This document discusses rotational spectra and molecular spectroscopy. It begins by explaining that molecular spectra appear as broad bands due to transitions between different molecular energy states caused by absorption, emission, or scattering of photons. It then discusses the differences between atomic and molecular spectroscopy, noting that molecular spectroscopy provides information about molecular structure, properties, and degrees of freedom. The main focus is on rotational spectroscopy, which occurs in the microwave or far-infrared region and arises from transitions between rotational energy states. This is observed in heteronuclear diatomic polar molecules with a permanent electric dipole moment. The energy levels of rotating diatomic molecules are also explained.