Javaid Iqbal Mohsin
E12-343
Department of Metallurgy & Materials Engineering
University of the Punjab,Lahore.
 Is Made from salt (57 per cent) and oil/gas (43 per
cent).
 Commercial production: salt dissolved in water is
chemically decomposed by passing an electric current
produces chlorine caustic soda & hydrogen while
oil/gas is refined and cracked to give ethylene.
 When chlorine & ethylene are combined, the product is
ethylene dichloride ; again transformed to give vinyl
chloride, the basic building block of PVC.
 chemical formula for vinyl
chloride C2H3Cl.
 Molecular weight=62.5g/mol
 The half life of vinyl chloride
in air is a few hours.
 Slightly soluble in water &
extremely flammable.
 Weathering stability.
PVC is resistant to aggressive environmental factors.
 Versatility.
PVC can be flexible or rigid & can last up to 100 years and even more.
 Fire protection.
PVC is a material resistant to ignition due to its chlorine content.
 Recyclability.
PVC is very recyclable, more so than many other plastics. .
 Economical efficiency.
PVC is the cheapest polymers providing products with the best quality-
price ratio.
 Medical applications i-e blood
storage containers
 Transport (dash board
& door panels)
 Building and construction
 Packaging, pipes & wires coatings.
 Art and design
 This paper presents the production technique, characterization
of polymer composites based on plasticized PVC and
vulcanized nit rile rubber waste suitable for irrigations pipes
for agricultural use.
 Materials used to obtain required polymer are as follows:
 PVC with a 64 K-wert value (moisture and volatile 0.2%
 dioctyl phthalate(density 0.984 g/cm3, pH 7, 99.5% purity)
 PVC stabilizer LGP 8008 (tribasic lead sulphate content 30–
60%, lead stearate diatomic content 10%–30%), (Zn content
11%, melting point 127°C).
 vulcanized nit rile rubber powder obtained by buffing the
rubberized metallic rolls.
 have lower hardness
 higher elongation at break
 a better tensile strength
 The selected polymer have good behavior under
accelerated aging and for immersion in water also.
The rapid expansion & consumption of PVC is due
to:
 Lower cost
 Greater availability
 Good mechanical properties
Characteristics Compression molded
sample
Cl injected
sample
Elasticity % 7 8
Elongation at break% 300 300
Hardness °ShA 73 73
The results in above table show that the values for physical
mechanical characteristics for compression molded samples, and
injected samples are similar excepting:
a slight decrease of elasticity
a slight decrease of tensile strength and 100% modulus.
The increase of rubber powder quantity leads to an increase of
hardness, tear strength & decrease of elongation at break.
Thank you.
 http://www.pvc.org/en/p/pvcs-physical-pr
 http://www.pvc.org/en/p/what-is-pvcoperties
 http://www.hindawi.com/journals/isrn/2013/726121/
 http://ec.europa.eu/environment/waste/pvc/
 http://www.waterworld.com/topics/pvc-pipe.htm
 http://www.questia.com/newspaper/1G1-168415102/letter-
assets-and-advantages-of-pvc-as-material
 http://www.hindawi.com/journals/isrn/2013/726121/tab3/
 http://www.essentialchemicalindustry.org/polymers/polychl
oroethene.html

(Pvc)

  • 1.
    Javaid Iqbal Mohsin E12-343 Departmentof Metallurgy & Materials Engineering University of the Punjab,Lahore.
  • 2.
     Is Madefrom salt (57 per cent) and oil/gas (43 per cent).  Commercial production: salt dissolved in water is chemically decomposed by passing an electric current produces chlorine caustic soda & hydrogen while oil/gas is refined and cracked to give ethylene.  When chlorine & ethylene are combined, the product is ethylene dichloride ; again transformed to give vinyl chloride, the basic building block of PVC.
  • 3.
     chemical formulafor vinyl chloride C2H3Cl.  Molecular weight=62.5g/mol  The half life of vinyl chloride in air is a few hours.  Slightly soluble in water & extremely flammable.
  • 4.
     Weathering stability. PVCis resistant to aggressive environmental factors.  Versatility. PVC can be flexible or rigid & can last up to 100 years and even more.  Fire protection. PVC is a material resistant to ignition due to its chlorine content.  Recyclability. PVC is very recyclable, more so than many other plastics. .  Economical efficiency. PVC is the cheapest polymers providing products with the best quality- price ratio.
  • 5.
     Medical applicationsi-e blood storage containers  Transport (dash board & door panels)  Building and construction  Packaging, pipes & wires coatings.  Art and design
  • 6.
     This paperpresents the production technique, characterization of polymer composites based on plasticized PVC and vulcanized nit rile rubber waste suitable for irrigations pipes for agricultural use.  Materials used to obtain required polymer are as follows:  PVC with a 64 K-wert value (moisture and volatile 0.2%  dioctyl phthalate(density 0.984 g/cm3, pH 7, 99.5% purity)  PVC stabilizer LGP 8008 (tribasic lead sulphate content 30– 60%, lead stearate diatomic content 10%–30%), (Zn content 11%, melting point 127°C).  vulcanized nit rile rubber powder obtained by buffing the rubberized metallic rolls.
  • 7.
     have lowerhardness  higher elongation at break  a better tensile strength  The selected polymer have good behavior under accelerated aging and for immersion in water also. The rapid expansion & consumption of PVC is due to:  Lower cost  Greater availability  Good mechanical properties
  • 8.
    Characteristics Compression molded sample Clinjected sample Elasticity % 7 8 Elongation at break% 300 300 Hardness °ShA 73 73 The results in above table show that the values for physical mechanical characteristics for compression molded samples, and injected samples are similar excepting: a slight decrease of elasticity a slight decrease of tensile strength and 100% modulus. The increase of rubber powder quantity leads to an increase of hardness, tear strength & decrease of elongation at break.
  • 9.
  • 10.
     http://www.pvc.org/en/p/pvcs-physical-pr  http://www.pvc.org/en/p/what-is-pvcoperties http://www.hindawi.com/journals/isrn/2013/726121/  http://ec.europa.eu/environment/waste/pvc/  http://www.waterworld.com/topics/pvc-pipe.htm  http://www.questia.com/newspaper/1G1-168415102/letter- assets-and-advantages-of-pvc-as-material  http://www.hindawi.com/journals/isrn/2013/726121/tab3/  http://www.essentialchemicalindustry.org/polymers/polychl oroethene.html