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Passive, No-Purge, Sampling
           Snap Sampler
with the

      Know your sample
       Trust your data


       Mr. Sandy Britt, PG, CHG
            ProHydro, Inc.
        Sandy.Britt@ProHydroInc.com




                                      1
            www.SnapSampler.com
Snap Sampler
The                             is a passive,
      Equilibrated Grab Sampler

•   Deploy with bottles in an
      open position.

•   Sample after short or long
      residence time in the well—
      1-2 weeks or 3 or 6 months

•   Simple mechanical trigger
      closes bottles in situ.

•   No sample transfer required
      at the well head for VOCs
      -No exposure to air                       2
How the Snap Sampler works….


                        Insert




Insert




                                 Push
                                 down to
         40ml   125ml            set Snap
                                 Cap




                                            3
How the Snap Sampler works…continued


                                                             Hang on
                                           Lower downhole
Insert                                                      Dock Ring
                                Trim
trigger
                                excess
                    Add
                                Snap Cap
                    safety
                    cable
                    tie




                                           Secure


Attach
fitting




                   • Modular samplers allow up to 4
                     bottles per trigger
                   • Multiple triggers can be used for
                     multiple sampling depths                  4
Passive, No-Purge, Sampling…
      Natural flow-through: Naturally Purged.

Robin and Gillham (1987) natural background flow in a
 moderate permeability sand flushed tracers from an isolated
 screen interval in 24 hours or less. Ground Water Monitoring Review, v. 7, no. 4,
 p. 85-93


Powell and Puls (1993) “passive sampling devices…could
 remain open in the screen interval during the recovery
 period, then be closed to the collect the sample and brought
 to the surface.” Journal of Contaminant Hydrology, v12, p51-77
ASTM (2002) “Low-flow purging differs from traditional
 purging…in that its use is based on the observations of
 many researchers that water moving through the formation
 also moves through the well screen. Thus, the water in the
 screen is representative of the formation water surrounding
 the screen” Emphasis Added. ASTM designation D-6771-02

USEPA-recommended LOW FLOW sampling relies
  on the same natural flow through conditions
                                            5
The Advantages…

• FAST, EASY, HIGH DATA QUALITY.

• Fast and easy improves cost, while

     high data quality sets
       the Snap Sampler apart

• All critical actions take place
      submerged in the well

    • no well-head sample transfer
    • very repeatable

•   Sampling personnel do not
      affect sample collection         6
You can Snap Sample by yourself…


  …without this truck…


  …and with almost none
    of this equipment




                                   7
What analytes can be Snap Sampled?

Any--as long as you can collect enough water.

   VOCs including MTBE, MEK, TMBs and 1,4-dioxane

   Metals, general wet chemistry, SVOCs, PCBs,
   perchlorate, pharmaceuticals, and many others.



Long analyte lists are a practical limitation.

             However, much is still possible with….

   • Minimum Sample Volumes (ITRC)

   • Improvements in laboratory technology

             Large Volume Injector                    8
How does comparison data look for the
                        Snap Sampler?


Example conclusions
     from independent Snap Sampler trials:


           “passed with flying colors”
                       -US Army Cold Regions Research Lab



     “more consistently representative”
                                     -Parsons



                                                        9
• Very good correlations (R2=0.99+, 0.98)
• No exposure during pouring yields
      slightly higher concentrations
• CVOC constituents
                                            10
Britt, Parker, Cherry, in Prep.
• Very good correlation (R2 = 0.99+)
• No exposure during pouring yields slightly
      higher concentrations
• BTEX MTBE CVOC                               11
TN & Associates, US Navy, unpublished data
• Very good correlation (R2 = 0.99+)
• Non volatile shows equivalent concentrations
• Perchlorate
                                                 12
Private site, unpublished data
Snap Sampler vs. Low Flow


                                                       R2 = 0.99 for all analyte
                                                      comparisons to low flow
       Snap Sample Concentration (g/L)




                                                                 125ml



                                                                          Little
                                                                         Scatter       40ml




                                          Low Flow Purge Sample Concentration (g/L)

• Very good correlation (R2 = 0.99+) for ALL comparisons
• No exposure during pouring yields slightly higher
      concentrations
• VOCS, 1,4-dioxane, anions                                                                   13
Parsons, 2005, McClellan Air Force Base, Sacramento, CA
Low Flow vs. PDB
             Low Flow vs. 3 Volume
                     R2 = 0.76 for VOCs                         R2 = 0.79 for VOCs




                           R2 = 0.58 for VOCs                    R2 = 0.99 for VOCs




                                                                         Little
                                                                        Scatter




                3 Volume vs. PDB                       Low Flow vs. Snap Sampler
                                                                             14
Parsons, 2005, Demonstration of No-Purge Groundwater
Sampling Devices, McClellan AFB, Sacramento, CA
3 volume vs Hydrasleeve
 PDB vs Hydrasleeve
                                       R2 = 0.50 for VOCs
    R2 = 0.38 for VOCs




        R2 = 0.95 for VOCs              R2 = 0.90 for VOCs




               Less                            Less
              Scatter                         Scatter




Snap Sampler vs. PDB         Snap Sampler vs. 3 volume
                                                    15
McClellan Conclusion Summary       (Parsons)



“..the Snap Sampler …may be more consistently
   representative of the actual VOC concentrations in
   the well at the time of sample collection.”


               What does better data do for you?




                                                    16
See Data Trends Sooner…




                                           Fewer variables for Snap: actual
Many variables for purge: actual
concentration, pump deployment position concentration, transport, analytical
                                           variability.
variations, equipment calibration,
pumping duration, stability criteria
                                           Discern your data trend…
requirements, wind, temperature, site
surface or ambient air contamination,           • Reduce monitoring
bottle fill rate, pour technique, speed of
                                                • Close sites sooner
bottle closure, transport, analytical
variability.
                 www.SnapSampler.com
                                                                            17
Cost Savings for No-Purge
                                                              Snap Sampling?
YES!
                                              NPV Comparison
                                                                                       30-yr cost
                                                                                       $401,660
                           $450,000
                           $400,000
       NPV $ (After Tax)




                           $350,000
                                              10-yr cost
                           $300,000
                                              $201,758
                           $250,000
                           $200,000
                           $150,000
                                                                                       30-yr cost
                           $100,000
                                                                                        $196,349
                            $50,000
                                                10-yr cost
                                $0               $105,122
                                      1   4   7   10    13      16     19   22    25   28
                                                           Time (Years)
        Nice early                             Snap Sampler          Well Purge
       break-even


                             www.SnapSampler.com                                                    18
Dedicated Snap Sampler Equipment?

                    Guarantee consistent,
                                                                                             Snap Samplers are dedicated
                    long-term, high quality
                                                                                             equipment that will be reused
                    data with a one-time
                                                                                             for years
                    expenditure.
                                                                                             The one-time expense is
                                                                                             never repeated, so your after
                                                                                             one event, savings is
                                       NPV Comparison
                                                                                30-yr cost
                                                                                             comparable to other passive
                                                                                $401,660
                    $450,000

                                                                                             approaches that have minimal
                    $400,000
NPV $ (After Tax)




                    $350,000

                                                                                             dedicated equipment cost
                                       10-yr cost
                    $300,000
                                       $201,758
                    $250,000
                    $200,000
                    $150,000

                                                                                             Cost per well depends on may
                                                                                30-yr cost
                    $100,000
                                                                                $196,349
                     $50,000
                                                                                             factors, but can be as low as
                                         10-yr cost
                          $0              $105,122
                               1   4   7   10    13      16     19   22    25   28
                                                                                             $225 at standard prices, less
                                                    Time (Years)

                                                                                             with bulk purchases
                                        Snap Sampler          Well Purge



                                             www.SnapSampler.com                                                     19
Snap Sampling:
• Saves Money

• Improves Consistency and
    Repeatability

• Corresponds well with traditional
    purge methods

• Generates no waste water

• Improves Health and Safety - no
    heavy equipment or noise; short
    time in process or traffic areas.

         www.SnapSampler.com            20

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Snap Quick Compare 1 09

  • 1. Passive, No-Purge, Sampling Snap Sampler with the Know your sample Trust your data Mr. Sandy Britt, PG, CHG ProHydro, Inc. Sandy.Britt@ProHydroInc.com 1 www.SnapSampler.com
  • 2. Snap Sampler The is a passive, Equilibrated Grab Sampler • Deploy with bottles in an open position. • Sample after short or long residence time in the well— 1-2 weeks or 3 or 6 months • Simple mechanical trigger closes bottles in situ. • No sample transfer required at the well head for VOCs -No exposure to air 2
  • 3. How the Snap Sampler works…. Insert Insert Push down to 40ml 125ml set Snap Cap 3
  • 4. How the Snap Sampler works…continued Hang on Lower downhole Insert Dock Ring Trim trigger excess Add Snap Cap safety cable tie Secure Attach fitting • Modular samplers allow up to 4 bottles per trigger • Multiple triggers can be used for multiple sampling depths 4
  • 5. Passive, No-Purge, Sampling… Natural flow-through: Naturally Purged. Robin and Gillham (1987) natural background flow in a moderate permeability sand flushed tracers from an isolated screen interval in 24 hours or less. Ground Water Monitoring Review, v. 7, no. 4, p. 85-93 Powell and Puls (1993) “passive sampling devices…could remain open in the screen interval during the recovery period, then be closed to the collect the sample and brought to the surface.” Journal of Contaminant Hydrology, v12, p51-77 ASTM (2002) “Low-flow purging differs from traditional purging…in that its use is based on the observations of many researchers that water moving through the formation also moves through the well screen. Thus, the water in the screen is representative of the formation water surrounding the screen” Emphasis Added. ASTM designation D-6771-02 USEPA-recommended LOW FLOW sampling relies on the same natural flow through conditions 5
  • 6. The Advantages… • FAST, EASY, HIGH DATA QUALITY. • Fast and easy improves cost, while high data quality sets the Snap Sampler apart • All critical actions take place submerged in the well • no well-head sample transfer • very repeatable • Sampling personnel do not affect sample collection 6
  • 7. You can Snap Sample by yourself… …without this truck… …and with almost none of this equipment 7
  • 8. What analytes can be Snap Sampled? Any--as long as you can collect enough water. VOCs including MTBE, MEK, TMBs and 1,4-dioxane Metals, general wet chemistry, SVOCs, PCBs, perchlorate, pharmaceuticals, and many others. Long analyte lists are a practical limitation. However, much is still possible with…. • Minimum Sample Volumes (ITRC) • Improvements in laboratory technology Large Volume Injector 8
  • 9. How does comparison data look for the Snap Sampler? Example conclusions from independent Snap Sampler trials: “passed with flying colors” -US Army Cold Regions Research Lab “more consistently representative” -Parsons 9
  • 10. • Very good correlations (R2=0.99+, 0.98) • No exposure during pouring yields slightly higher concentrations • CVOC constituents 10 Britt, Parker, Cherry, in Prep.
  • 11. • Very good correlation (R2 = 0.99+) • No exposure during pouring yields slightly higher concentrations • BTEX MTBE CVOC 11 TN & Associates, US Navy, unpublished data
  • 12. • Very good correlation (R2 = 0.99+) • Non volatile shows equivalent concentrations • Perchlorate 12 Private site, unpublished data
  • 13. Snap Sampler vs. Low Flow R2 = 0.99 for all analyte comparisons to low flow Snap Sample Concentration (g/L) 125ml Little Scatter 40ml Low Flow Purge Sample Concentration (g/L) • Very good correlation (R2 = 0.99+) for ALL comparisons • No exposure during pouring yields slightly higher concentrations • VOCS, 1,4-dioxane, anions 13 Parsons, 2005, McClellan Air Force Base, Sacramento, CA
  • 14. Low Flow vs. PDB Low Flow vs. 3 Volume R2 = 0.76 for VOCs R2 = 0.79 for VOCs R2 = 0.58 for VOCs R2 = 0.99 for VOCs Little Scatter 3 Volume vs. PDB Low Flow vs. Snap Sampler 14 Parsons, 2005, Demonstration of No-Purge Groundwater Sampling Devices, McClellan AFB, Sacramento, CA
  • 15. 3 volume vs Hydrasleeve PDB vs Hydrasleeve R2 = 0.50 for VOCs R2 = 0.38 for VOCs R2 = 0.95 for VOCs R2 = 0.90 for VOCs Less Less Scatter Scatter Snap Sampler vs. PDB Snap Sampler vs. 3 volume 15
  • 16. McClellan Conclusion Summary (Parsons) “..the Snap Sampler …may be more consistently representative of the actual VOC concentrations in the well at the time of sample collection.” What does better data do for you? 16
  • 17. See Data Trends Sooner… Fewer variables for Snap: actual Many variables for purge: actual concentration, pump deployment position concentration, transport, analytical variability. variations, equipment calibration, pumping duration, stability criteria Discern your data trend… requirements, wind, temperature, site surface or ambient air contamination, • Reduce monitoring bottle fill rate, pour technique, speed of • Close sites sooner bottle closure, transport, analytical variability. www.SnapSampler.com 17
  • 18. Cost Savings for No-Purge Snap Sampling? YES! NPV Comparison 30-yr cost $401,660 $450,000 $400,000 NPV $ (After Tax) $350,000 10-yr cost $300,000 $201,758 $250,000 $200,000 $150,000 30-yr cost $100,000 $196,349 $50,000 10-yr cost $0 $105,122 1 4 7 10 13 16 19 22 25 28 Time (Years) Nice early Snap Sampler Well Purge break-even www.SnapSampler.com 18
  • 19. Dedicated Snap Sampler Equipment? Guarantee consistent, Snap Samplers are dedicated long-term, high quality equipment that will be reused data with a one-time for years expenditure. The one-time expense is never repeated, so your after one event, savings is NPV Comparison 30-yr cost comparable to other passive $401,660 $450,000 approaches that have minimal $400,000 NPV $ (After Tax) $350,000 dedicated equipment cost 10-yr cost $300,000 $201,758 $250,000 $200,000 $150,000 Cost per well depends on may 30-yr cost $100,000 $196,349 $50,000 factors, but can be as low as 10-yr cost $0 $105,122 1 4 7 10 13 16 19 22 25 28 $225 at standard prices, less Time (Years) with bulk purchases Snap Sampler Well Purge www.SnapSampler.com 19
  • 20. Snap Sampling: • Saves Money • Improves Consistency and Repeatability • Corresponds well with traditional purge methods • Generates no waste water • Improves Health and Safety - no heavy equipment or noise; short time in process or traffic areas. www.SnapSampler.com 20