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by Group III Base Oils
SK Energy Introduction

Backgrounds of Group III Base Oil

Trends of High Quality Lubricants

                       Summary
Holding    • SK Holdings                                           Sales Ratio
Company


            •   SK Energy
            •   SK E&S
 Energy
            •   SK Chemicals
   &        •   SKC
Chemicals   •   SK Incheon Oil
            •   Dopco
            •   K-Power

            •   SK Telecom
            •   SK C&C
Telecom     •   SK Telink
            •   SK Telesys
            •   Helio

            •   SK Networks                     • Sales :                    73.7 billion USD
Trading     •   SK Engineering & Construction
   &        •   SK Shipping                     • Total Assets :             63.3 billion USD
Services    •   Sheraton Walkerhill             • Employees :                About 30,000
            •   SK Securities

                                                  * Includes the sales from SK Networks
                                                     (Data in 2006)
History
                    Established in 1962 as Korea’s first domestic oil refining company.
Korea Oil Company   Acquired by SK Group in 1982, and called YUKONG.
                    Name changed to SK Corporation in 1997.
     1962-1982
                    Split into SK Holdings and SK Energy in July 1, 2007


    YUKONG          Business Areas
     1982-1997      Refining, Petrochemicals, Exploration & Production, Coal, Lubricants, etc.


                    Leading Energy & Petrochemical player in Korea
                    Largest refiner in Korea’s oil industry, holding over 1/3 of the market
                    share, and leading Petrochemical, Lubricant player in Korea.
    1997- 2007

                    Globalization
                    SK Energy is in a transitive phase, increasingly penetrating into
                    overseas markets with a view to becoming a major player in the Asia-
      Present       Pacific region.
                    SK Corporation(Former SK Energy) has been ranked as 98th in Fortune
                    Global 500 company list, 2007
Domestic market share: 34%     Ethylene:     830,000 Ton/Yr
CDU capacity:    1,115 m b/d   Propylene: 540,000 Ton/Yr
Gas station:          4,185    BTX:        3,600,000 Ton/Yr




                               Engaged in 24 blocks
   Lubricant: 4,000 B/D                       in 14 countries
                               Oil equivalent reserves
   Base Oil: 20,000 B/D                     : 510 million Bbl
   Grease: 6,000 Ton/Yr        Production(E) : 25,000 B/D
Production Capacity                      World Top 10 Base Oil Suppliers

•   Lubricants : 4,000 bbls/day          •   Capacity : 20,000 bbs/day
    Grease : 6,000 tons/year
                                         50% world M/S in Group III base oil market
No.1 player in Korea since 1968 in the
competition of worldwide majors          Brand name is ‘YUBASE’

Premium brand name is ‘ZIC’              Has worldwide supply network for global
                                         customers
Has a 30% M/S in engine oil market
(Total 16% market share in Korea)        Found JV with PT. PERTAMINA for new
                                         350,000MT/year capacity refinery in Dumai
Continuing to expand markets abroad
Launched co-branding product named
‘ZIPEX’ with PT. PERTAMINA in Pakistan
Saturates     Sulfur
API Category   Viscosity Index
                                   (%)          (%)


  Group I          80-120          < 90        >0.03


 Group II          80-120          ≥ 90        ≤ 0.03


 Group III         120 +           ≥ 90        ≤ 0.03


 Group IV                           PAO


  Group V                         All others
ASTM
         Item                    YUBASE 4   YUBASE 6   YUBASE 8
                        Method
KV @ 40°C, cSt           D445      19.6       36.9       47.0

KV @ 100°C, cSt          D445      4.25       6.46       7.60

Viscosity Index         D2270      123        130        128

NOACK Volatility, wt%   D5800      14.7       7.1        5.0

Pour Point, °C           D92       -15        -12        -12

Flash Point, °C          D97       230        240        260
[KMT]                         10~%
                       7~8%
                                     Group III
30,000          4%
         2%
                                     Group II
25,000


20,000
                                     Group I

15,000


10,000


5,000



         2000   2005   2010   2015
[BPD]




[Unit: B/D]




              Source: Lubes n Grease, 2006
Chemical Type Structure    VI         Pour      Oxidation Toxicity

                          Very High     Solid      Excellent      Low
 n-Paraffin (Wax)           ~175       @50°C
iso-Paraffins with
                            High        Good       Excellent      Low
Branched chains
                            ~150
iso-Paraffins with
                            Good        Good        Excellent     Low
 highly branched
                            ~130
  chains (PAO's)
 cyclo-Paraffin-           Good         Good         Good         Low
 single ring with          ~130
   long chains
                            Poor        Good        Medium        Low
  Naphthenes,               ~60
 polycondensed
                            Poor        Good        Medium      Medium
 Monoaromatics,             ~60
  long chains
                          Very Poor     Good       Very Poor    Very High
 Polyaromatics
                             <0
YUBASE



                  High Isoparaffin Content
                  Some Naphthenic Compound
                  Small or Zero Aromatic




                  Low Isoparaffin Content
Group I




          N
                  Some Naphthenic Compound

              S
                  High Aromatic
Low Temp. Performance: CCS Viscosity[cp]    Oxidation Performance: RBOT[min] 1)




  Oxidation Performance: PCT[mg] 2)          Oil Consumption: Noack [wt%] 3)




   1)   ASTM D2270, + 0.3wt% Antioxidant
   2)   10.3% A3/B3 DI Additive + 10% VII
   3)   250'C, 1hr
Features

• Low Wax
• Very High VI


• Low Volatility
• Narrow Boiling Ranges


• High Saturates
• Good Additive Response


• Very High VI
• Low Aromatics


• Low Aromatics
• Low volatility
Features                        Reasons

                                 • Low Wax
• Better Low Temp. Performance
                                 • Very High VI


• Low Oil Consumption            • Low Volatility
• Higher Flash Points            • Narrow Boiling Ranges


• Higher Thermal/Oxidative       • High Saturates
  Stability (Longer life)        • Good Additive Response


• Good Friction Behavior         • Very High VI
• Wear Reduction                 • Low Aromatics


                                 • Low Aromatics
• Environmentally Friendliness
                                 • Low volatility
Reduce Fuel Costs




     Reduce Lubricant Costs


                                 Reduce
                              Personal and
                              Social Costs
     Reduce Emissions




Reduce Maintenance Costs
AP
                                       IG          Ash
                                          rad
                     Backward                e
 Emis
      sion          Compatibility                     Wear
                     y                        Oxid
                  om                              atio
               on                                     n
          l Ec                                                 ns
                                                            o
       ue                                           M icati
     F                                           OE ecif
Viscosity Dep                                      Sp
                     os
                        it                          e Su
                                       ACEA Sequenc      lfu
       th  etic?                                             r
   Syn                Low T               Phospha
                            emper                 te
    Soot             Perfor      ature
                           mance
2004              2005            2006            2007      2008              2009


          ILSAC GF-4   Gasoline                                                      ILSAC GF-5

 US
           API CI-4+   Diesel                          API CJ-4
Japan
         GM Dexron IIIH ATF                          GM Dexron VI



                                ACEA C3, C2                                   ACEA ??
                                 MB 229.31      Gasoline                      MB 229.??

Europe                 Euro IV                                       Euro V
                                  ACEA E6                                     ACEA ??
                                  MB 228.51     Diesel                        MB 228.??
PM
                           (g/km)   Emissions Standards
 Legislation                        - Passenger Car Diesel -



                                                          Euro 3
• Set Emission Target
• Reduce PM/NOx/SAPS
• Increase Fuel Economy
                                           Euro 4

                                    US Tier 2 bin 5


                                     Euro 5
     OEMs

                                                               NOx (g/km)

        Source: Lubrizol
P content
                             in oil
                                                 GF-1:
 Legislation
                             (wt%)
                                                 0.12 max
                               0.12
                                                            GF-2:      GF-3:
                                                            0.10 max   0.10 max
                               0.10
• Set Emission Target
                               0.08
• Reduce PM/NOx/SAPS
                                                                                    GF-4
• Increase Fuel Economy                                                             0.08 max
                               0.06


                               0.04



     OEMs                                          1995         2000         2005
                                       1990


                                              ILSAC : Phosphorus Content Limit


        Source: Lubrizol
Seq.VI F/E                                              Seq.VIB F/E
                           improvement          5W20 & 0W20                        improvement
                           %(vs.20W30)
 Legislation                                    5W30 & 0W30
                                                                                   %(vs.5W30)

                                                10W30                              3
                                  5
                                                                                   2

• Set Emission Target             4
                                                                                   1
                                                                             GF-
• Reduce PM/NOx/SAPS              3                                          4
                                                                     GF-           0
• Increase Fuel Economy                                  GF-2        3
                                  2              GF-
                                                 1
                                  1       SG



     OEMs                                1990    1995         2000         2005


                                            ILSAC : Fuel Efficiency Requirement


        Source: Lubrizol
Legislation


• Set Emission Target
• Reduce PM/NOx/SAPS
• Increase Fuel Economy



                        • Newly Designed Engines

     OEMs               • Severer Operating Condition
                                                        Lubricant
                                                        Manufacturers
                        • After-treatment Devices
High
        LTHS                                        HTHS

                                                             Major
        Cranking, Startability                       Wear
                                                             Performanc
                                                             e
             CCS, KV@40℃                      HTHS, TBS      Test Item

                                   Fuel
                                 Economy




             MRV, Brookfield           NOACK, KV@100℃


        Pumpability                        Oil Consumption

Low      LTLS                                       HTLS

       Low                                            High
x     SAE 40   Lubricating
                                                        General Benefits of
                                                       Multi-grade Lubricants
                                Area
Max. Viscosity
 (Low Temp)                                             Good Startability
                                                        Better Bearing Lubrication
                                                        Reduced Oil Consumption
                                                        Better Fuel Economy


                                          SAE 10W/40
Min. Viscosity
 (High Temp)

                        SAE 10W
                                   x
                 Low              High
High

                             Low Viscosity Index




                    High Viscosity Index




Low




       Low   High
Solutions to Increase
                            Viscosity Index



High                Viscosity Modifier
                    High Viscosity Index Base Oils


                          Consideration Points


                    Formulation Economics
                    Toxicity
                    Impacts on Other Performance


Low




       Low   High
Seq.VI F/E                                    Seq.VIB F/E
improvement      5W20 & 0W20                  improvement
%(vs.20W30)                                   %(vs.5W30)
                 5W30 & 0W30

                 10W30
                                                   3




                                                            Relative Fuel Saving
  5
                                                   2

  4                                                                                 5W/30          10W/40
                                         GF-4      1

  3                             GF-3
                     GF-2                          0

              GF-1                                                                                                  15W/50
  2
                                                                                                    15W/40

  1    SG

                                                                                                                    20W/50

      1990    1995       2000          2005                                                  High Sheer Viscosity



      ILSAC : Fuel Efficiency Requirement                                          Fleet Car Trial - Average Fuel Savings
Consumer


• Longer Drain Intervals
 • Better Fuel Economy
      • Price Efficiency




         Lubricant
        Manufacturers
Cost Efficiency
       ‘Synthetic’ Claims
  Product Differentiation
Operational Conveniences    Lubricant
                            Manufacturers
Features


•   Very Low Sulfur (≤ 0.03 %)

•   Very High Viscosity Index (120 + )

•   Excellent Low Temperature Performance

•   Low Volatility & High Flash Point

•   Excellent Thermal and Oxidative stability

※ Can be marketed as ‘Synthetic’




      Group III Base Oils
2nd




1st
+7.5KBD




                  +7.7KBD

                                        +5.5KBD

                            +3KBD




          S-Oil    Neste    GS Caltex Petronas    ?   GTL
[BPD]    Demand (Case 1 & 2)

         Supply


         Supply by SK energy


75,000




50,000




25,000




         2003              2006   2009   2012   2015
Viscosity Index                                 NOACK


                                          20
140
                                          18
130

120                                       16

110
                                          14
100
                                          12
 90

 80                                       10
      Gr-Ⅰ   Gr-Ⅱ   Gr-Ⅲ   New     PAO4        Gr-Ⅰ   Gr-Ⅱ     Gr-Ⅲ   New     PAO4
      100N   100N   4cSt YUBASE4               100N   100N     4cSt YUBASE4
Technical Needs
− Drive Towards Lighter Viscosity Multigrades

− With Tightened Approval Specifications in Lube Industry

− Limitation of using Harmful Additives to meet Demanding Performance



Marketing Needs
− Drive Cost effective, ‘Synthetic’ labeling High Quality Lubricants

− Is Encouraged by availability of large volumes of Group III/GTL production
Reduce
Personal and
Social Costs
London
                SK Corp.
                                 Tokyo
                 Tianjin                                        Houston




                                  Jakarta




         Branch Office     Storage Tank     Agent/Distributer
04   sk energy, j. rock lee

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04 sk energy, j. rock lee

  • 1. by Group III Base Oils
  • 2. SK Energy Introduction Backgrounds of Group III Base Oil Trends of High Quality Lubricants Summary
  • 3. Holding • SK Holdings Sales Ratio Company • SK Energy • SK E&S Energy • SK Chemicals & • SKC Chemicals • SK Incheon Oil • Dopco • K-Power • SK Telecom • SK C&C Telecom • SK Telink • SK Telesys • Helio • SK Networks • Sales : 73.7 billion USD Trading • SK Engineering & Construction & • SK Shipping • Total Assets : 63.3 billion USD Services • Sheraton Walkerhill • Employees : About 30,000 • SK Securities * Includes the sales from SK Networks (Data in 2006)
  • 4. History Established in 1962 as Korea’s first domestic oil refining company. Korea Oil Company Acquired by SK Group in 1982, and called YUKONG. Name changed to SK Corporation in 1997. 1962-1982 Split into SK Holdings and SK Energy in July 1, 2007 YUKONG Business Areas 1982-1997 Refining, Petrochemicals, Exploration & Production, Coal, Lubricants, etc. Leading Energy & Petrochemical player in Korea Largest refiner in Korea’s oil industry, holding over 1/3 of the market share, and leading Petrochemical, Lubricant player in Korea. 1997- 2007 Globalization SK Energy is in a transitive phase, increasingly penetrating into overseas markets with a view to becoming a major player in the Asia- Present Pacific region. SK Corporation(Former SK Energy) has been ranked as 98th in Fortune Global 500 company list, 2007
  • 5. Domestic market share: 34% Ethylene: 830,000 Ton/Yr CDU capacity: 1,115 m b/d Propylene: 540,000 Ton/Yr Gas station: 4,185 BTX: 3,600,000 Ton/Yr Engaged in 24 blocks Lubricant: 4,000 B/D in 14 countries Oil equivalent reserves Base Oil: 20,000 B/D : 510 million Bbl Grease: 6,000 Ton/Yr Production(E) : 25,000 B/D
  • 6. Production Capacity World Top 10 Base Oil Suppliers • Lubricants : 4,000 bbls/day • Capacity : 20,000 bbs/day Grease : 6,000 tons/year 50% world M/S in Group III base oil market No.1 player in Korea since 1968 in the competition of worldwide majors Brand name is ‘YUBASE’ Premium brand name is ‘ZIC’ Has worldwide supply network for global customers Has a 30% M/S in engine oil market (Total 16% market share in Korea) Found JV with PT. PERTAMINA for new 350,000MT/year capacity refinery in Dumai Continuing to expand markets abroad Launched co-branding product named ‘ZIPEX’ with PT. PERTAMINA in Pakistan
  • 7.
  • 8. Saturates Sulfur API Category Viscosity Index (%) (%) Group I 80-120 < 90 >0.03 Group II 80-120 ≥ 90 ≤ 0.03 Group III 120 + ≥ 90 ≤ 0.03 Group IV PAO Group V All others
  • 9. ASTM Item YUBASE 4 YUBASE 6 YUBASE 8 Method KV @ 40°C, cSt D445 19.6 36.9 47.0 KV @ 100°C, cSt D445 4.25 6.46 7.60 Viscosity Index D2270 123 130 128 NOACK Volatility, wt% D5800 14.7 7.1 5.0 Pour Point, °C D92 -15 -12 -12 Flash Point, °C D97 230 240 260
  • 10. [KMT] 10~% 7~8% Group III 30,000 4% 2% Group II 25,000 20,000 Group I 15,000 10,000 5,000 2000 2005 2010 2015
  • 11. [BPD] [Unit: B/D] Source: Lubes n Grease, 2006
  • 12. Chemical Type Structure VI Pour Oxidation Toxicity Very High Solid Excellent Low n-Paraffin (Wax) ~175 @50°C iso-Paraffins with High Good Excellent Low Branched chains ~150 iso-Paraffins with Good Good Excellent Low highly branched ~130 chains (PAO's) cyclo-Paraffin- Good Good Good Low single ring with ~130 long chains Poor Good Medium Low Naphthenes, ~60 polycondensed Poor Good Medium Medium Monoaromatics, ~60 long chains Very Poor Good Very Poor Very High Polyaromatics <0
  • 13. YUBASE High Isoparaffin Content Some Naphthenic Compound Small or Zero Aromatic Low Isoparaffin Content Group I N Some Naphthenic Compound S High Aromatic
  • 14. Low Temp. Performance: CCS Viscosity[cp] Oxidation Performance: RBOT[min] 1) Oxidation Performance: PCT[mg] 2) Oil Consumption: Noack [wt%] 3) 1) ASTM D2270, + 0.3wt% Antioxidant 2) 10.3% A3/B3 DI Additive + 10% VII 3) 250'C, 1hr
  • 15. Features • Low Wax • Very High VI • Low Volatility • Narrow Boiling Ranges • High Saturates • Good Additive Response • Very High VI • Low Aromatics • Low Aromatics • Low volatility
  • 16. Features Reasons • Low Wax • Better Low Temp. Performance • Very High VI • Low Oil Consumption • Low Volatility • Higher Flash Points • Narrow Boiling Ranges • Higher Thermal/Oxidative • High Saturates Stability (Longer life) • Good Additive Response • Good Friction Behavior • Very High VI • Wear Reduction • Low Aromatics • Low Aromatics • Environmentally Friendliness • Low volatility
  • 17. Reduce Fuel Costs Reduce Lubricant Costs Reduce Personal and Social Costs Reduce Emissions Reduce Maintenance Costs
  • 18. AP IG Ash rad Backward e Emis sion Compatibility Wear y Oxid om atio on n l Ec ns o ue M icati F OE ecif Viscosity Dep Sp os it e Su ACEA Sequenc lfu th etic? r Syn Low T Phospha emper te Soot Perfor ature mance
  • 19. 2004 2005 2006 2007 2008 2009 ILSAC GF-4 Gasoline ILSAC GF-5 US API CI-4+ Diesel API CJ-4 Japan GM Dexron IIIH ATF GM Dexron VI ACEA C3, C2 ACEA ?? MB 229.31 Gasoline MB 229.?? Europe Euro IV Euro V ACEA E6 ACEA ?? MB 228.51 Diesel MB 228.??
  • 20.
  • 21. PM (g/km) Emissions Standards Legislation - Passenger Car Diesel - Euro 3 • Set Emission Target • Reduce PM/NOx/SAPS • Increase Fuel Economy Euro 4 US Tier 2 bin 5 Euro 5 OEMs NOx (g/km) Source: Lubrizol
  • 22. P content in oil GF-1: Legislation (wt%) 0.12 max 0.12 GF-2: GF-3: 0.10 max 0.10 max 0.10 • Set Emission Target 0.08 • Reduce PM/NOx/SAPS GF-4 • Increase Fuel Economy 0.08 max 0.06 0.04 OEMs 1995 2000 2005 1990 ILSAC : Phosphorus Content Limit Source: Lubrizol
  • 23. Seq.VI F/E Seq.VIB F/E improvement 5W20 & 0W20 improvement %(vs.20W30) Legislation 5W30 & 0W30 %(vs.5W30) 10W30 3 5 2 • Set Emission Target 4 1 GF- • Reduce PM/NOx/SAPS 3 4 GF- 0 • Increase Fuel Economy GF-2 3 2 GF- 1 1 SG OEMs 1990 1995 2000 2005 ILSAC : Fuel Efficiency Requirement Source: Lubrizol
  • 24. Legislation • Set Emission Target • Reduce PM/NOx/SAPS • Increase Fuel Economy • Newly Designed Engines OEMs • Severer Operating Condition Lubricant Manufacturers • After-treatment Devices
  • 25. High LTHS HTHS Major Cranking, Startability Wear Performanc e CCS, KV@40℃ HTHS, TBS Test Item Fuel Economy MRV, Brookfield NOACK, KV@100℃ Pumpability Oil Consumption Low LTLS HTLS Low High
  • 26. x SAE 40 Lubricating General Benefits of Multi-grade Lubricants Area Max. Viscosity (Low Temp) Good Startability Better Bearing Lubrication Reduced Oil Consumption Better Fuel Economy SAE 10W/40 Min. Viscosity (High Temp) SAE 10W x Low High
  • 27. High Low Viscosity Index High Viscosity Index Low Low High
  • 28. Solutions to Increase Viscosity Index High Viscosity Modifier High Viscosity Index Base Oils Consideration Points Formulation Economics Toxicity Impacts on Other Performance Low Low High
  • 29. Seq.VI F/E Seq.VIB F/E improvement 5W20 & 0W20 improvement %(vs.20W30) %(vs.5W30) 5W30 & 0W30 10W30 3 Relative Fuel Saving 5 2 4 5W/30 10W/40 GF-4 1 3 GF-3 GF-2 0 GF-1 15W/50 2 15W/40 1 SG 20W/50 1990 1995 2000 2005 High Sheer Viscosity ILSAC : Fuel Efficiency Requirement Fleet Car Trial - Average Fuel Savings
  • 30. Consumer • Longer Drain Intervals • Better Fuel Economy • Price Efficiency Lubricant Manufacturers
  • 31. Cost Efficiency ‘Synthetic’ Claims Product Differentiation Operational Conveniences Lubricant Manufacturers
  • 32. Features • Very Low Sulfur (≤ 0.03 %) • Very High Viscosity Index (120 + ) • Excellent Low Temperature Performance • Low Volatility & High Flash Point • Excellent Thermal and Oxidative stability ※ Can be marketed as ‘Synthetic’ Group III Base Oils
  • 34. +7.5KBD +7.7KBD +5.5KBD +3KBD S-Oil Neste GS Caltex Petronas ? GTL
  • 35. [BPD] Demand (Case 1 & 2) Supply Supply by SK energy 75,000 50,000 25,000 2003 2006 2009 2012 2015
  • 36. Viscosity Index NOACK 20 140 18 130 120 16 110 14 100 12 90 80 10 Gr-Ⅰ Gr-Ⅱ Gr-Ⅲ New PAO4 Gr-Ⅰ Gr-Ⅱ Gr-Ⅲ New PAO4 100N 100N 4cSt YUBASE4 100N 100N 4cSt YUBASE4
  • 37. Technical Needs − Drive Towards Lighter Viscosity Multigrades − With Tightened Approval Specifications in Lube Industry − Limitation of using Harmful Additives to meet Demanding Performance Marketing Needs − Drive Cost effective, ‘Synthetic’ labeling High Quality Lubricants − Is Encouraged by availability of large volumes of Group III/GTL production
  • 39. London SK Corp. Tokyo Tianjin Houston Jakarta Branch Office Storage Tank Agent/Distributer