SALTS XYLENE AR
1) MEANING OF SALTS
2) SOLUBILITY OF
SALTS
3) PREPARATION OF
SALTS
Xylene AR
THE MEANING OF SALTS
Salts is a compound produced when the
hydrogen ion, H+, from an acid is replaced
by a metal ion or an ammonium ion, NH4
+
SALTS = IONIC COMPOUND
HOW HYDROGEN ION IS REPLACED?
KOH
K+
OH -
H +
Cl -
K+
Cl - OH -
H2O
H +
HCl KCl
+  +
H +
HOW HYDROGEN ION IS REPLACED??
NH4OH
NH4
+
OH - H +
NO3
-
OH -
H2O
H +
HNO3 NH4NO3
+  +
NH4
+
NO3
-
H +
HOW HYDROGEN ION IS REPLACED??
NaOH
Na+
OH -
H +
SO4
2- OH -
H2O
H+
H2SO4 Na2SO4
+  +
SO4
2-
Na+
Na – 1
OH – 1
H – 2
SO4– 1
Na – 2
SO4– 1
H – 2
OH– 1
HOW HYDROGEN ION IS REPLACED?
NaOH
Na+
OH -
H +
SO4
2-
OH -
H2O
H+
H2SO4 Na2SO4
+  +
SO4
2-
2
2H+
Na+
2
2
SOLUBILITY OF SALTS
Type of salts Soluble Insoluble
Nitrate All nitrate salts None
Sulphate All sulphate salts PbSO4, CaSO4, BaSO4
Chloride All chloride salts PbCl2, AgCl, HgCl2
Carbonate
Na2CO3, (NH4)2CO3,
K2CO3
All carbonate salts
Neutralisation
PREPARATION
OF
SALTS
SOLUBLE
INSOLUBLE
Sodium salts
Ammonium salts
Potassium salts
Acid + Alkali  Salt + Water
Other type
of salts
Acid + etal  salt + H2
Acid + metal xide  Salt + water
Acid + metal arbonate  Salt + water + CO2
Double Decomposition
ACID +
Solution 1 + Solution 2  Precipitation (insoluble salt) + Solution 3
PREPARATION
OF
SALTS
Soluble salts Sodium salts
Ammonium salts
Potassium salts
Acid + Alkali  Salt + Water
Neutralisation
HNO3 + KOH  KNO3 + H2O
HNO3 + NaOH  NaNO3 + H2O
HNO3 + NH4OH  NH4NO3 + H2O
Substitute HNO3 with
HCl and H2SO4
Acid
Burette
Alkali
Retort stand
Conical flask
PREPARATION
OF
SALTS Soluble
salts
Other type of
salts
Acid + metal  salt + H2
Acid + metal oxide  salt + water
Acid + metal carbonate  Salt + water + CO2
HCl + MgCO3  MgCl2 + H2O + CO2
HCl + Mg  MgCl2 + H2
HCl + MgO  MgCl2 + H2O
Heat
PREPARATION
OF
SALTS Insoluble salt Double decomposition
Solution 1 + Solution 2  Precipitation (insoluble salt) + Solution 3
Salts can be prepared by double decomposition method:
1) PbSO4 4) PbCl2 7) other carbonate salts
2) CaSO4 5) AgCl
3) BaSO4 6) HgCl
PbI2 + K2SO4  PbSO4 + 2KI
PbI2
K2SO4
PbSO4
KI
PREPARATION OF SALTS
Soluble salts Insoluble salts
Salt of Na, K and NH4
Other salts
Titration
Heat the solution until become saturated/ become 1/3 of initial volume
Cool the saturated solution to form the crystal
Filter the salt crystal
Rinse the salt crystal
Dry the salt crystal between the filter paper
Heat the acid + pour excess of metal
carbonate / metal oxide/ metal
Filter the excess metal carbonate/
metal oxide/ metal
Pour two solutions
into a beaker
Salt solution is prepared
Salt solution is prepared

Salts

  • 1.
  • 2.
    1) MEANING OFSALTS 2) SOLUBILITY OF SALTS 3) PREPARATION OF SALTS Xylene AR
  • 3.
    THE MEANING OFSALTS Salts is a compound produced when the hydrogen ion, H+, from an acid is replaced by a metal ion or an ammonium ion, NH4 + SALTS = IONIC COMPOUND
  • 4.
    HOW HYDROGEN IONIS REPLACED? KOH K+ OH - H + Cl - K+ Cl - OH - H2O H + HCl KCl +  + H +
  • 5.
    HOW HYDROGEN IONIS REPLACED?? NH4OH NH4 + OH - H + NO3 - OH - H2O H + HNO3 NH4NO3 +  + NH4 + NO3 - H +
  • 6.
    HOW HYDROGEN IONIS REPLACED?? NaOH Na+ OH - H + SO4 2- OH - H2O H+ H2SO4 Na2SO4 +  + SO4 2- Na+ Na – 1 OH – 1 H – 2 SO4– 1 Na – 2 SO4– 1 H – 2 OH– 1
  • 7.
    HOW HYDROGEN IONIS REPLACED? NaOH Na+ OH - H + SO4 2- OH - H2O H+ H2SO4 Na2SO4 +  + SO4 2- 2 2H+ Na+ 2 2
  • 8.
    SOLUBILITY OF SALTS Typeof salts Soluble Insoluble Nitrate All nitrate salts None Sulphate All sulphate salts PbSO4, CaSO4, BaSO4 Chloride All chloride salts PbCl2, AgCl, HgCl2 Carbonate Na2CO3, (NH4)2CO3, K2CO3 All carbonate salts
  • 9.
    Neutralisation PREPARATION OF SALTS SOLUBLE INSOLUBLE Sodium salts Ammonium salts Potassiumsalts Acid + Alkali  Salt + Water Other type of salts Acid + etal  salt + H2 Acid + metal xide  Salt + water Acid + metal arbonate  Salt + water + CO2 Double Decomposition ACID + Solution 1 + Solution 2  Precipitation (insoluble salt) + Solution 3
  • 10.
    PREPARATION OF SALTS Soluble salts Sodiumsalts Ammonium salts Potassium salts Acid + Alkali  Salt + Water Neutralisation HNO3 + KOH  KNO3 + H2O HNO3 + NaOH  NaNO3 + H2O HNO3 + NH4OH  NH4NO3 + H2O Substitute HNO3 with HCl and H2SO4 Acid Burette Alkali Retort stand Conical flask
  • 11.
    PREPARATION OF SALTS Soluble salts Other typeof salts Acid + metal  salt + H2 Acid + metal oxide  salt + water Acid + metal carbonate  Salt + water + CO2 HCl + MgCO3  MgCl2 + H2O + CO2 HCl + Mg  MgCl2 + H2 HCl + MgO  MgCl2 + H2O Heat
  • 12.
    PREPARATION OF SALTS Insoluble saltDouble decomposition Solution 1 + Solution 2  Precipitation (insoluble salt) + Solution 3 Salts can be prepared by double decomposition method: 1) PbSO4 4) PbCl2 7) other carbonate salts 2) CaSO4 5) AgCl 3) BaSO4 6) HgCl PbI2 + K2SO4  PbSO4 + 2KI PbI2 K2SO4 PbSO4 KI
  • 13.
    PREPARATION OF SALTS Solublesalts Insoluble salts Salt of Na, K and NH4 Other salts Titration Heat the solution until become saturated/ become 1/3 of initial volume Cool the saturated solution to form the crystal Filter the salt crystal Rinse the salt crystal Dry the salt crystal between the filter paper Heat the acid + pour excess of metal carbonate / metal oxide/ metal Filter the excess metal carbonate/ metal oxide/ metal Pour two solutions into a beaker Salt solution is prepared Salt solution is prepared