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2000-CE
CHEM                      HONG KONG EXAMINATIONS AUTHORITY

2               HONG KONG CERTIFICATE OF EDUCATION EXAMINATION 2000



                           CHEMISTRY PAPER 2

    10.45 am – 11.45 am      (1 hour)
                                                              Subject Code 160




    1.    Read carefully the instructions on the Answer Sheet and insert the information
          required (including the Subject Code) in the spaces provided.

    2.    When told to open this book, check that all the questions are there.   Look for
          the words ‘END OF PAPER’ after the last question.

          ANSWER ALL QUESTIONS.
    3.                                       All the answers should be marked on the
          Answer Sheet.

          Note that you may only mark ONE answer to each question.
    4.                                                                     Two or more
          answers will score NO MARKS.

    5.    All questions carry equal marks.     No marks will be deducted for wrong
          answers.




    香 港 考 試 局     保 留 版 權
    Hong Kong Examinations Authority
    All Rights Reserved 2000


    2000-CE-CHEM 2–1
There are 50 questions in this paper.


1.      A compound formed from element X and sulphur has the following
        electronic structure :


                               S
                      S   X

        (Only electrons in the outermost shells are shown.)

        How many electrons are there in the outermost shell of an atom of X ?

                 A.       2
                 B.       4
                 C.       6
                 D.       8


2.      Caesium (Cs) is a Group I element in the Periodic Table and its relative
        atomic mass is greater than that of potassium. Which of the following
        statements concerning caesium is INCORRECT ?

                 A.       Caesium is a weaker reducing agent than potassium.
                 B.       Caesium reacts violently with water.
                 C.       Caesium is a soft metal.
                 D.       Caesium reacts with oxygen to form an oxide with
                          formula Cs2O.


3.      Iron cans used for canning food are usually coated with tin instead of zinc.
        This is because

                 A.       tin is more reactive than zinc.
                 B.       tin ions are non-toxic but zinc ions are toxic.
                 C.       tin forms an alloy with iron and this alloy is corrosion
                          resistant.
                 D.       tin prevents iron cans from rusting by sacrificial
                          protection.




2000-CE-CHEM 2−2                        –1–
         保留版權 All Rights Reserved 2000
4.     Metal X forms an oxide. 27.53 g of this oxide contains 24.96 g of X. What
       is the mole ratio of X to oxygen in the oxide ?

       (Relative atomic masses : O = 16.0, X = 207.0)

                A.       1:1
                B.       1:2
                C.       2:3
                D.       3:4


5.     Which of the following gases are the major products liberated in the
       electrolysis of concentrated sodium chloride solution using carbon
       electrodes ?

                         Cathode            Anode

                A.       hydrogen           chlorine
                B.       chlorine           hydrogen
                C.       hydrogen           oxygen
                D.       oxygen             hydrogen


6.     Which of the following pairs of compounds can be distinguished by treating
       with an acidified potassium dichromate solution ?

                A.       ethane and ethene
                B.       ethanol and propan-1-ol
                C.       sodium carbonate and sodium hydrogencarbonate
                D.       sodium sulphite and sodium sulphate


       Element X occurs in nature as two isotopes, 63X and 65X. If the relative
7.
       atomic mass of X is 63.5, what is the relative abundance of the 63X isotope ?

                A.       25%
                B.       60%
                C.       75%
                D.       90%




                                                             Go on to the next page
2000-CE-CHEM 2–3                      –2–
        保留版權 All Rights Reserved 2000
8.     Which of the following statements concerning members of a homologous
       series is INCORRECT ?

               A.      They contain carbon and hydrogen only.
               B.      They can be represented by the same general formula.
               C.      They have similar chemical properties.
               D.      Their boiling points increase with their relative molecular
                       masses.


9.     The atomic number of element X is 12. X reacts with element Y to form
       an ionic compound with formula XY2. To which group of the Periodic
       Table does Y belong ?

               A.      Group I
               B.      Group IV
               C.      Group VI
               D.      Group VII


10.    Manufacturing ammonia by the Haber process involves the reversible
       reaction :

               N2(g) + 3H2(g)      2NH3(g)

       Which of the      following   statements   concerning    the   process   is
       INCORRECT ?

               A.      The forward reaction can go to completion if iron powder
                       is used as a catalyst.
               B.      The optimum conditions for the process are 500°C and
                       200 atm.
               C.      The raw materials are derived from air and water.
               D.      The forward reaction and backward reaction occur
                       simultaneously.




2000-CE-CHEM 2−4                     –3–
        保留版權 All Rights Reserved 2000
11.    Different volumes of 2.0 M potassium hydroxide solution and 2.0 M
       sulphuric acid are mixed in a polystyrene cup. In which of the following
       combinations would the temperature rise be the greatest ?

            Volume of 2.0 M KOH(aq)/cm 3       Volume of 2.0 M H 2 SO 4 (aq)/cm 3

       A.                20.0                                     40.0
       B.                30.0                                     30.0
       C.                40.0                                     20.0
       D.                45.0                                     15.0


12.    Which of the following natural substances is essentially a single
       compound ?

                A.       air
                B.       coal
                C.       petroleum
                D.       quartz


13.    Consider the compounds represented by the two structures below :

                O        HH                     HHO
                                     and
            H   C    O   C   C   H         H    C   C    C   OH
                         HH                     HH

       Which of the following statements concerning these compounds is correct ?

                A.       Both compounds can turn wet blue litmus paper red.
                B.       Both compounds have the same odour.
                C.       Both compounds have the same molecular formula.
                D.       Both compounds have the same boiling point.




                                                             Go on to the next page
2000-CE-CHEM 2−5                     –4–
        保留版權 All Rights Reserved 2000
14.    Which of the following solutions can react with bromine water to give a
       colourless solution ?

               A.       sodium chloride solution
               B.       sodium sulphite solution
               C.       sodium iodide solution
               D.       sodium hypochlorite solution

15.    A polymer has the following structure :
                    CH3       CH3

                    C         C
                                     n
                    H         H

       What is the monomer of this polymer ?

               A.       butane
               B.       but-1-ene
               C.       but-2-ene
               D.       2-methylpropene

16.    Consider the following equation :

                                                    →
               3Zn(s) + 2NO3–(aq) + 8H+(aq)             3Zn2+(x) + 2NO(y) + 4H2O(z)

       Which of the following combinations is correct ?

                                    y
                          x                    z
               A.       aq          g          aq
               B.       aq          g
               C.       aq          aq
               D.                   g          aq

       The melting point and boiling point of substance X are 321°C and 765°C
17.
                      In its molten state, X conducts electricity without
       respectively.
       decomposition. X probably has

               A.       an ionic structure.
               B.       a metallic structure.
               C.       a simple molecular structure.
               D.       a covalent network structure.


2000-CE-CHEM 2−6                         –5–
        保留版權 All Rights Reserved 2000
18.    Some potassium carbonate solution is added to a sample of tap water. The
       mixture then appears cloudy. Which of the following ions is probably
       present in the sample ?

                         NH4+
                A.
                         Mg2+
                B.
                         Br–
                C.
                         SO42–
                D.


19.    Gold ornaments are usually made from an alloy of gold and copper instead
       of pure gold. This is because the alloy

                A.      can be found free in nature.
                B.      is more corrosion resistant than pure gold.
                C.      is denser than pure gold.
                D.      is stronger than pure gold.


       A sample of concentrated sulphuric acid has a density of 1.83 g cm–3 and
20.
       contains 94.0% of sulphuric acid by mass. What is the concentration
       (correct to one decimal place) of sulphuric acid in the sample ?

       (Relative atomic masses : H = 1.0, O = 16.0, S = 32.1)

                A.       17.5 M
                B.       18.3 M
                C.       18.7 M
                D.       19.8 M


21.    Which of the following processes requires a catalyst ?

                A.       preparation of ethyl ethanoate from ethanoic acid and
                         ethanol
                B.       conversion of sulphur trioxide to concentrated sulphuric
                         acid
                C.       manufacture of chlorine bleach from brine
                D.       reduction of iron(III) oxide to iron




                                                                Go on to the next page
2000-CE-CHEM 2−7                      –6–
        保留版權 All Rights Reserved 2000
22.    A white solid dissolves in water to give an alkaline solution. The solution
       reacts with dilute hydrochloric acid to give a gas. The solid is probably

                A.       calcium oxide.
                B.       calcium carbonate.
                C.       potassium hydroxide.
                D.       potassium carbonate.


       In an experiment, 21.8 g of zinc was treated with 250.0 cm3 o f 2 M
23.                                                                     .0
       hydrochloric acid. What volume of hydrogen was liberated at room
       temperature and pressure ?

       (Relative atomic mass : Zn = 65.4;
                                                                      3
        molar volume of gas at room temperature and pressure = 24.0 dm )

                         4.0 dm3
                A.
                         6.0 dm3
                B.
                         8.0 dm3
                C.
                        12.0 d m3
                D.


24.    Which of the following compounds is insoluble in water ?

                A.       methanol
                B.       methanoic acid
                C.       methyl methanoate
                D.       sodium methanoate

       (This item was deleted.)

25.    Which of the following processes is endothermic ?

                A.       cracking of petroleum fractions
                B.       fermentation of glucose solution
                C.       manufacture of ammonia by the Haber process
                D.       oxidation of sulphur dioxide to sulphur trioxide in the
                         contact process




2000-CE-CHEM 2−8                     –7–
       保留版權 All Rights Reserved 2000
26.    Which of the following combinations is correct ?

                         Type of fire            Type of fire extinguisher to use

                A.       electrical fire                       water
                B.       electrical fire                       foam
                C.       kerosene fire                         water
                D.       kerosene fire                         foam


27.    Which of the following changes occurs in a catalytic converter installed in a
       motor car ?

                A.       Nitrogen monoxide changes to nitrogen dioxide.
                B.       Carbon monoxide changes to carbon dioxide.
                C.       Unburnt hydrocarbons change to carbon particles.
                D.       Sulphur changes to sulphur dioxide.


28.    Which of the following changes is NOT a redox reaction ?

                         Fe2(SO4)3 + H2S → 2FeSO4 + S + H2SO4
                A.
                         2Al + 6HCl → 2AlCl3 + 3H2
                B.
                         CaCO3 + CO2 + H2O → Ca(HCO3)2
                C.
                         2KClO3 → 2KCl + 3O2
                D.


29.    Which of the following compounds would react with ammonium chloride
       on heating ?

                A.       concentrated nitric acid
                B.       concentrated hydrochloric acid
                C.       sodium hydroxide solution
                D.       magnesium sulphate solution




                                                             Go on to the next page
2000-CE-CHEM 2−9                        –8–
        保留版權 All Rights Reserved 2000
30.    In which of the following substances does nitrogen has the smallest
       oxidation number ?

                A.       NH3
                B.       NO
                C.       N2O
                D.       N2

31.    Which of the following uses of sulphuric acid is/are correct ?

       (1)      manufacture of soaps
       (2)      manufacture of paint additives
       (3)      manufacture of fertilizers

                A.       (1) only
                B.       (2) only
                C.       (1) and (3) only
                D.       (2) and (3) only

32.    Which of the following articles should be made from thermosetting
       plastics ?

       (1)      wall paper
       (2)      television casing
       (3)      water bucket

                A.       (1) only
                B.       (2) only
                C.       (1) and (3) only
                D.       (2) and (3) only

33.    In an experiment, a piece of calcium metal was added to a beaker of water.
       Which of the following statements concerning the experiment is/are
       correct ?

       (1)      The calcium metal sank to the bottom of the beaker.
       (2)      The calcium metal burnt with a brick red flame.
       (3)      At the end of the experiment, an alkaline solution was formed in
                the beaker.

                A.       (1) only
                B.       (2) only
                C.       (1) and (3) only
                D.       (2) and (3) only



2000-CE-CHEM 2−10                     –9–
        保留版權 All Rights Reserved 2000
34.      Which of the following statements concerning helium is/are correct ?

         (1)      The outermost electron shell of a helium atom has an octet
                  structure.
         (2)      Helium is used to fill weather balloons.
         (3)      Helium exists as monatomic molecules.

                  A.       (1) only
                  B.       (2) only
                  C.       (1) and (3) only
                  D.       (2) and (3) only


35.      Consider the chemical cell shown below :




                                          salt bridge
           magnesium                                                      copper




      1M magnesium
                                                                         1M copper(II)
      sulphate solution
                                                                         sulphate solution
                              Beaker X                  Beaker Y


         Which of the following statements concerning the cell is/are correct ?

         (1)      Oxidation takes place at the copper electrode.
                  The concentration of magnesium ions in beaker X increases.
         (2)
         (3)      The salt bridge allows electrons to flow from one electrode to the
                  other electrode.

                  A.       (1) only
                  B.       (2) only
                  C.       (1) and (3) only
                  D.       (2) and (3) only




                                                                   Go on to the next page
2000-CE-CHEM 2−11                        – 10 –
          保留版權 All Rights Reserved 2000
36.    Which of the following polymers is/are made by condensation
       polymerization ?

                    O                   O    H             H
       (1)          C     (CH2)4        C    N    (CH2)6   N
                                                               n
                              O

                              C       OCH3

       (2)          CH2       C
                                             n
                              CH3

                    F     F
       (3)          C     C
                                  n
                    F     F


               A.         (1) only
               B.         (2) only
               C.         (1) and (3) only
               D.         (2) and (3) only

37.    Which of the following statements concerning drugs is/are correct ?

       (1)     Morphine is an effective painkiller.
       (2)     Acetaminophen (paracetamol) can damage the stomach lining.
       (3)     A suspension of milk of magnesia in water has a pH greater than 7.

               A.         (1) only
               B.         (2) only
               C.         (1) and (3) only
               D.         (2) and (3) only




2000-CE-CHEM 2−12                        – 11 –
        保留版權 All Rights Reserved 2000
38.




                                                                  sink




                                                                  catchpot




       Some concentrated sulphuric acid was poured into a sink connected to a
       catchpot made of polyvinyl chloride (PVC). After some time, the catchpot
       became deformed.        Which of the following explanations for the
       deformation of the catchpot is/are correct ?

       (1)     The heat liberated when the concentrated sulphuric acid mixed with
               the water in the catchpot caused PVC to soften.
       (2)     PVC was decomposed into its monomers by the concentrated
               sulphuric acid.
       (3)     PVC was oxidized by the concentrated sulphuric acid.

               A.      (1) only
               B.      (2) only
               C.      (1) and (3) only
               D.      (2) and (3) only




                                                          Go on to the next page
2000-CE-CHEM 2−13                   – 12 –
        保留版權 All Rights Reserved 2000
X can form X2– ions.
39.    X is an element in Group VI of the Periodic Table.
       Which of the following statements are correct ?

               The oxidation number of X decreases when X2– ion is formed.
       (1)
               Both X atom and X2– ion have the same number of electron shells.
       (2)
               Both X atom and X2– ion have the same nuclear charge.
       (3)

               A.       (1) and (2) only
               B.       (1) and (3) only
               C.       (2) and (3) only
               D.       (1), (2) and (3)


40.    Which of the following measures can reduce the emission of pollutants from
       a coal-fired power station ?

       (1)     installation of scrubbers
       (2)     installation of electrostatic precipitators
       (3)     increasing the height of the chimney

               A.       (1) and (2) only
               B.       (1) and (3) only
               C.       (2) and (3) only
               D.       (1), (2) and (3)

41.    Which of the following statements concerning soaps are correct ?

       (1)     They are esters.
       (2)     They can reduce the surface tension of water.
       (3)     Their aqueous solutions are alkaline.

               A.       (1) and (2) only
               B.       (1) and (3) only
               C.       (2) and (3) only
               D.       (1), (2) and (3)




2000-CE-CHEM 2−14                     – 13 –
        保留版權 All Rights Reserved 2000
42.    Which of the following statements concerning carbon, silicon and
       phosphorus are correct ?

       (1)     Carbon forms numerous compounds with hydrogen and oxygen.
       (2)     Silicon is used to make computer chips.
       (3)     Phosphorus is an essential element for plant growth.

               A.       (1) and (2) only
               B.       (1) and (3) only
               C.       (2) and (3) only
               D.       (1), (2) and (3)

43.    Which of the following statements concerning a zinc-carbon cell are correct ?

       (1)     The ammonium chloride in the cell acts as an electrolyte.
       (2)     The manganese(IV) oxide in the cell acts as an oxidizing agent.
       (3)     The zinc case of the cell acts as the positive terminal.

               A.       (1) and (2) only
               B.       (1) and (3) only
               C.       (2) and (3) only
               D.       (1), (2) and (3)


44.    Which of the following statements concerning sulphur dioxide are correct ?

       (1)     It can be prepared by heating copper turnings with concentrated
               sulphuric acid.
       (2)     It is denser than air.
       (3)     It can be absorbed by sodium hydroxide solution.

               A.       (1) and (2) only
               B.       (1) and (3) only
               C.       (2) and (3) only
               D.       (1), (2) and (3)




                                                            Go on to the next page
2000-CE-CHEM 2−15                    – 14 –
        保留版權 All Rights Reserved 2000
Directions : Each question below (Question Nos. 45 to 50) consists of two
             separate statements. Decide whether each of the two statements is
             true or false; if both are true, then decide whether or not the second
             statement is a correct explanation of the first statement. Then select
             one option from A to D according to the following table :

A. Both statements are true and the 2nd statement is a correct explanation of the
   1st statement.
B. Both statements are true but the 2nd statement is NOT a correct explanation of
   the 1st statement.
C. The 1st statement is false but the 2nd statement is true.
D. Both statements are false.


               1st statement                             2nd statement

45. Concentrated sulphuric acid can            Concentrated sulphuric acid is a
    turn a piece of filter paper black.        strong oxidizing agent.

46. Carbon dioxide and silicon dioxide         The atoms of carbon and silicon
    have similar physical properties.          have the same number of electrons
                                               in their outermost shells.

47. Chlorine is a better bleaching agent       Chlorine bleaches by reduction.
    for silk than sulphur dioxide.

48. The volume of 10.0 g of gaseous            10.0 g of gaseous carbon dioxide
    carbon dioxide is the same as the          contains the same number of
    volume of 10.0 g of solid carbon           molecules as 10.0 g of solid carbon
    dioxide.                                   dioxide.

49. Adding lime to acidic soil can             Lime can neutralize the acid in the
    increase crop yield.                       soil.

50. Aluminium was used earlier than            Aluminium is more abundant than
    iron in the history of mankind.            iron in the earth crust.



                                END OF PAPER




2000-CE-CHEM 2−16                     – 15 –
         保留版權 All Rights Reserved 2000
2000 Chemistry Paper 2

Question No.        Key                 Question No.   Key

   1.                B                     26.          D
   2.                A                     27.          B
   3.                B                     28.          C
   4.                D                     29.          C
   5.                A                     30.          A

   6.                D                     31.          D
   7.                C                     32.          B
   8.                A                     33.          C
   9.                D                     34.          D
   10.               A                     35.          B

   11.               C                     36.          A
   12.               D                     37.          C
   13.               C                     38.          A
   14.               B                     39.          D
   15.               C                     40.          A

   16.               B                     41.          C
   17.               B                     42.          D
   18.               B                     43.          A
   19.               D                     44.          D
   20.               A                     45.          B

   21.                 A                   46.          C
   22.                 D                   47.          D
   23.                 B                   48.          C
24.                                     49.          A
   25.                 A                   50.          C




    保留版權 All Rights Reserved 2000

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Chemistry 2000 Paper2

  • 1. 2000-CE CHEM HONG KONG EXAMINATIONS AUTHORITY 2 HONG KONG CERTIFICATE OF EDUCATION EXAMINATION 2000 CHEMISTRY PAPER 2 10.45 am – 11.45 am (1 hour) Subject Code 160 1. Read carefully the instructions on the Answer Sheet and insert the information required (including the Subject Code) in the spaces provided. 2. When told to open this book, check that all the questions are there. Look for the words ‘END OF PAPER’ after the last question. ANSWER ALL QUESTIONS. 3. All the answers should be marked on the Answer Sheet. Note that you may only mark ONE answer to each question. 4. Two or more answers will score NO MARKS. 5. All questions carry equal marks. No marks will be deducted for wrong answers. 香 港 考 試 局     保 留 版 權 Hong Kong Examinations Authority All Rights Reserved 2000 2000-CE-CHEM 2–1
  • 2. There are 50 questions in this paper. 1. A compound formed from element X and sulphur has the following electronic structure : S S X (Only electrons in the outermost shells are shown.) How many electrons are there in the outermost shell of an atom of X ? A. 2 B. 4 C. 6 D. 8 2. Caesium (Cs) is a Group I element in the Periodic Table and its relative atomic mass is greater than that of potassium. Which of the following statements concerning caesium is INCORRECT ? A. Caesium is a weaker reducing agent than potassium. B. Caesium reacts violently with water. C. Caesium is a soft metal. D. Caesium reacts with oxygen to form an oxide with formula Cs2O. 3. Iron cans used for canning food are usually coated with tin instead of zinc. This is because A. tin is more reactive than zinc. B. tin ions are non-toxic but zinc ions are toxic. C. tin forms an alloy with iron and this alloy is corrosion resistant. D. tin prevents iron cans from rusting by sacrificial protection. 2000-CE-CHEM 2−2 –1– 保留版權 All Rights Reserved 2000
  • 3. 4. Metal X forms an oxide. 27.53 g of this oxide contains 24.96 g of X. What is the mole ratio of X to oxygen in the oxide ? (Relative atomic masses : O = 16.0, X = 207.0) A. 1:1 B. 1:2 C. 2:3 D. 3:4 5. Which of the following gases are the major products liberated in the electrolysis of concentrated sodium chloride solution using carbon electrodes ? Cathode Anode A. hydrogen chlorine B. chlorine hydrogen C. hydrogen oxygen D. oxygen hydrogen 6. Which of the following pairs of compounds can be distinguished by treating with an acidified potassium dichromate solution ? A. ethane and ethene B. ethanol and propan-1-ol C. sodium carbonate and sodium hydrogencarbonate D. sodium sulphite and sodium sulphate Element X occurs in nature as two isotopes, 63X and 65X. If the relative 7. atomic mass of X is 63.5, what is the relative abundance of the 63X isotope ? A. 25% B. 60% C. 75% D. 90% Go on to the next page 2000-CE-CHEM 2–3 –2– 保留版權 All Rights Reserved 2000
  • 4. 8. Which of the following statements concerning members of a homologous series is INCORRECT ? A. They contain carbon and hydrogen only. B. They can be represented by the same general formula. C. They have similar chemical properties. D. Their boiling points increase with their relative molecular masses. 9. The atomic number of element X is 12. X reacts with element Y to form an ionic compound with formula XY2. To which group of the Periodic Table does Y belong ? A. Group I B. Group IV C. Group VI D. Group VII 10. Manufacturing ammonia by the Haber process involves the reversible reaction : N2(g) + 3H2(g) 2NH3(g) Which of the following statements concerning the process is INCORRECT ? A. The forward reaction can go to completion if iron powder is used as a catalyst. B. The optimum conditions for the process are 500°C and 200 atm. C. The raw materials are derived from air and water. D. The forward reaction and backward reaction occur simultaneously. 2000-CE-CHEM 2−4 –3– 保留版權 All Rights Reserved 2000
  • 5. 11. Different volumes of 2.0 M potassium hydroxide solution and 2.0 M sulphuric acid are mixed in a polystyrene cup. In which of the following combinations would the temperature rise be the greatest ? Volume of 2.0 M KOH(aq)/cm 3 Volume of 2.0 M H 2 SO 4 (aq)/cm 3 A. 20.0 40.0 B. 30.0 30.0 C. 40.0 20.0 D. 45.0 15.0 12. Which of the following natural substances is essentially a single compound ? A. air B. coal C. petroleum D. quartz 13. Consider the compounds represented by the two structures below : O HH HHO and H C O C C H H C C C OH HH HH Which of the following statements concerning these compounds is correct ? A. Both compounds can turn wet blue litmus paper red. B. Both compounds have the same odour. C. Both compounds have the same molecular formula. D. Both compounds have the same boiling point. Go on to the next page 2000-CE-CHEM 2−5 –4– 保留版權 All Rights Reserved 2000
  • 6. 14. Which of the following solutions can react with bromine water to give a colourless solution ? A. sodium chloride solution B. sodium sulphite solution C. sodium iodide solution D. sodium hypochlorite solution 15. A polymer has the following structure : CH3 CH3 C C n H H What is the monomer of this polymer ? A. butane B. but-1-ene C. but-2-ene D. 2-methylpropene 16. Consider the following equation : → 3Zn(s) + 2NO3–(aq) + 8H+(aq) 3Zn2+(x) + 2NO(y) + 4H2O(z) Which of the following combinations is correct ? y x z A. aq g aq B. aq g C. aq aq D. g aq The melting point and boiling point of substance X are 321°C and 765°C 17. In its molten state, X conducts electricity without respectively. decomposition. X probably has A. an ionic structure. B. a metallic structure. C. a simple molecular structure. D. a covalent network structure. 2000-CE-CHEM 2−6 –5– 保留版權 All Rights Reserved 2000
  • 7. 18. Some potassium carbonate solution is added to a sample of tap water. The mixture then appears cloudy. Which of the following ions is probably present in the sample ? NH4+ A. Mg2+ B. Br– C. SO42– D. 19. Gold ornaments are usually made from an alloy of gold and copper instead of pure gold. This is because the alloy A. can be found free in nature. B. is more corrosion resistant than pure gold. C. is denser than pure gold. D. is stronger than pure gold. A sample of concentrated sulphuric acid has a density of 1.83 g cm–3 and 20. contains 94.0% of sulphuric acid by mass. What is the concentration (correct to one decimal place) of sulphuric acid in the sample ? (Relative atomic masses : H = 1.0, O = 16.0, S = 32.1) A. 17.5 M B. 18.3 M C. 18.7 M D. 19.8 M 21. Which of the following processes requires a catalyst ? A. preparation of ethyl ethanoate from ethanoic acid and ethanol B. conversion of sulphur trioxide to concentrated sulphuric acid C. manufacture of chlorine bleach from brine D. reduction of iron(III) oxide to iron Go on to the next page 2000-CE-CHEM 2−7 –6– 保留版權 All Rights Reserved 2000
  • 8. 22. A white solid dissolves in water to give an alkaline solution. The solution reacts with dilute hydrochloric acid to give a gas. The solid is probably A. calcium oxide. B. calcium carbonate. C. potassium hydroxide. D. potassium carbonate. In an experiment, 21.8 g of zinc was treated with 250.0 cm3 o f 2 M 23. .0 hydrochloric acid. What volume of hydrogen was liberated at room temperature and pressure ? (Relative atomic mass : Zn = 65.4; 3 molar volume of gas at room temperature and pressure = 24.0 dm ) 4.0 dm3 A. 6.0 dm3 B. 8.0 dm3 C. 12.0 d m3 D. 24. Which of the following compounds is insoluble in water ? A. methanol B. methanoic acid C. methyl methanoate D. sodium methanoate (This item was deleted.) 25. Which of the following processes is endothermic ? A. cracking of petroleum fractions B. fermentation of glucose solution C. manufacture of ammonia by the Haber process D. oxidation of sulphur dioxide to sulphur trioxide in the contact process 2000-CE-CHEM 2−8 –7– 保留版權 All Rights Reserved 2000
  • 9. 26. Which of the following combinations is correct ? Type of fire Type of fire extinguisher to use A. electrical fire water B. electrical fire foam C. kerosene fire water D. kerosene fire foam 27. Which of the following changes occurs in a catalytic converter installed in a motor car ? A. Nitrogen monoxide changes to nitrogen dioxide. B. Carbon monoxide changes to carbon dioxide. C. Unburnt hydrocarbons change to carbon particles. D. Sulphur changes to sulphur dioxide. 28. Which of the following changes is NOT a redox reaction ? Fe2(SO4)3 + H2S → 2FeSO4 + S + H2SO4 A. 2Al + 6HCl → 2AlCl3 + 3H2 B. CaCO3 + CO2 + H2O → Ca(HCO3)2 C. 2KClO3 → 2KCl + 3O2 D. 29. Which of the following compounds would react with ammonium chloride on heating ? A. concentrated nitric acid B. concentrated hydrochloric acid C. sodium hydroxide solution D. magnesium sulphate solution Go on to the next page 2000-CE-CHEM 2−9 –8– 保留版權 All Rights Reserved 2000
  • 10. 30. In which of the following substances does nitrogen has the smallest oxidation number ? A. NH3 B. NO C. N2O D. N2 31. Which of the following uses of sulphuric acid is/are correct ? (1) manufacture of soaps (2) manufacture of paint additives (3) manufacture of fertilizers A. (1) only B. (2) only C. (1) and (3) only D. (2) and (3) only 32. Which of the following articles should be made from thermosetting plastics ? (1) wall paper (2) television casing (3) water bucket A. (1) only B. (2) only C. (1) and (3) only D. (2) and (3) only 33. In an experiment, a piece of calcium metal was added to a beaker of water. Which of the following statements concerning the experiment is/are correct ? (1) The calcium metal sank to the bottom of the beaker. (2) The calcium metal burnt with a brick red flame. (3) At the end of the experiment, an alkaline solution was formed in the beaker. A. (1) only B. (2) only C. (1) and (3) only D. (2) and (3) only 2000-CE-CHEM 2−10 –9– 保留版權 All Rights Reserved 2000
  • 11. 34. Which of the following statements concerning helium is/are correct ? (1) The outermost electron shell of a helium atom has an octet structure. (2) Helium is used to fill weather balloons. (3) Helium exists as monatomic molecules. A. (1) only B. (2) only C. (1) and (3) only D. (2) and (3) only 35. Consider the chemical cell shown below : salt bridge magnesium copper 1M magnesium 1M copper(II) sulphate solution sulphate solution Beaker X Beaker Y Which of the following statements concerning the cell is/are correct ? (1) Oxidation takes place at the copper electrode. The concentration of magnesium ions in beaker X increases. (2) (3) The salt bridge allows electrons to flow from one electrode to the other electrode. A. (1) only B. (2) only C. (1) and (3) only D. (2) and (3) only Go on to the next page 2000-CE-CHEM 2−11 – 10 – 保留版權 All Rights Reserved 2000
  • 12. 36. Which of the following polymers is/are made by condensation polymerization ? O O H H (1) C (CH2)4 C N (CH2)6 N n O C OCH3 (2) CH2 C n CH3 F F (3) C C n F F A. (1) only B. (2) only C. (1) and (3) only D. (2) and (3) only 37. Which of the following statements concerning drugs is/are correct ? (1) Morphine is an effective painkiller. (2) Acetaminophen (paracetamol) can damage the stomach lining. (3) A suspension of milk of magnesia in water has a pH greater than 7. A. (1) only B. (2) only C. (1) and (3) only D. (2) and (3) only 2000-CE-CHEM 2−12 – 11 – 保留版權 All Rights Reserved 2000
  • 13. 38. sink catchpot Some concentrated sulphuric acid was poured into a sink connected to a catchpot made of polyvinyl chloride (PVC). After some time, the catchpot became deformed. Which of the following explanations for the deformation of the catchpot is/are correct ? (1) The heat liberated when the concentrated sulphuric acid mixed with the water in the catchpot caused PVC to soften. (2) PVC was decomposed into its monomers by the concentrated sulphuric acid. (3) PVC was oxidized by the concentrated sulphuric acid. A. (1) only B. (2) only C. (1) and (3) only D. (2) and (3) only Go on to the next page 2000-CE-CHEM 2−13 – 12 – 保留版權 All Rights Reserved 2000
  • 14. X can form X2– ions. 39. X is an element in Group VI of the Periodic Table. Which of the following statements are correct ? The oxidation number of X decreases when X2– ion is formed. (1) Both X atom and X2– ion have the same number of electron shells. (2) Both X atom and X2– ion have the same nuclear charge. (3) A. (1) and (2) only B. (1) and (3) only C. (2) and (3) only D. (1), (2) and (3) 40. Which of the following measures can reduce the emission of pollutants from a coal-fired power station ? (1) installation of scrubbers (2) installation of electrostatic precipitators (3) increasing the height of the chimney A. (1) and (2) only B. (1) and (3) only C. (2) and (3) only D. (1), (2) and (3) 41. Which of the following statements concerning soaps are correct ? (1) They are esters. (2) They can reduce the surface tension of water. (3) Their aqueous solutions are alkaline. A. (1) and (2) only B. (1) and (3) only C. (2) and (3) only D. (1), (2) and (3) 2000-CE-CHEM 2−14 – 13 – 保留版權 All Rights Reserved 2000
  • 15. 42. Which of the following statements concerning carbon, silicon and phosphorus are correct ? (1) Carbon forms numerous compounds with hydrogen and oxygen. (2) Silicon is used to make computer chips. (3) Phosphorus is an essential element for plant growth. A. (1) and (2) only B. (1) and (3) only C. (2) and (3) only D. (1), (2) and (3) 43. Which of the following statements concerning a zinc-carbon cell are correct ? (1) The ammonium chloride in the cell acts as an electrolyte. (2) The manganese(IV) oxide in the cell acts as an oxidizing agent. (3) The zinc case of the cell acts as the positive terminal. A. (1) and (2) only B. (1) and (3) only C. (2) and (3) only D. (1), (2) and (3) 44. Which of the following statements concerning sulphur dioxide are correct ? (1) It can be prepared by heating copper turnings with concentrated sulphuric acid. (2) It is denser than air. (3) It can be absorbed by sodium hydroxide solution. A. (1) and (2) only B. (1) and (3) only C. (2) and (3) only D. (1), (2) and (3) Go on to the next page 2000-CE-CHEM 2−15 – 14 – 保留版權 All Rights Reserved 2000
  • 16. Directions : Each question below (Question Nos. 45 to 50) consists of two separate statements. Decide whether each of the two statements is true or false; if both are true, then decide whether or not the second statement is a correct explanation of the first statement. Then select one option from A to D according to the following table : A. Both statements are true and the 2nd statement is a correct explanation of the 1st statement. B. Both statements are true but the 2nd statement is NOT a correct explanation of the 1st statement. C. The 1st statement is false but the 2nd statement is true. D. Both statements are false. 1st statement 2nd statement 45. Concentrated sulphuric acid can Concentrated sulphuric acid is a turn a piece of filter paper black. strong oxidizing agent. 46. Carbon dioxide and silicon dioxide The atoms of carbon and silicon have similar physical properties. have the same number of electrons in their outermost shells. 47. Chlorine is a better bleaching agent Chlorine bleaches by reduction. for silk than sulphur dioxide. 48. The volume of 10.0 g of gaseous 10.0 g of gaseous carbon dioxide carbon dioxide is the same as the contains the same number of volume of 10.0 g of solid carbon molecules as 10.0 g of solid carbon dioxide. dioxide. 49. Adding lime to acidic soil can Lime can neutralize the acid in the increase crop yield. soil. 50. Aluminium was used earlier than Aluminium is more abundant than iron in the history of mankind. iron in the earth crust. END OF PAPER 2000-CE-CHEM 2−16 – 15 – 保留版權 All Rights Reserved 2000
  • 17. 2000 Chemistry Paper 2 Question No. Key Question No. Key 1. B 26. D 2. A 27. B 3. B 28. C 4. D 29. C 5. A 30. A 6. D 31. D 7. C 32. B 8. A 33. C 9. D 34. D 10. A 35. B 11. C 36. A 12. D 37. C 13. C 38. A 14. B 39. D 15. C 40. A 16. B 41. C 17. B 42. D 18. B 43. A 19. D 44. D 20. A 45. B 21. A 46. C 22. D 47. D 23. B 48. C
  • 18. 24. 49. A 25. A 50. C 保留版權 All Rights Reserved 2000