The ozone layer forms through a photochemical process where ultraviolet light splits oxygen molecules (O2) into individual oxygen atoms, which then combine with unbroken oxygen molecules to create ozone (O3). This cycle was discovered by Sidney Chapman in 1930. While unstable, ozone in the stratosphere is replenished through this process, forming a protective layer between 10-50km above Earth. However, in the 1980s scientists found that man-made chemicals like CFCs were depleting the ozone layer.