IHD = 1 Therefore there can be only 1 -bond or ring. The two signals.pdf

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IHD = 1 Therefore there can be only 1 -bond or ring. The two signals composed of singlets means all the hydrogens are isolated from one another, but there are two types in the molecule giving differing chemical shifts. The structure must be symmetrical. Likely compound is 2,2- dimethylpropanal (three methyl groups contributing one signal, and one aldehyde hydrogen contributing another signal. All non-equivalent hydrogens are too far apart to split the signal, resulting in singlets) Solution IHD = 1 Therefore there can be only 1 -bond or ring. The two signals composed of singlets means all the hydrogens are isolated from one another, but there are two types in the molecule giving differing chemical shifts. The structure must be symmetrical. Likely compound is 2,2- dimethylpropanal (three methyl groups contributing one signal, and one aldehyde hydrogen contributing another signal. All non-equivalent hydrogens are too far apart to split the signal, resulting in singlets).

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What does absense of MHC Class I indicate? Almost all nucleated cells will have MHC Class I molecules on their surface and their main role is to present foreign protein to cytotoxic T cells (Tc Cells) so that the cells which got infected can be cleared by these Tc cells. But in some cases, it has been observed that some tumor cells will escape killing or elimination by Tc cells by becoming MHC Class I negative, here they will not express MHC Class I molecules on their surface and thus there will not be any expression of tumor antigens to Tc cells and these will survive and will go on producing new cells and form the tumor. Like this MHC class I negative cells present within the primary tumor will develop into unnoticed micrometastases and will have an immunological equilibrium and succeeds in surviving in a dormant stage for long periods of time What does the presentation of tyrosinase indicate? The tyrosinase will cleave the tumor proteins and will express the melanoma antigens on the cell surface as peptides and overexpression of these antigens in tumor cells will result in an abnormally high density of specific peptide:MHC complexes on the cell surface making them immunogenic and provides them tolerance and is seen as tumor rejection in most of the cases. What dos decreased CTL infiltratioin indicate? It is the CD8+ cytotoxic T lymphocytes (CTLs) which will reject the tumor by infiltrating the solid tumors by recognizing the tumor antigens, and will kill those tumor cells. And to do this CTLs will try to infiltrate tumors in depth and it is done only when tumor cells express the cognate CTL antigen. If the tumor will not express the cognate antigen, CTL infiltration will not occur and the tumor cells cannot be killed and so the expression of tumor antigen on the cells will attract CTL infiltration, at the same time when the tumor antigens are not presented on these cells, it will decrease the CTL infiltration. Solution What does absense of MHC Class I indicate? Almost all nucleated cells will have MHC Class I molecules on their surface and their main role is to present foreign protein to cytotoxic T cells (Tc Cells) so that the cells which got infected can be cleared by these Tc cells. But in some cases, it has been observed that some tumor cells will escape killing or elimination by Tc cells by becoming MHC Class I negative, here they will not express MHC Class I molecules on their surface and thus there will not be any expression of tumor antigens to Tc cells and these will survive and will go on producing new cells and form the tumor. Like this MHC class I negative cells present within the primary tumor will develop into unnoticed micrometastases and will have an immunological equilibrium and succeeds in surviving in a dormant stage for long periods of time What does the presentation of tyrosinase indicate? The tyrosinase will cleave the tumor proteins and will express the melanoma antigens on the cell surface as peptides and overexpres.

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1. IHD = 1 Therefore there can be only 1 -bond or ring. The two signals composed of singlets means all the hydrogens are isolated from one another, but there are two types in the molecule giving differing chemical shifts. The structure must be symmetrical. Likely compound is 2,2- dimethylpropanal (three methyl groups contributing one signal, and one aldehyde hydrogen contributing another signal. All non-equivalent hydrogens are too far apart to split the signal, resulting in singlets) Solution IHD = 1 Therefore there can be only 1 -bond or ring. The two signals composed of singlets means all the hydrogens are isolated from one another, but there are two types in the molecule giving differing chemical shifts. The structure must be symmetrical. Likely compound is 2,2- dimethylpropanal (three methyl groups contributing one signal, and one aldehyde hydrogen contributing another signal. All non-equivalent hydrogens are too far apart to split the signal, resulting in singlets)

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