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ACIDS & BASES
               DEFINITIONS
                1. Operational
                2. Conceptual
                    a. Arrhenius
                    b. Bronsted-Lowry
                    c. Lewis

               AMPHOTERISM
                1. water and ammonia
8/19/2006
                2. polyprotic acids
                 /rmbb            1
OPERATIONAL
 DEFINITION based on experimental data
  - These are definitions
   using our senses with the help of colorimetric
   instruments such as indicators (litmus,
   phenolphthalein, methyl orange, etc.).
   ACIDS                       BASES
   • Electrolytes*             • Electrolytes*
   • Taste sour                • With bitter taste
   • Turn blue litmus          • Feel slippery
     red                       • Turn red litmus blue
   • React with metal to       • Pink  violet with
     form H2 gas                 phph
    • Colorless with phph • Yellow with methyl
ectrolytes can bemethyl
    • Red with classified as weak or strong depending 2on it
                                 orange
                           /rmbb
/rmbb   3
/rmbb   4
8/19/2006   /rmbb   5
CONCEPTUAL DEFINITION
- These are definitions of acids and bases based on
  theories proposed by different scientists namely:

                       Acid               Base
             - yields          - yields
  Arrhenius hydrogen ion (H+) hydroxide ion
            in aq’s solution  (OH-) in aq’s
                              solution
                               - proton
Bronsted & Lowry
             - proton donor
                              acceptor


      Lewis        - e- pair
                  acceptor
                                    -   e- pair donor
                         /rmbb                          6
Limitations of each definition:
 • H+ vs. H3O+
 • inability of compounds without OH_ to be a base
 • hydrogen containing compounds that cannot donate
  H+
 • inability of compounds without H+ to be an acid
                 Example
                s:




                       /rmbb                     7
Examples of Arrhenius acids &
bases
 1) HCl → H+(aq) + Cl-(aq)
 2) NaOH → Na+(aq) + OH-(aq)
 3) CH3COOH → CH3COO-(aq) + H+(aq)
 4) H2SO4 → H+(aq) + HSO4-(aq)
 5) Ba(OH)2 → Ba2+(aq) + 2 OH-(aq)
 6) KOH → K+(aq) + OH-(aq)
 7) NaCl → Na+(aq) + Cl-(aq)



                  /rmbb              8
Conjugate Acids & Bases
      A conjugate pair is composed of one
       acid and one base.



                1      2
                                   1   2




     Examples of Bronsted-Lowry acids &
     bases
8/19/2006                  /rmbb             9
/rmbb   10
Relative Strengths of Bronsted-Lowry
Acids & Bases

   According to this theory, the strength of an
    acid is measured by its tendency to donate a
    proton, while that of a base is measured by
    its tendency to accept a proton.

     RULE 1: The stronger an acid is, the weaker its
    conjugate base. The stronger the base is, the
    weaker its conjugate acid.
     RULE 2: Proton transfer reactions tend to favor
    the formation of the weaker acid and the weaker
    base.                /rmbb                       11
A. Complete and identify the
 conjugate acid-base pairs in the
 following reactions:
1. NH3 + HF ⇔
 CN- + H2O ⇔
B. Complete the following acid-base
reactions & predict the direction of
the predominant proton transfer
reaction and show it by the lengths of
the arrows.:
 HCl + H2O →
 CH3COOH + H2O →
                   /rmbb                 12
Examples of Lewis acids & bases
  1.Electron-deficient
   molecules
  2.Cations
  3.Super-octet molecules
  4.Molecules with multiple
   bonds




                 /rmbb            13

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Ab Lec1

  • 1. ACIDS & BASES  DEFINITIONS 1. Operational 2. Conceptual a. Arrhenius b. Bronsted-Lowry c. Lewis  AMPHOTERISM 1. water and ammonia 8/19/2006 2. polyprotic acids /rmbb 1
  • 2. OPERATIONAL DEFINITION based on experimental data - These are definitions using our senses with the help of colorimetric instruments such as indicators (litmus, phenolphthalein, methyl orange, etc.). ACIDS BASES • Electrolytes* • Electrolytes* • Taste sour • With bitter taste • Turn blue litmus • Feel slippery red • Turn red litmus blue • React with metal to • Pink  violet with form H2 gas phph • Colorless with phph • Yellow with methyl ectrolytes can bemethyl • Red with classified as weak or strong depending 2on it orange /rmbb
  • 3. /rmbb 3
  • 4. /rmbb 4
  • 5. 8/19/2006 /rmbb 5
  • 6. CONCEPTUAL DEFINITION - These are definitions of acids and bases based on theories proposed by different scientists namely: Acid Base - yields - yields Arrhenius hydrogen ion (H+) hydroxide ion in aq’s solution (OH-) in aq’s solution - proton Bronsted & Lowry - proton donor acceptor Lewis - e- pair acceptor - e- pair donor /rmbb 6
  • 7. Limitations of each definition: • H+ vs. H3O+ • inability of compounds without OH_ to be a base • hydrogen containing compounds that cannot donate H+ • inability of compounds without H+ to be an acid Example s: /rmbb 7
  • 8. Examples of Arrhenius acids & bases 1) HCl → H+(aq) + Cl-(aq) 2) NaOH → Na+(aq) + OH-(aq) 3) CH3COOH → CH3COO-(aq) + H+(aq) 4) H2SO4 → H+(aq) + HSO4-(aq) 5) Ba(OH)2 → Ba2+(aq) + 2 OH-(aq) 6) KOH → K+(aq) + OH-(aq) 7) NaCl → Na+(aq) + Cl-(aq) /rmbb 8
  • 9. Conjugate Acids & Bases  A conjugate pair is composed of one acid and one base. 1 2 1 2 Examples of Bronsted-Lowry acids & bases 8/19/2006 /rmbb 9
  • 10. /rmbb 10
  • 11. Relative Strengths of Bronsted-Lowry Acids & Bases According to this theory, the strength of an acid is measured by its tendency to donate a proton, while that of a base is measured by its tendency to accept a proton. RULE 1: The stronger an acid is, the weaker its conjugate base. The stronger the base is, the weaker its conjugate acid. RULE 2: Proton transfer reactions tend to favor the formation of the weaker acid and the weaker base. /rmbb 11
  • 12. A. Complete and identify the conjugate acid-base pairs in the following reactions: 1. NH3 + HF ⇔  CN- + H2O ⇔ B. Complete the following acid-base reactions & predict the direction of the predominant proton transfer reaction and show it by the lengths of the arrows.:  HCl + H2O →  CH3COOH + H2O → /rmbb 12
  • 13. Examples of Lewis acids & bases 1.Electron-deficient molecules 2.Cations 3.Super-octet molecules 4.Molecules with multiple bonds /rmbb 13