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Laser and its applications
Prof. Dr. Taha Zaki Sokker
By
Laser and its applications
Chapter (1): Theory of Lasing (2)
Chapter (2): Characteristics of laser beam ( )
Chapter (3): Types of laser sources ( )
Chapter (4): Laser applications ( )
Contents page
Chapter (1) Theory of Lasing
1.Introduction (Brief history of laser)
The laser is perhaps the most important optical device
to be developed in the past 50 years. Since its arrival in
the 1960s, rather quiet and unheralded outside the
scientific community, it has provided the stimulus to make
optics one of the most rapidly growing fields in science
and technology today.
The laser is essentially an optical amplifier. The word
laser is an acronym that stands for “light amplification
by the stimulated emission of radiation”. The theoretical
background of laser action as the basis for an optical
amplifier was made possible by Albert Einstein, as early
as 1917, when he first predicted the existence of a new
irradiative process called “stimulated emission”. His
theoretical work, however, remained largely unexploited
until 1954, when C.H. Townes and Co-workers developed
a microwave amplifier based on stimulated emission
radiation. It was called a maser.
Following the birth of the ruby and He-Ne lasers, others devices
followed in rapid succession, each with a different laser medium
and a different wavelength emission. For the greater part of the
1960s, the laser was viewed by the world of industry and
technology as scientific curiosity.
In 1960, T.H.Maiman built the first laser device (ruby
laser). Within months of the arrival of Maiman’s ruby laser,
which emitted deep red light at a wavelength of 694.3 nm,
A. Javan and associates developed the first gas laser (He-
Ne laser), which emitted light in both the infrared (at
1.15mm) and visible (at 632.8 nm) spectral regions..
1.Einstein’s quantum theory of radiation
In 1916, according to Einstein, the interaction of
radiation with matter could be explained in terms of
three basic processes: spontaneous emission,
absorption and stimulated emission. The three
processes are illustrated and discussed in the
following:
(i) Stimulated absorption
ii) Spontaneous emission)
(iii) Stimulated emission
)ii) Spontaneous emission
Consider an atom (or molecule) of the material is existed
initially in an excited state Ε2 No external radiation is
required to initiate the emission. Since Ε2>Ε1, the atom will
tend to spontaneously decay to the ground state Ε1, a
photon of energy hν =Ε2-Ε1 is released in a random direction
as shown in (Fig. 1-ii). This process is called “spontaneous
emission”
Note that; when the release energy difference (Ε2-Ε1) is
delivered in the form of an e.m wave, the process called
"radiative emission" which is one of the two possible ways
“non-radiative” decay is occurred when the energy
difference (Ε2-Ε1) is delivered in some form other than e.m
radiation (e.g. it may transfer to kinetic energy of the
(iii) Stimulated emission
Quite by contrast “stimulated emission” (Fig. 1-iii)
requires the presence of external radiation when an
incident photon of energy hν =Ε2-Ε1 passes by an atom
in an excited state Ε2, it stimulates the atom to drop or
decay to the lower state Ε1. In this process, the atom
releases a photon of the same energy, direction, phase
and polarization as that of the photon passing by, the
net effect is two identical photons (2hν) in the place of
one, or an increase in the intensity of the incident beam.
It is precisely this processes of stimulated emission that
makes possible the amplification of light in lasers.
Growth of Laser Beam
Atoms exist most of the time in one of a number of
certain characteristic energy levels. The energy level
or energy state of an atom is a result of the energy
level of the individual electrons of that particular
atom. In any group of atoms, thermal motion or
agitation causes a constant motion of the atoms
between low and high energy levels. In the absence
of any applied electromagnetic radiation the
distribution of the atoms in their various allowed
states is governed by Boltzman’s law which states
that:
The theory of lasing
if an assemblage of atoms is in state of thermal
equilibrium at an absolute temp. Τ, the number of
atoms Ν2 in one energy level Ε2 is related to the
number Ν1 in another energy level Ε1 by the equation.
Where Ε2>Ε1 clearly Ν2<Ν1
Κ Boltzmann’s constant = 1.38x10-16
erg / degree
=1.38x10-23
j/K
Τ the absolute temp. in degrees Kelvin
KT/)1E2E(
12 eNN −−
=
At absolute zero all atoms will be in the ground
state. There is such a lack of thermal motion among the
electrons that there are no atoms in higher energy
levels. As the temperature increases atoms change
randomly from low to the height energy states and back
again. The atoms are raised to high energy states by
chance electron collision and they return to the low
energy state by their natural tendency to seek the lowest
energy level. When they return to the lower energy state
electromagnetic radiation is emitted. This is
spontaneous emission of radiation and because of its
random nature, it is incoherent
As indicated by the equation, the number of atoms
decreases as the energy level increases. As the temp
increases, more atoms will attain higher energy levels.
However, the lower energy levels will be still more
populated.
Einstein in 1917 first introduced the concept of
stimulated or induced emission of radiation by atomic
systems. He showed that in order to describe completely
the interaction of matter and radiative, it is necessary to
include that process in which an excited atom may be
induced by the presence of radiation emit a photon and
decay to lower energy state.
An atom in level Ε2 can decay to level Ε1 by emission
of photon. Let us call Α21 the transition probability per
unit time for spontaneous emission from level Ε2 to level
Ε1. Then the number of spontaneous decays per second
is Ν2Α21, i.e. the number of spontaneous decays per
second=Ν2Α21.
In addition to these spontaneous transitions, there
will induced or stimulated transitions. The total rate to
these induced transitions between level 2 and level 1 is
proportional to the density (Uν) of radiation of frequency
ν, where
ν = ( Ε2-Ε1 )/h , h Planck's const.
Let Β21 and Β12 denote the proportionality constants for
stimulated emission and absorption. Then number of
stimulated downward transition in stimulated emission
per second = Ν2 Β21 Uν
similarly , the number of stimulated upward transitions
per second = Ν1 Β12 Uν
The proportionality constants Α and Β are known as the
Einstein Α and Β coefficients. Under equilibrium
conditions we have
by solving for Uν (density of the radiation) we obtain
Uν [Ν1 Β12- Ν2 Β21 ] = Α21 Ν2
212121
212
BNBN
AN
)(U
−
=ν∴
N2 A21 + N2 B21 Uν =N1 B12 Uν
SP ST
A b






−
=∴
1
)(
2
1
21
12
21
21
N
N
B
B
B
A
U ν
KT/hKT/)EE(
1
2
ee
N
N 12 ν−−−
==






−
=ν∴
ν
1e
B
B
B
A
)(U
KT/h
21
12
21
21
According to Planck’s formula of radiation
[ ]1e
1
c
h8
)(U KT/h3
3
−
νπ
=ν ν )2)
)1)
from equations 1 and 2 we have
B12=B21 (3)
213
3
21 B
c
h8
A
νπ
=
equation 3 and 4 are Einstein’s relations.
Thus for atoms in equilibrium with thermal
radiation.
)4(
21
21
212
212
A
)(UB
AN
)(UBN
emissioneoustanspon
emissionstimulate ν
=
ν
=
from equation 2 and 4
[ ]1e
1
c
h8
h8
c
)(U
h8
c
emission.spon
emission.stim
KT/h3
3
3
3
3
3
−
νπ
νπ
=
ν
νπ
=
ν
[ ]1e
1
emission.spon
emission.stim
KT/h
−
= ν
)5(
Accordingly, the rate of induced emission is extremely
small in the visible region of the spectrum with
ordinary optical sources ( Τ≈10 3 °
K .(
Hence in such sources, most of the radiation is
emitted through spontaneous transitions. Since these
transitions occur in a random manner, ordinary sources
of visible radiation are incoherent.
On the other hand, in a laser the induced transitions
become completely dominant. One result is that the
emitted radiation is highly coherent. Another is that the
spectral intensity at the operating frequency of the laser
is much greater than the spectral intensities of ordinary
light sources.
Amplification in a Medium
Consider an optical medium through which radiation is
passing. Suppose that the medium contains atoms in various
energy levels Ε1, Ε2, Ε3,….let us fitt our attention to two levels
Ε1& Ε2 where Ε2>Ε1 we have already seen that the rate of
stimulated emission and absorption involving these two levels
are proportional to Ν2Β21&Ν1Β12 respectively. Since Β21=Β12, the
rate of stimulated downward transitions will exceed that of the
upward transitions when Ν2>Ν1,.i.e the population of the upper
state is greater than that of the lower state such a condition is
condrary to the thermal equilibrium distribution given by
Boltzmann’s low. It is termed a population inversion. If a
population inversion exist, then a light beam will increase in
intensity i.e. it will be amplified as it passes through the
medium. This is because the gain due to the induced emission
exceeds the loss due to absorption.
gives the rate of growth of the beam intensity in the
direction of propagation, an is the gain constant at
frequency ν
x
,o eII να
νν =
Quantitative Amplification of light
In order to determine quantitatively the amount of
amplification in a medium we consider a parallel beam of
light that propagate through a medium enjoying
population inversion. For a collimated beam, the spectral
energy density Uν is related to the intensity Ιν in the
frequency interval ν to ν + ∆ν by the formula.
Due to the Doppler effect and other line-broadening
effects not all the atoms in a given energy level are
effective for emission or absorption in a specified
frequency interval. Only a certain number ∆Ν1 of the Ν1
atoms at level 1 are available for absorption. Similarly of
the Ν2 atoms in level 2, the number ∆ Ν2 are available for
emission. Consequently, the rate of upward transitions is
given by:
c
IU
ν∆
=ν∆ νν
v
I
U =
1L
I
U
×
=
c
I
U =
221221 N)c/I(BNUB ∆=∆ νν
and the rate of stimulated or induced downward
transitions is given by:
Now each upward transition subtracts a quantum energy
hν from the beam. Similarly, each downward transition
adds the same amount therefore the net time rate of
change of the spectral energy density in the interval ∆ν is
given by
νν ∆−∆ν=ν∆ U)NBNB(h)U(
dt
d
112221
where (hν B∆ ΝU)= the rate of transition of quantum
energy
c
I
)NBNB(h)
c
I
(
dt
d
112221
νν
∆−∆ν=ν∆
In time dt the wave travels a distance dx = c dt i.e
dx
c
dt
1
= then
ν
ν
ν∆
∆
−
ν∆
∆ν
= IB)
NN
(
c
h
dx
dI
21
12
νν
ν
α= I
dx
dI
dx
I
dI
ν
ν
ν
α=
x.
,o eII να
νν =
in which αν is the gain constant at frequency ν it is
given by:
12
12
B)
NN
(
c
h
ν∆
∆
−
ν∆
∆ν
=αν
an approximate expression is
1212max B)NN(
c
h
−
ν∆
ν
=α ∆ν being the line
width
Doppler width
This is one of the few causes seriously affecting equally
both emission and absorption lines. Let all the atoms emit
light of the same wavelength. The effective wavelength
observed from those moving towards an observer is
diminished and for those atoms moving away it is increased
in accordance with Doppler’s principle.
When we have a moving source sending out waves
continuously it moves. The velocity of the waves is often not
changed but the wavelength and frequency as noted by
stationary observed alter.
Thus consider a source of waves moving towards an
observer with velocity v. Then since the source is moving
the waves which are between the source and the observer
will be crowded into a smaller distance than if the source
had been at rest. If the frequency is νo , then in time t the
source emit νot waves. If the frequency had been at rest
these waves would have occupied a length AB. But due to
its motion the source has caused a distance vt, hence
these νot waves are compressed into a length
where

BA
vtBAAB 
=−
vttt 
oo =λν−λνthus
o
 v
ν
=λ−λ
o
 v
ν
−λ=λ
)
v
1(
o

λν
−λ=λ
Observer
)
c
v
1(
−λ=λ
)
c
v
1(
cc
o
−
ν
=
ν
where nλ=c
)
c
v
1(
cc
o
−
ν
=
ν
)
c
v
1(o
+ν=ν
c
v
1
o
=−
ν
ν
c
v
o
o
=
ν
ν−ν
)(
c
v o
o
ν−ν
ν
=
Evaluation of Doppler half width :
According to Maxwelliam distribution of velocities, from
the kinetic theory of gasses, the probability that the
velocity will be between v and v+∆v is given by:
dve
B 2Bv−
π
So that the fraction of atoms whose their velocities lie
between v and v+ ∆v is given by the following equation
ve
B
N
)(N 2
Bv
∆
π
=
ν∆ −
where B= m = molecular weight, K=gas constant,
T=absolute temp
KT2
m
Substituting for v in the last equation from equation (1)
and since the intensity emitted will depend on the
number of atoms having the velocity in the region v and
( )vv ∆+ then, i. e.
N
)(N
)(I
ν∆
∝ν
I(ν) = const .
2)o(
2
o
2c
B
e
ν−ν
ν
−
ν = νοat
I(ν
)=I
=const
Ι) ν)= Ι max= const
There for
Ι)ν)=Ι max
2)o(
2
o
2c
B
e
ν−ν
ν
−
2
1
e
I
)2/(I 4
2
2
o
2c
B
max
o
==
δ−ν
δ
ν
−
being the half width of the spectral line it is the width atδ
2
Imax , then
4
c
B2ln
2
2
o
2
δ
ν
=
ν∆=
ν
=δ 2ln
m
kT2
c
2 o
Calculation of Doppler width:
1- Calculate the Doppler’s width for Hg198
. where
Κ=1.38x10-16
erg per degree at temp=300k and =5460Ao
solution
λ
v∆
m
KT
2ln2
c
2 oν
=
molecular weight m = const. ( atomic mass m )
const.=1.668x10-24
gm

o
m
T
.cont
K
2ln2
c
2ν
=ν∆
o
7
m
T
1017.7 ν×=ν∆ −
wave number oν
λ
1
=
=.015 cm-1ν∆
2- Calculate the half-maximum line width (Doppler width)
for He-Ne laser transition assuming a discharge
temperature of about 400K and a neon atomic mass of
20 and wavelength of 632.8nm.
(Ans., ν=1500MHz)

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Laser and its applications1

  • 1. Laser and its applications Prof. Dr. Taha Zaki Sokker By
  • 2. Laser and its applications Chapter (1): Theory of Lasing (2) Chapter (2): Characteristics of laser beam ( ) Chapter (3): Types of laser sources ( ) Chapter (4): Laser applications ( ) Contents page
  • 3. Chapter (1) Theory of Lasing 1.Introduction (Brief history of laser) The laser is perhaps the most important optical device to be developed in the past 50 years. Since its arrival in the 1960s, rather quiet and unheralded outside the scientific community, it has provided the stimulus to make optics one of the most rapidly growing fields in science and technology today.
  • 4. The laser is essentially an optical amplifier. The word laser is an acronym that stands for “light amplification by the stimulated emission of radiation”. The theoretical background of laser action as the basis for an optical amplifier was made possible by Albert Einstein, as early as 1917, when he first predicted the existence of a new irradiative process called “stimulated emission”. His theoretical work, however, remained largely unexploited until 1954, when C.H. Townes and Co-workers developed a microwave amplifier based on stimulated emission radiation. It was called a maser.
  • 5. Following the birth of the ruby and He-Ne lasers, others devices followed in rapid succession, each with a different laser medium and a different wavelength emission. For the greater part of the 1960s, the laser was viewed by the world of industry and technology as scientific curiosity. In 1960, T.H.Maiman built the first laser device (ruby laser). Within months of the arrival of Maiman’s ruby laser, which emitted deep red light at a wavelength of 694.3 nm, A. Javan and associates developed the first gas laser (He- Ne laser), which emitted light in both the infrared (at 1.15mm) and visible (at 632.8 nm) spectral regions..
  • 6. 1.Einstein’s quantum theory of radiation In 1916, according to Einstein, the interaction of radiation with matter could be explained in terms of three basic processes: spontaneous emission, absorption and stimulated emission. The three processes are illustrated and discussed in the following:
  • 7. (i) Stimulated absorption ii) Spontaneous emission) (iii) Stimulated emission
  • 8. )ii) Spontaneous emission Consider an atom (or molecule) of the material is existed initially in an excited state Ε2 No external radiation is required to initiate the emission. Since Ε2>Ε1, the atom will tend to spontaneously decay to the ground state Ε1, a photon of energy hν =Ε2-Ε1 is released in a random direction as shown in (Fig. 1-ii). This process is called “spontaneous emission” Note that; when the release energy difference (Ε2-Ε1) is delivered in the form of an e.m wave, the process called "radiative emission" which is one of the two possible ways “non-radiative” decay is occurred when the energy difference (Ε2-Ε1) is delivered in some form other than e.m radiation (e.g. it may transfer to kinetic energy of the
  • 9. (iii) Stimulated emission Quite by contrast “stimulated emission” (Fig. 1-iii) requires the presence of external radiation when an incident photon of energy hν =Ε2-Ε1 passes by an atom in an excited state Ε2, it stimulates the atom to drop or decay to the lower state Ε1. In this process, the atom releases a photon of the same energy, direction, phase and polarization as that of the photon passing by, the net effect is two identical photons (2hν) in the place of one, or an increase in the intensity of the incident beam. It is precisely this processes of stimulated emission that makes possible the amplification of light in lasers.
  • 10. Growth of Laser Beam Atoms exist most of the time in one of a number of certain characteristic energy levels. The energy level or energy state of an atom is a result of the energy level of the individual electrons of that particular atom. In any group of atoms, thermal motion or agitation causes a constant motion of the atoms between low and high energy levels. In the absence of any applied electromagnetic radiation the distribution of the atoms in their various allowed states is governed by Boltzman’s law which states that: The theory of lasing
  • 11. if an assemblage of atoms is in state of thermal equilibrium at an absolute temp. Τ, the number of atoms Ν2 in one energy level Ε2 is related to the number Ν1 in another energy level Ε1 by the equation. Where Ε2>Ε1 clearly Ν2<Ν1 Κ Boltzmann’s constant = 1.38x10-16 erg / degree =1.38x10-23 j/K Τ the absolute temp. in degrees Kelvin KT/)1E2E( 12 eNN −− =
  • 12. At absolute zero all atoms will be in the ground state. There is such a lack of thermal motion among the electrons that there are no atoms in higher energy levels. As the temperature increases atoms change randomly from low to the height energy states and back again. The atoms are raised to high energy states by chance electron collision and they return to the low energy state by their natural tendency to seek the lowest energy level. When they return to the lower energy state electromagnetic radiation is emitted. This is spontaneous emission of radiation and because of its random nature, it is incoherent
  • 13. As indicated by the equation, the number of atoms decreases as the energy level increases. As the temp increases, more atoms will attain higher energy levels. However, the lower energy levels will be still more populated. Einstein in 1917 first introduced the concept of stimulated or induced emission of radiation by atomic systems. He showed that in order to describe completely the interaction of matter and radiative, it is necessary to include that process in which an excited atom may be induced by the presence of radiation emit a photon and decay to lower energy state.
  • 14. An atom in level Ε2 can decay to level Ε1 by emission of photon. Let us call Α21 the transition probability per unit time for spontaneous emission from level Ε2 to level Ε1. Then the number of spontaneous decays per second is Ν2Α21, i.e. the number of spontaneous decays per second=Ν2Α21. In addition to these spontaneous transitions, there will induced or stimulated transitions. The total rate to these induced transitions between level 2 and level 1 is proportional to the density (Uν) of radiation of frequency ν, where ν = ( Ε2-Ε1 )/h , h Planck's const.
  • 15. Let Β21 and Β12 denote the proportionality constants for stimulated emission and absorption. Then number of stimulated downward transition in stimulated emission per second = Ν2 Β21 Uν similarly , the number of stimulated upward transitions per second = Ν1 Β12 Uν The proportionality constants Α and Β are known as the Einstein Α and Β coefficients. Under equilibrium conditions we have
  • 16. by solving for Uν (density of the radiation) we obtain Uν [Ν1 Β12- Ν2 Β21 ] = Α21 Ν2 212121 212 BNBN AN )(U − =ν∴ N2 A21 + N2 B21 Uν =N1 B12 Uν SP ST A b
  • 17.       − =∴ 1 )( 2 1 21 12 21 21 N N B B B A U ν KT/hKT/)EE( 1 2 ee N N 12 ν−−− ==       − =ν∴ ν 1e B B B A )(U KT/h 21 12 21 21 According to Planck’s formula of radiation [ ]1e 1 c h8 )(U KT/h3 3 − νπ =ν ν )2) )1)
  • 18. from equations 1 and 2 we have B12=B21 (3) 213 3 21 B c h8 A νπ = equation 3 and 4 are Einstein’s relations. Thus for atoms in equilibrium with thermal radiation. )4( 21 21 212 212 A )(UB AN )(UBN emissioneoustanspon emissionstimulate ν = ν = from equation 2 and 4
  • 19. [ ]1e 1 c h8 h8 c )(U h8 c emission.spon emission.stim KT/h3 3 3 3 3 3 − νπ νπ = ν νπ = ν [ ]1e 1 emission.spon emission.stim KT/h − = ν )5( Accordingly, the rate of induced emission is extremely small in the visible region of the spectrum with ordinary optical sources ( Τ≈10 3 ° K .(
  • 20. Hence in such sources, most of the radiation is emitted through spontaneous transitions. Since these transitions occur in a random manner, ordinary sources of visible radiation are incoherent. On the other hand, in a laser the induced transitions become completely dominant. One result is that the emitted radiation is highly coherent. Another is that the spectral intensity at the operating frequency of the laser is much greater than the spectral intensities of ordinary light sources.
  • 21. Amplification in a Medium Consider an optical medium through which radiation is passing. Suppose that the medium contains atoms in various energy levels Ε1, Ε2, Ε3,….let us fitt our attention to two levels Ε1& Ε2 where Ε2>Ε1 we have already seen that the rate of stimulated emission and absorption involving these two levels are proportional to Ν2Β21&Ν1Β12 respectively. Since Β21=Β12, the rate of stimulated downward transitions will exceed that of the upward transitions when Ν2>Ν1,.i.e the population of the upper state is greater than that of the lower state such a condition is condrary to the thermal equilibrium distribution given by Boltzmann’s low. It is termed a population inversion. If a population inversion exist, then a light beam will increase in intensity i.e. it will be amplified as it passes through the medium. This is because the gain due to the induced emission exceeds the loss due to absorption.
  • 22. gives the rate of growth of the beam intensity in the direction of propagation, an is the gain constant at frequency ν x ,o eII να νν =
  • 23. Quantitative Amplification of light In order to determine quantitatively the amount of amplification in a medium we consider a parallel beam of light that propagate through a medium enjoying population inversion. For a collimated beam, the spectral energy density Uν is related to the intensity Ιν in the frequency interval ν to ν + ∆ν by the formula.
  • 24. Due to the Doppler effect and other line-broadening effects not all the atoms in a given energy level are effective for emission or absorption in a specified frequency interval. Only a certain number ∆Ν1 of the Ν1 atoms at level 1 are available for absorption. Similarly of the Ν2 atoms in level 2, the number ∆ Ν2 are available for emission. Consequently, the rate of upward transitions is given by: c IU ν∆ =ν∆ νν v I U = 1L I U × = c I U =
  • 25. 221221 N)c/I(BNUB ∆=∆ νν and the rate of stimulated or induced downward transitions is given by: Now each upward transition subtracts a quantum energy hν from the beam. Similarly, each downward transition adds the same amount therefore the net time rate of change of the spectral energy density in the interval ∆ν is given by νν ∆−∆ν=ν∆ U)NBNB(h)U( dt d 112221 where (hν B∆ ΝU)= the rate of transition of quantum energy c I )NBNB(h) c I ( dt d 112221 νν ∆−∆ν=ν∆
  • 26. In time dt the wave travels a distance dx = c dt i.e dx c dt 1 = then ν ν ν∆ ∆ − ν∆ ∆ν = IB) NN ( c h dx dI 21 12 νν ν α= I dx dI dx I dI ν ν ν α= x. ,o eII να νν =
  • 27. in which αν is the gain constant at frequency ν it is given by: 12 12 B) NN ( c h ν∆ ∆ − ν∆ ∆ν =αν an approximate expression is 1212max B)NN( c h − ν∆ ν =α ∆ν being the line width
  • 28. Doppler width This is one of the few causes seriously affecting equally both emission and absorption lines. Let all the atoms emit light of the same wavelength. The effective wavelength observed from those moving towards an observer is diminished and for those atoms moving away it is increased in accordance with Doppler’s principle. When we have a moving source sending out waves continuously it moves. The velocity of the waves is often not changed but the wavelength and frequency as noted by stationary observed alter.
  • 29. Thus consider a source of waves moving towards an observer with velocity v. Then since the source is moving the waves which are between the source and the observer will be crowded into a smaller distance than if the source had been at rest. If the frequency is νo , then in time t the source emit νot waves. If the frequency had been at rest these waves would have occupied a length AB. But due to its motion the source has caused a distance vt, hence these νot waves are compressed into a length where BA
  • 30. vtBAAB =− vttt oo =λν−λνthus o v ν =λ−λ o v ν −λ=λ ) v 1( o λν −λ=λ Observer ) c v 1( −λ=λ ) c v 1( cc o − ν = ν where nλ=c
  • 32. Evaluation of Doppler half width : According to Maxwelliam distribution of velocities, from the kinetic theory of gasses, the probability that the velocity will be between v and v+∆v is given by: dve B 2Bv− π So that the fraction of atoms whose their velocities lie between v and v+ ∆v is given by the following equation ve B N )(N 2 Bv ∆ π = ν∆ − where B= m = molecular weight, K=gas constant, T=absolute temp KT2 m
  • 33. Substituting for v in the last equation from equation (1) and since the intensity emitted will depend on the number of atoms having the velocity in the region v and ( )vv ∆+ then, i. e. N )(N )(I ν∆ ∝ν I(ν) = const . 2)o( 2 o 2c B e ν−ν ν − ν = νοat I(ν )=I =const Ι) ν)= Ι max= const
  • 34. There for Ι)ν)=Ι max 2)o( 2 o 2c B e ν−ν ν − 2 1 e I )2/(I 4 2 2 o 2c B max o == δ−ν δ ν − being the half width of the spectral line it is the width atδ 2 Imax , then 4 c B2ln 2 2 o 2 δ ν = ν∆= ν =δ 2ln m kT2 c 2 o
  • 35. Calculation of Doppler width: 1- Calculate the Doppler’s width for Hg198 . where Κ=1.38x10-16 erg per degree at temp=300k and =5460Ao solution λ v∆ m KT 2ln2 c 2 oν = molecular weight m = const. ( atomic mass m ) const.=1.668x10-24 gm o m T .cont K 2ln2 c 2ν =ν∆ o 7 m T 1017.7 ν×=ν∆ − wave number oν λ 1 = =.015 cm-1ν∆
  • 36. 2- Calculate the half-maximum line width (Doppler width) for He-Ne laser transition assuming a discharge temperature of about 400K and a neon atomic mass of 20 and wavelength of 632.8nm. (Ans., ν=1500MHz)