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1
                                 SAMPLE PAPER


                                                  Level 1 Science
        90944 (1.5): Demonstrate understanding of aspects of
                         acids and bases

                                                                Credits: Four

 You should answer ALL parts of ALL questions in this booklet.

 A table of ions and a periodic table are provided in the resource booklet for Science 90944 (1.5). Check
 that you have been supplied with the resource booklet for Science 90944 (1.5).

 If you need more space for any answer, use the page(s) provided at the back of this booklet and clearly
 number the question.

 Check that this booklet has pages 2–11 in the correct order and that none of these pages is blank.

 YOU MUST HAND THIS BOOKLET TO YOUR TEACHER AT THE END OF THE ALLOTTED TIME.



   For Assessor’s
   use only                                             Achievement Criteria

                                                              Achievement                                     Achievement
               Achievement
                                                               with Merit                                    with Excellence

   Demonstrate understanding of                    Demonstrate in-depth                            Demonstrate comprehensive
   aspects of acids and bases.                     understanding of aspects of                     understanding of aspects of
                                                   acids and bases.                                acids and bases.


                                             Overall Level of Performance




                                                        © New Zealand Qualifications Authority, 2010
All rights reserved. No part of this publication may be reproduced by any means without the prior permission of the New Zealand Qualifications Authority.
2                                                   Assessor’s
                                                                                                use only
       You are advised to spend 60 minutes answering the questions in this booklet.

QUESTION ONE: IONIC COMPOUNDS

(a)   Magnesium and calcium atoms both form ions with a charge of +2. Magnesium atoms form
      Mg2+ ions, and calcium atoms form Ca2+ ions.

      Explain why magnesium and calcium atoms form ions with the same charge of +2. In your
      answer, you should:
      • define an ion
      • explain why atoms form ions
      • identify the group on the periodic table where the two atoms are found
      • explain why both magnesium and calcium ions have a charge of +2.




(b)   Sodium and beryllium atoms form ions with different charges.

      Complete the table below.

                     Periodic table          Electron arrangement     Charge on the ion that
       Element
                     group number            of atom                  the atom forms



       Sodium




       Beryllium




                                          Science 90944 (1.5)
3                                                 Assessor’s
                                                                                                   use only
(c)   Explain why the ions in sodium hydroxide combine to give the formula NaOH but the ions in
      beryllium hydroxide combine to give the formula Be(OH)2.

      In your answer, you should:
      • compare the charges on the individual ions found in the compounds sodium hydroxide and
        beryllium hydroxide
      • explain why the ions combine in the ratios the way they do to form the compounds NaOH
        and Be(OH)2.




                                         Science 90944 (1.5)
4                                                 Assessor’s
                                                                                                            use only
QUESTION TWO: ISOTOPES AND IONS

                                                                                                       6
Lithium atoms can exist in different forms called isotopes. Two of these isotopes are Lithium-6 (      3

                          7
Li    ) and Lithium-7 (   3   Li).

                     6               7
(a)   Explain why    3   Li and      3   Li are both neutral atoms. In your answer, you should fully
      describe their atomic structure and state their electron configuration.




                                                 Science 90944 (1.5)
5                                                      Assessor’s
                                                                                                           use only
                                                                            7
(b)   Berylium can exist as an isotope in the form of beryllium-7 (         4   Be).

                                 7                         6            7
      Discuss how the mass of    4   Be compares with      3   Li AND   3       Li. In your answer, you
      should:
      • consider the atomic structure of each atom
      • consider the meaning of the numbers ‘6’ and ‘7’ in terms of the atomic structures
      • explain how the particles within an atom contribute to its overall mass.

      You may draw labelled diagrams in the box below to support your answer.




                                           Science 90944 (1.5)
6             Assessor’s
                       use only




Science 90944 (1.5)
7                                                                      Assessor’s
                                                                                                         use only
QUESTION THREE: ACID AND BASE REACTIONS

A student puts 5 mL of dilute hydrochloric acid into a boiling tube and adds five drops of universal
indicator to the solution. The student then takes a solution of sodium hydroxide of the same
concentration as the acid and adds it one drop at a time to the acid until the colour stops changing.

(a)   (i)    Describe the colour of the universal indicator solution:

             •   in the hydrochloric acid before any sodium hydroxide was added.




             •   when the sodium hydroxide was added and the colour of the solution stopped
                 changing.




      (ii)    As the sodium hydroxide is added several colour changes occur.

              Explain how the colour changes relate to pH AND what ions are present in the solution
              colour changes.




                                             Science 90944 (1.5)
8                                                  Assessor’s
                                                                                                   use only
(b)   The student combines equal volumes of nitric acid solution and sodium carbonate solution.
      Both solutions have the same concentration.

      Discuss what happens in this reaction. In your answer, you should:
      • name the type of reaction involved and the ions involved
      • describe what the student would observe
      • state the products of the reaction and link these to the observations made
      • write a word equation for the reaction
      • write a balanced symbol equation for the reaction.




      Word equation:




      Balanced symbol equation:




                                          Science 90944 (1.5)
9                                                   Assessor’s
                                                                                                        use only
QUESTION FOUR: RATES OF REACTION

Marble chips (calcium carbonate) are added to dilute hydrochloric acid in a conical flask. The flask
is connected to an inverted measuring cylinder in a trough of water, as shown in the diagram below.

The volume of gas produced is measured over a few minutes, and the results used to sketch a graph.




(a)   The slope of the graph is steep at the beginning and then levels off over time.

      Explain what is happening, in terms of particles, during the reaction.




                                           Science 90944 (1.5)
10                                                   Assessor’s
                                                                                                    use only
(c)   Complete the word and symbol equations below to show the reaction in the experiment.

      Word equation:




      Balanced symbol equation:




(d)   The experiment is repeated but this time the same mass of marble chips is crushed into a
      powder before it is added to the flask.

      Discuss the effect on the reaction rate of using powdered marble with hydrochloric acid
      compared with using marble chips. In your answer, you should:
      • compare the rates of reaction
      • explain the differences in the reaction rate by discussing how crushing the marble chips
        affects the number of particle collisions.




                                          Science 90944 (1.5)
11                                 Assessor’s
                                                                    use only
           Extra paper for continuing your answers, if required.
                      Clearly number the question.


Question
number




                           Science 90944 (1.5)
12                                 Assessor’s
                                                                    use only
           Extra paper for continuing your answers, if required.
                      Clearly number the question.


Question
number




                           Science 90944 (1.5)

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90944 sample paper-2010 acids and bases

  • 1. 1 SAMPLE PAPER Level 1 Science 90944 (1.5): Demonstrate understanding of aspects of acids and bases Credits: Four You should answer ALL parts of ALL questions in this booklet. A table of ions and a periodic table are provided in the resource booklet for Science 90944 (1.5). Check that you have been supplied with the resource booklet for Science 90944 (1.5). If you need more space for any answer, use the page(s) provided at the back of this booklet and clearly number the question. Check that this booklet has pages 2–11 in the correct order and that none of these pages is blank. YOU MUST HAND THIS BOOKLET TO YOUR TEACHER AT THE END OF THE ALLOTTED TIME. For Assessor’s use only Achievement Criteria Achievement Achievement Achievement with Merit with Excellence Demonstrate understanding of Demonstrate in-depth Demonstrate comprehensive aspects of acids and bases. understanding of aspects of understanding of aspects of acids and bases. acids and bases. Overall Level of Performance © New Zealand Qualifications Authority, 2010 All rights reserved. No part of this publication may be reproduced by any means without the prior permission of the New Zealand Qualifications Authority.
  • 2. 2 Assessor’s use only You are advised to spend 60 minutes answering the questions in this booklet. QUESTION ONE: IONIC COMPOUNDS (a) Magnesium and calcium atoms both form ions with a charge of +2. Magnesium atoms form Mg2+ ions, and calcium atoms form Ca2+ ions. Explain why magnesium and calcium atoms form ions with the same charge of +2. In your answer, you should: • define an ion • explain why atoms form ions • identify the group on the periodic table where the two atoms are found • explain why both magnesium and calcium ions have a charge of +2. (b) Sodium and beryllium atoms form ions with different charges. Complete the table below. Periodic table Electron arrangement Charge on the ion that Element group number of atom the atom forms Sodium Beryllium Science 90944 (1.5)
  • 3. 3 Assessor’s use only (c) Explain why the ions in sodium hydroxide combine to give the formula NaOH but the ions in beryllium hydroxide combine to give the formula Be(OH)2. In your answer, you should: • compare the charges on the individual ions found in the compounds sodium hydroxide and beryllium hydroxide • explain why the ions combine in the ratios the way they do to form the compounds NaOH and Be(OH)2. Science 90944 (1.5)
  • 4. 4 Assessor’s use only QUESTION TWO: ISOTOPES AND IONS 6 Lithium atoms can exist in different forms called isotopes. Two of these isotopes are Lithium-6 ( 3 7 Li ) and Lithium-7 ( 3 Li). 6 7 (a) Explain why 3 Li and 3 Li are both neutral atoms. In your answer, you should fully describe their atomic structure and state their electron configuration. Science 90944 (1.5)
  • 5. 5 Assessor’s use only 7 (b) Berylium can exist as an isotope in the form of beryllium-7 ( 4 Be). 7 6 7 Discuss how the mass of 4 Be compares with 3 Li AND 3 Li. In your answer, you should: • consider the atomic structure of each atom • consider the meaning of the numbers ‘6’ and ‘7’ in terms of the atomic structures • explain how the particles within an atom contribute to its overall mass. You may draw labelled diagrams in the box below to support your answer. Science 90944 (1.5)
  • 6. 6 Assessor’s use only Science 90944 (1.5)
  • 7. 7 Assessor’s use only QUESTION THREE: ACID AND BASE REACTIONS A student puts 5 mL of dilute hydrochloric acid into a boiling tube and adds five drops of universal indicator to the solution. The student then takes a solution of sodium hydroxide of the same concentration as the acid and adds it one drop at a time to the acid until the colour stops changing. (a) (i) Describe the colour of the universal indicator solution: • in the hydrochloric acid before any sodium hydroxide was added. • when the sodium hydroxide was added and the colour of the solution stopped changing. (ii) As the sodium hydroxide is added several colour changes occur. Explain how the colour changes relate to pH AND what ions are present in the solution colour changes. Science 90944 (1.5)
  • 8. 8 Assessor’s use only (b) The student combines equal volumes of nitric acid solution and sodium carbonate solution. Both solutions have the same concentration. Discuss what happens in this reaction. In your answer, you should: • name the type of reaction involved and the ions involved • describe what the student would observe • state the products of the reaction and link these to the observations made • write a word equation for the reaction • write a balanced symbol equation for the reaction. Word equation: Balanced symbol equation: Science 90944 (1.5)
  • 9. 9 Assessor’s use only QUESTION FOUR: RATES OF REACTION Marble chips (calcium carbonate) are added to dilute hydrochloric acid in a conical flask. The flask is connected to an inverted measuring cylinder in a trough of water, as shown in the diagram below. The volume of gas produced is measured over a few minutes, and the results used to sketch a graph. (a) The slope of the graph is steep at the beginning and then levels off over time. Explain what is happening, in terms of particles, during the reaction. Science 90944 (1.5)
  • 10. 10 Assessor’s use only (c) Complete the word and symbol equations below to show the reaction in the experiment. Word equation: Balanced symbol equation: (d) The experiment is repeated but this time the same mass of marble chips is crushed into a powder before it is added to the flask. Discuss the effect on the reaction rate of using powdered marble with hydrochloric acid compared with using marble chips. In your answer, you should: • compare the rates of reaction • explain the differences in the reaction rate by discussing how crushing the marble chips affects the number of particle collisions. Science 90944 (1.5)
  • 11. 11 Assessor’s use only Extra paper for continuing your answers, if required. Clearly number the question. Question number Science 90944 (1.5)
  • 12. 12 Assessor’s use only Extra paper for continuing your answers, if required. Clearly number the question. Question number Science 90944 (1.5)