on Radiative Heat Transfer
17 Effect of Potash on Carbon Formation
18 Application of a Pre-reformer
19 Effect of Activity on Carbon Formation
Calculation of an Ammonia Plant Energy Consumption: Gerard B. Hawkins
Calculation of an Ammonia Plant Energy Consumption:
Case Study: #06023300
Plant Note Book Series: PNBS-0602
CONTENTS
0 SCOPE
1 CALCULATION OF NATURAL GAS PROCESS FEED CONSUMPTION
2 CALCULATION OF NATURAL GAS PROCESS FUEL CONSUMPTION
3 CALCULATION OF NATURAL GAS CONSUMPTION FOR PILOT BURNERS OF FLARES
4 CALCULATION OF DEMIN. WATER FROM DEMIN. UNIT
5 CALCULATION OF DEMIN. WATER TO PACKAGE BOILERS
6 CALCULATION OF MP STEAM EXPORT
7 CALCULATION OF LP STEAM IMPORT
8 DETERMINATION OF ELECTRIC POWER CONSUMPTION
9 DETERMINATION OF THE TOTAL ENERGY CONSUMPTION OF THE AMMONIA PLANT ISBL
10 ADJUSTMENT OF ELECTRIC POWER CONSUMPTION FOR TEST RUN CONDITIONS
11 CALCULATION OF AMMONIA SHARE IN MP STEAM CONSUMPTION IN UTILITIES
12 CALCULATION OF AMMONIA SHARE IN ELECTRIC POWER CONSUMPTION IN UTILITIES
13 DETERMINATION OF THE TOTAL ENERGY CONSUMPTION OF THE AMMONIA PLANT OSBL
14 DETERMINATION OF THE TOTAL ENERGY CONSUMPTION OF THE AMMONIA PLANT
Ammonia Plant Technology
Pre-Commissioning Best Practices
Piping and Vessels Flushing and Cleaning Procedure
CONTENTS
1 Scope
2 Aim/purpose
3 Responsibilities
4 Procedure
4.1 Main cleaning methods
4.1.1 Mechanical cleaning
4.1.2 Cleaning with air
4.1.3 Cleaning with steam (for steam networks only)
4.1.4 Cleaning with water
4.2 Choice of the cleaning method
4.3 Cleaning preparation
4.4 Protection of the devices included in the network
4.5 Protection of devices in the vicinity of the network
4.6 Water flushing procedure
4.6.1 Specific problems of water flushing
4.6.2 Preparation for water flushing
4.6.3 Performing a water flush
4.6.4 Cleanliness criteria
4.7 Air blowing procedure
4.7.1 Specific problems of air blowing
4.7.2 Preparation for air blowing
4.7.3 Performing air blowing
4.7.4 Cleanliness checks
4.8 Steam blowing procedure
4.8.1 Specific problems of steam blowing
4.8.2 Preparation for steam blowing
4.8.3 Performing steam blowing
4.8.4 Cleanliness checks
4.9 Chemical cleaning procedure
4.9.1 Specific problems of cleaning with a chemical solution
4.9.2 Preparation for chemical cleaning
4.9.3 Performing a chemical cleaning
4.9.4 Cleanliness criteria
4.10 Re-assembly - general guideline
4.11 Preservation of flushed piping
PRACTICAL GUIDE ON THE SELECTION OF PROCESS TECHNOLOGY FOR THE TREATMENT OF A...Gerard B. Hawkins
PRACTICAL GUIDE ON THE SELECTION OF PROCESS TECHNOLOGY FOR THE TREATMENT OF AQUEOUS ORGANIC EFFLUENT STREAMS
CONTENTS
0 INTRODUCTION/PURPOSE
1 SCOPE
2 FIELD OF APPLICATION
3 DEFINITIONS
3.1 IPU
3.2 AOS
3.3 BODs
3.4 COD
3.5 TOC
3.6 Toxicity
3.7 Refractory Organics/Hard COD
3.8 Heavy Metals
3.9 EA
3.10 Biological Treatment Terms
3.11 BATNEEC
3.12 BPEO
3.13 EQS/LV
3.14 IPC
3.15 VOC
3.16 F/M Ratio
3.17 MLSS
3.18 MLVSS
4 DESIGN/ECONOMIC GUIDELINES
5 EUROPEAN LEGISLATION
5.1 General
5.2 Integrated Pollution Control (IPC)
5.3 Best Available Techniques Not Entailing Excessive Costs (BATNEEC)
5.4 Best Practicable Environmental Option (BPEO)
5.5 Environmental Quality Standards(EQS)
6 IPU EXIT CONCENTRATION
7 SITE/LOCAL REQUIREMENTS
8 PROCESS SELECTION PROCEDURE
8.1 Waste Minimization Techniques (WMT)
8.2 AOS Stream Definition
8.3 Technical Check List
8.4 Preliminary Selection of Suitable Technologies
8.5 Process Sequences
8.6 Economic Evaluation
8.7 Process Selection
APPENDICES
A DIRECTIVE 76/464/EEC - LIST 1
B DIRECTIVE 76/464/EEC - LIST 2
C THE EUROPEAN COMMISSION PRIORITY CANDIDATE LIST
D THE UK RED LIST
E CURRENT VALUES FOR EUROPEAN COMMUNITY ENVIRONMENTAL QUALITY STANDARDS AND CORRESPONDING LIMIT VALUES
F ESTABLISHED TECHNOLOGIES
G EMERGING TECHNOLOGY
H PROPRIETARY/LESS COMMON TECHNOLOGIES
J COMPARATIVE COST DATA
PRACTICAL GUIDE ON THE REDUCTION OF DISCHARGES TO ATMOSPHERE OF VOLATILE ORGA...Gerard B. Hawkins
PRACTICAL GUIDE ON THE REDUCTION OF DISCHARGES TO ATMOSPHERE OF VOLATILE ORGANIC COMPOUNDS (VOCs)
FOREWORD
CONTENTS
1 INTRODUCTION
2 THE NEED FOR VOC CONTROL
3 CONTROL AT SOURCE
3.1 Choice or Solvent
3.2 Venting Arrangements
3.3 Nitrogen Blanketing
3.4 Pump Versus Pneumatic Transfer
3.5 Batch Charging
3.6 Reduction of Volumetric Flow
3.7 Stock Tank Design
4 DISCHARGE MEASUREMENT
4.1 By Inference or Calculation
4.2 Flow Monitoring Equipment
4.3 Analytical Instruments
4.4 Vent Emissions Database
5 ABATEMENT TECHNOLOGY
5.1 Available Options
5.2 Selection of Preferred Option
5.3 Condensation
5.4 Adsorption
5.5 Absorption
5.6 Thermal Incineration
5.7 Catalytic Oxidation
5.8 Biological Filtration
5.9 Combinations of Process technologies
5.10 Processes Under Development
6 GLOSSARY OF TERMS
7 REFERENCES
Appendix 1. Photochemical Ozone Creation Potentials
Appendix 2. Examples of Adsorption Preliminary Calculations
Appendix 3. Example of Thermal Incineration Heat and Mass Balance
Appendix 4. Cost Correlations
Getting the Most Out of Your Refinery Hydrogen PlantGerard B. Hawkins
Getting the Most Out of Your Refinery Hydrogen Plant
Contents
Summary
1 Introduction
2 "On-purpose" Hydrogen Production
3 Operational Aspects
4 Uprating Options on the Steam Reformer
4.1 Steam Reforming Catalysts and Tube Metallurgy
4.2 Oxygen-blown Secondary Reformer
4.3 Pre-reforming
4.4 Post-reforming
5 Downstream Units
6 Summary of Uprating Options
7 Conclusions
EMERGENCY ISOLATION OF CHEMICAL PLANTS
CONTENTS
1 Introduction
2 When should Emergency Isolation Valves be Installed
3 Emergency Isolation Valves and Associated Equipment
3.1 Installations on existing plant
3.2 Actuators
3.3 Power to close or power to open
3.4 The need for testing
3.5 Hand operated Emergency Valves
3.6 The need to stop pumps in an emergency
3.7 Location of Operating Buttons
3.8 Use of control valves for Isolation
4 Detection of Leaks and Fires
5 Precautions during Maintenance
6 Training Operators to use Emergency Isolation Valves
7 Emergency Isolation when no remotely operated valve is available
References
Glossary
Appendix I Some Fires or Serious Escapes of Flammable Gases or Liquids that could have been controlled by Emergency Isolation Valves
Appendix II Some typical Installations
Amine Gas Treating Unit - Best Practices - Troubleshooting Guide Gerard B. Hawkins
Amine Gas Treating Unit Best Practices - Troubleshooting Guide for H2S/CO2 Amine Systems
Contents
Process Capabilities for gas treating process
Typical Amine Treating
Typical Amine System Improvements
Primary Equipment Overview
Inlet Gas Knockout
Absorber
Three Phase Flash Tank
Lean/Rich Heat Exchanger
Regenerator
Filtration
Amine Reclaimer
Operating Difficulties Overview
Foaming
Failure to Meet Gas Specification
Solvent Losses
Corrosion
Typical Amine System Improvements
Degradation of Amines and Alkanolamines during Sour Gas Treating
APPENDIX
Best Practices - Troubleshooting Guide
Burner Design, Operation and Maintenance on Ammonia PlantsGerard B. Hawkins
Burner Design, Operation and Maintenance on Ammonia Plants
Brief History
Reformer Burner Types/Design
Types of Reformers
Combustion Characteristics
Excess Air/Heater Efficiency
Maintenance, Good Practice
Low Nox Equipment
Summary
Kubernetes & AI - Beauty and the Beast !?! @KCD Istanbul 2024Tobias Schneck
As AI technology is pushing into IT I was wondering myself, as an “infrastructure container kubernetes guy”, how get this fancy AI technology get managed from an infrastructure operational view? Is it possible to apply our lovely cloud native principals as well? What benefit’s both technologies could bring to each other?
Let me take this questions and provide you a short journey through existing deployment models and use cases for AI software. On practical examples, we discuss what cloud/on-premise strategy we may need for applying it to our own infrastructure to get it to work from an enterprise perspective. I want to give an overview about infrastructure requirements and technologies, what could be beneficial or limiting your AI use cases in an enterprise environment. An interactive Demo will give you some insides, what approaches I got already working for real.
Accelerate your Kubernetes clusters with Varnish CachingThijs Feryn
A presentation about the usage and availability of Varnish on Kubernetes. This talk explores the capabilities of Varnish caching and shows how to use the Varnish Helm chart to deploy it to Kubernetes.
This presentation was delivered at K8SUG Singapore. See https://feryn.eu/presentations/accelerate-your-kubernetes-clusters-with-varnish-caching-k8sug-singapore-28-2024 for more details.
Dev Dives: Train smarter, not harder – active learning and UiPath LLMs for do...UiPathCommunity
💥 Speed, accuracy, and scaling – discover the superpowers of GenAI in action with UiPath Document Understanding and Communications Mining™:
See how to accelerate model training and optimize model performance with active learning
Learn about the latest enhancements to out-of-the-box document processing – with little to no training required
Get an exclusive demo of the new family of UiPath LLMs – GenAI models specialized for processing different types of documents and messages
This is a hands-on session specifically designed for automation developers and AI enthusiasts seeking to enhance their knowledge in leveraging the latest intelligent document processing capabilities offered by UiPath.
Speakers:
👨🏫 Andras Palfi, Senior Product Manager, UiPath
👩🏫 Lenka Dulovicova, Product Program Manager, UiPath
GDG Cloud Southlake #33: Boule & Rebala: Effective AppSec in SDLC using Deplo...James Anderson
Effective Application Security in Software Delivery lifecycle using Deployment Firewall and DBOM
The modern software delivery process (or the CI/CD process) includes many tools, distributed teams, open-source code, and cloud platforms. Constant focus on speed to release software to market, along with the traditional slow and manual security checks has caused gaps in continuous security as an important piece in the software supply chain. Today organizations feel more susceptible to external and internal cyber threats due to the vast attack surface in their applications supply chain and the lack of end-to-end governance and risk management.
The software team must secure its software delivery process to avoid vulnerability and security breaches. This needs to be achieved with existing tool chains and without extensive rework of the delivery processes. This talk will present strategies and techniques for providing visibility into the true risk of the existing vulnerabilities, preventing the introduction of security issues in the software, resolving vulnerabilities in production environments quickly, and capturing the deployment bill of materials (DBOM).
Speakers:
Bob Boule
Robert Boule is a technology enthusiast with PASSION for technology and making things work along with a knack for helping others understand how things work. He comes with around 20 years of solution engineering experience in application security, software continuous delivery, and SaaS platforms. He is known for his dynamic presentations in CI/CD and application security integrated in software delivery lifecycle.
Gopinath Rebala
Gopinath Rebala is the CTO of OpsMx, where he has overall responsibility for the machine learning and data processing architectures for Secure Software Delivery. Gopi also has a strong connection with our customers, leading design and architecture for strategic implementations. Gopi is a frequent speaker and well-known leader in continuous delivery and integrating security into software delivery.
Securing your Kubernetes cluster_ a step-by-step guide to success !KatiaHIMEUR1
Today, after several years of existence, an extremely active community and an ultra-dynamic ecosystem, Kubernetes has established itself as the de facto standard in container orchestration. Thanks to a wide range of managed services, it has never been so easy to set up a ready-to-use Kubernetes cluster.
However, this ease of use means that the subject of security in Kubernetes is often left for later, or even neglected. This exposes companies to significant risks.
In this talk, I'll show you step-by-step how to secure your Kubernetes cluster for greater peace of mind and reliability.
Elevating Tactical DDD Patterns Through Object CalisthenicsDorra BARTAGUIZ
After immersing yourself in the blue book and its red counterpart, attending DDD-focused conferences, and applying tactical patterns, you're left with a crucial question: How do I ensure my design is effective? Tactical patterns within Domain-Driven Design (DDD) serve as guiding principles for creating clear and manageable domain models. However, achieving success with these patterns requires additional guidance. Interestingly, we've observed that a set of constraints initially designed for training purposes remarkably aligns with effective pattern implementation, offering a more ‘mechanical’ approach. Let's explore together how Object Calisthenics can elevate the design of your tactical DDD patterns, offering concrete help for those venturing into DDD for the first time!
DevOps and Testing slides at DASA ConnectKari Kakkonen
My and Rik Marselis slides at 30.5.2024 DASA Connect conference. We discuss about what is testing, then what is agile testing and finally what is Testing in DevOps. Finally we had lovely workshop with the participants trying to find out different ways to think about quality and testing in different parts of the DevOps infinity loop.
Essentials of Automations: Optimizing FME Workflows with ParametersSafe Software
Are you looking to streamline your workflows and boost your projects’ efficiency? Do you find yourself searching for ways to add flexibility and control over your FME workflows? If so, you’re in the right place.
Join us for an insightful dive into the world of FME parameters, a critical element in optimizing workflow efficiency. This webinar marks the beginning of our three-part “Essentials of Automation” series. This first webinar is designed to equip you with the knowledge and skills to utilize parameters effectively: enhancing the flexibility, maintainability, and user control of your FME projects.
Here’s what you’ll gain:
- Essentials of FME Parameters: Understand the pivotal role of parameters, including Reader/Writer, Transformer, User, and FME Flow categories. Discover how they are the key to unlocking automation and optimization within your workflows.
- Practical Applications in FME Form: Delve into key user parameter types including choice, connections, and file URLs. Allow users to control how a workflow runs, making your workflows more reusable. Learn to import values and deliver the best user experience for your workflows while enhancing accuracy.
- Optimization Strategies in FME Flow: Explore the creation and strategic deployment of parameters in FME Flow, including the use of deployment and geometry parameters, to maximize workflow efficiency.
- Pro Tips for Success: Gain insights on parameterizing connections and leveraging new features like Conditional Visibility for clarity and simplicity.
We’ll wrap up with a glimpse into future webinars, followed by a Q&A session to address your specific questions surrounding this topic.
Don’t miss this opportunity to elevate your FME expertise and drive your projects to new heights of efficiency.
Slack (or Teams) Automation for Bonterra Impact Management (fka Social Soluti...Jeffrey Haguewood
Sidekick Solutions uses Bonterra Impact Management (fka Social Solutions Apricot) and automation solutions to integrate data for business workflows.
We believe integration and automation are essential to user experience and the promise of efficient work through technology. Automation is the critical ingredient to realizing that full vision. We develop integration products and services for Bonterra Case Management software to support the deployment of automations for a variety of use cases.
This video focuses on the notifications, alerts, and approval requests using Slack for Bonterra Impact Management. The solutions covered in this webinar can also be deployed for Microsoft Teams.
Interested in deploying notification automations for Bonterra Impact Management? Contact us at sales@sidekicksolutionsllc.com to discuss next steps.
UiPath Test Automation using UiPath Test Suite series, part 4DianaGray10
Welcome to UiPath Test Automation using UiPath Test Suite series part 4. In this session, we will cover Test Manager overview along with SAP heatmap.
The UiPath Test Manager overview with SAP heatmap webinar offers a concise yet comprehensive exploration of the role of a Test Manager within SAP environments, coupled with the utilization of heatmaps for effective testing strategies.
Participants will gain insights into the responsibilities, challenges, and best practices associated with test management in SAP projects. Additionally, the webinar delves into the significance of heatmaps as a visual aid for identifying testing priorities, areas of risk, and resource allocation within SAP landscapes. Through this session, attendees can expect to enhance their understanding of test management principles while learning practical approaches to optimize testing processes in SAP environments using heatmap visualization techniques
What will you get from this session?
1. Insights into SAP testing best practices
2. Heatmap utilization for testing
3. Optimization of testing processes
4. Demo
Topics covered:
Execution from the test manager
Orchestrator execution result
Defect reporting
SAP heatmap example with demo
Speaker:
Deepak Rai, Automation Practice Lead, Boundaryless Group and UiPath MVP
Key Trends Shaping the Future of Infrastructure.pdfCheryl Hung
Keynote at DIGIT West Expo, Glasgow on 29 May 2024.
Cheryl Hung, ochery.com
Sr Director, Infrastructure Ecosystem, Arm.
The key trends across hardware, cloud and open-source; exploring how these areas are likely to mature and develop over the short and long-term, and then considering how organisations can position themselves to adapt and thrive.
State of ICS and IoT Cyber Threat Landscape Report 2024 previewPrayukth K V
The IoT and OT threat landscape report has been prepared by the Threat Research Team at Sectrio using data from Sectrio, cyber threat intelligence farming facilities spread across over 85 cities around the world. In addition, Sectrio also runs AI-based advanced threat and payload engagement facilities that serve as sinks to attract and engage sophisticated threat actors, and newer malware including new variants and latent threats that are at an earlier stage of development.
The latest edition of the OT/ICS and IoT security Threat Landscape Report 2024 also covers:
State of global ICS asset and network exposure
Sectoral targets and attacks as well as the cost of ransom
Global APT activity, AI usage, actor and tactic profiles, and implications
Rise in volumes of AI-powered cyberattacks
Major cyber events in 2024
Malware and malicious payload trends
Cyberattack types and targets
Vulnerability exploit attempts on CVEs
Attacks on counties – USA
Expansion of bot farms – how, where, and why
In-depth analysis of the cyber threat landscape across North America, South America, Europe, APAC, and the Middle East
Why are attacks on smart factories rising?
Cyber risk predictions
Axis of attacks – Europe
Systemic attacks in the Middle East
Download the full report from here:
https://sectrio.com/resources/ot-threat-landscape-reports/sectrio-releases-ot-ics-and-iot-security-threat-landscape-report-2024/
State of ICS and IoT Cyber Threat Landscape Report 2024 preview
Avoiding Stress Corrosion Cracking of Carbon Low Alloy and Austenitic Stainless Steels in Chloride and Caustic Environments
1. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
GBH Enterprises, Ltd.
Maintenance Best Practice Guide:
GBHE_MBPG_1614
Avoiding Stress
Corrosion Cracking of
Carbon Low Alloy and
Austenitic Stainless
Steels in Chloride and
Caustic Environments
Process Information Disclaimer
Information contained in this publication or as otherwise supplied to Users is
believed to be accurate and correct at time of going to press, and is given in
good faith, but it is for the User to satisfy itself of the suitability of the Product for
its own particular purpose. GBHE gives no warranty as to the fitness of the
Product for any particular purpose and any implied warranty or condition
(statutory or otherwise) is excluded except to the extent that exclusion is
prevented by law. GBHE accepts no liability for loss, damage or personnel injury
caused or resulting from reliance on this information. Freedom under Patent,
Copyright and Designs cannot be assumed.
2. Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology – Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology – Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
Maintenance Best Practice Guide:
Avoiding Stress Corrosion Cracking of Carbon Low Alloy and Austenitic
Stainless Steels in Chloride and Caustic Environments
CONTENTS
0 PURPOSE
1 SCOPE
2 KEY DEFINITIONS
3 RELEVANT DOCUMENTATION
4 SPECIFIC LEGAL REQUIREMENTS
5 FACTORS PROMOTING STRESS CORROSION CRACKING (SCC)
IN CHLORIDE AND CAUSTIC ENVIRONMENTS
6 AVOIDING STRESS CORROSION CRACKING (SCC)
IN CHLORIDE AND CAUSTIC ENVIRONMENTS
6.1 CONTROL OF STRESS
6.2 CONTROL OF ENVIRONMENT
7 SUMMARY
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APPENDICES
A GUIDANCE ON HYDROTEST WATER QUALITY FOR AUSTENITIC
STAINLESS STEEL EQUIPMENT TO AVOID CHLORIDE SCC
B GUIDANCE ON THE PREVENTION OF CHLORIDE SCC FOR
AUSTENITIC STAINLESS STEEL HEAT EXCHANGERS ON COOLING
WATER DUTIES
C SUMMARY FOR GENERAL GUIDANCE ON SCC OF CARBON STEELS
AND AUSTENITIC STAINLESS STEELS IN CHLORIDE AND CAUSTIC
ENVIRONMENTS
FIGURES
1 SCC OF AUSTENITIC STAINLESS STEELS AS A FUNCTION OF
CHLORIDE CONCENTRATION AND TEMPERATURE
2 CAUSTIC SODA SERVICE FOR AUSTENITIC STAINLESS STEELS
3 GBHE CAUSTIC SODA SERVICE CHART FOR CARBON/LOW ALLOY
STEELS
4 SCC AT TUBE/TUBEPLATE JOINTS DUE TO CONCENTRATION OF
CHLORIDE OR CAUSTIC (HYDROXIDE).
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0 PURPOSE
The purpose of this Maintenance Best Practice Guide is to assist
engineers to avoid stress corrosion cracking when designing or specifying
equipment, to aid in diagnostic work and to guide inspection personnel
dealing with equipment which may hold fluids containing chloride or
caustic (hydroxides).
1 SCOPE
This Maintenance Best Practice Guide is concerned with the performance
of carbon, low alloy steels, and austenitic stainless steels, in fluids
containing chloride or caustic (hydroxides). Those factors which are
known to promote stress corrosion cracking are outlined, and service
charts defining environmental boundaries for stress corrosion cracking in
chloride and caustic containing fluids are presented. General guidance on
the avoidance of stress corrosion cracking is provided.
The avoidance of 'external' stress corrosion cracking of austenitic
stainless steels beneath thermal insulation is covered in a separate
Maintenance Best Practice Guide.
2 KEY DEFINITIONS
Stress Corrosion Cracking Cracking Cracking produced by the
(SCC) combined action of corrosion
and tensile stresses.
3 RELEVANT DOCUMENTATION
GBHE-MBPG-1814 Materials of Construction Review
GBHE-MBPG-1914 Unfired Fusion Welded Pressure Vessels
GBHE-MBPG-2014 Light Duty Items in Stainless Steel
GBHE-MBPG-0714 The Pressure Testing of In-Service Pressurized
Equipment.
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4 SPECIFIC LEGAL REQUIREMENTS
Account shall be taken of relevant local legislation.
5 FACTORS PROMOTING STRESS CORROSION CRACKING (SCC) IN
CHLORIDE AND CAUSTIC ENVIRONMENTS
The common grades of carbon and low alloy steels are vulnerable to
stress corrosion cracking (SCC) in fluids containing sodium or potassium
hydroxide (caustics). They are not vulnerable to SCC in chloride
containing fluids, but can suffer from general corrosion. High strength
grades of steel (>950MPa UTS) can suffer SCC due to hydrogen
produced by corrosion reactions on their surfaces, including those induced
by chloride containing fluids. However, this topic is beyond the scope of
this Best Practice Guide,
All of the common grades of 18%Cr, 8-10%Ni austenitic stainless steel,
including types 304, 304L, 316, 316L, 321 and 347, are vulnerable to SCC
in both chloride and caustic containing fluids. Other grades of stainless
steel, including the more highly alloyed austenitic grades (e.g. those
grades containing >25Ni such as types 904L and 825) and 'duplex' grades
(i.e. those containing 5-7%Ni such as types 2205 and 2507) are also
vulnerable to SCC in chloride and caustic containing fluids, but are beyond
the scope of this Best Practice Guide.
Guides to safe operating conditions in chloride and caustic containing
fluids are shown in Figures 1 to 3. Although this data can be used for
general guidance, it is important to be alert to the effects of local
concentration and heating. Various factors can concentrate otherwise
benign levels of corrodent to concentrations which promote SCC
including:
(a) boiling and evaporative concentration due to locally high heat fluxes/skin
temperatures;
(b) intermittent wetting and drying of surfaces associated with liquid injection
into hot pipelines, level variation in storage vessels, etc.;
(c) the presence of crevices and surface deposits leading to diffusional
concentration.
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Residual fabrication stresses commonly trigger SCC at welds and at cold worked
areas, including cold-formed bends, pressed components, expansions, etc.
Highly stressed equipment such as bellows are also particularly vulnerable.
Heat exchangers of all types are potentially vulnerable to SCC. In the case of
tubular exchangers, problems are more likely if the corrodent is on the shellside,
with heat transfer into the tube/tubeplate crevice. Favored cracking sites are in,
and adjacent to tube/tubesheet welds, and at the overlap zones of the expansion
stages. Vertical or inclined bundles can be particularly vulnerable to such
problems if the top tubesheet is inadequately vented, and a vapor space
develops, as shown schematically in Figure 4. In such cases, even high quality
demineralized waters with trace levels of chloride or caustic can concentrate and
promote cracking in time periods as short as a few days.
In the case of chloride induced SCC of austenitic stainless steels, the qualities of
waters used for pressure testing and cooling are significant issues. Some general
guidance is provided in Appendices A and B.
6 AVOIDING STRESS CORROSION CRACKING IN CHLORIDE AND
CAUSTIC ENVIRONMENTS
6.1 Control of Stress
In the case of carbon and low alloy steels, tensile stresses around yield are
required to promote SCC, which as a result is commonly associated with residual
rather than operating loads. Cracking can then be prevented by appropriate
stress relief procedures, of which thermal stress relief is the more widely
practiced and effective. Equipment design codes contain procedures for thermal
stress relief, but do not give information on when it is required to prevent SCC.
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In the case of austenitic stainless steels, stress corrosion cracking can be
initiated by relatively low stresses. Thermal stress relief in austenitic stainless
steels requires much high temperatures than carbon steels, it is therefore
considered to be a less practicable procedure than for carbon steels. As a result,
thermal stress relief is rarely used to control SCC in austenitic stainless steels.
Dissimilar welds between carbon or low alloy and austenitic materials cannot be
thermally stress relieved effectively, and their use should be avoided in
circumstances where they are vulnerable to SCC.
The use of mechanical stress relief procedures such as shot peening can be
beneficial in specific circumstances. However, such techniques are specialized
and require careful control; a materials engineer should be consulted about their
use whenever possible.
6.2 Control of Environment
Figures 1 to 3 provide guidance on safe operating windows to avoid SCC of
equipment, but care is needed to ensure that local heating/concentration effects
are anticipated successfully at the design stage and avoided. In certain
circumstances, corrosion inhibitors can be used to reduce the propensity of an
environment to promote SCC, e.g. the use of phosphates in waters. However,
there are many traps for the unwary, and some factors which have resulted in
SCC in practice which were not anticipated at the design stage are:
(a) Injection of water with traces of free chloride or caustic to desuperheating
steam, resulting in concentration due to wetting/drying of downstream
surfaces;
(b) Failure to appreciate that some sources of caustic have high chloride
levels;
(c) Hydro testing equipment with poor quality water;
(d) Allowing excessive fouling of tubular heat exchanger shellside surfaces,
resulting in local heating/concentration;
(e) Gagging back on water supply to heat exchangers to control process
temperatures resulting in local heating/concentration;
(f) Using high temperature tubeside process cleaning procedures resulting in
dry out and therefore concentration, of water in the shellside.
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7 SUMMARY
The main factors outlined in this Good Practice Guide are summarized in
Appendix C.
Stress corrosion cracking is a complex topic, and a materials engineer should be
Consulted whenever possible.
Effect of Cu-content on crack growth rate. The effect of initial stress
on time to failure of maraging
steel in 3.5% NaCI solution.
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APPENDIX A GUIDANCE ON HYDROTEST WATER QUALITY
FOR AUSTENITIC STAINLESS STEEL EQUIPMENT TO
AVOID CHLORIDE SCC
Control of the quality of hydro test water is necessary for the prevention of stress
corrosion cracking by chlorides present in the test water, which remain in the
equipment after the hydraulic test. The greatest susceptibility is at high chloride
concentrations and service temperatures more than 60o
C.
(a) Do not use salt or contaminated water for testing, e.g. borehole, river,
canal, lake, estuarine, or sea water.
(b) When the process operating temperature is less than 60o
C then use of
potable quality test water is acceptable.
(c) When the operating temperature is above 600
C but the metal is flushed by
process fluids or condensing steam at start up, then the use of potable
quality test water is acceptable, provided the equipment is completely self-
draining.
(d) When the operating conditions are above 60o
C and the metal is not
flushed by process fluids or condensing steam on start up, then, provided
the equipment is completely self-draining, test water of potable quality can
be used, followed by flushing with water containing less than 1ppm
chloride.
(e) When the operating temperature is above 60o
C, and the vessel is not
flushed by process fluids or condensing steam and is NOT completely
self-draining, test water with less than 1ppm chloride should be used. Dry
out carefully by swabbing, and/or blowing with warm air (less than 60oC).
(f) Reference (c) and (d) above, enclosed spaces such as shell sides of heat
exchangers or vessel or pipe jackets which operate above 600C should
always be tested with water containing less than 1ppm chloride.
Experience dictates that residual chloride cannot be removed successfully
by flushing.
Note:
Less than 1ppm chloride = demineralized water, or pure condensate.
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APPENDIX B GUIDANCE ON THE PREVENTION OF CHLORIDE
SCC FOR AUSTENITIC STAINLESS STEEL HEAT
EXCHANGERS ON COOLING WATER DUTIES
The '300' series of 18%Cr, 8-10%Ni austenitic stainless steels are used
commonly for heat exchanger construction. Their weakness is their susceptibility
to stress corrosion cracking in chloride-containing media, and, materials
engineers are often asked, 'What is the critical level of chloride ions which
stainless steel will tolerate?’ This is not a question to which there is a simple
answer.
A much easier question to answer is, ‘what is the critical temperature below
which chloride stress corrosion cracking will not occur?' There is no unique
answer to this question either, but most materials engineers would agree that
below 700
C stress corrosion cracking is unlikely, and below 600
C it is extremely
rare. For this reason, prevention of stress corrosion cracking in heat exchangers
in the Company cooling systems has been based upon control of skin
temperature rather than chloride level per se.
In broad terms, the chloride contents of the Company cooling systems in the US
are generally < 200 ppm, and rarely, if ever, exceed 600 ppm. In Europe,
somewhat higher levels have to be tolerated, but even so, chloride contents
rarely exceed 800 ppm. Where flow rates are high and crevices/deposits are
absent, i.e. when cooling water flow is through the tubes, US experience
indicates that skin temperatures up to 100O
C can be tolerated in such fluids.
However, stress corrosion cracking commonly initiates from pitting or
crevice/deposit corrosion, and is thus favored by low flow conditions and
occluded areas associated with joints, scales, foulants, etc. Thus for water-in-
shell bundles or plate exchangers, the only reliable defense against stress
corrosion cracking is to restrict skin temperatures to a maximum of 600
C.
In practice most cases of stress corrosion cracking in austenitic stainless steel
heat exchangers are associated with operational practices resulting in higher skin
temperatures and/or higher chloride contents than anticipated at the design
stage. Thus, excessive fouling of shellside tube surfaces, restricting water flow to
adjust process temperatures, high temperature tubeside cleaning resulting
in shellside dry out etc, etc, can lead to failure by stress corrosion cracking in
systems which would have otherwise proved benign. If you have any doubts
about the integrity of your own system, contact a materials engineer.
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APPENDIX C
SUMMARY FOR GENERAL GUIDANCE ON SCC OF CARBON STEELS AND
AUSTENITIC STAINLESS STEELS IN CHLORIDE AND CAUSTIC
ENVIRONMENTS
CHLORIDE ENVIRONMENTS (CL¯ )
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CAUSTIC ENVIRONMENTS (OH¯ )
Notes:
1 The term austenitic stainless steels as used in this note includes grades
304, 304L, 316, 316L 321 and 347.
2 The term carbon steels includes carbon-manganese and low alloy steels.
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FIGURE 1 SCC OF AUSTENITIC STAINLESS STEELS AS A FUNCTION
OF CHLORIDE CONCENTRATION AND TEMPERATURE
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FIGURE 2 CAUSTIC SODA (SODIUM HYDROXIDE) SERVICE CHART FOR
AUSTENITIC STAINLESS STEELS
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FIGURE 3 GBHE CAUSTIC SODA (SODIUM HYDROXIDE) SERVICE
CHART FOR CARBON/LOW ALLOY STEELS
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FIGURE 4 SCC AT TUBE/TUBEPLATE JOINTS DUE TO
CONCENTRATION OF CHLORIDE OR CAUSTIC (HYDROXIDE)
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