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Review: Eco-Friendly Corrosion Inhibitors on Mild Steel in Acidic Medium
1.
International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 09 Issue: 03 | Mar 2022 www.irjet.net p-ISSN: 2395-0072 © 2022, IRJET | Impact Factor value: 7.529 | ISO 9001:2008 Certified Journal | Page 536 Review: Eco-Friendly Corrosion Inhibitors on Mild Steel in Acidic Medium Shashirekha K.1, 2, Shubrajyotsna Aithal1*, B.M. Praveen1* 1 Professor, Department of Chemistry, College of Engineering and Technology, Srinivas University, Mukka, Mangalore, Karnataka, India. 2 Assistant Professor, Department of Chemistry, Yenepoya Institute of Technology, Thodar, Mangalore, Karnataka, India. -------------------------------------------------------------------------***------------------------------------------------------------------------ Abstract - Eco friendly corrosion inhibitors were chosen for this review, and their corrosion inhibition tendency was examined. The inhibitory property of these inhibitors on mild steel (MS) in an acidic environment are being explored. It was determined the rate of corrosion by the applications of chemical and electrochemical systems. Corrosion inhibition rises with inhibition efficiency and decreases with temperature, according to these studies. In all of these papers, on mechanisms of adsorption and thermodynamics were explored. Scanning Electron Microscopic investigations were used to discuss surface morphology. Few academics have recently published theoretical studies such as quantum studies. In this paper, all of the works have been discussed. Key Words: Inhibitors, Electrochemical measurements, Eco Friendly, Weight Loss, Tafel 1.Introduction Technical, economic, environmental, and aesthetic perspective, mild steel corrosion control is critical. In the past, cathodic protection, control activities, metal impurity content reduction, surface treatment techniques, and the integration of appropriate alloys were all used to reduce corrosion. On the other hand, inhibitors among the top effective strategies to hinder corrosion in metals and alloys [1-4]. Corrosion hindrances become one of the most cost- effective and easy method of corrosion prevention in acidic environments [5-7]. These corrosion inhibitors reduce the rate of corrosion, hence minimising the economic costs of corrosive attack on commercial containers, machinery, and surroundings. Because both corrosion inhibitors, natural and inorganic are harmful and expensive, researchers have increasingly focused on developing ecologically acceptable corrosion prevention solutions. Several recent studies have concentrated on mild steel corrosion prevention through the use of green inhibitors in acidic solutions to mimic industrial processes, with promising results [8-10]. Many researchers have looked into the corrosion protection of mild steel against corrosive chloride attack using inorganic oxidants like chromate [11-14], Molybdate [15-18], and Tungstate, polar organic molecules such as oxygen, sulphur, and nitrogen [19], with heterocyclic compounds having functional groups and conjugated double bonds as corrosion inhibitors [19-21]. The interaction of polar functional groups through the adsorbent surface on metal particles is usually believed to constitute the mechanism of inhibition [21]. Polar functional groups are normally considered to behave as response centres in organic compounds. A variety of factors influence the adsorption of an inhibitor on a surface of the metal. These parameters include the metal's nature and surface charge, the adsorption process, the inhibitor's chemical composition, and the type of electrolyte utilised. The use of various aliphatic and aromatic amines, as well as nitrogen-heterocyclic compounds, revealed that their inhibitory action is linked to several factors, including (I) molecule structure, (ii) adsorption type, (iii) charge distribution in the molecule, and (iv) the type of organic-metallic surface interaction. The paper provides a summary of the subject of eco-friendly inhibitors for MS in acid environment. It also gives the insights on adsorption and inhibition tendency of the inhibitors. 2. Corrosion Inhibitors Corrosion inhibitors are chemical substances that prevent metal from corroding when exposed to the environment in modest concentrations where a metal would corrode, reduce, slow, or prevent the metal from corroding. Inhibitors frequently act by adsorbing themselves to the metallic surface and producing a layer to protect it. a. Inhibitors inhibit corrosion by polarization effect on the working electrode. b. Due to polarization, it reduces the movement of metal ions.
2.
International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 09 Issue: 03 | Mar 2022 www.irjet.net p-ISSN: 2395-0072 © 2022, IRJET | Impact Factor value: 7.529 | ISO 9001:2008 Certified Journal | Page 537 c. Increasing the metallic surface's electrical resistance. d. Reduction of diffusion of reactants to the metal surface. e. Ion/molecule adsorption on metal surfaces When selecting an inhibitor, several variables must be addressed, including cost and volume, ease of presence, and, very prominently, security to the ecosystem as well as its species. 2.1 Organic Inhibitors Corrosion inhibitors that are organic are widely employed due of its wide temperature range in industrially performance, compatibility with covered substances, water dissolvability, low cost, and low toxicity. Organic corrosion inhibitors bind to the metal's surface, providing a protective coating that repels water and prevents corrosion. Lone pairs of electrons in nitrogen, oxygen, sulphur, and phosphorus, in addition to structural agglomerations containing – electrons that interact with metal and favour the adsorption process, are effective organic corrosion inhibitors. Even while most synthetic organic inhibitors are pricey, they have a harmful and damaging impact on the environment, posing a variety of dangers when discharged into numerous streams. Because of the toxicity of these organic inhibitors, researchers are now looking into using nontoxic pharmaceuticals or natural compounds as inhibitors that are also environmentally friendly and biodegradable. This has boosted the popularity of medicines and green corrosion inhibitors. Table -1: Few Organic Corrosion Inhibitors and its Properties Name of the Compound (Drug) Biology of Compound Adsorption Method Features Inhibition efficiency with respect to inhibitor concentration Ref Donaxine Adiponectin receptor (AdipoR1)1 Langmuir adsorption is followed by a mixed type inhibitor Temperature is an adverse effect on inhibition efficiency 98% at 7.5 mM 22 Penicillin G Antibacterial Langmuir adsorption is followed by a mixed type inhibitor Water soluble 98% at 10 mM 23 Atenolol β1receptorantagonis t Langmuir adsorption is followed by a mixed type inhibitor Theoretical studies supports practical results 93.8% at 300ppm 24 Cephalothin Broad spectrum antibiotics Langmuir adsorption Efficiency decreases with temperature 92% ppm at 660 25 Telmisartan Angiotensin II receptor, Antihypertension Mixed type and follows Temkin adsorption Mechanism was established 97.39% at 125 mgL-1 26 Metronidazole antimicrobial, anti-trichomonas antigiardial, Anodic type inhibitor and follows Temkin adsorption Theoretical Studies were carried out 80.01% at10µM 27
3.
International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 09 Issue: 03 | Mar 2022 www.irjet.net p-ISSN: 2395-0072 © 2022, IRJET | Impact Factor value: 7.529 | ISO 9001:2008 Certified Journal | Page 538 Tinidazole Antibacterial, anticancer, antitubercular, antifungal Langmuir adsorption is followed by a mixed type inhibitor Higher efficiency at room temperature 90% at 400 Ppm 28 Cimetidine Histamine H2 receptor Antagonist Langmuir adsorption is followed by a mixed type inhibitor Theoretical Studies were carried out 95.6% at 500ppm 29 Ranitidine H2 histamine receptor Antagonist Langmuir adsorption is followed by a mixed type inhibitor Theoretical Studies were carried out 95.53% at 2x10- 3M 30 Ketosulphide - Langmuir adsorption is followed by a mixed type inhibitor Theoretical Studies were carried out 75.4% at 100ppm 31 Chlorphenicol Primarily bacteriostaticactivity . Langmuir adsorption is followed by a mixed type inhibitor Higher efficiency at room temperature 78.10% at 50ppm 32 Hydralazine Antihypertensive agent Langmuir adsorption is followed by a mixed type inhibitor. Theoretical Studies were carried out 94.11% at1250 ppm 33 Aspirin Non-steroidal Anti-inflammatory agent. Mixed type inhibitor and follows Langmuir adsorption Experimental results were Supported by theoretical results 77.58% at 50ppm 34 Ketosulfone Antihypertensive agent Langmuir adsorption is followed by a mixed type inhibitor. Higher efficiency at room temperature 85.80%at200pp m 35 Chloroquinolin es Anti-cancer activity Langmuir adsorption is followed by a mixed type inhibitor. Higher efficiency at room temperature 94% at 5.00×10- 4 36 2.2. Corrosion inhibitors made from plant extracts Extraction of plant sources yields molecules with a variety of chemical, biological, and physical properties, some of which have complicated molecular structures. Natural occurring substances are frequently employed because to their environmental friendliness, cost effectiveness, and accessibility. These advantages support the use of plant extracts and their derivatives as metal and alloy corrosion inhibitors in a range of settings. Because the active ingredient's composition determines how green inhibitors work, several researchers have offered a variety of ideas to explain this phenomena. Corrosion inhibitors can be made from plant extracts, sometimes known as green corrosion inhibitors.
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International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 09 Issue: 03 | Mar 2022 www.irjet.net p-ISSN: 2395-0072 © 2022, IRJET | Impact Factor value: 7.529 | ISO 9001:2008 Certified Journal | Page 539 Green corrosion inhibitors are recyclable and contain no toxic metals or other possibly dangerous substances. They are also environmentally friendly. Researchers have proven that the easily available occurring compounds to keep metals from corroding in acidic and alkaline environments conditions is a valid method of corrosion prevention. The adsorption of natural corrosion inhibitors on metal surfaces is determined by the nature of the metal, testing medium, chemical composition of the inhibitor, nature of linkers present in the inhibitor, presence of additives, solution temperature, and solution concentration. Table 2 lists recent investigations on the suppression of MS by means of plant extracts by various authors. Table -2: Plant extracts as corrosion inhibitors for mild steel Sl. No Name of the Inhibitor Active constituents Inhibition efficiency (%) Remarks Ref 1 Cotula cinerea, Anagyrine, cytosine 67 % Weight loss and electrochemical methods were used to investigate mild steel corrosion in sulphuric acid. 37 2 Rauvolfia serpentina Reserpine, ajmalicine, ajmaline, isoajmaline, ajmalinine, chandrine 94 % Corrosion studies at 303,313,and 323 K 38 3 Nauclea latifolia Monoterpene, triterpene indole alkaloid, saponins 76 % corrosion studies in H2SO4 solutions at 300 and 600C 39 4 Embilicauflicianalis, Terminaliachebula and Terminalia bellirica Emblicanin A & B, puniglucanin, pedunculagin, tannic acid, chebulinic acid, and gallic acid 80 % Chemical and Electrochemical method in HCl medium 40 5 Carica papaya and Azadirachta indica Papain, carpaine, chymopapain, azadirachtin, salanningedunin, and azadirone 87 % Inhibition increases with concentration of the inhibitor 41 6 Mentha pulegium Pulegone 80 % It is cathodic inhibitor 42 7 Zanthoxylum alatun Terpineol, isoxazolid ine, and imidazolinedione 85 % Corrsoion studies at 50–80◦C in HCl medium 43 8 Thyme, Coriander, Hibiscus, Anis, Black Cumin and Garden Cress Thymol, malic acid, salicin, glutamic acid, leucine, and methionine 85 % Mixed type inhibitor 44 9 Phoenix dactylifera, Lawsoniainermis, and Zea mays Lawsone, esculetin, fraxetin, allantoin, sterols, and hordenine 90 % Used as inhibitor for steel and Aluminum 45 10 Datura metel Scopolamine, b- sitosterol, daturadiol, tropine, and daturilin 86 % Electrochemical studies were carried out in these experiments 46 11 Ricinus communis Ricinoleic or ricinic acid, ricinolein, and palmitin 84 % Studied in Electrochemical Method. 47
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International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 09 Issue: 03 | Mar 2022 www.irjet.net p-ISSN: 2395-0072 © 2022, IRJET | Impact Factor value: 7.529 | ISO 9001:2008 Certified Journal | Page 540 12 Mentha pulegium Pugelone, alpha- pinene, limonene, methone, andpiperitone 80 % Corrosion rate was decreases with temperature 48 13 Carica papaya Chymopapain,pectin,ca rposide,carpaine,pseud ocarpaine,dehydrocarp ines,carotenoids, cryptoglavine, cis- violaxanthin, and antheraxanthin 92 % Gravimetric and gasometric techniques were used 49 14 Acacia seyal Catechu, dimethyltryptamine(D MT) 95 % Corrosion studies on mild steel in drinking water 50 15 Calotropis procera a-and b- Amyrins,cyanidin-3- rhamnoglucoside,cyclo art-23-en-3b,25- diol,cyclosadol 89 % Chemical and Electrochemical method was used 51 Following the review of the summary literature in the table, plant extracts as green corrosion inhibitors, they've been studied. for mild steel. The results of the review summary analysis are presented in Table 2. The research was carried out in sulphuric acid and hydrochloric acid, with some cases present in together, then so encompassed a wide range of real-world industrial settings using steel that were exposed to the acids in question. Although only in limited quantities, it is worth noting this nitric acid and as well as salt media were tested. Researchers have discovered that green corrosion inhibitors are beginning to appear in genuine wastewater as a result of their research into the industrial effluent medium, which could pave the way for their widespread use. 3. Effects of Temperature and Inhibitor Concentration In all assays, increasing inhibitor concentration resulted in better inhibition efficiency, with the exception of one involving a Caesalpiniapulcherrima extract, in which inhibition efficiency increased as inhibitor concentration declined. The reason is, environment friendly inhibitors is used in very less dose, they are less expensive and safer for the environment, which is a great piece of news to hear. The inhibitory efficiency reduced in the majority of cases as the temperature climbed, demonstrating that the approach works best at ambient temperature or mild temperatures. At high temperatures in a few cases, the inhibitory efficiency was high, which can be advantageous in applications using mild steel. 4. Corrosion investigation techniques The weight loss strategy was used in all of the cases in order to assess inhibitory effectiveness. Gravimetric analysis was another approach that was widely used. Among the most often used techniques for evaluating inhibitor type and adsorption mechanism, potentiodynamic polarisation and electrochemical impedance spectroscopy were commonly used techniques. The use of tafel polarisation, as well as gasometric and thermometric approaches, was employed in a few instances. The Langmuir isotherm model was used to describe the adsorption of plant extracts and acid ions on MS surfaces in the vast great popular of the investigations conducted on the subject 5. Research Gap All of the studies described in this paper show that mild steel can be inhibited effectively in acidic environments. The inhibitors have been proven to be environmentally beneficial by researchers. The majority of researchers aren't focused on high-temperature research. Theoretical research like as quantum mechanics and molecular dynamics are useful in determining the structure-property link and its impact on corrosion inhibition efficiency. 6. CONCLUSION Eco Friendly Corrosion inhibitors were tabulates in this paper. With increasing concentrations, all of these inhibitors
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International Research Journal
of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 09 Issue: 03 | Mar 2022 www.irjet.net p-ISSN: 2395-0072 © 2022, IRJET | Impact Factor value: 7.529 | ISO 9001:2008 Certified Journal | Page 541 show increased inhibitory efficiency. In our research, the majority of the inhibitors were discovered to be mixed inhibitors. Electrochemical impedance spectroscopy, linear polarisation resistance, and weight loss all provide similar findings. This paper will give the more benefits for the fresh researchers to initiate the research in corrosion topic. REFERENCES [1] Hebbar, N., Praveen, B. M., Prasanna, B. M., & Venkatesha, T. V. (2015). Anticorrosion potential of a pharmaceutical intermediate Floctafenine for zinc in 0.1 M HCl solution. International Journal of Industrial Chemistry, 6(3), 221-231. [2] Raicheva, S. N., Aleksiev, B. V., sokolova, E. J., (1993). The effect of the chemical structure of some nitrogen and sulphur containing organic compounds on their corrosion inhibiting action. Corrosion Sci, 34, 343-350. [3] Arab, S.T., Noor, E. A., (1993). Inhibition of acid corrosion of steel by some S-alkylisothio-Uranium iodides. Corrosion 49:122-129. [4] E. J., Sayed, (1997). Phenothiazineas inhibitor of the corrosion of cadmium in acidic solutions. J.Appl Elecrochem 27: 193-200. [5] Cheng X. L., Ma, H. Y., Chen, S., Yu, R.,Chen, X.,Yao, Z. M., (1998). Corrosion of stainlesssteels in acid solutions with organic sulphur containing compounds. Corros Sci 41:321-333. [6] Abd EL, Rehim S. S., Magdy, A. M., Ibrahim Khaled, K. F., (1999). 4-Aminoan tipyrine as an inhibitor of mild mild steel corrosion in HCl solution. J.Appl Electro Chem 29:593-599. [7] Saha, S. K., Dutta, A., Ghosh, P., Sukul, D., & Banerjee, P., (2015). Adsorption and corrosion inhibition effect of Schiff base molecules on the mild steel surface in 1 M HCl medium: a combined experimental and theoretical approach. Physical Chemistry Chemical Physics, 17(8), 5679-5690. [8] Bouklah, M., Benchat, N., Hammouti, B., Aouniti, A., Kertit, S. (2006). Thermodynamic characterisation of steel corrosion and inhibitor adsorption of pyridazine compounds in 0.5 M H2SO4. Materials Letters, 60(15), 1901-1905. [9]. Bentiss, F., Traisnel, M., Lagrenee, M. (2001). Influence of 2, 5-bis (4-dimethylaminophenyl)-1, 3, 4-thiadiazole on corrosion inhibition of mild steel in acidic media. Journal of Applied Electrochemistry, 31(1), 41-48. [10] Koch, G. H., Brongers, M. P., Thompson, N. G., Virmani, Y. P., & Payer, J. H. (2002). Corrosion cost and preventive strategies in the United States (No. FHWA-RD-01-156,) [11] Rehim, S. S. A., Hassan, H. H., & Amin, M. A. (2002). Corrosion and corrosion inhibition of Al and some alloys in sulphate solutions containing halide ions investigated by an impedance technique. Applied Surface Science, 187(3-4), 279-290. [12] Sherif, E. M., & Park, S. M. (2006). Effects of 1, 4-naphthoquinone on aluminum corrosion in 0.50 M sodiumchloride solutions. Electrochimica acta, 51(7),1313-1321. [13] Badawy, W. A., Al-Kharafi, F. M., & El-Azab, A. S. (1999). Electrochemical behaviour and corrosion inhibition of Al, Al-6061 and Al–Cu in neutral aqueous solutions. Corrosion Science, 41(4), 709-727. [14] El Abedin, S. Z., (2001). Role of chromate, molybdate and tungstate anions on the inhibition of aluminiumin chloride solutions. Journal of Applied Electrochemistry, 31(6), 711-718. [15] Natishan, P. M., McCafferty, E., &Hubler, G. K., (1988). Surface Charge Considerations in the Pitting of Ion‐ Implanted Aluminum. Journal of the Electrochemical Society, 135(2), 321. [16] Zarrouk, A., Hammouti, B., Dafali, A., Zarrok, H., Touzani, R., Bouachrine, M., & Zertoubi, M. (2012). Inhibition of copper corrosion in acid solution by N-1-naphthylethylenediamine dihydrochloride monomethanolate: experimental and theoretical study: part-1. Research on Chemical Intermediates, 38(3), 1079-1089. [17] Sherif, E. M., & Park, S. M. (2006). Effects of 1, 4-naphthoquinone on aluminum corrosion in 0.50 M sodium chloride solutions. Electrochimica acta, 51(7), 1313-1321.
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of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 09 Issue: 03 | Mar 2022 www.irjet.net p-ISSN: 2395-0072 © 2022, IRJET | Impact Factor value: 7.529 | ISO 9001:2008 Certified Journal | Page 542 [18] Ebenso, E. E., Ekpe, U. J., Ita, B. I., Offiong, O. E., & Ibok, U. J. (1999). Effect of molecular structure on the efficiency of amides and thiosemicarbazones used for corrosion inhibition of mild steel in hydrochloric acid. Materials chemistry and physics, 60(1), 79-90. [19] Oguzie, E. E., Okolue, B. N., Ebenso, E. E., Onuoha, G. N., & Onuchukwu, A. I. (2004). Evaluation of the inhibitory effect of methylene blue dye on the corrosion of aluminium in hydrochloric acid. Materials Chemistry and Physics, 87(2-3), 394-401. [20] Saidman, S. B., & Bessone, J. B. (2002). Electrochemical preparation and characterisation of polypyrrole on aluminium in aqueous solution. Journal of Electroanalytical Chemistry, 521(1-2), 87-94. [21] Ferreira, E. S., Giacomelli, C., Giacomelli, F. C., & Spinelli, A. (2004). Evaluation of the inhibitor effect of L-ascorbic acid on the corrosion of mild steel. Materials Chemistry and Physics, 83(1), 129-134. [22] Quartarone, G., Ronchin, L., Vavasori, A., Tortato, C., & Bonaldo, L. (2012). Inhibitive action of gramine towards corrosion of mild steel in deaerated 1.0 M hydrochloric acid solutions. Corros. Sci. 64, 82-89. [23] Golestani, G., Shahidi, M., & Ghazanfari, D. (2014). Electrochemical evaluation of antibacterial drugs as environment-friendly inhibitors for corrosion of carbon steel in HCl solution. Appl. Sur. Sci. 308, 347 -362. [24] Karthik, G., & Sundaravadivelu, M. (2016). Studies on the inhibition of mild steel corrosion in hydrochloric acid solution by atenolol drug. Egyptian J. Petrol. 25, 183 -191. [25] Aldana-Gonzalez, J., Espinoza-Vazquez, A., Romero-Romo, M., Uruchurtu-Chavarin, J., & Palomar-Pardave, M. (2019). Electrochemical evaluation of cephalothin as corrosion inhibitor for API 5L X52 steel immersed in an acid medium, Arabian J. Chem., 12, 3244-3253. [26] Verma, C., Chauhan, D. S., & Quraishi, M. A. (2017). Drugs as environmentally benign corrosion inhibitors for ferrous and nonferrous materials in acid environment: an overview. J. Mater. Environ. Sci, 8, 4040-4051. [27] Obat, I. B., Ebenso, E. E., & Kaba, M.M. (2013). Drugs as environmentally benign corrosion inhibitors for ferrous and nonferrous materials in acid environment: An overview. J. Environ. Chem. Eng. 1, 431. [28] Narayana Hebbar, Praveen, B. M., Prasanna, B.M., & Vishwantah, P., (2020). Electrochemical and Adsorption Studies of 4-Chloro,8-(Trifluoromethyl)Quinoline (CTQ) for Mild Steel in Acidic Medium. Journal of Failure Analysis and prevention. J Fail. Anal. and Preven. 20,1516-1523. [29] Shylesha, B . S., Venkatesha, T.V., Praveen, B.M., & Nataraja, S.E., (2012) Acid Corrosion Inhibition of Steel by Lamotrigine, ISRN Corrosion, 2012. [30] Rajappa, S. K., Praveen, B. M., & Venkatesha, T. V. (2014). Chemical and electrochemical studies of ranitidine as a corrosion inhibitor for mild steel in hydrochloric acid medium. Int. Res. J. Chem, 1(2), 010-017. [31] Narayana Hebbar., Praveen, B. M., Prasanna, B.M., & Venkatesha, T .V. (2015). Adsorption, thermodynamic, and electrochemical studies of ketosulfide for mild steel in acidic medium International Research Journal of Chemistry , 2(1), 018-020. [32 ] Prasanna, B. M., Praveen, B. M., Hebbar, N., & Venkatesha, T. V. (2015). Corrosion inhibitory action of mild steel in 1M HCl by Chlorophenicol. Moroccan Journal of Chemistry, 3(4), 1-14. [33] Prasanna, B. M., Praveen, B. M., Hebbar, N., & Venkatesha, T. V. (2015). Anticorrosion potential of Hydralazine for corrosion of mild steel in 1M Hydrochloric acid solution. Journal of Fundamental and Applied Sciences, 7(2), 222-243. [34] Prasanna, B. M., Praveen, B. M., Hebbar, N., Venkatesha, T. V., Tandon, H. C., & Abd Hamid, S. B. (2017). Electrochemical study on inhibitory effect of Aspirin on mild steel in 1 M hydrochloric acid. Journal of the Association of Arab Universities for Basic and Applied Sciences, 22, 62-69. [35] Matad, P. B., Mokshanatha, P. B., Hebbar, N., Venkatesha, V. T., & Tandon, H. C. (2014). Ketosulfone drug as a green corrosion inhibitor for mild steel in acidic medium. Industrial & Engineering Chemistry Research, 53(20), 8436-8444. [36] Shanbhag, A. V., Venkatesha, T. V., Praveen, B. M., & Abd Hamid, S. B. (2014). Inhibition Effects of Chloroquinolines
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of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 09 Issue: 03 | Mar 2022 www.irjet.net p-ISSN: 2395-0072 © 2022, IRJET | Impact Factor value: 7.529 | ISO 9001:2008 Certified Journal | Page 543 on Corrosion of Mild Steel in Hydrochloric Acid Solution. Journal of Iron and Steel Research, International, 21(8), 804- 808. [37] Prabhu, R.A., Venkatesha, T.V., Praveen, B.M., Chandrappa, K.G., Abd Hamid, S.B., (2014) Inhibition Effect of Azadirachta indica, a Natural Product, on the Corrosion of Zinc in Hydrochloric Acid Solution. Transactions of Indian Institute of Metals 67(5):675–679. [38] Raja, P. B., & Sethuraman, M. G. (2008). Natural products as corrosion inhibitor for metals in corrosive media—a review. Materials letters, 62(1), 113-116. [39] Uwah, I. E., Okafor, P. C., & Ebiekpe, V. E. (2013). Inhibitive action of ethanol extracts from Nauclea latifolia on the corrosion of mild steel in H2SO4 solutions and their adsorption characteristics. Arabian journal of chemistry, 6(3), 285- 293. [40] Manohar R. Rathod, Rajappa, S.K., Praveen, B.M., Bharath D.K., (2021), Investigation of Dolichandra unguis-cati leaves extract as a corrosion inhibitor for mild steel in acid medium. Current Research in Green and Sustainable Chemistry. 4 (2021) 100113. [41] Abdallah, M., Hatem M. Altass, AL Jahdaly, B.A. & Salem, M.M., (2018) Some natural aqueous extracts of plants as green inhibitor for carbon steel corrosion in 0.5 M sulfuric acid. Green Chemistry Letters and Reviews . 11(3) 189 – 196. [42] Bouyanzer, A., Hammouti, B., & Majidi, L. (2006). Pennyroyal oil from Mentha pulegium as corrosion inhibitor for steel in 1 M HCl. Materials Letters, 60(23), 2840-2843. [43] Chauhan, L. R., & Gunasekaran, G. (2007). Corrosion inhibition of mild steel by plant extract in dilute HCl medium. Corrosion science, 49(3), 1143-1161. [44] Khamis, E., & Alandis, N. (2002). Herbs as new type of green inhibitors for acidic corrosion of steel. Materialwissenschaft und Werkstofftechnik: Entwicklung, Fertigung, Prüfung, Eigenschaften und Anwendungen technischer Werkstoffe, 33(9), 550-554. [45] Rehan, H. H. (2003). Corrosion control by water‐soluble extracts from leaves of economic plants. Material wissenschaft und Werkstofftechnik: Entwicklung, Fertigung, Prüfung, Eigenschaften und Anwendungen technischer Werkstoffe, 34(2), 232-237. [46] Sethuraman, M. G., & Raja, P. B. (2005). Corrosion inhibition of mild steel by Datura metel in acidic medium. Pigment & Resin Technology. [47] Sathiyanathan, R. A. L., Essa, M. M., Maruthamuthu, S., Selvanayagam, M., & Palaniswamy, N. (2005). Inhibitory effect of Ricinus communis (Castor-oil plant) leaf extract on corrosion of mild steel in low chloride medium. Journal of the Indian Chemical Society, 82(4), 357-359. [48] Chaieb, E., Bouyanzer, A., Hammouti, B., & Benkaddour, M. (2005). Inhibition of the corrosion of steel in 1 M HCl by eugenol derivatives. Applied Surface Science, 246(1-3), 199-206. [49] Okafor, P. C., & Ebenso, E. E. (2007). Inhibitive action of Carica papaya extracts on the corrosion of mild steel in acidic media and their adsorption characteristics. Pigment & Resin Technology. [50] Buchweishaija, J., & Mhinzi, G. S., (2008). Natural products as a source of environmentally friendly corrosion inhibitors: the case of gum exudate from Acacia seyal var. seyal. [51] Raja, P. B., & Sethuraman, M. G., (2009). Inhibition of corrosion of mild steel in sulphuric acid medium by Calotropis procera. Pigment & Resin Technology. 38(1).
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