This document provides a sample chemistry question paper for Class XII. It includes:
1) Details on the number and type of questions, including short answer, long answer and value based questions.
2) Instructions for students on completing the paper.
3) Sample questions covering topics in chemistry like thermodynamics, equilibrium, redox reactions, organic chemistry and biomolecules.
4) A value based question assessing students' ability to apply chemistry knowledge to an ethical scenario.
Dear Students/Parents
We at 'Apex Institute' are committed to provide our students best quality education with ethics. Moving in this direction, we have decided that unlike other expensive and 5star facility type institutes who are huge investors and advertisers, we shall not invest huge amount of money in advertisements. It shall rather be invested on the betterment, enhancement of quality and resources at our center.
We are just looking forward to have 'word-of-mouth' publicity instead. Because, there is only a satisfied student and his/her parents can judge an institute's quality and it's faculty members coaching.
Those coaching institutes, who are investing highly on advertisements, are actually, wasting their money on it, in a sense. Rather, the money should be invested on highly experienced faculty members and on teaching gears.
We all at 'Apex' are taking this initiative to improve the quality of education along-with each student's development and growth.
Committed to excellence...
With best wishes.
S . Iqbal
( Motivator & Mentor)
Dear Students/Parents
We at 'Apex Institute' are committed to provide our students best quality education with ethics. Moving in this direction, we have decided that unlike other expensive and 5star facility type institutes who are huge investors and advertisers, we shall not invest huge amount of money in advertisements. It shall rather be invested on the betterment, enhancement of quality and resources at our center.
We are just looking forward to have 'word-of-mouth' publicity instead. Because, there is only a satisfied student and his/her parents can judge an institute's quality and it's faculty members coaching.
Those coaching institutes, who are investing highly on advertisements, are actually, wasting their money on it, in a sense. Rather, the money should be invested on highly experienced faculty members and on teaching gears.
We all at 'Apex' are taking this initiative to improve the quality of education along-with each student's development and growth.
Committed to excellence...
With best wishes.
S . Iqbal
( Motivator & Mentor)
INVESTIGATE THE PROPERTIES OF IONIC BOND AND COVALENT BOND THROUGH AN EXPERIMENTMISS ESTHER
CHEMISTRY FORM 4 KSSM
CHAPTER 5 : CHEMICAL BONDS (IONIC BOND AND COVALENT BOND)
EXPERIMENT 5.1 TO INVESTIGATE THE PROPERTIES OF IONIC BOND AND COVALENT BOND THROUGH EXPERIMENT
INVESTIGATE THE PROPERTIES OF IONIC BOND AND COVALENT BOND THROUGH AN EXPERIMENTMISS ESTHER
CHEMISTRY FORM 4 KSSM
CHAPTER 5 : CHEMICAL BONDS (IONIC BOND AND COVALENT BOND)
EXPERIMENT 5.1 TO INVESTIGATE THE PROPERTIES OF IONIC BOND AND COVALENT BOND THROUGH EXPERIMENT
1 Question 1 (Alcohols and Carbonyl Compounds - 20 marks.docxjoyjonna282
1
Question 1 (Alcohols and Carbonyl Compounds - 20 marks)
(a) Why does hexan-2-one have a lower boiling point than hexan-2-ol?
O OH
(2)
(b) Dehydration of the compound below in acid gives mainly one product. Suggest, with a
reason, what would be the major product.
H
+
heatOH .
(1)
(c) Esters are known for their very pleasant fragrances. The aroma is dependent on the
starting materials used to prepare the ester. Give the original starting materials used to
produce the ester below.
O
O
(2)
(d) The substitution reaction between the alkyl halide below and water results in an alcohol.
2
(i) Show the full mechanism of the reaction as it occurs via an SN1 pathway. Identify
all the elements of the reaction.
(5)
(ii) Which factor can be investigated to determine if the reaction proceeds by a
unimolecular or bimolecular mechanism, and how is it relevant in terms of the
mechanism?
(2)
(iii) Explain briefly whether the chlorine analogue of the substrate would react faster
or slower than the given compound above.
(2)
(iv) Draw a fully labeled energy profile for this SN1 reaction.
(4)
3
Question 2 (Saccharides - Total 14 marks)
(a) Below is the Fischer projection of a sugar.
CHO
HHO
OHH
OHH
HHO
CH2OH
(i) Show a Haworth projection of the cyclic form of the sugar, identifying the
anomeric centre as either or .
(2)
(ii) Fully classify the saccharide above in terms of its optical rotation, carbon skeleton
and class.
(2)
(iii) When the compound is reduced with NaBH4, is the product optically active or
not? Explain your answer.
(2)
(b) What is the process called when the optical rotation of an aqueous solution of a pure
anomer of glucose changes with time? Use chemical structures to demonstrate what is
happening.
(3)
4
(c) The following question relates to the structure below:
A. B.
C.
O
HO
HO
OH
O
OH
O
HO
OH
O
HO
OH
O
O
HO2C
OH OH
(i) Use arrows to identify the glycoside links between sugars a and b as well as b and
c and name them appropriately.
(3)
(ii) Explain if this is a reducing sugar or not.
(2)
5
Question 3 (Amines and Amides - Total 11 marks)
(a) Briefly explain why amines have lower boiling points than amides of similar molecular
weight.
(2)
(b) (i) What is the name of the following amine?
N
(1)
(ii) What is the structure of 2,2-dimethylpentanamine?
(1)
(c) Give the outcome of the reactions below.
(i) Ph-NH2 + CH3-CO2H
(1)
(ii)
H3O
+
N
H
O
(2)
(d) The structure of N-methylpropanamide is given below.
N
H
O
Predict the solubility of N-methylpropanamide by showing the full extent of H-
bonding between the compound and water.
(2)
6
(e) Explain with refe ...
The French Revolution, which began in 1789, was a period of radical social and political upheaval in France. It marked the decline of absolute monarchies, the rise of secular and democratic republics, and the eventual rise of Napoleon Bonaparte. This revolutionary period is crucial in understanding the transition from feudalism to modernity in Europe.
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How to Split Bills in the Odoo 17 POS ModuleCeline George
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This is a presentation by Dada Robert in a Your Skill Boost masterclass organised by the Excellence Foundation for South Sudan (EFSS) on Saturday, the 25th and Sunday, the 26th of May 2024.
He discussed the concept of quality improvement, emphasizing its applicability to various aspects of life, including personal, project, and program improvements. He defined quality as doing the right thing at the right time in the right way to achieve the best possible results and discussed the concept of the "gap" between what we know and what we do, and how this gap represents the areas we need to improve. He explained the scientific approach to quality improvement, which involves systematic performance analysis, testing and learning, and implementing change ideas. He also highlighted the importance of client focus and a team approach to quality improvement.
Operation “Blue Star” is the only event in the history of Independent India where the state went into war with its own people. Even after about 40 years it is not clear if it was culmination of states anger over people of the region, a political game of power or start of dictatorial chapter in the democratic setup.
The people of Punjab felt alienated from main stream due to denial of their just demands during a long democratic struggle since independence. As it happen all over the word, it led to militant struggle with great loss of lives of military, police and civilian personnel. Killing of Indira Gandhi and massacre of innocent Sikhs in Delhi and other India cities was also associated with this movement.
Unit 8 - Information and Communication Technology (Paper I).pdfThiyagu K
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Students, digital devices and success - Andreas Schleicher - 27 May 2024..pptxEduSkills OECD
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1.
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SAMPLE QUESTION PAPER
CHEMISTRY (043)
CLASS – XII – (2014-2015)
QUESTION PAPER DESIGN
CLASS XII CBSE
Types of Questions
S.No Type of Question Marks for
each
Question
No. of
Questions
Total Marks
1. Long Answers (LA) 5 03 15
2. Value based question 4 01 04
3. Short Answers-II(SA II) 3 12 36
4. Short Answers-I(SA I) 2 05 10
5. Very Short Answer (VSA) 1 05 05
Total 26 70
Type of questions VSA(1) SA1(2) SA2(3) VB(4) LA(5) Total(%)
Knowledge 2 1 1 - - 07 (10%)
Understanding - 2 4 - 1 21 (30%)
Application - 2 4 - 1 21 (30%)
HOTS (Higher order thinking skills) 2 - 1 - 1 10(14%)
Evaluation and Multi-disciplinary 1 - 2 1 - 11(16%)
2.
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SAMPLE QUESTION PAPER
CHEMISTRY
CLASS – XII (2014 – 2015)
Time Allowed: 3 hr Maximum marks: 70
General Instructions:
(a) All questions are compulsory.
(b) Q.no. 1 to 5 are very short answer questions and carry 1 mark each.
(c) Q.no. 6 to 10 are short answer questions and carry 2 marks each.
(d) Q.no. 11 to 22 are also short answer questions and carry 3 marks each
(e) Q.no. 23 is a value based question and carry 4 marks.
(f) Q.no. 24 to 26 are long answer questions and carry 5 marks each
(g) Use log tables if necessary, use of calculators is not allowed.
1. The following figure shows the variation of adsorption of N2 on charcoal with pressure at
different constant temperatures:
3.
Page 3 of 10
Arrange the temperatures T1, T2 and T3 in the increasing order.
2. Give the formula of a noble gas species which is isostructural with IBr2
-
.
3. What is the effect of synergic bonding interactions in a metal carbonyl complex?
4. PCl5 acts as an oxidizing agent. Justify.
5. Write the name of the product formed when benzenediazonium chloride solution is treated with
potassium iodide.
6. Name the crystal defect which reduces the density of an ionic solid? What type of ionic
substances show this defect?
7. The molar conductivity (
m
λ ) of KCl solutions at different concentrations at 298 K is plotted as
shown in the figure given below:
Determine the value of 0
mλ and A for KCl.
8. Aluminum crystallizes in anfcc structure. Atomic radius of the metal is 125 pm. What is the
length of the side of the unit cell of the metal?
9. Draw the structure of the following compounds:
(i) H2S2O7
(ii) XeOF4
OR
Write balanced chemical equations for the following:
(i) Reaction of chlorine with hot and concentrated NaOH.
4.
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(ii) Sulphur dioxide is passed through an aqueous solution of Fe (III) salt.
10. 0.5 g of KCl was dissolved in 100 g of water and the solution originally at 200
C, froze at
-0.240
C. Calculate the percentage dissociation of the salt.
(Given :Kf for water = 1.86 K kg /mol, Atomic mass: K = 39 u, Cl= 35.5 u)
11. State briefly the principles involved in the following operations in metallurgy. Give an
example.
(i) Hydraulic washing.
(ii) Zone refining.
12.
i) What type of deviation from Raoult’s law is observed, when two volatile liquids A and
B on mixing produce a warm solution? Explain with the help of a well labeled vapour
pressure graph.
ii) Consider separate solutions of 0.5 M CH3OH, 0.250 M KCl (aq) and 0.125 M Na3PO4
(aq). Arrange the above solutions in the increasing order of their Van’t Hoff factor.
13. Write the Nernst equationand calculate the emffor the following cell at 298 K:
Mg(s) / Mg2+
(0.001 M) // Cu2+
(0.0001 M) / Cu(s)
How does Ecellvary with the concentration of both Mg2+
and Cu2+
ions?
(GivenEo
cell= 2.71 V)
14. Explain the following observations giving appropriate reasons:
(i) Ozone is thermodynamically unstable with respect to oxygen. .
(ii) The HEH bond angle of the hydrides of group 15 elements decrease as we move down
the group.
(iii) Bleaching effect of chlorine is permanent.
15.
(i) Predict the number of unpaired electrons in the tetrahedral [MnBr4]2-
ion.
(ii) Draw structures of geometrical isomers of [Co(NH3)4Cl2]+
.
(iii) Write the formula for the following coordinate compound:
Amminebromidochloridonitrito-N-platinate(II)
16. Explain what is observed when
(i) Silver nitrate solution is added to potassium iodide solution.
(ii) The size of the finest gold sol particles increases in the gold sol.
(iii) Two oppositely charged sols are mixed in almost equal proportions.
5.
Page 5 of 10
17.
(i) In the following pairs of halogen compounds, which would undergo SN1 reaction
faster? Explain.
and
Cl
Cl
(ii) Amongst the isomeric dihalobenzenes which isomer has the highest melting point and
why?
(iii) Arrange the following haloalkanes in the increasing order of density. Justify your
answer.
CCl4, CH2Cl2 and CHCl3.
18. An organic compound ( A ) has characteristic odour. On treatment with NaOH, it forms
compounds ( B ) and ( C ). Compound ( B ) has molecular formula C7H 8Owhich on oxidation
gives back ( A ). The compound ( C ) is a sodium salt of an acid. When ( C ) is treated with
soda-lime, it yields an aromatic compound ( D ). Deduce the structures of ( A ), ( B ), ( C ) and
( D ). Write the sequence of reactions involved.
19. (a) Give one chemical test to distinguish between the following pairs of compounds:
(i) Methylamine and dimethylamine.
(ii) Aniline and benzylamine
(b) Write the structures of different isomers corresponding to the molecular formula C3H9N,
which will liberate nitrogen gas on treatment with nitrous acid.
20. (a) Exemplify the following reactions:
(i) Rosenmund reduction reaction.
(ii) Kolbe electrolysis reaction.
(b) Arrange the following compounds in increasing order of their reactivity towards HCN:
Acetaldehyde, Acetone, Di-tert-butyl ketone.
OR
(a) Predict the products of the following reactions:
6.
Page 6 of 10
(i)
(i) Cl2 / Red phosphorous
(ii) H2O
CH3-CH2-COOH
(ii)
CH3
+ CrO2Cl2
(i) CS2
(ii) H3O+
(b) Arrange the following compounds in increasing order of acid strength:
Benzoic acid, 4-Nitrobenzoic acid, 4-Methoxybenzoic acid.
21.
(i) Identify the monomer in the following polymeric structure:
[ CH2-CH=CH-CH2-CH2-CH ]n
CN
(ii) On the basis of forces between their molecules in a polymer to which class does
neoprene belong?
(iii) Can both addition and condensation polymerization result in the formation of a co-
polymer?
22.
(i) Which of the following biomolecule is insoluble in water? Justify.
Insulin, Haemoglobin, Keratin.
(ii) Draw the Haworth structure for α-D-Glucopyranose.
(iii) Write chemical reaction to show that glucose contains aldehyde as carbonyl group.
23. John had gone with his mother to the doctor as he was down with fever. He then went to the
chemist shop with his mother to purchase medicines prescribed by the doctor. There he
observed a young man pleading with the chemist to give him medicines as he had nasal
congestion. The chemist gave him cimetidine. John advised and also explained to the young
man that he should only take the medicines prescribed by the doctor.
Answer the following questions:
a) Did the chemist give an appropriate medicine? Justify your answer.
7.
Page 7 of 10
b) John’s action was appreciated by his mother. List any two reasons.
24. (a) Write the mechanism of hydration of ethene to form ethanol.
(b) How are the following conversions carried out?
(i) Propanol to propan-2-ol.
(ii) Propanol to 1-propoxypropane.
(c) Give the structure and the IUPAC name of the major product obtained in the following
reaction:
OH
conc. HNO3
OR
(a) Write the mechanism of the reaction of HI with methoxymethane.
(b) Identify A and B in the following reactions:
(i)
OH
NaOH
A
(i) CO2
(ii) H+
B
(ii)
A BC2H5OH
Cu, 573 K CH3MgBr
H2O / H+
(c) Give the structure and the IUPAC name of the major product obtained in the following
reaction:
OC2H5 conc. HNO3
conc. H2SO4
25. (a) A blackish brown coloured solid (A) which is an oxide of manganese, when fused with
alkali metal hydroxide and an oxidizing agent like KNO3, produces a dark green coloured
8.
Page 8 of 10
compound (B). Compound (B) on disproportionation in neutral and acidic solution gives a
purple coloured compound (C). Identify A, B and C and write the reaction involved when
compound (C) is heated to 513 K.
(b)
(i) E0
M3+
/ M2+
values for the first series of transitionelements are given below.
Answer the question that follows:
E0
(V) Ti V Cr Mn Fe Co
M3+
/ M2+
-0.37 -0.26 -0.41 +1.57 +0.77 +1.97
Identify the two strongest oxidizing agents in the aqueous solution from the
above data.
ii) Copper (I) ion is not known in aqueous solution
iii) The highest oxidation state of a metal is exhibited in its oxide.
OR
(a) Write balanced equations to represent what happens when
(i) Cu2+
is treated with KI.
(ii) Acidified potassium dichromate solution is reacted with iron (II) solution.
(ionic equation)
(b)
i) The figure given below illustrates the first ionization enthalpies of first, second
and third series of transition elements. Answer the question that follows
9.
Page 9 of 10
Which series amongst the first, second and third series of transition elements have
the highest first ionization enthalpy and why?
ii) Separation of lanthanide elements is difficult. Explain.
iii) Sm2+
, Eu2+
and Yb2+
ions in solutions are good reducing agents but an
aqueous solution of Ce4+
is a good oxidizing agent. Why?
26.
i) Graphically explain the effect of temperature on the rate constant of reaction? How can
this temperature effect on rate constant be represented quantitatively?
ii) The decomposition of a hydrocarbon follows the equation
Calculate Ea
OR
i) In the reaction
Q + R → Products
The time taken for 99% reaction of Q is twice the time taken for 90% reaction of Q.
The concentration of R varies with time as shown in the figure below:
What is the overall order of the reaction? Give the units of the rate constant for the
same. Write the rate expression for the above reaction.
ii) Rate constant for a first order reaction has been found to be 2.54 x 10-3
s-1.
Calculate its three-fourth life.
T
K
esxk
28000111
)105.4(
−−
=