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Kassidy Klink
Peak Environmental
Volume-Average
Purge Sampling
Low-flow
Sampling
Non-purge
Sampling
Well screen >5ˈ = multiple samples
Firms need to be certified
Field calibration at correct temperature
pH
SC
ORP
DO
NTU
 A measure of how acidic/basic water is;
 Ranges from 0-14, with 7 being neutral
 Reported in logarithmic units (ex. pH of 5 is 10x more
acidic than 6)
 pH of water determines solubility and biological
availability of chemical constituents
 Nutrients (phosphorus, nitrogen, and carbon)
 Heavy metals (lead, copper, cadmium, etc.)
 pH determines activity of organisms and there ability to
use nutrients
 pH determines toxicity of heavy metals
 Generally more toxic at lower pH (solubility)
 The measure of the ability of water to conduct electrical
current
 Conductivity + area of electrodes = SC
 Highly dependent on the amount of dissolved solids
(such as salt) in water
 A good indicator of the amount of dissolved material in
water
 Dissolved solids can affect the suitability of water for
domestic, industrial, and agricultural uses
 Can give drinking water unpleasant taste or odor
 Can cause gastrointestinal problems
 Can deteriorate plumbing fixtures and appliances
 Saline water can affect crops
 Very high levels can inhibit bacterial activity
 Oxidation → net loss of electrons, Reduction → net gain
of electrons
 A measure of the tendency of a chemical substance to
oxidize or reduce another chemical substance
 Under proper ORP conditions, contaminants can
transform and/or become immobilized (ex. Heavy
metals)
 Cr+6 → Cr+3 under reducing conditions (good)
 As+5 → As+3 under reducing conditions (bad)
 Chlorinated solvents: Dechlorination (reducing
conditions) or ISCO (oxidizing conditions)
 Dechlorination of chlorinated compounds occurs as a
stepwise process with each step requiring a lower ORP
 Oxygen dissolved in water
 Typical Range → 0 to 8 mg/L
 Indicates whether conditions are:
 Oxidizing (aerobic)
 Reducing (anaerobic)
 Oxygen is the first electron acceptor available for biotic
transformations and is quickly consumed
 If DO is low (<2 mg/L) – look at other electron acceptors
 The amount of particulate matter (i.e. clay, silt, organic
matter, microscopic organisms) suspended in water
 High turbidity in samples can influence analytical results
 Organics/inorganics sorbed to particulates
 Suspended inorganics
 Can vary with:
 Depth
 Seasons
 Impacts biological activity
 Colder = slower
 Impacts probe calibrations
 Field parameters are actually important
o Geochemistry of site
o Look at trends during remediation & MNA
o Tells us if remediation might be working
 Know what to expect
o Historical readings
o What type of remediation → geochemical impacts
 Question the data
 If it doesn’t make sense – check calibration
 Once the sampling is complete – It’s too late!

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2013-03-01 peak field parameters presentation

  • 3. Well screen >5ˈ = multiple samples Firms need to be certified Field calibration at correct temperature
  • 4.
  • 6.  A measure of how acidic/basic water is;  Ranges from 0-14, with 7 being neutral  Reported in logarithmic units (ex. pH of 5 is 10x more acidic than 6)
  • 7.  pH of water determines solubility and biological availability of chemical constituents  Nutrients (phosphorus, nitrogen, and carbon)  Heavy metals (lead, copper, cadmium, etc.)  pH determines activity of organisms and there ability to use nutrients  pH determines toxicity of heavy metals  Generally more toxic at lower pH (solubility)
  • 8.  The measure of the ability of water to conduct electrical current  Conductivity + area of electrodes = SC  Highly dependent on the amount of dissolved solids (such as salt) in water  A good indicator of the amount of dissolved material in water
  • 9.  Dissolved solids can affect the suitability of water for domestic, industrial, and agricultural uses  Can give drinking water unpleasant taste or odor  Can cause gastrointestinal problems  Can deteriorate plumbing fixtures and appliances  Saline water can affect crops  Very high levels can inhibit bacterial activity
  • 10.  Oxidation → net loss of electrons, Reduction → net gain of electrons  A measure of the tendency of a chemical substance to oxidize or reduce another chemical substance
  • 11.  Under proper ORP conditions, contaminants can transform and/or become immobilized (ex. Heavy metals)  Cr+6 → Cr+3 under reducing conditions (good)  As+5 → As+3 under reducing conditions (bad)  Chlorinated solvents: Dechlorination (reducing conditions) or ISCO (oxidizing conditions)  Dechlorination of chlorinated compounds occurs as a stepwise process with each step requiring a lower ORP
  • 12.  Oxygen dissolved in water  Typical Range → 0 to 8 mg/L  Indicates whether conditions are:  Oxidizing (aerobic)  Reducing (anaerobic)  Oxygen is the first electron acceptor available for biotic transformations and is quickly consumed  If DO is low (<2 mg/L) – look at other electron acceptors
  • 13.  The amount of particulate matter (i.e. clay, silt, organic matter, microscopic organisms) suspended in water  High turbidity in samples can influence analytical results  Organics/inorganics sorbed to particulates  Suspended inorganics
  • 14.  Can vary with:  Depth  Seasons  Impacts biological activity  Colder = slower  Impacts probe calibrations
  • 15.  Field parameters are actually important o Geochemistry of site o Look at trends during remediation & MNA o Tells us if remediation might be working  Know what to expect o Historical readings o What type of remediation → geochemical impacts  Question the data  If it doesn’t make sense – check calibration  Once the sampling is complete – It’s too late!

Editor's Notes

  1. Oxidation-Reduction Potential (mV)