Mechanical and chemical weathering break down rocks into smaller pieces. Mechanical weathering causes physical disintegration through processes like frost wedging, plant roots, and temperature changes without altering the rock's chemical composition. Chemical weathering alters rocks through chemical reactions with water, oxygen, carbon dioxide, and acids. Water is the main agent of chemical weathering, dissolving minerals and rocks through hydrolysis and hydration. Carbon dioxide forms carbonic acid, which breaks down minerals like limestone. Oxidation also contributes to chemical weathering.