This document provides an overview of phosphate processing for fertilizer and animal feed production. It discusses the key steps which include mining and beneficiation of phosphate rock, drying it in rotary dryers, processing it into phosphoric acid, and then granulating the acid with other materials using equipment like rotary granulators, pug mills, dryers and coolers to produce products like MAP, DAP, MCP and DCP. It also highlights FEECO's approach using a high speed mixer to improve the quality of animal feed granulation.
This is a precise presentation on NPK fertilizers or complex fertilizers. It has detailed flowsheets with descriptions about all manufacturing processes of NPK fertilizers as well
This document discusses ammonia production including the Haber process, key steps in production, plant design software, and modeling and simulation. The main points are:
- Ammonia is produced from nitrogen and hydrogen using the Haber process under high temperature, pressure, and with a catalyst.
- The main steps in production are preparing PFDs and BFDs, plant designing, and modeling and simulation.
- Common software used for plant design include Smart 3D, PDMS, PDS, and AutoCAD plant-3D. Aspen HYSYS is used to accurately model and simulate ammonia production processes.
In the plant, ammonia is produced from synthesis gas containing hydrogen and nitrogen in the ratio of approximately 3:1. Besides these components, the synthesis gas contains inert gases such as argon and methane to a limited extent. The source of H2 is demineralized water and the hydrocarbons in the natural gas. The source of N2 is the atmospheric air. The source of CO2 is the hydrocarbons in the natural gas feed. Product ammonia and CO2 is sent to urea plant. The present article intended the description of ammonia plant for natural gas based plants and the possible material balance of some section.
Most modern ammonia processes are based on steam-reforming of natural gas or naphtha.
The 3 main technology suppliers are Uhde (Uhde/JM Partnership), Topsoe & KBR.
The process steps are very similar in all cases.
Other suppliers are Linde (LAC) & Ammonia Casale.
This document discusses near infrared reflectance spectroscopy (NIRS) and its principles. NIRS is a nondestructive technique used to evaluate food quality by determining components like protein, moisture, starch and lipids. It works by measuring the absorption of near infrared light as it interacts with molecular bonds in organic materials. Different bonds like C=H, C=O and N=H absorb different wavelengths. The absorbed energy is detected to create a spectral profile that can be analyzed using chemometrics to quantify various chemical components through calibration.
The document discusses various technologies for producing hydrogen and synthesis gas, including steam reforming, partial oxidation, coal gasification, and water electrolysis. It provides an overview of the main industrial processes used for ammonia synthesis gas production, noting that about 85% is based on steam reforming of natural gas or other light hydrocarbons. Various hydrogen and syngas production processes are also compared in terms of energy consumption, investment cost, and production cost.
This document provides details on the urea granulation process. It describes the characteristics of granular urea including composition requirements. It outlines the granulation process which involves spraying liquid urea solution onto seed material in a fluidized bed. Key equipment involved includes the granulator, fluid bed coolers, screens, and conveying equipment. Startup and operating procedures are also summarized, focusing on gradually heating and preparing the granulator while maintaining proper process conditions.
This is a precise presentation on NPK fertilizers or complex fertilizers. It has detailed flowsheets with descriptions about all manufacturing processes of NPK fertilizers as well
This document discusses ammonia production including the Haber process, key steps in production, plant design software, and modeling and simulation. The main points are:
- Ammonia is produced from nitrogen and hydrogen using the Haber process under high temperature, pressure, and with a catalyst.
- The main steps in production are preparing PFDs and BFDs, plant designing, and modeling and simulation.
- Common software used for plant design include Smart 3D, PDMS, PDS, and AutoCAD plant-3D. Aspen HYSYS is used to accurately model and simulate ammonia production processes.
In the plant, ammonia is produced from synthesis gas containing hydrogen and nitrogen in the ratio of approximately 3:1. Besides these components, the synthesis gas contains inert gases such as argon and methane to a limited extent. The source of H2 is demineralized water and the hydrocarbons in the natural gas. The source of N2 is the atmospheric air. The source of CO2 is the hydrocarbons in the natural gas feed. Product ammonia and CO2 is sent to urea plant. The present article intended the description of ammonia plant for natural gas based plants and the possible material balance of some section.
Most modern ammonia processes are based on steam-reforming of natural gas or naphtha.
The 3 main technology suppliers are Uhde (Uhde/JM Partnership), Topsoe & KBR.
The process steps are very similar in all cases.
Other suppliers are Linde (LAC) & Ammonia Casale.
This document discusses near infrared reflectance spectroscopy (NIRS) and its principles. NIRS is a nondestructive technique used to evaluate food quality by determining components like protein, moisture, starch and lipids. It works by measuring the absorption of near infrared light as it interacts with molecular bonds in organic materials. Different bonds like C=H, C=O and N=H absorb different wavelengths. The absorbed energy is detected to create a spectral profile that can be analyzed using chemometrics to quantify various chemical components through calibration.
The document discusses various technologies for producing hydrogen and synthesis gas, including steam reforming, partial oxidation, coal gasification, and water electrolysis. It provides an overview of the main industrial processes used for ammonia synthesis gas production, noting that about 85% is based on steam reforming of natural gas or other light hydrocarbons. Various hydrogen and syngas production processes are also compared in terms of energy consumption, investment cost, and production cost.
This document provides details on the urea granulation process. It describes the characteristics of granular urea including composition requirements. It outlines the granulation process which involves spraying liquid urea solution onto seed material in a fluidized bed. Key equipment involved includes the granulator, fluid bed coolers, screens, and conveying equipment. Startup and operating procedures are also summarized, focusing on gradually heating and preparing the granulator while maintaining proper process conditions.
This document summarizes a new process for converting coal to ammonia using Kellogg Brown & Root's (KBR) Transport Reactor Integrated Gasifier (TRIG) technology. The process involves:
1. Gasifying coal using KBR's TRIG technology to produce syngas. The syngas is then purified through steps like acid gas removal.
2. Compressing the purified syngas and feeding it into an ammonia synthesis loop to produce ammonia using a conventional KBR ammonia process.
3. Recovering the ammonia produced and refrigerating it for storage or transport.
The paper provides details on the major unit operations in the coal gasification and ammonia
This document summarizes different processes for removing carbon dioxide from ammonia plant streams. It discusses why CO2 removal is important, and describes common processes like MEA and MDEA absorption. The Benfield process uses hot potassium carbonate solution promoted by diethanolamine to physically absorb CO2. Issues with the Benfield process include foaming, corrosion, and vanadation problems. Retrofitting with a new amine promoter called LRS 10 can improve CO2 removal efficiency and reduce energy costs for the Benfield process.
Manufacture of manufacturing of single superphosphate and triple superphospah...MuhammadAyyanKhan
Triple superphosphate (TSP) is produced through a two-stage process of reacting sulfuric acid with phosphate rock to produce phosphoric acid, and then reacting the phosphoric acid with more phosphate rock. This results in granular TSP which contains 47% P2O5. TSP has excellent physical properties for storage and application to fields, and is commonly used in blended fertilizers due to its affordable phosphorus content. It also has some non-agricultural uses as a leavening agent and mineral supplement.
Urea Dust & Ammonia Emission Control Prill Tower Project at Al BayroniAli Akbar
This document summarizes a presentation given about a project to control urea dust and ammonia emissions from a prilling tower at an urea plant in Saudi Arabia. The project involved installing an air cleaning unit with acid wash scrubbers to absorb urea dust and ammonia from the exit air stream. The absorbed materials were then sent to a crystallization unit to produce ammonium sulfate as the final product. The project successfully reduced urea dust and ammonia emissions below international standards and produced a new fertilizer product. It provided lessons learned for other plants seeking to control emissions from prilling towers.
Phosphate rock is ground and reacted with sulfuric acid in a reactor to produce phosphoric acid and a gypsum byproduct, with the phosphoric acid then concentrated through evaporation to the desired strength. The wet process using sulfuric acid is the most common method for producing fertilizer-grade phosphoric acid on an industrial scale, with the phosphate rock and sulfuric acid reacting at high temperatures and pressures to extract over 98% of the phosphoric acid. The resulting slurry of phosphoric acid and gypsum is then filtered and the phosphoric acid concentrated through evaporation for use or further processing.
The document summarizes the ball mill, which is a grinder used to grind and blend materials. It discusses the basic parts of a ball mill including the hollow cylinder and balls. It then explains the principle of operation through impact and attrition. The document also covers the theory behind maintaining critical speed for optimum efficiency. Additionally, it describes the working process, how to improve efficiency, merits and demerits, applications, and concludes that ball mills are widely used in pharmaceutical industries for grinding processes.
Single superphosphate (SSP) is a commercially important fertilizer produced by thoroughly mixing finely ground phosphate rock with concentrated sulfuric acid. This reaction produces calcium dihydrogen phosphate (CaH4(PO4)2), calcium sulfate (CaSO4), water (H2O), hydrofluoric acid (HF), and silicon tetrafluoride (SiF4). The quality of the SSP product depends on the grade of phosphate rock used. Finely grinding the rock increases the reaction rate and allows for use of less sulfuric acid. The fresh mixture is then cured for one hour before being cut into thin slices for use as fertilizer.
POWER PLANT CHEMISTRY( WATER TREATMENT FOR BOILERS)Dilip Kumar
This document discusses the treatment of water for high pressure boilers and steam-water quality parameters. It describes the various processes involved - intake of raw water from rivers, aeration, addition of chemicals for coagulation and disinfection, clarification, filtration, and demineralization. It then discusses water treatment for boilers, including dosing of chemicals to prevent corrosion. Various sampling points and parameters for treated water and steam are listed. Finally, it briefly covers generator chemistry, including cooling of stator and rotor, hydrogen purity requirements, and primary water system treatment.
This presentation looks at the choice between a rotary drum agglomerator and a disc pelletizer, when looking for an effective agglomeration solution. The advantages of each piece of equipment are discussed for a variety of considerations.
A heat exchanger is a device that transfers heat between two or more fluids. There are several types of heat exchangers, including parallel-flow, counter-flow, cross-flow, double pipe, shell and tube, plate, and spiral. Heat exchangers are widely used in applications like heating, cooling, chemical processes, and power generation to efficiently exchange heat between fluids. Proper selection and maintenance of heat exchangers depends on factors such as temperature ranges, pressure, materials, fouling potential, and cleanability.
The document discusses the Hardgrove Grindability Index (HGI) test method for determining the grindability of coal. It describes how the HGI test works, factors that influence grindability values, and the effects of coal blending on HGI values. Experimentally determined HGI values for coal blends sometimes differed from calculated weighted average values, with the difference generally within ±2 HGI units. The optimal coal blends for different applications can be identified based on considering both HGI values and other coal properties.
This document provides information about urea. Urea has a molecular formula of NH2CONH2, molecular weight of 60, and decomposes at its boiling point of 1320°C. It is fairly soluble in water and is primarily used as solid and liquid fertilizer. Urea is also used in animal feed, formaldehyde resins, and adhesives. The largest production method for urea is the ammonium carbamate decomposition method, which involves compressing ammonia and carbon dioxide at high pressure and temperature to form ammonium carbamate, then dehydrating it to form urea. The conversion of ammonium carbamate to urea increases with temperature and pressure.
In this article includes many studies and investigation reporting on the effect of various parameters to the prills quality like crushing strength, size distribution, abrasion and impact resistance, humidity factors urea moisture absorption, vacuum studies etc. The Nitrogen, moisture, Prill strength &Biuret contents and the size distribution of prilled urea are important factors of determining urea quality. High temperature of prilled product is a common in most of urea plant in India. In some plants in India the temperature of prills as high 80oC in hot summer days at high load. Our plant temperature of prills is also 65-700C.This result in poor strength dust formation, increase in caking tendency. Granulated urea has definite advantage over prilled urea but expensive to produce till recently. We have installed BFC for line-1 & 2.A modification also done in Urea line –I plant in month of March 2018 to solve foaming problem in waste water section (distillation tower) and this modification proven and beneficial.
This document summarizes the key components and design of ammonia synthesis converters. It describes the main parts of the converter including the pressure shell, basket for catalyst, and heat exchangers. It then discusses the two main types of converters - axial and radial flow. The document focuses on the Haldor Topsoe radial flow converter, describing its types and available versions. It provides details on design considerations for the pressure shell, catalyst basket, and material selection. The goals are to resist hydrogen attack, nitriding, and hydrogen induced cracking at high temperatures and pressures during ammonia synthesis.
This document provides steps for starting up a urea production plant using the Saipem process. It describes conducting sealing tests, purging sections with nitrogen, heating equipment, charging ammonia, and feeding ammonia and carbon dioxide into the reactor while monitoring pressures and temperatures. The goal is to reach stable operating conditions for urea production. Diagrams are included to illustrate the reactor, separators, decomposers, and other key equipment involved in the startup process.
Phosphates are a critical component in many animal feed products. This presentation looks at the production of Monocalcium Phosphate (MCP) and Dicalcium Phosphate (DCP), including the improved processing method of adding a high speed mixer.
The document summarizes the process for producing ammonia from natural gas and/or naphtha. Key steps include:
1) Desulphurization of the hydrocarbon feedstock using hydrogenation and ZnO absorption to remove sulfur.
2) Reforming the desulphurized feedstock with steam and air at high pressure and temperature in multiple reactors to produce synthesis gas containing hydrogen, nitrogen, carbon dioxide and carbon monoxide.
3) Purifying the synthesis gas through shift conversion and CO2/CO removal to increase hydrogen yield before sending the gas to the ammonia synthesis loop.
The document describes the modified Claus process for sulfur recovery. It discusses the basic Claus reaction and how the modified process improved on it with a free flame oxidation ahead of the catalyst bed and catalytic step revisions, allowing for higher sulfur recovery efficiencies of 90-99.9%. The key steps of the modified Claus process are presented as the combustion step and multiple catalytic steps. Process variations like the straight-through and split-flow configurations are described along with tail gas handling and other sulfur removal processes. Sample calculations are provided to determine the optimum operating parameters for a 80 long ton per day sulfur recovery unit using the modified Claus process.
Determination of Residue and Oil in Anhydrous AmmoniaGerard B. Hawkins
Plant Analytical Techniques
Determination of Residue and Oil in Anhydrous Ammonia
This method is suitable for the determination of residue and oil in anhydrous ammonia.
FIELD OF APPLICATION
This method may be applied to standard and premium grade anhydrous ammonia having residue content in the range 10-5000 micrograms per gram and oil content in the range l-500 micrograms per gram
This presentation looks at the processes used to transform phosphate rock into Monoammonium Phosphate (MAP) and Diammonium Phosphate (DAP) fertilizers.
Phosphates can present a number of challenges to processors. From its abrasive nature, to the variance throughout the phosphate rock deposit, phosphate processors need to be prepared for the issues they may face. This presentation looks at many of the problems that can come up when processing phosphates, as well as how to combat those issues.
This document summarizes a new process for converting coal to ammonia using Kellogg Brown & Root's (KBR) Transport Reactor Integrated Gasifier (TRIG) technology. The process involves:
1. Gasifying coal using KBR's TRIG technology to produce syngas. The syngas is then purified through steps like acid gas removal.
2. Compressing the purified syngas and feeding it into an ammonia synthesis loop to produce ammonia using a conventional KBR ammonia process.
3. Recovering the ammonia produced and refrigerating it for storage or transport.
The paper provides details on the major unit operations in the coal gasification and ammonia
This document summarizes different processes for removing carbon dioxide from ammonia plant streams. It discusses why CO2 removal is important, and describes common processes like MEA and MDEA absorption. The Benfield process uses hot potassium carbonate solution promoted by diethanolamine to physically absorb CO2. Issues with the Benfield process include foaming, corrosion, and vanadation problems. Retrofitting with a new amine promoter called LRS 10 can improve CO2 removal efficiency and reduce energy costs for the Benfield process.
Manufacture of manufacturing of single superphosphate and triple superphospah...MuhammadAyyanKhan
Triple superphosphate (TSP) is produced through a two-stage process of reacting sulfuric acid with phosphate rock to produce phosphoric acid, and then reacting the phosphoric acid with more phosphate rock. This results in granular TSP which contains 47% P2O5. TSP has excellent physical properties for storage and application to fields, and is commonly used in blended fertilizers due to its affordable phosphorus content. It also has some non-agricultural uses as a leavening agent and mineral supplement.
Urea Dust & Ammonia Emission Control Prill Tower Project at Al BayroniAli Akbar
This document summarizes a presentation given about a project to control urea dust and ammonia emissions from a prilling tower at an urea plant in Saudi Arabia. The project involved installing an air cleaning unit with acid wash scrubbers to absorb urea dust and ammonia from the exit air stream. The absorbed materials were then sent to a crystallization unit to produce ammonium sulfate as the final product. The project successfully reduced urea dust and ammonia emissions below international standards and produced a new fertilizer product. It provided lessons learned for other plants seeking to control emissions from prilling towers.
Phosphate rock is ground and reacted with sulfuric acid in a reactor to produce phosphoric acid and a gypsum byproduct, with the phosphoric acid then concentrated through evaporation to the desired strength. The wet process using sulfuric acid is the most common method for producing fertilizer-grade phosphoric acid on an industrial scale, with the phosphate rock and sulfuric acid reacting at high temperatures and pressures to extract over 98% of the phosphoric acid. The resulting slurry of phosphoric acid and gypsum is then filtered and the phosphoric acid concentrated through evaporation for use or further processing.
The document summarizes the ball mill, which is a grinder used to grind and blend materials. It discusses the basic parts of a ball mill including the hollow cylinder and balls. It then explains the principle of operation through impact and attrition. The document also covers the theory behind maintaining critical speed for optimum efficiency. Additionally, it describes the working process, how to improve efficiency, merits and demerits, applications, and concludes that ball mills are widely used in pharmaceutical industries for grinding processes.
Single superphosphate (SSP) is a commercially important fertilizer produced by thoroughly mixing finely ground phosphate rock with concentrated sulfuric acid. This reaction produces calcium dihydrogen phosphate (CaH4(PO4)2), calcium sulfate (CaSO4), water (H2O), hydrofluoric acid (HF), and silicon tetrafluoride (SiF4). The quality of the SSP product depends on the grade of phosphate rock used. Finely grinding the rock increases the reaction rate and allows for use of less sulfuric acid. The fresh mixture is then cured for one hour before being cut into thin slices for use as fertilizer.
POWER PLANT CHEMISTRY( WATER TREATMENT FOR BOILERS)Dilip Kumar
This document discusses the treatment of water for high pressure boilers and steam-water quality parameters. It describes the various processes involved - intake of raw water from rivers, aeration, addition of chemicals for coagulation and disinfection, clarification, filtration, and demineralization. It then discusses water treatment for boilers, including dosing of chemicals to prevent corrosion. Various sampling points and parameters for treated water and steam are listed. Finally, it briefly covers generator chemistry, including cooling of stator and rotor, hydrogen purity requirements, and primary water system treatment.
This presentation looks at the choice between a rotary drum agglomerator and a disc pelletizer, when looking for an effective agglomeration solution. The advantages of each piece of equipment are discussed for a variety of considerations.
A heat exchanger is a device that transfers heat between two or more fluids. There are several types of heat exchangers, including parallel-flow, counter-flow, cross-flow, double pipe, shell and tube, plate, and spiral. Heat exchangers are widely used in applications like heating, cooling, chemical processes, and power generation to efficiently exchange heat between fluids. Proper selection and maintenance of heat exchangers depends on factors such as temperature ranges, pressure, materials, fouling potential, and cleanability.
The document discusses the Hardgrove Grindability Index (HGI) test method for determining the grindability of coal. It describes how the HGI test works, factors that influence grindability values, and the effects of coal blending on HGI values. Experimentally determined HGI values for coal blends sometimes differed from calculated weighted average values, with the difference generally within ±2 HGI units. The optimal coal blends for different applications can be identified based on considering both HGI values and other coal properties.
This document provides information about urea. Urea has a molecular formula of NH2CONH2, molecular weight of 60, and decomposes at its boiling point of 1320°C. It is fairly soluble in water and is primarily used as solid and liquid fertilizer. Urea is also used in animal feed, formaldehyde resins, and adhesives. The largest production method for urea is the ammonium carbamate decomposition method, which involves compressing ammonia and carbon dioxide at high pressure and temperature to form ammonium carbamate, then dehydrating it to form urea. The conversion of ammonium carbamate to urea increases with temperature and pressure.
In this article includes many studies and investigation reporting on the effect of various parameters to the prills quality like crushing strength, size distribution, abrasion and impact resistance, humidity factors urea moisture absorption, vacuum studies etc. The Nitrogen, moisture, Prill strength &Biuret contents and the size distribution of prilled urea are important factors of determining urea quality. High temperature of prilled product is a common in most of urea plant in India. In some plants in India the temperature of prills as high 80oC in hot summer days at high load. Our plant temperature of prills is also 65-700C.This result in poor strength dust formation, increase in caking tendency. Granulated urea has definite advantage over prilled urea but expensive to produce till recently. We have installed BFC for line-1 & 2.A modification also done in Urea line –I plant in month of March 2018 to solve foaming problem in waste water section (distillation tower) and this modification proven and beneficial.
This document summarizes the key components and design of ammonia synthesis converters. It describes the main parts of the converter including the pressure shell, basket for catalyst, and heat exchangers. It then discusses the two main types of converters - axial and radial flow. The document focuses on the Haldor Topsoe radial flow converter, describing its types and available versions. It provides details on design considerations for the pressure shell, catalyst basket, and material selection. The goals are to resist hydrogen attack, nitriding, and hydrogen induced cracking at high temperatures and pressures during ammonia synthesis.
This document provides steps for starting up a urea production plant using the Saipem process. It describes conducting sealing tests, purging sections with nitrogen, heating equipment, charging ammonia, and feeding ammonia and carbon dioxide into the reactor while monitoring pressures and temperatures. The goal is to reach stable operating conditions for urea production. Diagrams are included to illustrate the reactor, separators, decomposers, and other key equipment involved in the startup process.
Phosphates are a critical component in many animal feed products. This presentation looks at the production of Monocalcium Phosphate (MCP) and Dicalcium Phosphate (DCP), including the improved processing method of adding a high speed mixer.
The document summarizes the process for producing ammonia from natural gas and/or naphtha. Key steps include:
1) Desulphurization of the hydrocarbon feedstock using hydrogenation and ZnO absorption to remove sulfur.
2) Reforming the desulphurized feedstock with steam and air at high pressure and temperature in multiple reactors to produce synthesis gas containing hydrogen, nitrogen, carbon dioxide and carbon monoxide.
3) Purifying the synthesis gas through shift conversion and CO2/CO removal to increase hydrogen yield before sending the gas to the ammonia synthesis loop.
The document describes the modified Claus process for sulfur recovery. It discusses the basic Claus reaction and how the modified process improved on it with a free flame oxidation ahead of the catalyst bed and catalytic step revisions, allowing for higher sulfur recovery efficiencies of 90-99.9%. The key steps of the modified Claus process are presented as the combustion step and multiple catalytic steps. Process variations like the straight-through and split-flow configurations are described along with tail gas handling and other sulfur removal processes. Sample calculations are provided to determine the optimum operating parameters for a 80 long ton per day sulfur recovery unit using the modified Claus process.
Determination of Residue and Oil in Anhydrous AmmoniaGerard B. Hawkins
Plant Analytical Techniques
Determination of Residue and Oil in Anhydrous Ammonia
This method is suitable for the determination of residue and oil in anhydrous ammonia.
FIELD OF APPLICATION
This method may be applied to standard and premium grade anhydrous ammonia having residue content in the range 10-5000 micrograms per gram and oil content in the range l-500 micrograms per gram
This presentation looks at the processes used to transform phosphate rock into Monoammonium Phosphate (MAP) and Diammonium Phosphate (DAP) fertilizers.
Phosphates can present a number of challenges to processors. From its abrasive nature, to the variance throughout the phosphate rock deposit, phosphate processors need to be prepared for the issues they may face. This presentation looks at many of the problems that can come up when processing phosphates, as well as how to combat those issues.
This presentation looks at the process equipment used in both phosphatic fertilizer and animal feed production. This includes major equipment such as rotary dryers, coolers, kilns, and granulation drums, as well as other equipment such as pipe reactors, hammer mills, and coating drums.
The document provides information about fertilizers and the fertilizer industry. It discusses the types of fertilizers, nutrients needed by plants, manufacturing processes, and safety aspects. The key points are:
1) Fertilizers supply essential nutrients like nitrogen, phosphorus, and potassium to support plant growth. Common fertilizers include urea, ammonium phosphate, and potassium chloride.
2) The fertilizer manufacturing process involves synthesizing raw materials into fertilizer components like ammonia and phosphoric acid, then granulating and blending the components.
3) IIFCO's Kandla unit in India produces various NPK fertilizer grades using a conventional slurry granulation process. It has safety measures and
This document provides guidelines for the management and handling of phosphogypsum generated from phosphoric acid plants in India. It discusses the phosphoric acid manufacturing process, which produces phosphogypsum as a byproduct. It outlines the characteristics and environmental impacts of phosphogypsum. The guidelines cover best practices for the storage, management, handling, disposal, and beneficial use of phosphogypsum to minimize environmental impacts. It also provides a monitoring protocol for phosphogypsum storage areas.
Potassium fulvate contains both humic acid and fulvic acid, is mainly extracted from lignite. As it possess good water solubility, strong resistance to hard water, meanly used for spray irrigation,drip irrigation.
Other trade names: potassium fulvic acid, k fulvate, Resisting hard water potassium humate, deflocculation potassium humate or non-flocculating potassium humate, super potassium f humate.
Rotary dryers are an integral component throughout the processing of phosphate rock into phosphatic fertilizers and animal feed products. This presentation goes over how rotary dryers are used in the phosphates industry, the benefits they can offer, and factors to consider during the phosphate dryer design stage.
Fertilizers and crop-nutrition programs help produce the food required for a growing world population. In addition, these industrial products and solutions contribute to reduced emissions, improved air quality and support safe and efficient operations.
Phosphate rock is a key component to sustaining life on Earth. However, it is also a finite resource. This presentation looks at the opportunity to recycle phosphorus from existing waste streams such as manure and biosolids.
PHOSPHATIC FERTILIZERS - BEHAVIOR IN SOILS AND MANAGEMENT.pptxAVINASH K
Phosphorus (P) was first discovered by Brandt in 1669. The word is derived from Greek, ‘phos’
meaning light and ‘phorus’ meaning bringing. Phosphorus is a major nutrient next to N and
plays an important role in plant physiology and biochemistry. It is involved in the building blocks,
a component of genetic material (nucleic acids) and an energy currency (ATP) of plants. However,
unlike N and K, P is taken up in smaller quantities by the plants. Further, P contrasts from N with
respect to its transformation in soil after fertilizer P is applied. While N is easily lost from the soil
system, P does not. It is mined from the finite natural resources and the supply is expected to
dwindle in the next 100–150 years. Thus, efficient use of the P fertilizers will play a key role in
sustaining crop production. understanding different forms of soil P and its transformation
in soils and the various factors influencing P availability is crucial. Followed by the role of P in plants,
its absorption and crop P requirements. Understanding Fertilizer P materials and the various
strategies that are needed for efficient use of P are important for field applications.
The document discusses zero liquid discharge systems for fertilizer production. It provides details on different types of nitrogen and phosphate fertilizers and their manufacturing processes. This can generate wastewater containing nutrients like phosphorus and nitrogen, as well as other pollutants. Zero liquid discharge systems aim to treat this wastewater on-site to allow water reuse and recover fertilizer products, minimizing liquid discharges.
Phosphate-based fertilizers are produced through various chemical reactions between phosphate rock, acids like phosphoric and sulfuric acid, and bases like ammonia. Common phosphate fertilizers include single super phosphate (SSP), triple super phosphate (TSP), monoammonium phosphate (MAP), and diammonium phosphate (DAP). NPK compound fertilizers contain multiple nutrients and are produced by granulation processes that mix raw materials like ammonium phosphates, urea, and potassium salts.
Phosphorus is a critical nutrient required for all life. It cycles through the lithosphere, hydrosphere, and biosphere. Plants uptake phosphates from soil, which are then consumed by herbivores and passed up the food chain. Human activities like fertilizer use and wastewater discharge disrupt the natural phosphorus cycle, leading to issues like nutrient runoff and water pollution. Sustainable phosphorus management practices are needed to minimize impacts and preserve this essential nutrient cycle.
This document discusses different types of complex fertilizers including their composition and manufacturing processes. It describes nitrophosphate fertilizers which contain nitrogen and phosphorus in various proportions. Diammonium phosphate and ammonium phosphate are mentioned as important complex fertilizers produced through chemical reactions. The document also discusses ammonium polyphosphate, potassium polyphosphate, and zincated polyphosphates as recently developed complex fertilizers that supply nutrients and micronutrients to plants.
Well matured organic manure fortified with high grade rock phosphate mineral in fine size works as efficiently as Di Ammonium Phosphate a well known chemical phosphate fertilizer.
Increasing efficiency of ROCK PHOSPHATE on problematic soilssamanyita94
PHOSPHATE ROCK-
Phosphate rock denotes the product obtained from the mining and subsequent metallurgical processing of P-bearing ores.
PRs can be used-
as raw materials in the industrial manufacture of WSP fertilizers,or as P sources for direct application in agriculture
Phosphate rocks as raw materials for P-fertilizer manufacturing:
1.Sulphuric acid and PR are the raw materials used in the production of single superphosphate (SSP) and phosphoric acid.
2.Phosphoric acid is an important intermediate by-product that is used to make triple superphosphate (TSP) and ammonium phosphate.
3.It is used for industrial purposes and for the production of animal feed supplements and food products.
4.used in the manufacture of elemental P and its derivatives, in particular sodium tri-polyphosphate(a major component of heavy-duty laundry detergents).
Rock phosphate for direct application:
As mentioned above, PRs mainly of sedimentary origin are suitable for direct application because they consist of fairly open, loosely consolidated aggregates of micro crystals with a relatively large specific surface area.
They show a considerable proportion of isomorphic substitution in the crystal lattice and contain a variable proportion and amounts of accessory minerals and impurities.
Advantages – less expensive , slow and steady supply of P and More P restoration capacity.
Factors affecting the effectiveness of rock phosphate:
Reactivity of RP: Reactivity is a measure of its rate of dissolution.
Particle size: Finer the particle size, more is the dissolution.
Usually less than 0.15mm.
Soil properties:Low pH (less than 5.5 ), high organic-matter content and low solution concentration of Ca ions.
Soil acidity, Cation exchange capacity, and exchangeable calcium and magnesium, Soil organic matter, Crop species and Soil solution ‘P’ concentration and retension capacity
B. Management practices: PR placement, Rate of PR application, Timing of PR application, Lime application
ways for improving efficiency of rock phosphates:
Depends on various factors:-
the physical and chemical properties of PRs;
soil and climate factors;
plant species and the cropping system; and
farming management practices.
biological,chemical and physical means of increasing efficiency
5 R's of reduce India's dependency on phosphate rock derived P
The document discusses biological phosphorus removal from wastewater. It describes how phosphorus enters wastewater from human and industrial sources. Phosphorus needs to be removed to prevent eutrophication in natural water bodies. The process relies on microorganisms called phosphate accumulating organisms (PAOs) that uptake phosphorus under aerobic conditions. PAOs store phosphorus inside their cells under aerobic conditions. They release phosphorus from their cells and take up organic carbon sources under anaerobic conditions. Alternating anaerobic and aerobic zones in wastewater treatment systems selects for growth of PAOs, resulting in removal of phosphorus from wastewater.
The document summarizes a seminar presentation on using phosphogypsum in pavement construction. Phosphogypsum is a waste byproduct of fertilizer production that contains gypsum. It has several potential uses in road construction, such as soil stabilization, subgrade improvement, and as a base material or additive in asphalt. Experimental studies found that phosphogypsum has properties suitable for these uses, including adequate strength and permeability. While it poses disposal challenges due to potential radioactivity, utilizing phosphogypsum in pavement construction provides environmental benefits over disposal in landfills.
Lecture 12 phosphorus Microsoft Office PowerPoint.pptxssusercbb749
Human waste and detergents contain phosphorus that ends up in wastewater. Phosphorus causes eutrophication when discharged into surface waters, damaging ecosystems. It must be removed from wastewater to prevent these negative effects. Improving phosphorus recycling from waste and developing infrastructure for processing phosphorus waste can help address issues of phosphorus pollution, food security, and environmental sustainability.
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2. INTRO
Contents
About FEECO 1
Intro to Phosphates 3
PROCESSING
Processing Phosphates for Use in Fertilizer Products 5
Processing Phosphates for Use in Animal Feed 7
EQUIPMENT
Phosphate Processing Equipment Overview 11
Rotary Dryers: The Ideal Choice in Processing Phosphates 13
Material Handling in the Phosphates Industry 15
CONSIDERATIONS
Phosphate Processing Challenges 19
Testing Phosphates in the FEECO Innovation Center 20
OUTLOOK ON PHOSPHATES
Opportunities in Recycling Phosphorus 24
The FEECO Commitment to Quality 26
Crush strength test in the
FEECO Innovation Center
3. THE
PHOSPHATES
HANDBOOK
FEECO International was founded in 1951 as an engineering and equipment manufacturer. We quickly became
known as the material experts, able to solve all sorts of material processing and handling problems, and now
serve nearly every industry, from energy and agriculture, to mining and minerals.
As experts in the field of granulation, FEECO has been providing feasibility testing, process and product design,
and custom processing equipment for phosphate materials since the 1950s. From initial phosphate rock drying,
to animal feed and fertilizer granulation, we offer unparalleled capabilities in phosphate processing.
For further information on our custom phosphate processing equipment or our many other phosphate
processing capabilities, contact a FEECO expert today.
Introduction
FEECO US Headquarters
3913 Algoma Rd. Green Bay, WI 54311, USA
Phone: (920)468.1000
Fax: (920)469.5110
FEECO.com/contact
5. FEECO.com/contact
Phosphorus is an irreplaceable nutrient, utilized for its
life-giving capabilities to all life on Earth. Phosphorus
is critical to carrying out a variety of cellular and
biological processes that help plants, animals, and
even humans to grow strong and healthy. As such,
phosphorus is a key ingredient in fertilizers and
animal feeds.
Phosphorus is mined all over the world in the form of
phosphate rock and processed into all the products
that keep our world running. A key component in crop
production, livestock feed, and even in consumer
products, in 2014 alone, world phosphate rock
production was at a staggering 225 MT and projected
to increase in the coming years1
.
According to the USGS, 95% of the phosphate rock
mined in the United States is used in the production of
fertilizer products1
, with the rest going toward animal
feed, and food or chemical products.
Before phosphate rock can be used in the production
of fertilizers or animal feed, however, it must first be
processed.
The following will look at the common processing
methods used to produce phosphate products,
namely animal feed and fertilizers.
An Intro to Phosphates
THE PHOSPHATES PROCESSING HANDBOOK | 3
1. U.S. Geological Survey, 2015, Mineral commodity summaries 2015: U.S. Geological Survey, 196 p., http://dx.doi.org/10.3133/70140094
Granules under a microscrope in
the FEECO Innovation Center
7. FEECO.com/contact
No matter what product phosphate rock is destined
for, it must first be mined and beneficiated.
Mined phosphate rock beneficiation differs greatly
from one deposit to the next, with any combination of
crushing, screening, flotation, filtration, classification,
and more carrying out the job.
The ore resulting from the beneficiation process
must be dried before it can move on to subsequent
processing. This is typically carried out in a rotary
dryer, an industrial drying system ideal for processing
phosphate ore, because of its heavy-duty build and
high capacity capabilities.
The dried phosphate ore is then most commonly
processed into phosphoric acid through reaction with
sulfuric acid. Phosphoric acid is a versatile material
and is the base of phosphatic fertilizers and
animal feeds.
Processing Phosphates for
Use in Fertilizer Products
Phosphates have been used in the fertilizer industry
for generations. Phosphorus assists in many biological
processes that help to create strong stems and roots,
aid in resistance to disease, and create a more
productive plant overall.
While ground phosphate rock can be applied
directly to soil, it is most beneficial to first process the
phosphate rock into a form that allows the phosphorus
to be more readily absorbed by plants.
Phosphate rock can be processed into a variety of
phosphatic fertilizers. Most commonly, it is processed
into Monoammonium Phosphate and Diammonium
Phosphate fertilizers, also commonly known as MAP
and DAP.
MAP & DAP Fertilizer Production
MAP and DAP fertilizers are produced by reacting
phosphoric acid with ammonia and then granulating
the resulting material. This process is described here in
detail and illustrated on the next page.
The phosphoric acid and ammonia are pre-
neutralized (reacted) in tanks to form a slurry. This
slurry is then fed into a rotary granulator, where it forms
granules as it tumbles through the drum and solidifies.
These granules are then carried by a conveyor or
bucket elevator to a rotary dryer where they are dried
into their final form. The tumbling action of the dryer
further rounds and polishes the granules. Granules
exit the dryer and go through a screening process to
separate over- and under-size granules.
Oversize granules are crushed via a hammer mill
and fed with the under-size granules back into the
process as recycle. On-size product moves on to
cooling, which is carried out using a rotary cooler.
Cooling helps to prevent caking during storage, and is
necessary when material exiting the dryer is too hot for
subsequent material handling equipment.
An Alternative Approach to
MAP Granulation
While this is the primary processing method for MAP
THE PHOSPHATES PROCESSING HANDBOOK | 5
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production, an alternate process, which includes the
addition of a pipe reactor, is sometimes used for the
energy savings it can offer. This method is exclusive
to the production of MAP and is illustrated on the
following page.
Instead of being reacted in tanks, phosphoric acid
and ammonia are reacted in the cross pipe reactor.
The hot melt formed from this reaction is sparged
into the rotary granulator and the resulting heat from
the reaction flashes off moisture from the granular
material.
While a rotary dryer is still needed, energy
requirements are significantly reduced, because
the heat of the reaction can supplement much of
the drying energy required. Again, material is then
screened and recycle is separated out, while on-size
product moves on to cooling.
The addition of a pipe reactor can be a popular
option for retrofits, because it is easily installed, and
the pre-neutralizing tanks can serve as feeding tanks
to the operation. And while no operation requires the
use of a pipe reactor, in the right settings, it can offer
significant value in energy savings.
THE PHOSPHATES PROCESSING HANDBOOK | 6
TRADITIONAL MAP/DAP GRANULATION
9. FEECO.com/contact
Additional Phosphatic Fertilizers
While phosphate rock is most commonly made into
MAP and DAP, it can also be made into a variety of
other fertilizer products as well:
• Single Super Phosphate (SSP)
• Triple Super Phosphate (TSP)
• NPK – Although phosphate is not the base of
this product, it is included with potassium and
nitrogen to create a variety of NPK blends.
These materials may be comprised of varying
components, but all are produced using the
traditional granulation approach.
Processing Phosphates for
Use in Animal Feed
Phosphorus is critical to the nutrition of animals, aiding
in a variety of cell functions to build strong bones and
teeth, and contributing to a variety of other essential
processes in the body as well. As such, phosphorus is a
key ingredient in animal feeds, namely Monocalcium
Phosphate (MCP) and Dicalcium Phosphate (DCP).
While only about 5% of global phosphate consumption
goes toward animal feed production2
, the production
of phosphate animal feed plays a critical role in
maintaining livestock health and overall food security.
THE PHOSPHATES PROCESSING HANDBOOK | 7
2. “Markets & Industries.” PotashCorp. Web. Mar.-Apr. 2016. <http://www.potashcorp.com/investors/markets_industries/feed/>.
MAP GRANULATION WITH A PIPE REACTOR
10. FEECO.com/contact
Preparing Phosphate Ore for
Animal Feed Production
Much like for fertilizer, phosphate rock is first mined, the
ore beneficiated and then processed into phosphoric
acid. In some cases, processing in a kiln may also be
required if the phosphate is contaminated, or found in
the presence of organic materials that will necessitate
removal.
MCP and DCP are created by reacting the phosphoric
acid with calcium carbonate and granulating the
resulting material. It is worth noting that animal feed
was not always (and sometimes still isn’t) granulated,
but granulation has proven to add significant value to
the end product; a granular feed is much more easily
handled, provides a more uniform product, and offers
significantly less dust.
MCP and DCP Production
Traditionally, phosphoric animal feeds have been
produced utilizing a Spinden reactor, a horizontal
mixer/reactor similar to a pug mill. While this approach
yields effective results and is widely used throughout
the animal feed industry, FEECO has improved upon
the process through the addition of a high speed mixer.
How Feed Granulation with a
High Speed Mixer Works
Phosphoric acid and limestone (calcium carbonate)
are fed into the high speed mixer. The mixer is
comprised of a vertical chamber with a paddle shaft
running through the middle, which rotates at 300-400
RPMs to create an intense mixing action.
This intense mixing step serves to create a more
homogenous mixture, and subsequently, a better
reaction of the materials. The high speed mixer
thoroughly mixes the materials, and then drops them
via gravity into the pug mill on which it is mounted.
The pug mill completes the reaction, and granulates
the mixture as it moves down the length of the mixer.
Once the mixture has been granulated, it exits the pug
mill and is carried by conveyor to a rotary dryer.
THE PHOSPHATES PROCESSING HANDBOOK | 8
Phosphate granules created in
the FEECO Innovation Center
11. FEECO.com/contact
The dryer removes the desired amount of moisture
from the product and further polishes and rounds
the granules. After drying, under-size and over-size
material are screened out and fed back into the
process as recycle, with over-size pellets first going
through a grinding step in a hammer mill. On-size
product can move on to packaging, shipping, or
storage. The FEECO granulation process described
here is illustrated above.
Benefits of the
High Speed Mixer Approach
The FEECO animal feed granulation process utilizing
a high speed mixer offers significant value over the
traditional approach to animal feed granulation.
The mixing step in a granulation process sets the stage
for the quality of the end product. The addition of
a high speed mixer offers a more intimate mixing of
the materials. This not only improves the uniformity of
the pellet, but it also results in a better reaction of the
materials, yielding a higher quality pellet.
The FEECO approach to producing Monocalcium
Phosphate and Dicalcium Phosphate is an
improvement on the traditional approach, offering
increased product quality.
THE PHOSPHATES PROCESSING HANDBOOK | 9
MCP & DCP ANIMAL FEED PRODUCTION
WITH A HIGH SPEED MIXER
13. FEECO.com/contact
Phosphate Processing
Equipment Overview
The phosphate industry continues to gain attention
as of late, as the world begins to approach peak
phosphorus. With that, companies will increasingly be
looking to improve upon their phosphate products
and processing methods.
What follows is a basic overview of the equipment
commonly used in processing phosphate rock into
animal feed and fertilizer products. Some equipment
features may be specific to FEECO International.
Granulation Drums
Granulation drums are the centerpiece of most
phosphatic fertilizer operations. This is where material is
granulated after reaction.
Granulation drums are incredibly versatile and can
therefore be used to process a wide array of materials.
They are used frequently throughout the agriculture
industry to create a variety of inorganic fertilizer
products.
How Granulation Drums Work
In phosphatic fertilizer production, granulation drums
work by tumbling reacted material in a rotating drum.
As the material cools and solidifies, the tumbling action
rounds it into granules. Tumbler flights can be added
to increase material agitation and create the desired
product characteristics.
Flexible and corrosion-resistant drum liners can be
implemented to reduce or eliminate material build-
up on drum walls, and decrease the potential for
damage due to a corrosive material.
Pug Mills
In the phosphates industry, pug mills, also commonly
known as paddle mixers, are used in granular fertilizer
production to mix the recycle with the new raw
materials, and in animal feed production to thoroughly
mix, react, and granulate feed ingredients.
How Pug Mills Work
Pug mills use a folding and kneading action to
thoroughly mix materials. In granular fertilizer
production, they make a homogeneous blend prior
to entering the granulator. In animal feed production,
they facilitate the reaction between components. The
thorough mixing helps to ensure a uniform product.
Rotary Dryers
Rotary dryers are used prolifically throughout the
phosphates industry, for drying phosphate rock, as
well as for drying granular animal feeds and fertilizer
products.
How Rotary Dryers Work
Rotary dryers work by cascading material in a rotating
drum in the presence of a drying air/hot gas. Material
lifters, or flights, lift the material, carry it over, and drop
it through the drying air stream in order to maximize
heat transfer efficiency.
Rotary Coolers
Rotary coolers are typically used in fertilizer
granulation. A cooler is commonly used after the
drying step to cool material exiting the dryer.
THE PHOSPHATES PROCESSING HANDBOOK | 11
14. FEECO.com/contact
Cooling helps to bring down material temperature so
it is not too hot for subsequent handling, and it also
helps to prevent caking issues during storage.
How Rotary Coolers Work
Much like rotary dryers, rotary coolers cascade
material in a rotating drum. Instead of heated air,
however, they utilize chilled or ambient air. Here
again, flights are necessary to increase efficiency.
Hammer Mills
Hammer mills are used for both fertilizer and animal
feed granulation applications. Hammer mills are used
for crushing over-size granules so they can be worked
back into the process as recycle.
How Hammer Mills Work
Hammer mills use a spinning shaft affixed with
hammers and/or chains to break down oversize
product. Hammer mills produce maximum product in
the size range of minus 4 mesh down to plus 20 mesh.
High Speed Mixers
The high speed mixer is specific to the FEECO
approach to animal feed granulation and is the most
efficient type of reactor/mixer in the marketplace
today. The addition of a high speed mixer to the
pug mill provides an improved reaction and a more
uniform product.
How High Speed Mixers Work
High speed mixers are comprised of a vertical
chamber, through which a shaft extends. The shaft
is affixed with several paddles, and operates at 300-
400 RPM to provide thorough mixing and initiate the
reaction before material moves on to processing in
the pug mill.
Coating Drums
Coating drums are sometimes used in the production
of MAP and DAP. Coating drums coat granules with a
material that improves the end product in some way,
typically by reducing dusting issues, or employing an
anti-caking agent.
THE PHOSPHATES PROCESSING HANDBOOK | 12
FEECO Rotary Dryer
15. FEECO.com/contact THE PHOSPHATES PROCESSING HANDBOOK | 13
How Coating Drums Work
Similar to rotary granulators, coating drums consist
of a rotating drum through which material is fed.
The material tumbles through the drum, and a spray
system releases the coating agent onto the material.
Tumbler flights help to increase agitation, ensuring
uniform results.
Rotary Kilns
Rotary kilns are similar to rotary dryers, but operate
at much higher temperatures in order to cause a
chemical reaction or physical change in the material.
In the phosphates industry, kilns are typically used
to purify or upgrade low-grade or contaminated
phosphate ore.
How Rotary Kilns Work
Rotary kilns work by heating material to the
temperature at which the desired reaction will
take place, and holding it there until the reaction is
complete.
Pipe Reactors
Pipe reactors are an acid-base reaction vessel
sometimes used in the production of MAP fertilizers.
Although they are not required in any system, in the
right settings, they can provide significant energy
savings, because they allow for the heat of the
reaction to be captured, supplementing some of
the energy required for drying.
How Pipe Reactors Work
Phosphoric acid is fed into one side of the reactor,
and gaseous or liquid ammonia is fed into the reaction
chamber. A hot “melt” is produced, which is sprayed
onto a bed of recycle material in the rotary granulator.
The captured reaction heat helps to dry the material
as it tumbles through the granulator and solidifies.
Rotary Dryers: the Ideal
Choice in Processing
Phosphates
Despite such variation in end use, one industrial tool
helps to make all of the phosphate products we need
possible: the rotary dryer.
From the initial beneficiation, all the way through to
the end product, rotary dryers remain a key tool in
producing the many phosphate products our growing
world requires.
This article will look at three key areas where products
would not be possible without the help of this versatile
industrial dryer.
Drying Phosphate Rock
As mentioned, the beneficiation of phosphate rock
differs greatly from one deposit to the next. In general,
however, phosphate rock is processed via a wet
process, resulting in a wet phosphate rock, which
must be dried before it can move on to subsequent
processing.
Benefits of Drying Phosphate Rock
The drying of phosphate rock is an essential step in
transforming ore-bearing phosphate rock into usable
products, offering significant benefits to the process as
a whole, and to any subsequent processing that will
need to occur.
16. FEECO.com/contact
This includes:
Improved Product Handling: Drying phosphate
rock reduces moisture content, so handling issues
associated with wet or sticky phosphate rock are
avoided.
Reduced Potential for Buildup: Dried phosphate
rock offers reduced opportunity for buildup in
equipment. This decreases the potential for
equipment to clog, ultimately improving process
flow and efficiency.
Drying Phosphatic Fertilizers
Drying plays a critical role in the success of fertilizer
products. Since many fertilizer products will move on
to bagging, storage, or shipping, the moisture content
must be reduced to help prevent caking issues and to
maintain product integrity.
Drying Animal Feeds
Similar to fertilizer production, phosphate rock that is
processed into animal feed also requires a drying step.
Here again, phosphate materials are granulated into
agglomerates that must then be dried.
Benefits to Drying Granular Phosphate Products
Enhanced Product Quality: For both phosphatic
animal feeds and fertilizer products, drying can
offer an added benefit when dried in a rotary
dryer; granule characteristics are improved,
because the tumbling action imparted by
the dryer wears down rough edges, reducing the
opportunity for attrition later, and essentially
polishing the granules to create a premium
granular product.
Hardened Granule Surface: Drying cures granular
phosphate products into their final form, yielding
a hardened product that is capable of
withstanding handling, transportation, and even
application. As mentioned, this hardened surface
also reduces the potential for caking issues
during storage.
How Phosphate Dryers Work
Rotary dryers are the ideal choice in processing any
type of phosphate product. Rotary dryers are robust in
design and construction, allowing them to withstand
the rigors of drying phosphate products. Additionally,
their high throughput is ideal for the high capacity
requirements of phosphate processing.
These industrial drying systems are also valued for
their ability to accept variance in feedstock, which is
often a given in processing phosphates, particularly at
phosphate mining and beneficiation sites where ore
can vary in makeup and moisture content.
Phosphate rotary dryers work by tumbling the material
to be dried in a rotating drum in the presence of a
drying air. These dryers are typically of the co-current
air-flow configuration, meaning that the material and
drying air flow in the same direction. When drying
an animal feed or fertilizer product that has been
granulated by reaction, this helps prevent the most
dry material from becoming too hot, which would
result in the creation of fines and attrition. When drying
phosphate rock, the co-current configuration helps to
“flash off” initial surface moisture, and allow the rock
to be dried through to the core as it moves down the
length of the drum. Flights, or material lifters, pick up
THE PHOSPHATES PROCESSING HANDBOOK | 14
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the material and drop it through the stream of drying
air as the drum rotates in order to maximize heat
transfer efficiency.
Material Considerations in
Phosphate Drying
Phosphate can be a challenging material to work
with, presenting a number of characteristics that
affect the drying process. Some of the most common
characteristics to take into consideration during design
and development stages include:
Buildup
Because phosphate can tend to clump, knocking
systems are typically required on rotary dryers, with the
ball and tube type knocker being the most common
choice. A knocking system serves to dislodge potential
buildup inside the drum by “knocking” the exterior of
the drum as it rotates.
A screw conveyor may also be an option in
combatting buildup; screw conveyors “fling” material
into the dryer, helping to break up potential clumps as
they enter the dryer.
In addition, various materials of construction such as
stainless steel with a 2B finish can aid in the prevention
of buildup.
Abrasion
Phosphates can be abrasive. Because of this, materials
of construction must be carefully chosen. Additional
modifications may be required for high-wear areas,
such as the material inlet of the dryer.
Dusting
Phosphate can also be a dusty material to work
with. This is particularly problematic when drying
phosphate rock. Here, particulate matter in the form
of phosphate rock dust is collected in a baghouse as
part of the emissions control system.
Rotary dryers continue to provide an ideal drying
medium for all types of phosphate processing
operations. From animal feed and fertilizers, to
phosphate rock, rotary dryers play a critical role in
helping phosphoric products get to market while
offering many benefits along the way. And although
phosphates can present challenges in processing,
custom rotary dryers can be designed to work around
these difficult characteristics, producing an end
product of quality, and prolonging equipment life.
Material Handling in the
Phosphates Industry
No matter what material is being produced, all
phosphate operations have one thing in common:
they rely on heavy-duty material handling equipment
to keep operations running seamlessly.
Material handling equipment is used frequently
throughout animal feed granulation, fertilizer
granulation, and phosphate mining and beneficiation
operations in order to bring automation and flexibility
to a process.
THE PHOSPHATES PROCESSING HANDBOOK | 15
18. FEECO.com/contact
Common Phosphate
Handling Equipment
Bucket Elevators
Bucket elevators transfer phosphate materials
vertically and are often chosen because they are
ideal for high capacity handling applications.
While single chain bucket elevators are an option, the
most popular choice for phosphate bucket elevators
is the double chain continuous style, due to their
increased capacities and height capabilities.
Bucket elevators are highly customizable, allowing for
an optimal handling solution to be met for nearly
any application.
Belt Conveyors
Belt conveyors are also commonly used in phosphate
processing operations. Belt conveyors allow material
to be carried horizontally and are commonly used to
transport material from one process stop to the next, or
from one building to another. They are also extremely
customizable, with common modifications including
the addition of loading skirtboards, belt cleaning
systems, and more.
A variety of additional conveyor types exist to further
optimize the handling of a phosphate operation, with
two of the most popular being:
Reversing Shuttle Conveyors: A belt conveyor that is
mounted to a rail or track system, in order to allow for
more than one discharge point and conveying in
both directions.
Steep Incline Conveyors: Steep incline conveyors carry
material vertically, or at an angle that is too steep for
horizontal transport.
Belt Trippers & Plows
Belt trippers and plows allow for increased flexibility
of a material handling system. Trippers travel along
the length of the conveyor and can discharge
material at any point along the travel range, providing
for a continuous, long storage pile of material, as
compared to a single pile of material discharged
from the end of a conveyor. Trippers essentially “trip”
material off the conveyor at either fixed or movable
points, while belt plows are fixed, but allow for
discharge from the conveyor on one or both sides.
Belt Feeders
Belt feeders ensure controlled feed rate from a bin
or hopper onto a conveyor or other piece of process
equipment. They are highly versatile and can be used
in a variety of applications.
Considerations in Handling
Phosphates
Whether the material is animal feed, fertilizer, or
phosphate rock, phosphate products present a few
challenges that will require ingenuity on the part of the
equipment manufacturer…
Abrasion & Corrosion: Phosphates can be abrasive
and sometimes corrosive. Much like the industrial
drying system, material handling equipment will likely
require customizations to guard against abrasion and
corrosion in order to maintain process efficiency and
prolong equipment life.
THE PHOSPHATES PROCESSING HANDBOOK | 16
19. FEECO.com/contact
This might include reinforcing high-wear areas such as
transfer chutes, or using various alloys such as stainless
steel to construct the handling equipment.
Additionally, material should not be allowed to build
up in equipment, as this can promote excessive wear.
No matter what type of phosphate operation is at
hand, material handling equipment plays a critical
role in automating the process and allowing for
flexible, seamless operation.
FEECO Reversing Shuttle Conveyor
THE PHOSPHATES PROCESSING HANDBOOK | 17
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Phosphate Processing
Challenges
Just as with any mineral, phosphates can present
challenges during processing. However, careful
planning and preparation of both the process and
equipment can help to achieve desired results, while
also prolonging equipment life at the same time.
Below are some of the common issues processors face
when working with phosphates.
Abrasive
Depending on the form they’re in and what they’re
being processed into, phosphates can be anywhere
from mildly to extremely abrasive. Whether produced
to be a fertilizer such as MAP, DAP, or NPK, or an animal
feed such as MCP or DCP, abrasiveness can pose
problems to unprotected equipment, and therefore,
equipment will need to be designed with this in mind.
Dust Issues
Phosphate products can also be dusty, depending
on what form they’re in. Dust issues are especially
problematic at phosphate beneficiation plants, where
mined phosphate rock is dried after processing. The
phosphate rock becomes dusty upon drying, and fines
are commonly collected in a baghouse.
While these collected fines are dusty and difficult
to handle, opportunity exists in agglomerating the
fines so they are more easily handled and processed
down the line. The agglomeration of fines significantly
reduces issues associated with dust, and also allows
the product to be more easily reintroduced to
the process.
Corrosive
In processing phosphate products, many corrosive
solutions are often added. The base of many
phosphate products is phosphoric acid, which is a
highly corrosive material. Specialty alloys and linings
are often required on equipment to protect against
corrosion.
Clumping
Clumping can also be an issue when processing
phosphate products. Wet phosphates are prone to
sticking and clumping, causing issues in processing
equipment and impacting overall process efficiency.
While drying the phosphates, sticking and clumping
can occur on the belt conveyors and chutes going
to the dryer, as well as on the walls and flights of the
dryer. For this reason, phosphate rotary dryers are
commonly fitted with knocking systems in order to
reduce clumping during drying.
Variability
Phosphate deposits are incredibly diverse. Phosphate
ore differs greatly from one deposit to the next,
and even within the same deposit. This can be a
challenge, because each deposit will likely require
modifications to processing methods in order to
produce a quality product with the desired properties.
Contamination
Similar to variation, phosphate rock is sometimes
considered contaminated, meaning it is found in
the presence of organics. This causes the phosphate
rock to be low in value or even unusable as-is. In
these cases, the phosphate rock will typically require
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purification via calcination in a rotary kiln, a process
commonly referred to as the upgrading of
phosphate ore.
Combatting Phosphate
Challenges
Feasibility and Pilot Testing
It is often both necessary and desirable to conduct
testing, whether it be to troubleshoot and improve
an existing process, collect data for a new process,
or to take a concept from idea to product. Testing
of phosphates at batch and pilot scale helps to work
out process variables and provide the information
necessary for successful process scale-up and
equipment design. These early testing stages allow
for a familiarity with the unique sample to be gained,
helping to minimize surprises later.
Testing is also especially critical when looking to purify
contaminated phosphate ore. Because the makeup
of phosphate ore deposits vary considerably, the
times and temperatures required to remove organic
components will also vary. Testing in a batch rotary kiln
is frequently used to develop the time and temperature
profiles necessary to remove the organic components
and produce desired results. Testing of phosphates is
covered more in-depth in the next section.
High Quality Equipment
When it comes to processing phosphates, high quality
equipment is essential. Equipment will need to be
robust and designed around the characteristics of the
sample at hand, as well as any additives that may
be included in the process. Choosing an equipment
manufacturer that is familiar with the potential
challenges that phosphate products can present
will go a long way in prolonging equipment life and
ensuring process efficiency.
Critical wear points such as paddles and plows
on agglomeration equipment will likely require
modifications to protect against abrasion and
corrosion. This might include constructing high wear
areas with abrasion-resistant materials, or reinforcing
them with specialty linings.
Testing Phosphates in the
FEECO Innovation Center
While phosphate production is a well-established
industry, testing remains a critical component in the
success of many phosphate operations.
Why Testing is Important
There are many reasons why testing is both necessary
and desirable. The most common reasons for testing
phosphate materials include:
To Create a New Product/Process
New phosphate products are constantly being
developed in all sectors. When working with fertilizers, it
is common to try new blends for custom applications.
Similarly with animal feed, new products aimed at
better nutrition are tested. With consumer products,
testing is used to develop new detergents, cleaners,
and other products for consumer use.
To Improve an Existing Product
Improvement of an existing product is perhaps the
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most common reason for testing. When new market
opportunities open up, or a product isn’t performing
as intended (or could perform better), a variety
of characteristics can be modified to improve
performance or enhance the product in some way.
This might include adjusting the blend or formulation of
the product, or altering physical characteristics such
as granule size, crush strength, or bulk density to make
the product easier to handle or apply.
To Improve an Existing Process
Testing is also frequently conducted to improve on
an existing process. This could be to troubleshoot
an inefficient process, work out the incorporation of
a new addition to the process, or even test out an
improved way of carrying out the process.
What Types of Testing are
Available?
Various types of testing can be conducted. In the
FEECO Innovation Center, the following types of
processes can be tested:
Agglomeration
Agglomeration of phosphates is frequently tested for a
variety of reasons. This may be to test a new product
for process knowledge or to introduce a product to
a new or existing market. It may also include testing
feasibility of granulating ground ore fines, recycle or
baghouse fines into a usable product, or the blending
of phosphates with other materials.
Granulation
Granulation of phosphate products is frequently tested
in the Innovation Center for both fertilizer and animal
feed applications. The FEECO Innovation Center can
accommodate the use of phosphoric acid, sulfuric
acid, or ammonia, allowing various reactions in the
granulation process to be tested; all pumps, spray
systems, heat tanks, and agglomeration equipment
is designed to handle both heated and non-heated
phosphoric acids and gases.
Thermal Testing
Phosphate rock can be processed in a rotary kiln
to accomplish a variety of goals. It can also be
processed in a rotary dryer to remove moisture.
Phosphate rock varies considerably in chemical
composition and the materials that it is found with
from one deposit to the next, and even within the
same deposit. This presents challenges when looking
to process the phosphate rock, because few samples
are alike.
For this reason, thermal testing in a kiln or dryer,
depending on the goal, is often conducted to
determine the time and temperature profiles required,
and collect emissions data for the unique deposit at
hand. This not only aids in designing a process that
most efficiently processes the material, but it also helps
in the design of a commercial size unit.
For all types of testing, depending on what information
the customer already knows and is looking to gather,
testing commonly starts at batch scale, with small
samples of material being tested to gather initial data
and determine feasibility of the intended goal. Once
batch testing has been successful, continuous pilot-
scale testing can be conducted. This is a much larger
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scale test, where a continuous process loop is tested.
Advantages to Testing with FEECO
Testing in the FEECO Innovation Center offers
unparalleled advantages to customers. FEECO has
a long history in the fertilizer and agriculture industry;
customers come to us because of our familiarity and
expertise in the process of producing the various
types of phosphate products and fertilizer blends. The
unique capabilities of our testing facility allow us to test
nearly any phosphate-based process, be it a common
process or a novel one. We can work with you to take
your project from idea to full-scale production, and
even produce the equipment required to do the job.
We have also partnered with Rockwell Automation
to bring our customers the best in automation control
and reporting capabilities, both as a service in the
Innovation Center, and as part of a system purchase.
Our automation system can collect and trend
numerous points of data, giving customers complete
transparency with their process, and allowing for
unmatched reporting capabilities.
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Opportunities in
Recycling Phosphorus
Why Recycle Phosphorus?
Mineralogical phosphate reserves are a finite and
irreplaceable resource. As economically accessible
reserves begin to diminish, scientists worldwide are
concerned about food security and the survival
of a world without this crucial mineral. This worry is
compounded by the fact that demand for phosphate
is constantly on the rise, as the world tries to feed a
growing population.
In 2008, a brief 800% spike in phosphate prices was
enough to cause riots and suicides in areas where
access to fertilizer became unavailable3
.
Simultaneously, the inefficient use of phosphorus is
causing it to end up in waterways, threatening the
environment and the surrounding ecology.
However, many are beginning to recognize that
existing sources of phosphorus waste streams,
particularly in the form of manure and wastewater,
may hold the key to ensuring an environmentally and
economically sustainable source of phosphorus for the
world over.
Phosphorus Recycling
Holds Promise
Studies around the world are looking at the
opportunity to recycle phosphorus from wastewater
treatment plants (biosolids), and from manure sources.
One recent study looked at three primary phosphorus
waste streams (human food waste, human excreta,
and animal manure), and how they could be
applied to corn production, one of the primary crops
produced in the United States.
The study found that just 37% of the phosphorus
available in existing waste streams could support the
annual phosphorus requirements of the U.S.
corn crop4
.
Another study found that the phosphorus available
in organic waste sources may even be more
readily available for plant uptake than that found
in traditional fertilizer products, depending on the
hygienization treatment, as well as the chemicals used
in the capture of phosphorus from waste sources5
.
The recovery and reuse of phosphorus from waste
streams is a fairly new endeavor, and much research
is needed to work out the feasibility and logistics
of such a concept. Currently, various technologies
for recovering phosphorus from such waste sources
are being developed with success, some that may
even be more cost-effective than the processing of
phosphate rock6
.
And while more research is needed in both the
recovery and the reuse of phosphorus from waste
streams, one technology is likely to lend a hand:
granulation.
THE PHOSPHATES PROCESSING HANDBOOK | 24
3. “The Phosphorus Challenge.” Phosphorus Futures. Web. Mar.-Apr. 2016.
4. Metson, Geneviève S., Graham K. MacDonald, Daniel Haberman, Thomas Nesme, and Elena M. Bennet. “Feeding the Corn Belt: Opportunities for Phosphorus Recycling
in U.S. Agriculture.” Science of the Total Environment 542, Part B (2016): 1117-1126. Web. Mar.-Apr. 2016.
5. Kahiluoto, Helena, Miia Kuisma, Elise Ketoja, Tapio Salo, and Janne Heikkinen. “Phosphorus in Manure and Sewage Sludge More Recyclable than in Soluble Inorganic
Fertilizer.” Environmental Science & Technology 49.4 (2015): 2115-122. ResearchGate. Web. Mar.-Apr. 2016.
6. Michigan State University. “New method to remove phosphorus from wastewater.” ScienceDaily. ScienceDaily, 15 August 2012.
27. FEECO.com/contact
Granulation: A Key Technology
in Phosphorus Recycling
Granulation is a process that can transform sludge and
other organic materials into a dry, granular product.
This technology is fairly established in the agriculture
industry already; granulation mitigates many of the
issues associated with raw manure, such as difficult
handling, high transportation costs, and challenges
in managing nutrients. Granulation produces a
marketable product and offers ample opportunity for
product customization, offering a premium product
where once waste management costs were incurred.
Furthermore, a granular product helps to reduce
opportunity for nutrient runoff, because no additional
moisture is being added.
In the case of manure, granulation works by taking
the nutrient-rich cake left over from the anaerobic
digestion process, and using tumble growth
agglomeration to process it into a granular product,
which is then dried and cooled. The resulting
product is nearly odor-free, and goes beyond EPA
qualifications for a Class A Biosolid, quelling many of
the worries associated with the issues surrounding the
traditional method of land-applying raw material.
Considering that phosphorus waste streams are
an inevitable part of human life on Earth, and
subsequently, a completely renewable resource,
the recovery and reuse of phosphorus from existing
waste streams looks to be a promising solution to our
disappearing phosphate rock reserves.
FEECO has been working with companies to reuse
nutrients recovered from manure and wastewater
sources through the practice of granulation for years.
We are currently working on a project that looks to
make on-farm granulation a scalable option in the
agriculture industry.
In 2015, we joined the North American Partnership
for Phosphorus Sustainability (NAPPS). Formed in
2014, NAPPS aims to take action on the looming
issues associated with phosphorus, bringing together
representatives from all sectors of the phosphate
industry.
This new approach to the recovery and reuse of
phosphorus from waste streams is still in its infancy
stages. Much research and development must be
done. As an expert in the reuse of nutrients recovered
from manure, FEECO intends to be on the front lines of
this endeavor.
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THE FEECO COMMITMENT TO QUALITY
With 65+ years of experience, FEECO International has provided full-scale process solutions for thousands of
satisfied customers (including some of the world’s largest corporations, engineering firms, and start-ups). Cited
in over 250 US patents, the name FEECO has become synonymous with innovation and the reimagining of
efficiency. As the leading manufacturer of processing and handling equipment in North America, no company
in the world can move or enhance a concept from process development to production like FEECO
International, Inc.
The choice to work with FEECO means a well-rounded commitment to quality. From initial feasibility testing, to
engineering, manufacturing, and aftermarket services, we bring our passion for quality into everything we do.
FEECO International is in the process of working towards ISO 9001:2015 quality management system
compliance, with the goal of achieving ISO 9001:2015 Certification within the next calendar year.
3913 Algoma Rd. Green Bay, WI 54311, USA • Phone: (920)468.1000 • Fax: (920)469.5110 • FEECO.com/contact
The FEECO Innovation Center can
aid in everything from feasibility
testing, to process design and
product development.
Engineering
We engineer custom
solutions to meet
your unique needs.
Aftermarket
+
Manufacturing
We manufacture the best
heavy-duty processing
equipment around.
Our Aftermarket
Engineering Team is
ready to serve, from
routine maintenance,
to emergency
service.
Innovation
Since 1951
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