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Stimulated emissionSpontaneous emission
Light Amplification by Stimulated Emission of Radiation
Energy level diagram
 The possible energies which electrons in
the atom can have is depicted in an
energy level diagram.
1E
2E
3E
4E
The operation of the Laser
 In 1958, Charles Townes and ArthurSchawlow
theorized about a visible laser, an invention that
would use infrared and/orvisible spectrumlight.
 Light Amplification by Stimulated Emission of
Radiation- (LASER).
 Properties of Lasers
 Produce monochromatic light of extremely high
intensity.
The operation of the Laser
The operation of the Laser
1E
2E
3E
4E
The operation of the Laser
1E
2E
3E
4E
absorption
The operation of the Laser
1E
2E
3E
4E
Spontaneous emission
The operation of the Laser
Spontaneous emission
1. Incoherent light
2. Accidental direction
The operation of the Laser
1E
2E
3E
4E
The operation of the Laser
1E
2E
3E
4E
Stimulated emission
The operation of the Laser
Light: Coherent, polarized
The stimulating and emitted
photons have the same:
frequency
phase
direction
Two level system
absorption Spontaneous
emission
Stimulated
emission
hν hν
hν
E1
E2
E1
E2
hν =E2-E1
E1
E2
• n1 - the number of electrons of
energy E1
• n2 - the number of electrons of
energy E2
2 2 1
1
( )
exp
n E E
n kT
− − 
=  ÷
 
Boltzmann’s equation
example: T=3000 K E2-E1=2.0 eV
42
1
4.4 10
n
n
−
= ×
Einstein’s coefficients
Probability of stimulated absorption R1-2
R1-2
= ρ (ν) B1-2
Probability of stimulated and spontaneous emission :
R2-1
= ρ (ν) B2-1
+ A2-1
assumption: n1
atoms of energy ε 1
and n2
atoms of energy ε 2
are in
thermal equilibrium at temperature T with the radiation of spectral
density ρ (ν):
n1
R1-2
= n2
R2-1
n1
ρ (ν) B1-2
= n2
(ρ (ν) B2-1
+ A2-1
)
⇒
2 1 2 1
1 1 2
2 2 1
/
=
1
A B
n B
n B
ρ ν − −
−
−
( )
−
E1
E2
B1-2
/B2-1
= 1
According to Boltzman statistics:
ρ (ν) = =
1
2 1
2
exp( )/ exp( / )
n
E E kT h kT
n
ν= − =
1)exp(
/
12
21
1212
−
−
−
−−
kT
h
B
B
BA
ν 1)/exp(
/8 33
−kTh
ch
ν
νπ
3
3
12
12 8
c
h
B
A νπ
=
−
−
Planck’s law
The probability of spontaneous emission A2-1
/the probability of stimulated
emission B2-1
ρ(ν ):
1. Visible photons, energy: 1.6eV – 3.1eV.
2. kT at 300K ~ 0.025eV.
3. stimulated emission dominates solely when hν /kT <<1!
(for microwaves: hν <0.0015eV)
The frequency of emission acts to the absorption:
if hν /kT <<1.
1)/exp(
)(12
12 −=
−
− kTh
B
A
ν
νρ
1
2
1
2
12
12
211
122122 ]
)(
1[
)(
)(
n
n
n
n
B
A
Bn
BnAn
x ≈+=
+
=
−
−
−
−−
νρνρ
νρ
x~ n2
/n1
Condition for the laser operation
If n1 > n2
• radiation is mostly absorbed
• spontaneous radiation dominates.
• most atoms occupy level E2, weak absorption
• stimulated emission prevails
• light is amplified
if n2 >> n1 - population inversion
Necessary condition:
population inversion
E1
E2
How to realize the population inversion?
Thermal excitation:
2
1
exp
n E
n kT
−∆ 
=  ÷
 
Optically,
electrically.
impossible.
The system has to be „pumped”
E1
E2
Measurement disturbes the system
The Uncertainty Principle
The Uncertainty Principle
 Classical physics
 Measurement uncertainty is due to limitations of
the measurement apparatus
 There is no limit in principle to how accurate a
measurement can be made
 Quantum Mechanics
 There is a fundamental limit to the accuracy of a
measurement determined by the Heisenberg
uncertainty principle
 If a measurement of position is made with precision
∆x and a simultaneous measurement of linear
momentum is made with precision ∆p, then the
product of the two uncertainties can never be less
than h/2π
xx p∆ ∆ ≥ h
The Uncertainty Principle
Virtual particles: created due to the UP
E t∆ ∆ ≥ h
Three level laser
The laser operation
E1
E3
E2
Fast transition
Laser action
• 1→3 pumping
• spontaneous emission 3 →2.
• state 2 is a metastable state
• population inversion between states 2 and 1.
• stimulated emission between 2 i 1.
h≥∆∆ tε
E1
E3
E2
Fast transition
lasing
- optical pumping - occupation of E3 of a short life time,
10-8s. It is a band, the metastable and ground states are narrow :
- electrons are collected on E2: population inversion
- stimulated emission (one photon emitted spontaneously starts the
stimulated radiation )
- Beam of photons moves normally to the mirrors – standing wave.
The laser operation
ruby laser
• discovered in 60-ies of the XX century.
• ruby (Al2O3) monocrystal, Cr doped.
• Lasing from the Cr3+
.
• three level laser
Energy
4
A2
4
T2
4
T1
2
T2
2
E
LASING
• optical pumping: 510-600nm and 360-
450nm.
• fast transition on 2
E.
• lasing: 2
E on 4
A2,
•694nm
rapid decay
Ruby laser
Al2O3
Cr+
Ruby laser
First laser: Ted Maiman
Hughes Research Labs
1960

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RUBY LASER

  • 1.
  • 2. Stimulated emissionSpontaneous emission Light Amplification by Stimulated Emission of Radiation
  • 3. Energy level diagram  The possible energies which electrons in the atom can have is depicted in an energy level diagram. 1E 2E 3E 4E
  • 4. The operation of the Laser  In 1958, Charles Townes and ArthurSchawlow theorized about a visible laser, an invention that would use infrared and/orvisible spectrumlight.  Light Amplification by Stimulated Emission of Radiation- (LASER).  Properties of Lasers  Produce monochromatic light of extremely high intensity.
  • 5. The operation of the Laser
  • 6. The operation of the Laser 1E 2E 3E 4E
  • 7. The operation of the Laser 1E 2E 3E 4E absorption
  • 8. The operation of the Laser 1E 2E 3E 4E Spontaneous emission
  • 9. The operation of the Laser Spontaneous emission 1. Incoherent light 2. Accidental direction
  • 10. The operation of the Laser 1E 2E 3E 4E
  • 11. The operation of the Laser 1E 2E 3E 4E Stimulated emission
  • 12. The operation of the Laser Light: Coherent, polarized The stimulating and emitted photons have the same: frequency phase direction
  • 13. Two level system absorption Spontaneous emission Stimulated emission hν hν hν E1 E2 E1 E2 hν =E2-E1
  • 14. E1 E2 • n1 - the number of electrons of energy E1 • n2 - the number of electrons of energy E2 2 2 1 1 ( ) exp n E E n kT − −  =  ÷   Boltzmann’s equation example: T=3000 K E2-E1=2.0 eV 42 1 4.4 10 n n − = ×
  • 15. Einstein’s coefficients Probability of stimulated absorption R1-2 R1-2 = ρ (ν) B1-2 Probability of stimulated and spontaneous emission : R2-1 = ρ (ν) B2-1 + A2-1 assumption: n1 atoms of energy ε 1 and n2 atoms of energy ε 2 are in thermal equilibrium at temperature T with the radiation of spectral density ρ (ν): n1 R1-2 = n2 R2-1 n1 ρ (ν) B1-2 = n2 (ρ (ν) B2-1 + A2-1 ) ⇒ 2 1 2 1 1 1 2 2 2 1 / = 1 A B n B n B ρ ν − − − − ( ) − E1 E2
  • 16. B1-2 /B2-1 = 1 According to Boltzman statistics: ρ (ν) = = 1 2 1 2 exp( )/ exp( / ) n E E kT h kT n ν= − = 1)exp( / 12 21 1212 − − − −− kT h B B BA ν 1)/exp( /8 33 −kTh ch ν νπ 3 3 12 12 8 c h B A νπ = − − Planck’s law
  • 17. The probability of spontaneous emission A2-1 /the probability of stimulated emission B2-1 ρ(ν ): 1. Visible photons, energy: 1.6eV – 3.1eV. 2. kT at 300K ~ 0.025eV. 3. stimulated emission dominates solely when hν /kT <<1! (for microwaves: hν <0.0015eV) The frequency of emission acts to the absorption: if hν /kT <<1. 1)/exp( )(12 12 −= − − kTh B A ν νρ 1 2 1 2 12 12 211 122122 ] )( 1[ )( )( n n n n B A Bn BnAn x ≈+= + = − − − −− νρνρ νρ x~ n2 /n1
  • 18. Condition for the laser operation If n1 > n2 • radiation is mostly absorbed • spontaneous radiation dominates. • most atoms occupy level E2, weak absorption • stimulated emission prevails • light is amplified if n2 >> n1 - population inversion Necessary condition: population inversion E1 E2
  • 19. How to realize the population inversion? Thermal excitation: 2 1 exp n E n kT −∆  =  ÷   Optically, electrically. impossible. The system has to be „pumped” E1 E2
  • 20. Measurement disturbes the system The Uncertainty Principle
  • 21. The Uncertainty Principle  Classical physics  Measurement uncertainty is due to limitations of the measurement apparatus  There is no limit in principle to how accurate a measurement can be made  Quantum Mechanics  There is a fundamental limit to the accuracy of a measurement determined by the Heisenberg uncertainty principle  If a measurement of position is made with precision ∆x and a simultaneous measurement of linear momentum is made with precision ∆p, then the product of the two uncertainties can never be less than h/2π xx p∆ ∆ ≥ h
  • 22. The Uncertainty Principle Virtual particles: created due to the UP E t∆ ∆ ≥ h
  • 23. Three level laser The laser operation E1 E3 E2 Fast transition Laser action • 1→3 pumping • spontaneous emission 3 →2. • state 2 is a metastable state • population inversion between states 2 and 1. • stimulated emission between 2 i 1.
  • 24. h≥∆∆ tε E1 E3 E2 Fast transition lasing - optical pumping - occupation of E3 of a short life time, 10-8s. It is a band, the metastable and ground states are narrow : - electrons are collected on E2: population inversion - stimulated emission (one photon emitted spontaneously starts the stimulated radiation ) - Beam of photons moves normally to the mirrors – standing wave. The laser operation
  • 25. ruby laser • discovered in 60-ies of the XX century. • ruby (Al2O3) monocrystal, Cr doped.
  • 26. • Lasing from the Cr3+ . • three level laser Energy 4 A2 4 T2 4 T1 2 T2 2 E LASING • optical pumping: 510-600nm and 360- 450nm. • fast transition on 2 E. • lasing: 2 E on 4 A2, •694nm rapid decay Ruby laser Al2O3 Cr+
  • 27. Ruby laser First laser: Ted Maiman Hughes Research Labs 1960