This document discusses smart materials and provides examples. It defines smart materials as materials that can significantly change one or more properties in a controlled way due to external stimuli like stress, temperature, or electric fields. Examples given include piezoelectric materials that produce voltage when stressed, shape memory alloys that can remember their original shape, and pH sensitive polymers that change with pH levels. Applications described are uses in medical devices, aerospace, and more. Biomimetics and intelligent structures are also summarized briefly.
2. What is a Smart Material?
Smart materials are materials that have one or more
properties that can be significantly altered in a controlled
fashion by external stimuli, such as stress, temperature,
moisture, pH, electric or magnetic fields.
The change in the material can also be reversible, as a change
in stimulus can bring the material back to its previous state.
3. What are the examples?
Piezoelectric materials
Shape memory alloys
Magnetic shape memory alloys
PH sensitive polymers
Halochromic materials
Chromogenic systems
4. What are Piezoelectric materials?
Piezoelectric materials are materials that produce a
voltage when stress is applied. Since this effect also
applies in the reverse manner, a voltage across the
sample will produce stress within the sample. Suitably
designed structures made from these materials can
therefore be made that bend, expand or contract when a
voltage is applied.
Buzzers are piezoelectric.
5. Shape Memory Alloys (SMAs)
Metals that exhibit pseudo-elasticity and the “Shape Memory
Effect”
The basic principle behind SMAs is that a solid state phase
change occurs in these materials.
They switch between states ofAustenite and Martensite.
Shape memory alloys and shape memory polymers are
thermo responsive materials, where deformation can be
induced and recovered through temperature changes.
6. What are shape memory alloys?
An example is NiTinolTM (NickelTitanium)
Above its transformation temperature, Nitinol is
superelastic, able to withstand a large amount of
deformation when a load is applied and return to its
original shape when the load is removed. Below its
transformation temperature, it displays the shape
memory effect.When it is deformed it will remain in
that shape until heated above its transformation
temperature, at which time it will return to its original
shape.
7. Magnetic SMA
Magnetic Shape Memory alloys are materials that change their
shape in response to a significant change in the magnetic field.
9. Application of SMA
Nitinol is used in medicine for stents:
A collapsed stent can be inserted into
a vein and heated (returning to its
original expanded shape) helping to
improve blood flow.Also, as a
replacement for sutures where
nitinol wire can be weaved through
two structures then allowed to
transform into it's pre-formed shape
which should hold the structures in
place.
10. Appplications of SMA
Popular SMAs are NiTi, CuZnAl, and CuAlNi
Applications include:
Aeronautical
Making flexible wings using shape memory wires
Medicine
Bone plates made of NiTi
Bioengineering
Muscle wires that can mimic human movement
11. Smart Gels
A smart gel is a material that expands or contracts in response to
external stimuli.
A smart gel consists of fluid that exists in a matrix of polymer(s).
Stimulus can include
Light
Magnetic
pH
Temperature
Electrical
Mechanical
Stimulus will alter the polymer that makes it more or less
hydrophillic.
13. Applications of Smart Gels
Medical
Drug release
Organ replacement
Muscle replication
Industrial
Shake gels
Shock absorbers
14. Rheological Materials
Material that can change its physical state very quickly in
response to a stimulus
Stimulus include
Electrical
Magnetic
Ferromagnets
Magnetic field aligns ferromagnetic molecules in order in order to
achieve solid state structure
o Nanoparticles reduce IUT effect (In UseThickening)
16. Applications of Rheological Materials
MR materials
Structural Support
Dampers to minimize vibrational shock from wind and seismic activity.
Industrial
Break fluids
Shock absorbers
17. Magnetostrictive materials
Material that stretches or shrinks when a magnetic field is
applied.
Conversely, when a mechanical force is applied on the
material, a magnetic field is induced.
Ferromagnets
Magnetic field can be used to create an electric current
19. Fullerenes
A fullerene is any series of hollow
carbon molecules that form either a
closed cage, as in a buckyball, or a
cylinder, like a carbon nanotube.
Most researched/utilized fullerene is
the carbon-60 molecule (truncated
icosaheedron)
Three nanotubes can be made by
varying the chiral angle.
Arm-chair
Zig-zag
Chiral
Chiral angle determines conductivity
20. Applications of fullerenes
Superconductors
By doping fullerenes with three variable atoms, a
superconducting state can be achieved.
Medical
Atoms can be trapped in a buckyball, in order to create a
biological sponge.
HIV protease inhibitor
A buckyball can be inserted in the HIV protease active site in
order to stop replication.
21. PH sensitive polymers
pH-sensitive polymers are materials which swell/collapse when
the pH of the surrounding media changes.
The sensor is prepared by entrapping within a polymer matrix a
pH sensitive dye that responds, through visible colour changes (see
next slide) to spoilage volatile compounds that contribute to a
quantity known asTotalVolatile Basic Nitrogen (TVB-N).
22. PH sensitive polymers
The sample is outside the package.The others are all inside.
www.dcu.ie/chemistry/asg/pacquita/
23. Halochromic Materials
Halochromic materials are commonly materials that change their
colour as a result of changing acidity. One suggested application is
for paints that can change colour to indicate corrosion in the metal
underneath them.
24. Chromogenic systems
Chromogenic systems change colour in response to electrical,
optical or thermal changes. These include electro chromic
materials, which change their colour or opacity on the application
of a voltage (e.g. liquid crystal displays), thermochromic materials
change in colour depending on their temperature, and
photochromic materials, which change colour in response to light
- for example, light sensitive sunglasses that darken when exposed
to bright sunlight.
25. Electrochromic
Flip a switch and an
electrochromic window can
change from clear to fully
darkened or any level of tint in-
between.
The action of an electric field
signals the change in the
window's optical and thermal
properties. Once the field is
reversed, the process is also
reversed. The windows operate
on a very low voltage -- one to
three volts -- and only use
energy to change their
condition, not to maintain any
particular state.
26. Thermochromic
Kettles that change colour and signs that
glow-in-the-dark are two recent
examples of products becoming
‘smarter’ as a result of new materials.
Colour-changing thermochromic
pigments are now routinely made as inks
for paper and fabrics – and incorporated
into injection moulded plastics. A new
type of phosphorescent pigment, capable
of emitting light for up to 10 hours, has
opened up entirely new design
opportunities for instrumentation, low-
level lighting systems etc. Warm Cool
http://www.mutr.co.uk/catalog/index.php?cPath=79
27. Photochromic
Photochromism is the reversible transformation of colour upon exposure to
light.This phenomenon is illustrated in sun glasses.
28. QTC
QuantumTunneling Composites (or QTCs) are composite materials of metals and non-
conducting elastomeric binder, used as pressure sensors.
As the name implies, they operate using quantum tunneling: without pressure, the
conductive elements are too far apart to conduct electricity; when pressure is applied, they
move closer and electrons can tunnel through the insulator.The effect is far more
pronounced than would be expected from classical (non-quantum) effects alone, as classical
electrical resistance is linear (proportional to distance), while quantum tunneling is
exponential with decreasing distance, allowing the resistance to change by a factor of up to
1012 between pressured and unpressured states.
QTCs were discovered in 1996 and PeraTech Ltd was established to investigate them
further.
http://www.mutr.co.uk/catalog/product_info.php?products_id=1144
32. Smart materials
smart materials have appropriate responses
photochromic glass
• darkens in bright light
low melting point wax in a fire sprinkler
• blocks the nozzle until it gets hot
acoustic emission
• sounds emitted under high stress
embedded optical fibres
• broken ends reflect light back
microporous breathable fabrics
33. Waterproof clothing
(material or structure ?)
Goretex®
micro-porous expanded PTFE (Polytetrafluoroethylene )
discovered in 1969 by Bob Gore
~ 14 x 1012 micropores per m².
each pore is about 700x larger than
a water vapour molecule
water drop is 20,000x larger than a pore
40. Actuators
hydraulic, pneumatic and electric
piezoelectric crystals
shape changes when voltage applied
shape memory materials
shape changes at a specific temperature
alloys = SMA .... polymers = SMP
magneto-rheological (MR) fluids
viscosity changes with magnetic field
electro-rheological (ER) fluids
viscosity changes with electric field
42. Intelligent Structures: applications
artificial hand
SMA fingers controlled by
nerve (myoelectric) signals
vibration damping
apply electric field to ER fluid
skyscraper windows
acoustic emission warning system
43. Biomimetics
also known as
bionics
biognosis
synthetic biology
Biomimetic materials are materials developed
using inspiration from nature.This may be useful in the design
of composite materials. Natural structures have inspired and
innovated human creations. Notable examples of these natural
structures include: honeycomb structure of the beehive,
strength of spider silks, bird flight mechanics, and shark
skin water repellency
44. Biomimetics
the concept of taking ideas from nature to implement in another
technology
Chinese silk cultivation begins c.4000BC
• ColinThubron, Shadow of the Silk Road, Chatto &Windus, 2006.
Daedalus' wings - early design failures
gathering momentum due to the
ever increasing need for
sympathetic technology
45. Biomimetics
Notable innovations
from understanding nature
Velcro
Gecko tape
Lotus effect self-cleaning surfaces
Drag reduction by shark skin
PlateletTechnologyTM for pipe repair
Smart-fabric
ElekTex™
Chobham armour vs nacre
47. Gecko tape
image from
http://www.netcomposites.com/news.asp?3922
geckos to hang single-toed from sheer walls and walk along
ceilings using fine hairs on feet
University of California - Berkeley created an array of
synthetic micro-fibres
using very high friction
to support loads on smooth surfaces.
48. Biomimetics
Lotus effect self-cleaning surfaces
surface of leaf water droplet on leaf
Image from http://library.thinkquest.org/27468/e/lotus.htm
49. Biomimetics: Lotus effect
most efficient self-cleaning plant
= great sacred lotus
(Nelumbo nucifera)
mimicked in paints and
other surface coatings
pipe cleaning in oil refineries (Norway)
Images from
http://library.thinkquest.org/27468/e/lotus.htm
http://www.villalachouette.de/william/lotusv2.gif
http://www.nees.uni-bonn.de/lotus/en/vergleich.html
50. Biomimetics
drag reduction by shark skin
special alignment and grooved structure
of tooth-like scales embedded in shark skin
decrease drag and thus
greatly increase swimming proficiency
Airbus fuel consumption down 1½%
when “shark skin” coating applied to aircraft
o Image from http://www.pelagic.org/biology/scales.html
52. ElekTex™
looks and feels like a fabric
capable of electronic x-y-z sensing
fold it, scrunch it or wrap it
lightweight, durable, flexible
cost competitive
cloth keyboards and keypads
details: http://www.electrotextiles.com
53. Self-sensing tyres
The use of tyre pressure management systems (TPMS) in the
automotive industry is growing, as car manufacturers strive
for the most efficient use of fuel in their vehicles. Millions
fewer batteries would be manufactured ifTPMS were
powered by vibrations in the rubber of the tyre itself, and the
same logic applies to many other types of sensor.
Chris Bowen, from the University of Bath, said while energy
harvesting materials are unlikely to generate enough power
for an appliance such as a light, they could power a sensor.