2. MATERIALS FOR PRODUCTION OF
POLYSTYRENE
BASIC STUFF FOR PRODUCTION OF MATERIALS FROM PLASTIC IS OIL.
MATERIALS FOR PRODUCTION OF STYRENE:
*BENZENE
*ETHYLENE
3. HISTORY
POLYSTYRENE WAS DISCOVERED IN 1839 BY EDUARD
SIMON,AN APOTHECARY FROM BERLIN
From storax, the resin of the Turkish sweetgum
treeLiquidambar orientalis, he distilled an oily substance,
a monomer that he named styrol.
In 1866 Marcelin Berthelot correctly identified the formation
of metastyrol/Styroloxyd from styrol as
a polymerization process.
The crystal structure of isotactic polystyrene was reported
by Giulio Natta.
4. In 1954, the Koppers Company in Pittsburgh,
Pennsylvania, developed expanded polystyrene (EPS)
foam under the trade name Dylite.
In 1960, Dart Container, the largest manufacturer of
foam cups, shipped their first order.
In 1988, the first U.S. ban of general polystyrene
foam was enacted in Berkeley, California.
5. PRODUCTION OF POLYSTYRENE
POLYSTYRENE IS PREPARED BY POLYMYSERATION OF STYRENE
IT CAN BE REALISED BY VARIOUS TECHNIQUES:
SOLUTION POLYMERISATION
BLOCK POLYMERISATION
EMULSION POLYMERISATION
SUSPENSION POLYMERISATION
6. AREAS OF EXPLOITATION OF
POLYSTYRENE
BUILDING INDUSTRY
INSULANT CONTAINER
FINISHING PRODUCTS
GAMES,MODELLING,DECORATION
TECHNICAL PRODUCTS
TRAFFIC AND STORE RESOURCES
PACKING MATERIALS
PACKAGING RESOURCES
DIMENSION TIMBER
7. PHYSICAL PROPERTIES
Polystyrene has good thermal and electrical insulation properties
Density of EPS 16–640 kg/m3[15]
Young's modulus (E) 3000–3600 MPa
Tensile strength (st) 46–60 MPa
Elongation at break 3–4%
Notch test 2–5 kJ/m2
Glass transition temperature 100 °C[16]
Vicat B 90 °C[17]
Linear expansion coefficient (a) 8×10−5 /K
Specific heat (c) 1.3 kJ/(kg·K)
Water absorption (ASTM) 0.03–0.1
Decomposition X years, still decaying
8. CHEMICAL PROPERTIES
Polystyrene is chemically inert, and does not react
with most substances.
The transformation of carbon-carbon double bonds
into less reactive single bonds in polystyrene, is the
main reason for its chemical stability. Most of the
chemical properties of polystyrene are as a result of
the unique properties of carbon.
9. It dissolves in some organic solvents. It is soluble
in solvents that contain acetone, such as most
aerosol paint sprays and cyanoacrylate glues.
It is highly flammable and burns with an orange
yellow flame, giving off carbon particles or soot,
as a characteristic of all aromatic hydrocarbons.
Polystyrene, on complete oxidation, produces
only carbon dioxide and water vapour.